A review of low-temperature heat recovery technologies for industry processes

The amount of low-temperature heat generated in industrial processes is high,but recycling is limited due to low grade and low recycling efficiency,which is one of the reasons for low energy efficiency.It implies that there is a great potential for low-temperature heat recovery and utilization.This article provided a detailed review of recent advances in the development of low-temperature thermal upgrades,power generation,refrigeration,and thermal energy storage.The detailed description will be given from the aspects of system structure improvement,work medium improvement,and thermodynamic and economic performance evaluation.It also pointed out the development bottlenecks and future development trends of various technologies.The low-temperature heat combined utilization technology can recover waste heat in an all-round and effective manner,and has great development prospects.

Optimizing Low-Temperature Heat Recovery in a Refinery Fluid Catalytic Cracking Unit Based on Pinch Analysis

In this paper, the research was focused on optimizing low-temperature heat recovery to adopt multi-effect distillation (MED) in desalination by pinch technology. And further analysis indicated that phase changes occurred during the heat recovery process. In such case, the feed stream was divided into two streams: the liquid feed stream and the gaseous feed stream. Through calculation, the optimal ΔTmin was established at 26 ℃, and the total cost of heat exchange process was only $1.098×106. By using the Problem Table Algorithm for pinch analysis, the temperature of the hot and the cold steams was 119 ℃ and 93 ℃, respectively. At a temperature higher than 119 ℃, all heat of the hot stream could not be cooled by the condenser, and the minimum heat load of utility (QH,min) was 440457.64 kW; and at a temperature below 93 ℃, all heat of the cold stream could not be provided by the heater, and the minimum cold load of utility (QC,min) was 1965993.85 kW. Finally, the synthesis of heat exchanger network was established through integrating two heat exchanger networks.

Finite-Time Thermodynamic Simulation of Circulating Direct Condensation Heat Recovery on Chillers

A time series model is used in this paper to describe the progress of circulating direct condensation heat recovery of the compound condensing process (CCP) which is made of two water cooling condensing processes in series for a centrifugal chiller in the paper. A finite-time thermodynamics method is used to set up the time series simulation model. As a result, an upper bound of recoverable condensation heat for the compound condensing process is obtained which is in good agreement with experimental result. And the result is valuable and useful to optimization design of condensing heat recovery.

Piezoelectric Power Harvesting Process via Phase Changes of Low-Boiling-Point Medium Together with Water for Recovering Low-Temperature Heats

Low-temperature thermal energy conversions down to exergy zero to electric power must contribute energy sustainability. That is to say, reinforcements of power harvesting technologies from extremely low temperatures less than 373 K might be at least one of minimum roles for the current generations. Then, piezoelectric power harvesting process for recovering low-temperature heats was invented by using a unique biphasic operating medium of an underlying water-insoluble/low-boiling-point medium (i.e. NOVEC manufactured by 3M Japan Ltd.) in small quantity and upper-layered water in large quantity. The higher piezoelectric power harvesting densities were naturally revealed with an increase in heating temperatures. Excessive cooling of the operating medium deteriorated the power harvesting efficiency. The denser operating medium was surpassingly helpful to the higher piezoelectric power harvesting density. Concretely, only about 5% density increase of main operating medium (i.e. water with dissolving alum at 0.10 mol/dm3) came to the champion piezoelectric power harvesting density of 92.6 pW/dm2 in this study, which was about 1.4 times compared to that with the original biphasic medium of pure water together with a small quantity of NOVEC.

Waste Heat Recovery from a Drier Receiver of an A/C Unit Using Thermoelectric Generators

Thermoelectric generators(TEGs)are considered promising devices for waste heat recovery from various systems.The Seebeck effect can be utilized to generate power using the residual heat emitted by the filter dryer receiver(FDR)of an air conditioning(A/C)system,which would otherwise go to waste.The study aims to build a set of thermoelectric generators(TEG)to collect the waste heat of the FDR and generate low-power electricity.A novel electrical circuit with two transformers is designed and fabricated to produce a more stable voltage for operation and charging.The thermoelectric generator(TEGs)was installed on the FDR of the A/C unit.The test showed that climate conditions have a significant impact on the output power generated from the system.The results showed that the peak voltage recorded in the current study is 5.2 V per day(wet,cold,and wind weather)with an output power of 0.2 W.These values are acceptable for powering the load and charging a single battery with 3.5 V as the voltage increases battery 0.1 V/20 min charge.A case study of operating the emergency signs in a building was considered.The current heat recovery system is deemed to be easily installed and can be connected to a network of TEGs to produce more power.

