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Quantum transport characteristics in single and multiple N-channel junctionless nanowire transistors at low temperatures 被引量:1
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作者 王昊 韩伟华 +2 位作者 马刘红 李小明 杨富华 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第8期160-164,共5页
Single and multiple n-channel junctionless nanowire transistors (JNTs) are fabricated and experimentally investigated at variable temperatures. Clear current oscillations caused by the quantum-confinement effect are... Single and multiple n-channel junctionless nanowire transistors (JNTs) are fabricated and experimentally investigated at variable temperatures. Clear current oscillations caused by the quantum-confinement effect are observed in the curve of drain current versus gate voltage acquired at low temperatures (10 K-100 K) and variable drain bias voltages (10 mV- 90 mV). Transfer characteristics exhibit current oscillation peaks below flat-band voltage (VFB) at temperatures up to 75 K, which is possibly due to Coulomb-blocking from quantum dots, which are randomly formed by ionized dopants in the just opened n-type one-dimensional (1D) channel of silicon nanowires. However, at higher voltages than VFB, regular current steps are observed in single-channel JNTs, which corresponds to the fully populated subbands in the 1D channel. The subband energy spacing extracted from transconductance peaks accords well with theoretical predication. However, in multiple-channel JNT, only tiny oscillation peaks of the drain current are observed due to the combination of the drain current from multiple channels with quantum-confinement effects. 展开更多
关键词 junctionless nanowire transistors (JNT) quantum transport current oscillations low temperatures
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Effects of low temperatures on strength and power input into rock failure 被引量:1
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作者 Evgenii V.Zakharov Alexander S.Kurilko 《Research in Cold and Arid Regions》 CSCD 2014年第5期455-460,共6页
Study results of low temperature effects on the strength index and specific power input into rock failure are presented.It has been experimentally determined that within the range of-5 °С to-15 °С,there is... Study results of low temperature effects on the strength index and specific power input into rock failure are presented.It has been experimentally determined that within the range of-5 °С to-15 °С,there is a local minimum at which the compression strength and specific power input into failure of some rocks are 10%-50% lower than those at positive temperatures. 展开更多
关键词 STRENGTH power input into failure low temperatures carbonate rocks KIMBERLITE POROSITY
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Preparation and Properties of Sintered Corundum at Low Temperatures with Nano-η-Al2O3 Powder 被引量:1
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作者 LI Fengyou ZHANG Ling +2 位作者 SU Xin LI Yunlong HAO Xu 《China's Refractories》 CAS 2019年第4期35-39,共5页
In order to reduce the sintering temperature and improve the properties of sintered corundum,corundum specimens were prepared by granulation and sintering with nano-η-A l203 as the raw material and polyvinyl alcohol ... In order to reduce the sintering temperature and improve the properties of sintered corundum,corundum specimens were prepared by granulation and sintering with nano-η-A l203 as the raw material and polyvinyl alcohol as the binder.The effects of different sintering temperatures(1550,1600,1650 and 1700℃)and holding time(2,4 and 6 h)on the properties and microstructures of the specimens were studied,and the transformation mechanism ofη-Al203 was analyzed.The results show that dense sintered corundum with bulk density of 3.74 g/cm^3 and apparent porosity of 1.77%is obtained by calcinating at 1650℃for 6 h;the phase transition fromη-Al203 toα-Al203 occurs first on the surface of alumina particles and then diffuses rapidly to the interior;at lower sintering temperatures there is no abnormal growth of crystals,the bonding between the grains is tight,transgranular fracture is the main fracture mode,there are fewer intergranular pores,and the grain size is in the range of 3.5-7.5μm. 展开更多
关键词 nano-η-alumina low temperatures sintered corundum PROPERTIES
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Planck’s Oscillators at Low Temperatures and Haken’s Perturbation Approach to the Quantum Oscillators Reconsidered
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作者 Stanisław Olszewski 《Journal of Modern Physics》 2021年第12期1721-1728,共8页
