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建筑节能设计Low-E玻璃窗的遮阳参数取值分析
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作者 易嘉 《节能技术》 CAS 2024年第2期180-185,共6页
节能外窗属于精密工业制品,也是建筑工程外围护结构的重要组成部分。为能降低房间内的夏季太阳得热,工程中通常采用低辐射Low-E玻璃外窗,但由于国家及各地区的技术规范对Low-E玻璃窗的参数取值不尽相同、审图机构的把握尺度不一、门窗... 节能外窗属于精密工业制品,也是建筑工程外围护结构的重要组成部分。为能降低房间内的夏季太阳得热,工程中通常采用低辐射Low-E玻璃外窗,但由于国家及各地区的技术规范对Low-E玻璃窗的参数取值不尽相同、审图机构的把握尺度不一、门窗厂家的加工技术水平参差不齐,为能解决Low-E玻璃外窗的遮阳参数取值和选型困难的问题,达到概念清晰、数据可靠、便于实施的目的,文中采用公式计算和查表对比的方法,对规范的遮阳参数概念作补充说明,同时结合江苏某住宅项目的工程实践,给出Low-E玻璃窗遮阳参数的取值原则和建议,并认为一般Low-E玻璃的自遮阳系数取值最高不应超过0.60。 展开更多
关键词 建筑节能设计 low-e玻璃窗 遮阳系数 太阳得热系数 节能外窗选型
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基于全过程工程咨询视角的幕墙LOW-E玻璃质量控制 被引量:1
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作者 竺滨 季相鹏 +2 位作者 胡光松 曾昭华 张美华 《建设监理》 2024年第1期80-83,共4页
随着建筑业对建筑节能的要求日益提高,LOW-E玻璃在建筑门窗及幕墙工程中得到了越来越广泛的应用。结合某工业综合体项目,对幕墙LOW-E玻璃的设计、采购、施工各阶段质量控制要点进行探讨与研究,以供相关建筑门窗及幕墙工程参考。
关键词 low-e玻璃 节能要求 光污染 电子信息干扰
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三银LOW-E玻璃深加工技术:提升室内舒适度的新突破
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作者 王高友 《中国科技纵横》 2024年第10期91-93,共3页
玻璃作为建筑材料的重要组成部分,对提高室内舒适度具有至关重要的作用。然而,目前市场中常规玻璃的隔热性能和节能性能较差,不能很好地满足人们对室内舒适度的要求。近年来,研究人员不断探索新材料和新技术,以提升玻璃的性能。基于此,... 玻璃作为建筑材料的重要组成部分,对提高室内舒适度具有至关重要的作用。然而,目前市场中常规玻璃的隔热性能和节能性能较差,不能很好地满足人们对室内舒适度的要求。近年来,研究人员不断探索新材料和新技术,以提升玻璃的性能。基于此,三银LOW-E玻璃深加工技术应运而生。本文主要探究了三银LOW-E玻璃深加工技术的优势、不足以及未来发展方向,以实现该技术的推广和优化。 展开更多
关键词 三银low-e玻璃 加工技术 新突破
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三银Low-E玻璃对减少碳排放的计算及应用研究
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作者 王琦 戚越笙 +2 位作者 吕宜超 米永江 郝宽宽 《玻璃》 2024年第9期31-36,共6页
鉴于建筑物在其整个生命周期内的能源消耗占全球总能耗的显著比例,使用高效节能建材,是推动建筑绿色低碳化、助力实现“碳达峰”与“碳中和”目标的有效途径之一。三银Low-E玻璃凭借其独特的膜层结构,具有卓越的节能效果。为深入探究三... 鉴于建筑物在其整个生命周期内的能源消耗占全球总能耗的显著比例,使用高效节能建材,是推动建筑绿色低碳化、助力实现“碳达峰”与“碳中和”目标的有效途径之一。三银Low-E玻璃凭借其独特的膜层结构,具有卓越的节能效果。为深入探究三银Low-E玻璃的碳减排性能,通过对采用不同类型银基Low-E玻璃的建筑的碳排放量进行精确测算,对比分析单、双、三银Low-E玻璃的碳减排效果,从而为三银Low-E玻璃的市场推广提供坚实的理论依据。 展开更多
关键词 三银low-e玻璃 建筑能耗 碳减排
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Low-frequency hybridized excess vibrations of two-dimensional glasses
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作者 付立存 郑一鸣 王利近 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第5期550-555,共6页
One hallmark of glasses is the existence of excess vibrational modes at low frequenciesωbeyond Debye’s prediction.Numerous studies suggest that understanding low-frequency excess vibrations could help gain insight i... One hallmark of glasses is the existence of excess vibrational modes at low frequenciesωbeyond Debye’s prediction.Numerous studies suggest that understanding low-frequency excess vibrations could help gain insight into the anomalous mechanical and thermodynamic properties of glasses.However,there is still intensive debate as to the frequency dependence of the population of low-frequency excess vibrations.In particular,excess modes could hybridize with phonon-like modes and the density of hybridized excess modes has been reported to follow D_(exc)(ω)~ω^(2)in 2D glasses with an inverse power law potential.Yet,the universality of the quadratic scaling remains unknown,since recent work suggested that interaction potentials could influence the scaling of the vibrational