Waste heat recovery from hot steel slag on the production line:Numerical simulation,validation and industrial test

Waste heat recovery from hot steel slag was determined in a granular bed through the combination of numerical simulation and an industrial test method.First,the effective thermal conductivity of the granular bed was calculated.Then,the unsteady-state model was used to simulate the heat recovery under three different flow fields(O-type,S-type,and nonshielding type(Nontype)).Second,the simulation results were validated by in-situ industrial experiments.The two methods confirmed that the heat recovery efficiencies of the flow fields from high to low followed the order of Nontype,S-type,and O-type.Finally,heat recovery was carried out under the Nontype flow field in an industrial test.The heat recovery efficiency increased from~76%and~78%to~81%when the steel slag thickness decreased from 400 and 300 to 200 mm,corresponding to reductions in the steel slag mass from 3.96 and 2.97 to 1.98 t with a blower air volume of 14687 m^(3)/h.Therefore,the research results showed that numerical simulation can not only guide experiments on waste heat recovery but also optimize the flow field.Most importantly,the method proposed in this paper has achieved higher waste heat recovery from hot steel slag in industrial scale.

Full neurological recovery from severe nonexertional heat stroke with multiple organ dysfunction:A case report

BACKGROUND We report a rare case of full neurological recovery from severe nonexertional heat stroke in a 67-year-old woman with an initial Glasgow Coma Scale of 3.This report raises awareness among doctors that when heatstroke is diagnosed,comprehensive treatment should be implemented as soon as possible.Moreover,targeted temperature management,combination therapy with hemodialysis and hemoperfusion,and hyperbaric oxygen therapy may alleviate multiorgan failure and prevent neurological sequelae caused by heatstroke.CASE SUMMARY A previously healthy 67-year-old woman with an initial Glasgow Coma Scale of 3 was found lying prone on the road at noon on a summer day.Laboratory tests revealed multiorgan failure.As soon as heatstroke was diagnosed,comprehensive treatment was implemented.On hospital Day 3,the patient was extubated.Her initial Sequential Organ Failure Assessment score at hospitalization was 14 and decreased to 2 on hospital Day 4.On the seventh day following hospital admission,as the patient’s general condition improved,the levels of laboratory test findings decreased rapidly.Finally,the patient gradually recovered with no other neurological symptoms(the Glasgow Coma Scale at discharge was 15,and her ability to walk independently was restored).CONCLUSION This case demonstrated that targeted temperature management,combination therapy with hemodialysis and hemoperfusion,and hyperbaric oxygen therapy may alleviate multiorgan failure and prevent neurological sequelae caused by heatstroke.

Low-temperature heat capacities and standard molar enthalpy of formation of pyridine-2,6-dicarboxylic acid

This paper reports that the low-temperature heat capacities of pyridine-2,6-dicarboxylic acid were measured by a precision automatic calorimeter over a temperature range from 78 K to 380 K. A polynomial equation of heat capacities as a function of temperature was fitted by the least-squares method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15 K were calculated and tabulated at intervals of 5 K. The constant-volume energy of combustion of the compound was determined by means of a precision rotating-bomb combustion calorimeter. The standard molar enthalpy of combustion of the compound was derived from the constant-volume energy of combustion. The standard molar enthalpy of formation of the compound was calculated from a combination of the datum of the standard molar enthalpy of combustion of the compound with other auxiliary thermodynamic quantities through a Hess thermochemical cycle.

Off-Design Simulation of a CSP Power Plant Integrated with aWaste Heat Recovery System

Concentrating Solar Power(CSP)plants offer a promising way to generate low-emission energy.However,these plants face challenges such as reduced sunlight during winter and cloudy days,despite being located in high solar radiation areas.Furthermore,their dispatch capacities and yields can be affected by high electricity consumption,particularly at night.The present work aims to develop an off-design model that evaluates the hourly and annual performances of a parabolic trough power plant(PTPP)equipped with a waste heat recovery system.The study aims to compare the performances of this new layout with those of the conventional Andasol 1 plant,with the aim of assessing the improvements achieved in the new design.Based on the results,it can be concluded that the new layout has increased the annual generated power to almost 183 GWh(an increase of about 7.60% is achieved compared to the Andasol 1 layout that generates 169 GWh annually).Additionally,the proposed installation has achieved an efficiency of 20.55%,which represents a 7.87% increase compared to the previous design(19.05%).The Levelized Cost of Electricity(LCOE)of the new layout has been reduced by more than 5.8% compared to the Andasol 1 plant.Specifically,it has decreased from 13.11 to 12.35 c/kWh.This reduction in LCOE highlights the improved cost-effectiveness of the newlayout,making it amore economically viable option for generating electricity compared to the conventional Andasol 1 plant.