In the first step the extremal values of the vibrational specific heat and entropy represented by the Planck oscillators at the low temperatures could be calculated. The positions of the extrema are defined by the dim... In the first step the extremal values of the vibrational specific heat and entropy represented by the Planck oscillators at the low temperatures could be calculated. The positions of the extrema are defined by the dimensionless ratios between the quanta of the vibrational energy and products of the actual temperature multiplied by the Boltzmann constant. It became evident that position of a local maximum obtained for the Planck’s average energy of a vibration mode and position of a local maximum of entropy are the same. In the next step the Haken’s time-dependent perturbation approach to the pair of quantum non-degenerate Schr<span style="white-space:nowrap;">?</span>dinger eigenstates of energy is re-examined. An averaging process done on the time variable leads to a very simple formula for the coefficients entering the perturbation terms. 展开更多
关键词 Planck’s Quantum Oscillators at low temperatures Calculation of the Extremal Specific Heat of the Oscillator Energy and Extremal Entropy Simplified Haken’s Time-Dependent Approach to the Perturbation Energy of a Non-Degenerate Quantum State
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Oxidation of CO on Nanometer Metal Oxides at Low Temperatures 被引量:3
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作者 ZHANG Wen-xiang JIA Ming-jun +4 位作者 ZHAO Ing-zhe ZHANG Chun-lei WU Tong-hao WANG Xue-guang SUN Tie 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1997年第4期75-77,共3页
关键词 Oxidation of carbon monooxide Nanometer metal oxide low temperature
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A Review on Complete Oxidation of Methane at Low Temperatures 被引量:2
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作者 ZhenhuaLi GarB.Hoflund 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2003年第3期153-160,共8页
This paper reviews recent developments in complete oxidation of methane atlow temperatures over noble metal catalysts in the past 20 years. The Pd/Al_2O_3 catalyst system isfully discussed. The review mainly focuses o... This paper reviews recent developments in complete oxidation of methane atlow temperatures over noble metal catalysts in the past 20 years. The Pd/Al_2O_3 catalyst system isfully discussed. The review mainly focuses on the kinetic aspects of methane oxidation over thiscatalyst, and methane activation behavior over Pd and PdO phases (the form of PdO on the surface,transient behavior, the nature of the active sites, the influence of metal particle size and theirstructure sensitivities, and so on). Some Pd catalysts supported on other oxides besides the Al_2O_3support are briefly discussed. Possible routes of non-noble metal catalysts as substitutes for thePd catalyst are also proposed. 展开更多
关键词 METHANE complete oxidation REVIEW PD low temperature noble metal
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Highly efficient H-bonding charge-transfer complex for microsupercapacitors under extreme conditions of low temperatures
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作者 Libin Wang Ting Shu +3 位作者 Songtao Guo Shi Chen Yingjun Jiang Xianluo Hu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第12期182-189,共8页
Owing to sluggish ionic mobility at low temperatures, supercapacitors, as well as other energy-storage devices, always suffer from severe capacity decay and even failure under extreme low-temperature circumstances. So... Owing to sluggish ionic mobility at low temperatures, supercapacitors, as well as other energy-storage devices, always suffer from severe capacity decay and even failure under extreme low-temperature circumstances. Solar-thermal-enabled self-heating promises an attractive approach to overcome this issue.Here, we report a unique H-bonding charge-transfer complex with a high photothermal conversion efficiency of 79.5% at 405 nm based on chloranilic acid and albendazole. Integrated with a microsupercapacitor, the chloranilic acid-albendazole complex(CAC) film prompts an apparent temperature increase of 22.7 °C under 1 sun illumination at-32.6 °C, effectively elevating the working temperature of devices.As a result, the rate capability of the microsupercapacitor has been significantly improved with a 17-fold increase in capacitance at a current density of 60 μA cm^(-2), leading to outstanding low-temperature performances. Importantly, the integrated device is capable of working at a low temperature of-30 °C in the open air, which demonstrates the potential of CAC in practical applications for low-temperature ultracapacitive energy-storage devices. 展开更多