spectrum.Here,we extend the universality of the quadratic scaling for hybridized excess modes in 2D to glasses with potentials ranging from the purely repulsive soft-core interaction to the hard-core one with both repulsion and attraction as well as to glasses with significant differences in density or interparticle repulsion.Moreover,we observe that the number of hybridized excess modes exhibits a decrease in glasses with higher density or steeper interparticle repulsion,which is accompanied by a suppression of the strength of the sound attenuation.Our results indicate that the density bears some resemblance to the repulsive steepness of the interaction in influencing low-frequency properties. 展开更多
关键词 density of states vibrational modes sound attenuation two-dimensional glasses
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Dynamic and electrical responses of a curved sandwich beam with glass reinforced laminate layers and a pliable core in the presence of a piezoelectric layer under low-velocity impact
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作者 N.SHAHVEISI S.FELI 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第1期155-178,共24页
The dynamic responses and generated voltage in a curved sandwich beam with glass reinforced laminate(GRL)layers and a pliable core in the presence of a piezoelectric layer under low-velocity impact(LVI)are investigate... The dynamic responses and generated voltage in a curved sandwich beam with glass reinforced laminate(GRL)layers and a pliable core in the presence of a piezoelectric layer under low-velocity impact(LVI)are investigated.The current study aims to carry out a dynamic analysis on the sandwich beam when the impactor hits the top face sheet with an initial velocity.For the layer analysis,the high-order shear deformation theory(HSDT)and Frostig's second model for the displacement fields of the core layer are used.The classical non-adhesive elastic contact theory and Hunter's principle are used to calculate the dynamic responses in terms of time.In order to validate the analytical method,the outcomes of the current investigation are compared with those gained by the experimental tests carried out by other researchers for a rectangular composite plate subject to the LVI.Finite element(FE)simulations are conducted by means of the ABAQUS software.The effects of the parameters such as foam modulus,layer material,fiber angle,impactor mass,and its velocity on the generated voltage are reviewed. 展开更多
关键词 analytical model piezoelectric layer curved sandwich beam glass reinforced laminate(GRL) pliable core low-velocity impact(LVI) classical non-adhesive elastic contact theory
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节能建筑中Low-E玻璃选型及具体应用
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作者 秦军文 《建材发展导向》 2024年第1期13-15,共3页
通过对Low-E玻璃节能基本原理的介绍,详细从原片玻璃的选择、镀膜面位置及气体夹层三方面对Low-E玻璃的选型要求进行论述,最后重点分析Low-E玻璃在不同气候地区应用的具体情况,可实现建筑的有效节能,同时为选择使用节能玻璃提供建议。
关键词 节能建筑 low-e玻璃 材料选型 应用
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建筑低辐射膜玻璃Low-E的具体应用
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作者 李建欣 《建材发展导向》 2024年第1期7-9,共3页