An approach for IC engine coolant energy recovery based on low-temperature organic Rankine cycle

To promote the fuel utilization efficiency of IC engine, an approach was proposed for IC engine coolant energy recovery based on low-temperature organic Rankine cycle(ORC). The ORC system uses IC engine coolant as heat source, and it is coupled to the IC engine cooling system. After various kinds of organic working media were compared, R124 was selected as the ORC working medium. According to IC engine operating conditions and coolant energy characteristics, the major parameters of ORC system were preliminary designed. Then, the effects of various parameters on cycle performance and recovery potential of coolant energy were analyzed via cycle process calculation. The results indicate that cycle efficiency is mainly influenced by the working pressure of ORC, while the maximum working pressure is limited by IC engine coolant temperature. At the same working pressure, cycle efficiency is hardly affected by both the mass flow rate and temperature of working medium. When the bottom cycle working pressure arrives at the maximum allowable value of 1.6 MPa, the fuel utilization efficiency of IC engine could be improved by 12.1%.All these demonstrate that this low-temperature ORC is a useful energy-saving technology for IC engine.

Utilization and recycling of low-temperature waste heat of stainless steel continuous annealing furnace

Stainless steel continuous annealing furnace is mainly used for heat treatment of hot-rolled strip steel.The combustion air will be enabled to heat to 520℃by waste heat recovery system,but the discharge temperature is still up to about 300℃.Owing to with development of global emphasis on energy conservation energy saving and discharge reduction,it's significant to lower the discharge temperature to below 200℃, for the sake of achieving rational use of waste heat resource.Through the analysis of the existing heat recovery system by this study,it is proved that mixing low temperature with flue gas in high temperature standard will increase the capacity of the flue gas and deteriorate the quality of remaining heat resource.In stead of that,increasing the combustion air temperature to 600℃on the basis of stability temperature for the prerequisite of recuperator design,and giving priority to reducing fuel consumption are the better way.The recovery and recycle of low temperature gas are also be introduced.It is demonstrated by the way of setting a secondary recuperator at the exit of the primary recuperator,and using low temperature flue gas to heat the air used for drying the strip steel,the exhuast temperature of flue gas can be reduced to lower than 200℃.At the same time,the steam required for heating air is saved,the energy reserve as high as 2 300 t of standard coal per year.

Low-temperature heat capacities and standard molar enthalpy of formation of 4-(2-aminoethyl)-phenol (C_8H_(11)NO)

This paper reports that low-temperature heat capacities of 4-（2-aminoethyl）-phenol （C8H11NO） are measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 400 K. A polynomial equation of heat capacities as a function of the temperature was fitted by the least square method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15K were calculated and tabulated at the interval of 5K. The energy equivalent, εcalor, of the oxygen-bomb combustion calorimeter has been determined from 0.68g of NIST 39i benzoic acid to be εcalor=（14674.69±17.49）J·K^-1. The constant-volume energy of combustion of the compound at T=298.15 K was measured by a precision oxygen-bomb combustion calorimeter to be ΔcU=-（32374.25±12.93）J·g^-1. The standard molar enthalpy of combustion for the compound was calculated to be ΔcHm = -（4445.47 ± 1.77） kJ·mol^-1 according to the definition of enthalpy of combustion and other thermodynamic principles. Finally, the standard molar enthalpy of formation of the compound was derived to be ΔfHm（C8H11NO, s）=-（274.68 ±2.06） kJ·mol^-1, in accordance with Hess law.

Low-temperature heat capacities of crystalline Ho(Gly)_(3)Cl_(3)·3H_(2)O from 78 to 348 K

Heat capacities of the rare-earth complex with glycine [Ho(Gly)3Cl3·3H2O] were measured with a high-precision automatic adiabatic calorimeter over the temperature range from 78 to 348 K.In the experimental temperature range,the heat capacities increased in a smooth and continuous manner and no phase transition or thermal anomaly occurred.Therefore,the sample was stable in the above temperature range.The values of experimental heat capacities were fitted to a polynomial equation with least square method and ...

Anomalous low-temperature heat capacity in antiperovskite compounds

The low-temperature heat capacities are studied for antiperovskite compounds AX M_3（A = Al, Ga, Cu, Ag, Sn, X = C,N, M = Mn, Fe, Co）. A large peak in（C- γ T）/T^3 versus T is observed for each of a total of 18 compounds investigated,indicating an existence of low-energy phonon mode unexpected by Debye T^3 law. Such a peak is insensitive to the external magnetic field up to 80 k Oe（1 Oe = 79.5775 A·m-1）. For compounds with smaller lattice constant, the peak shifts towards higher temperatures with a reduction of peak height. This abnormal peak in（C- γ T）/T^3 versus T of antiperovskite compound may result from the strongly dispersive acoustic branch due to the heavier A atoms and the optical-like mode from the dynamic rotation of X M_6 octahedron. Such a low-energy phonon mode may not contribute negatively to the normal thermal expansion in AX M_3 compounds, while it is usually concomitant with negative thermal expansion in open-structure material（e.g., ZrW_2O_8, Sc F_3）.