关键词 Charge-transfer complexes Solar-thermal conversion Extreme conditions Microsupercapacitors low temperature
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A More Precise Determination of Gear Oil Viscosity at Low Temperatures
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作者 Kenneth O.Henderson Joseph T.Mastropierro 《润滑油》 CAS 2012年第1期45-49,共5页
Low temperature fluidity of gear oils is an important fluid property as it directly impacts the useful life of a gear set.This paper compares low temperature fluidity measurement precision of ASTM D6821 and ASTM D2983... Low temperature fluidity of gear oils is an important fluid property as it directly impacts the useful life of a gear set.This paper compares low temperature fluidity measurement precision of ASTM D6821 and ASTM D2983.Both tests are identical in the way they thermally condition the sample prior to viscosity measurement.While ASTM D2983 is cited in many current specifications,ASTM D6821 offers users and formulators a more accurate estimate of gear oil low temperature fluidity.The primary benefit in using ASTM D6821 is better precision.ASTM D6821 accomplishes this by automating the steps from prior to preheat through to viscosity measurement at end of test. 展开更多
关键词 dynamic viscosity low temperature viscosity gear oil viscosity ASTM D2983 ASTM D6821
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Low-molecular-weight supramolecular adhesive with resistance to low temperatures
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作者 Shuanggen Wu Wenbo Wang +2 位作者 Changyong Cai Fenfang Li Shengyi Dong 《Chinese Chemical Letters》 SCIE CAS CSCD 2023年第5期232-236,共5页
The design of adhesive materials with strong adhesion capacity at low temperatures is a great challenge.Herein,we report a low-molecular-weight supramolecular adhesive that exhibits good adhesion performance to variou... The design of adhesive materials with strong adhesion capacity at low temperatures is a great challenge.Herein,we report a low-molecular-weight supramolecular adhesive that exhibits good adhesion performance to various surfaces at low temperatures(from-18℃ to-80℃).Moreover,this supramolecular adhesive has good adhesion ability in the presence of water. 展开更多
关键词 Supramolecular adhesive low temperature resistance Underwater adhesion low-molecular-weight monomer Supramolecular adhesion
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Boosting the energy density of sulfide-based all-solid-state batteries at low temperatures by charging to high voltages up to 6 V
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作者 Lun Zhang Xuedong Zhang +9 位作者 Zhaoyu Rong Tao Wang Zhenyu Wang Zaifa Wang Longchen Zhang Qiao Huang Lingyun Zhu Liqiang Zhang Yongfu Tang Jianyu Huang 《Nano Research》 SCIE EI CSCD 2023年第8期10966-10975,共10页
Sulfide electrolyte-based all-solid-state batteries(ASSBs)are potential next generation energy storage technology due to the high ionic conductivity of sulfide electrolytes and potentially improved energy density and ... Sulfide electrolyte-based all-solid-state batteries(ASSBs)are potential next generation energy storage technology due to the high ionic conductivity of sulfide electrolytes and potentially improved energy density and safety.However,the performance of ASSBs at/below subzero temperatures has not been explored systematically.Herein,low temperature(LT)performance of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)|Li_(9.54)Si_(1.74)P_(1.44)S11.7Cl_(0.3)(LiSPSCl)|Li_(4)Ti_(5)O_(12)(LTO)ASSBs was investigated.By charging the ASSB to 6 V at−40℃,a capacity of 100.7 mAh∙g^(−1)at 20 mA∙g^(−1)was achieved,which is much higher than that charged to 4.3 V(4.6 mAh∙g^(−1))at−40℃.Moreover,atomic resolution microscopy revealed that the NCM811 remained almost intact even after being charged to 6 V.In contrast,NCM811 was entirely destructed when charged to 6 V at room temperature.The sharp difference arises from the large internal charge transfer resistance at LT which requires high voltage to overcome.Nevertheless,such high voltage is not harmful to the active material but beneficial to extracting most energy out of the ASSBs at LT.We also demonstrated that thinner electrolyte is favorable for LT operation of ASSBs due to the reduced ion transfer distance.This work provides new strategies to boost the capacity and energy density of sulfide-based ASSBs at LT for dedicated LT applications. 展开更多