Low-E玻璃是建筑工程中的常用玻璃材料,在了解Low-E玻璃节能效果影响因素的基础上,提出Low-E玻璃的选型思路,保证原片玻璃、镀膜面位置、气体夹层的合理性,研究了Low-E玻璃在寒冷气候区、温暖气候区、夏热冬冷气候区建筑工程中的应用要... Low-E玻璃是建筑工程中的常用玻璃材料,在了解Low-E玻璃节能效果影响因素的基础上,提出Low-E玻璃的选型思路,保证原片玻璃、镀膜面位置、气体夹层的合理性,研究了Low-E玻璃在寒冷气候区、温暖气候区、夏热冬冷气候区建筑工程中的应用要点,妥善应用Low-E玻璃,发挥出此类玻璃材料的节能环保优势,提升Low-E玻璃在建筑工程中的应用价值。 展开更多
关键词 建筑工程 low-e玻璃 选材 应用方法 节能环保
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Electromagnetic wave absorption and mechanical properties of SiC nanowire/low-melting-point glass composites sintered at 580°C in air 被引量:1
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作者 Ranran Shi Wei Lin +5 位作者 Zheng Liu Junna Xu Jianlei Kuang Wenxiu Liu Qi Wang Wenbin Cao 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第9期1809-1815,共7页
Si C nanowires are excellent high-temperature electromagnetic wave (EMW) absorbing materials. However, their polymer matrix composites are difficult to work at temperatures above 300℃, while their ceramic matrix comp... Si C nanowires are excellent high-temperature electromagnetic wave (EMW) absorbing materials. However, their polymer matrix composites are difficult to work at temperatures above 300℃, while their ceramic matrix composites must be prepared above 1000℃ in an inert atmosphere. Thus, for addressing the abovementioned problems, SiC/low-melting-point glass composites were well designed and prepared at 580℃ in an air atmosphere. Based on the X-ray diffraction results, SiC nanowires were not oxidized during air atmosphere sintering because of the low sintering temperature. Additionally, SiC nanowires were uniformly distributed in the glass matrix material. The composites exhibited good mechanical and EMW absorption properties. As the filling ratio of SiC nanowires increased from 5wt%to 20wt%, the Vickers hardness and flexural strength of the composite reached HV 564 and 213 MPa, which were improved by 27.7%and 72.8%, respectively, compared with the low-melting-point glass. Meanwhile, the dielectric loss and EMW absorption ability of SiC nanowires at 8.2–12.4 GHz were also gradually improved. The dielectric loss ability of low-melting-point glass was close to 0. However, when the filling ratio of SiC nanowires was 20wt%, the composite showed a minimum reflection loss (RL) of-20.2 dB and an effective absorption (RL≤-10 dB) bandwidth of2.3 GHz at an absorber layer thickness of 2.3 mm. The synergistic effect of polarization loss and conductivity loss in SiC nanowires was responsible for this improvement. 展开更多
关键词 SiC nanowires glass composite flexural strength dielectric properties microwave absorption
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遮阳型Low-E镀膜玻璃的制备及研究 被引量:1
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作者 沈子贤 《广东建材》 2023年第11期6-8,12,共4页
本文阐述了一种遮阳型Low-E镀膜玻璃的制备方法,实验结合磁控溅射技术与超声喷涂技术在普通的玻璃基板上镀制四层薄膜,并对制成的样品进行可见光透过率,表面形貌特征,遮阳系数等性能分析,制备一种性质相对稳定,且既具有高遮阳功能,又具... 本文阐述了一种遮阳型Low-E镀膜玻璃的制备方法,实验结合磁控溅射技术与超声喷涂技术在普通的玻璃基板上镀制四层薄膜,并对制成的样品进行可见光透过率,表面形貌特征,遮阳系数等性能分析,制备一种性质相对稳定,且既具有高遮阳功能,又具有适宜的可见光透过率的镀膜玻璃。 展开更多
关键词 遮阳型 low-e玻璃 遮阳系数 可见光透过率
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寒冷地区Low-E节能玻璃检测与应用技术研究
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作者 王磊 杨德壮 郑德玉 《建设科技》 2023年第3期32-35,共4页