Techno-economic feasibility assessment of a diesel exhaust heat recovery system to preheat mine intake air in remote cold climate regions

Underground mines in Arctic and Subarctic regions require the preheating of mine intake air during winter.The cold fresh air of those remote areas can be as severe as
40℃ and commonly needs to be heated to around+3℃.This extensive amount of heating is usually provided by employing large-size air heaters,fueled by diesel,propane,natural gas,or heavy oil,leading to high energy costs and large carbon footprints.At the same time,the thermal energy content of a diesel generator sets(gen-sets)exhaust is known to be one-third of the total heating value of its combusted fuel.Exhaust heat recovery from diesel gen-sets is a growing technology that seeks to mitigate the energy costs by capturing and redirecting this commonly rejected exhaust heat to other applications such as space heating or pre-heating of the mine intake air.The present study investigated the possibility of employing a simple system based on off-theshelf heat exchanger technology,which can recover the waste heat from the exhaust of the power generation units(diesel gen-sets)in an off-grid,cold,remote mine in Canada for heating of the mine intake air.Data from a real mine was used for the analysis along with environmental data of three different location-scenarios with distinct climates.After developing a thermodynamic model,the heat savings were calculated,and an economic feasibility evaluation was performed.The proposed system was found highly viable with annual savings of up to C$6.7 million and capable enough to provide an average of around 75%of the heating demand for mine intake air,leading to a payback period of about eleven months or less for all scenarios.Deployment of seasonal thermal energy storage has also been recommended to mitigate the mismatch between supply and demand,mainly in summertime,possibly allowing the system to eliminate fuel costs for intake air heating.

Dynamic test on waste heat recovery system with organic Rankine cycle

Dynamic performance is important to the controlling and monitoring of the organic Rankine cycle(ORC) system so to avoid the occurrence of unwanted conditions. A small scale waste heat recovery system with organic Rankine cycle was constructed and the dynamic behavior was presented. In the dynamic test, the pump was stopped and then started. In addition, there was a step change of the flue gas volume flow rate and the converter frequency of multistage pump, respectively. The results indicate that the working fluid flow rate has the shortest response time, followed by the expander inlet pressure and the expander inlet temperature.The operation frequency of pump is a key parameter for the ORC system. Due to a step change of pump frequency(39.49-35.24 Hz),the expander efficiency and thermal efficiency drop by 16% and 21% within 2 min, respectively. Besides, the saturated mixture can lead to an increase of the expander rotation speed.

Simulation of CO_2 Brayton Cycle for Engine Exhaust Heat Recovery under Various Operating Loads

A bottoming cycle system based on CO2 Brayton cycle is proposed to recover the engine exhaust heat. Its performance is compared with the conventional air Brayton cycle under five typical engine conditions. The results show that CO2 Brayton cycle proves to be superior to the air Brayton cycle in terms of the system net output power, thermal efficiency and recovery efficiency. In most cases, the recovery efficiency of CO2 Brayton cycle can be higher than 9% and the system has a better performance at the engine's high operating load. The thermal efficiency can be as large as 24.83% under 100% operating load, accordingly, the net output power of 14.86 kW is obtained.

Exploring heating performance of gas engine heat pump with heat recovery

In order to evaluate the heating performance of gas engine heat pump(GEHP) for air-conditioning and hot water supply, a test facility was developed and experiments were performed over a wide range of engine speed(1400-2600 r/min), ambient air temperature(2.4-17.8 °C) and condenser water inlet temperature(30-50 °C). The results show that as engine speed increases from 1400 r/min to 2600 r/min, the total heating capacity and energy consumption increase by about 30% and 89%, respectively; while the heat pump coefficient of performance(COP) and system primary energy ratio(PER) decrease by 44% and 31%, respectively. With the increase of ambient air temperature from 2.4 °C to 17.8 °C, the heat pump COP and system PER increase by 32% and 19%, respectively. Moreover, the heat pump COP and system PER decrease by 27% and 15%, respectively, when the condenser water inlet temperature changes from 30 °C to 50 °C. So, it is obvious that the effect of engine speed on the performance is more significant than the effects of ambient air temperature and condenser water inlet temperature.