关键词 all-solid-state lithium batteries sulfide solid electrolyte low temperature Li_(4)Ti_(5)O_(12)(LTO)
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Alkyl dimethyl betaine activates the low-temperature collection capacity of sodium oleate for scheelite
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作者 Xu Wang Zhengquan Zhang +5 位作者 Yanfang Cui Wei Li Congren Yang Hao Song Wenqing Qin Fen Jiao 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CSCD 2024年第1期71-80,共10页
The impact of alkyl dimethyl betaine (ADB) on the collection capacity of sodium oleate (NaOl) at low temperatures was evaluated using flotation tests at various scales. The low-temperature synergistic mechanism of ADB... The impact of alkyl dimethyl betaine (ADB) on the collection capacity of sodium oleate (NaOl) at low temperatures was evaluated using flotation tests at various scales. The low-temperature synergistic mechanism of ADB and NaOl was explored by infrared spectroscopy, X-ray photoelectron spectroscopy, surface tension measurement, foam performance test, and flotation reagent size measurement.The flotation tests revealed that the collector mixed with octadecyl dimethyl betaine (ODB) and NaOl in a mass ratio of 4:96 exhibited the highest collection capacity. The combined collector could increase the scheelite recovery by 3.48% at low temperatures of 8–12℃. This is particularly relevant in the Luanchuan area, which has the largest scheelite concentrate output in China. The results confirmed that ODB enhanced the collection capability of NaOl by improving the dispersion and foaming performance. Betaine can be introduced as an additive to NaOl to improve the recovery of scheelite at low temperatures. 展开更多
关键词 SCHEELITE BETAINE low temperature synergistic effect dispersion FOAMABILITY
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Electrolyte Design for Low‑Temperature Li‑Metal Batteries:Challenges and Prospects
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作者 Siyu Sun Kehan Wang +3 位作者 Zhanglian Hong Mingjia Zhi Kai Zhang Jijian Xu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第2期365-382,共18页
Electrolyte design holds the greatest opportunity for the development of batteries that are capable of sub-zero temperature operation.To get the most energy storage out of the battery at low temperatures,improvements ... Electrolyte design holds the greatest opportunity for the development of batteries that are capable of sub-zero temperature operation.To get the most energy storage out of the battery at low temperatures,improvements in electrolyte chemistry need to be coupled with optimized electrode materials and tailored electrolyte/electrode interphases.Herein,this review critically outlines electrolytes’limiting factors,including reduced ionic conductivity,large de-solvation energy,sluggish charge transfer,and slow Li-ion transportation across the electrolyte/electrode interphases,which affect the low-temperature performance of Li-metal batteries.Detailed theoretical derivations that explain the explicit influence of temperature on battery performance are presented to deepen understanding.Emerging improvement strategies from the aspects of electrolyte design and electrolyte/electrode interphase engineering are summarized and rigorously compared.Perspectives on future research are proposed to guide the ongoing exploration for better low-temperature Li-metal batteries. 展开更多
关键词 Solid electrolyte interphase Li metal low temperature Electrolyte design BATTERIES
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Interfacial built-in electric field and crosslinking pathways enabling WS_(2)/Ti_(3)C_(2)T_(x) heterojunction with robust sodium storage at low temperature
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作者 Jiabao Li Shaocong Tang +6 位作者 Jingjing Hao Quan Yuan Tianyi Wang Likun Pan Jinliang Li Shenbo Yang Chengyin Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期635-645,I0014,共12页
Developing efficient energy storage for sodium-ion batteries(SIBs)by creating high-performance heterojunctions and understanding their interfacial interaction at the atomic/molecular level holds promise but is also ch... Developing efficient energy storage for sodium-ion batteries(SIBs)by creating high-performance heterojunctions and understanding their interfacial interaction at the atomic/molecular level holds promise but is also challenging.Besides,sluggish reaction kinetics at low temperatures restrict the operation of SIBs in cold climates.Herein,cross-linking nanoarchitectonics of WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,featuring built-in electric field(BIEF),have been developed,employing as a model to reveal the positive effect of heterojunction design and BIEF for modifying the reaction kinetics and electrochemical activity.Particularly,the theoretical analysis manifests the discrepancy in work functions leads to the electronic flow from the electron-rich Ti_(3)C_(2)T_(x) to layered WS_(2),spontaneously forming the BIEF and“ion reservoir”at the heterogeneous interface.Besides,the generation of cross-linking pathways further promotes the transportation of electrons/ions,which guarantees rapid diffusion kinetics and excellent structure coupling.Consequently,superior sodium storage performance is obtained for the WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,with only 0.2%decay per cycle at 5.0 A g^(-1)(25℃)up to 1000 cycles and a high capacity of 293.5 mA h g^(-1)(0.1A g^(-1)after 100 cycles)even at-20℃.Importantly,the spontaneously formed BIEF,accompanied by“ion reservoir”,in heterojunction provides deep understandings of the correlation between structure fabricated and performance obtained. 展开更多
关键词 WS_(2)/Ti_(3)C_(2)T_(x)heterojunction Built-in electric field Ion reservoir Reaction kinetics Sodium storage performance at low temperature
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Genome-Wide Exploration of the Grape GLR Gene Family and Differential Responses of VvGLR3.1 and VvGLR3.2 to Low Temperature and Salt Stress
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作者 Honghui Sun Ruichao Liu +6 位作者 Yueting Qi Hongsheng Gao Xueting Wang Ning Jiang Xiaotong Guo Hongxia Zhang Chunyan Yu 《Phyton-International Journal of Experimental Botany》 SCIE 2024年第3期533-549,共17页
Grapes,one of the oldest tree species globally,are rich in vitamins.However,environmental conditions such as low temperature and soil salinization significantly affect grape yield and quality.The glutamate receptor(GLR... Grapes,one of the oldest tree species globally,are rich in vitamins.However,environmental conditions such as low temperature and soil salinization significantly affect grape yield and quality.The glutamate receptor(GLR)family,comprising highly conserved ligand-gated ion channels,regulates plant growth and development in response to stress.In this study,11 members of the VvGLR gene family in grapes were identified using whole-genome sequence analysis.Bioinformatic methods were employed to analyze the basic physical and chemical properties,phylogenetic trees,conserved domains,motifs,expression patterns,and evolutionary relationships.Phylogenetic and collinear analyses revealed that the VvGLRs were divided into three subgroups,showing the high conservation of the grape GLR family.These members exhibited 2 glutamate receptor binding regions(GABAb and GluR)and 3-4 transmembrane regions(M1,M2,M3,and M4).Real-time quantitative PCR analysis demonstrated the sensitivity of all VvGLRs to low temperature and salt stress.Subsequent localization studies in Nicotiana tabacum verified that VvGLR3.1 and VvGLR3.2 proteins were located on the cell membrane and cell nucleus.Additionally,yeast transformation experiments confirmed the functionality of VvGLR3.1 and VvGLR3.2 in response to low temperature and salt stress.Thesefindings highlight the significant role of the GLR family,a highly conserved group of ion channels,in enhancing grape stress resistance.This study offers new insights into the grape GLR gene family,providing fundamental knowledge for further functional analysis and breeding of stress-resistant grapevines. 展开更多
关键词 Genome-wide identification glutamate receptor(GLR)family low temperature stress salt stress GRAPE
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Advances in Molecular Regulatory Mechanisms of Fruit Trees under Low Temperature Stress
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作者 Huan LIU Lijuan GAO +3 位作者 Minghui JI Longfei LI Jintao XU Baofeng HAO 《Plant Diseases and Pests》 2024年第3期46-48,共3页
The most recent research findings on the tolerance of fruit trees to cold stress are reviewed from a molecular perspective,including the perception and transduction of low temperature calcium signaling,CBF-dependent m... The most recent research findings on the tolerance of fruit trees to cold stress are reviewed from a molecular perspective,including the perception and transduction of low temperature calcium signaling,CBF-dependent molecular regulatory mechanisms,non-CBF-dependent molecular regulatory mechanisms,and so forth.The objective is to provide a reference basis for further improving the cold resistance of fruit trees and cultivating new varieties of hardy plants. 展开更多
关键词 low temperature stress Fruit trees Growth and development Molecular mechanism Research progress
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Effects of Low Temperature Stress on Germination and Physiological Characteristics of Different Sweet Maize Varieties
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作者 Zhenxing WU Jianjian CHEN +1 位作者 Tingzhen WANG Guihua LU 《Plant Diseases and Pests》 2024年第1期1-3,6,共4页
[Objectives]The paper was to explore the effects of low temperature stress on germination and physiological characteristics of different sweet maize varieties.[Methods]Taking Taitian 264,Zhexuetian 1 and Chaotian 4 as... [Objectives]The paper was to explore the effects of low temperature stress on germination and physiological characteristics of different sweet maize varieties.[Methods]Taking Taitian 264,Zhexuetian 1 and Chaotian 4 as the research objects,the changes in germination potential,germination index,plant height,biomass,and antioxidant enzyme activity of maize seeds were studied under optimal temperature conditions(25℃)and low temperature stress conditions(10℃).[Results]Under 10℃stress,the germination rate and germination index of Taitian 264 were higher than that of Zhexuetian 1 and Chaotian 4.Under low temperature stress,Taitian 264 exhibited the least reduction in height and biomass,while Zhexuetian 1 had the most reduction.Additionally,the SOD and POD activities of Taitian 264 were higher than that of Zhexuetian 1 and Chaotian 4 under both temperature conditions,while the MDA content of Taitian 264 was lower.Taitian 264 showed strong germination ability against low temperature stress.[Conclusions]This study provides a basis for timely sowing practices of sweet maize in agricultural production. 展开更多
关键词 Sweet maize low temperature stress GERMINATION Antioxidant enzyme
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Characteristics of pellets with immobilized activated sludge and its performance in increasing nitrification in sequencing batch reactors at low temperatures 被引量:8
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作者 Wenjie Dong Guang Lu +2 位作者 Li Yan Zhenjia Zhang Yalei Zhang 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2016年第4期202-209,共8页
Immobilized pellets obtained by means of entrapping activated sludge in waterborne polyurethane were successfully adapted in ammonium(NH4^+–N)synthetic wastewater.Its physicochemical characteristics were determine... Immobilized pellets obtained by means of entrapping activated sludge in waterborne polyurethane were successfully adapted in ammonium(NH4^+–N)synthetic wastewater.Its physicochemical characteristics were determined using scanning electron microscope,pyrosequencing,and microelectrodes,and its influence on the nitrification process in sequencing batch reactors(SBRs)at low temperatures was evaluated.A large number of rod-shaped bacteria were observed on the surface of the immobilized pellet,in which Rudaea spp.(Xanthomonadaceae family)was an important bacterial component(23.44% of the total bacteria).The oxygen uptake rate of immobilized pellets reached 240.83±15.59 mg O2/(L·hr),and the oxygen was primarily consumed by the bacteria on the pellet surfaces(0–600μm).The dosing of the pellets(30 m L/L)into an SBR significantly improved the nitrification efficiency at low temperatures of 7–11℃,achieving an average NH4^+–N removal of 84.09%,which is higher than the removal of 67.46% observed for the control group. 展开更多
关键词 Immobilization Acclimation Nitrification low temperatures Sequencing batch reactor (SBR)
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Fatigue crack propagation in fine-grained magnesium under low temperature tension-tension cyclic loading
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作者 Qizhen Li 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第12期4420-4430,共11页
Fine-grained magnesium was tested under stress-controlled tension-tension cyclic loading at -30 ℃ and the tested sample was observed using scanning electron microscope and electron backscatter diffraction to explore ... Fine-grained magnesium was tested under stress-controlled tension-tension cyclic loading at -30 ℃ and the tested sample was observed using scanning electron microscope and electron backscatter diffraction to explore the fatigue behavior and crack propagation. The fatigue data showed that the material experienced cyclic softening followed by cyclic hardening before the final fracture failure. The microscopic observations demonstrated that the cracks were almost perpendicular to the loading direction with some zigzags and the cracks progressed along both small angle grain boundaries and large angle grain boundaries. Although the cracks were mainly propagated along large angle grain boundaries, the value of grain boundary angle was not the primary factor to determine the crack propagation direction. The local residual strain from the rolling process was released due to the crack propagation and there was more strain relaxation at regions closer to the cracks. 展开更多
关键词 Fine-grained magnesium Fatigue properties Tension Crack propagation low temperatures
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NH3-SCR performance and the resistance to SO2 for Nb doped vanadium based catalyst at low temperatures 被引量:9
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作者 Lin Zhu Zhaoping Zhong +3 位作者 Jianming Xue Yueyang Xu Chunhua Wang Lixia Wang 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2018年第3期306-316,共11页
Niobium oxide as the promoter was doped in the V/WTi catalyst for the selective catalytic reduction(SCR)of NO.The results showed that the addition of Nb2O5could improve the SCR activity at low temperatures and the 6... Niobium oxide as the promoter was doped in the V/WTi catalyst for the selective catalytic reduction(SCR)of NO.The results showed that the addition of Nb2O5could improve the SCR activity at low temperatures and the 6 wt.%additive was an appropriate dosage.The enhanced reaction activity of adsorbed ammonia species and the improved dispersion of vanadium oxide might be the reasons for the elevation of SCR activity at low temperatures.The resistances to SO2of 3V6Nb/WTi catalyst at different temperatures were investigated.FTIR spectrum and TG-FTIR result indicated that the deposition of ammonium sulfate species was the main deactivation reason at low temperatures,which still exhibited the reactivity with NO above 200℃ on the catalyst surface.There was a synergistic effect among NH3,H2O and SO2that NH3and H2O both accelerated the catalyst deactivation in the presence of SO2at 175℃.The thermal treatment at 400℃ could regenerate the deactivated catalyst and get SCR activity recovered.The particle and monolith catalysts both kept stable NOxconversion at 225℃ with high concentration of H2O and SO2during the long time tests. 展开更多
关键词 Niobium oxide Selective catalytic reduction low temperature H2O SO2 Catalytic deactivation
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Achieving nitritation at low temperatures using free ammonia inhibition on Nitrobacter and real-time control in an SBR treating landfill leachate 被引量:20
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作者 Hongwei Sun Yongzhen Peng +1 位作者 Shuying Wang Juan Ma 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2015年第4期157-163,共7页
Free ammonia(FA) inhibition on nitrite-oxidized bacteria(NOB) and real-time control are used to achieve nitrogen removal from landfill leachate via nitrite pathway at low temperatures in sequencing batch reactor. ... Free ammonia(FA) inhibition on nitrite-oxidized bacteria(NOB) and real-time control are used to achieve nitrogen removal from landfill leachate via nitrite pathway at low temperatures in sequencing batch reactor. The inhibition of FA on NOB activity during the aerobic period was prolonged using real-time control. The degree of nitrite accumulation was monitored along with variations of the ammonia-oxidizing bacteria and NOB population using fluorescence in situ hybridization techniques. It is demonstrated that the end-point of ammonia oxidization is detected from the on-line measured dissolved oxygen,oxidization–reduction potential, and p H signals, which could avoid the loss the FA inhibition on NOB caused by excess aeration. At low temperature(13.0–17.6°C), the level of nitrite pathway rapidly increased from 19.8% to 90%, suggesting that nitritation was successfully started up at low temperature by applying syntrophic association of the FA inhibition and real-time control, and then this high level of nitrite pathway was stably maintained for as long as 233 days. Mechanism analysis shows that the establishment of nitritation was primarily the result of predominant ammonia-oxidizing bacteria developed in the nitrifying bacteria population compared to NOB. This was mainly due to a gradual reduction of nitrite amount that is available to provide energy for the growth of NOB,eventually leading to the elimination of NOB from the bacterial clusters in sequencing batch reactor sludge system. 展开更多
关键词 Landfill leachate Nitritation low temperature Free ammonia Inhibition AOB and NOB
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