通过对Low-E节能玻璃传热系数的检测,找出影响Low-E中空玻璃传热系数K值的因素,生产企业可以根据这些因素择优制作Low-E节能玻璃。本文还给出常用玻璃与窗框配合后整窗传热系数K值,绿色建筑、超低能耗绿色建筑所用外窗的适配窗框与Low-... 通过对Low-E节能玻璃传热系数的检测,找出影响Low-E中空玻璃传热系数K值的因素,生产企业可以根据这些因素择优制作Low-E节能玻璃。本文还给出常用玻璃与窗框配合后整窗传热系数K值,绿色建筑、超低能耗绿色建筑所用外窗的适配窗框与Low-E节能玻璃一目了然。 展开更多
关键词 寒冷地区 low-e节能玻璃 检测 应用技术
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Efficient utilization of glass fiber separator for low-cost sodium-ion batteries
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作者 Xiaohang Ma Zhijie Chen +7 位作者 Tianwen Zhang Xueqian Zhang Yuan Ma Yanqing Guo Yiyong Wei Mengyuan Ge Zhiguo Hou Zhenfa Zi 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第10期1878-1886,共9页
The separator is a key component of sodium-ion battery,which greatly affects the electrochemical performances and safety characteristics of the battery.Conventional glass fiber separator cannot meet the requirements o... The separator is a key component of sodium-ion battery,which greatly affects the electrochemical performances and safety characteristics of the battery.Conventional glass fiber separator cannot meet the requirements of large-scale application because of high cost and poor mechanical properties.Herein,the novel composite separators are prepared by a simple slurry sieving process using glass fiber separator scraps and ordinary qualitative filter paper as raw materials.As the composite mass ratio is 1:1,the composite separator has excellent comprehensive properties,including tensile strength of 15.8 MPa,porosity of 74.3%,ionic conductivity of 1.57×10^(-3)S·cm^(-1)and thermal stability at 210℃.The assembled sodium-ion battery shows superior cycling performance(capacity retention of 94.1%after 500 cycles at 1C)and rate capacity(retention rate of 87.3%at 10C),and it maintains fine interface stability.The above results provide some new ideas for the separator design of high-performance and low-cost sodium-ion batteries. 展开更多
关键词 SEPARATOR glass fiber low cost sodium-ion batteries
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A Low-E Coated Glass Project of Xianyang Co.,Ltd.of Taiwanglass Group Started to Be Built
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《China's Refractories》 CAS 2013年第3期22-22,共1页
On July 24, 2013, a low-E coated glass project of Xianyang Co., Ltd. of Taiwanglass Group with a daily capacity of 1.2 thousand tons was started to be built, meanwhile a float glass production line was put into produc... On July 24, 2013, a low-E coated glass project of Xianyang Co., Ltd. of Taiwanglass Group with a daily capacity of 1.2 thousand tons was started to be built, meanwhile a float glass production line was put into production. The float glass line with CNY 1.5 billion of investment was built in July, 2008. Total investment of phase I of the Iow-E coated glass project was CNY one billion. The annual production value of the proiect can reach CNY one billion after completion of the whole project. 展开更多
关键词 PROJECT A low-e Coated glass Project of Xianyang Co Ltd.of Taiwanglass Group Started to Be Built BE
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Geochemistry of volcanic glass from Mahanadi offshore region,eastern continental margin of India:Constraints on the contribution of latest Toba super-eruption
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作者 Muralidhar Kocherla Durbar Ray +3 位作者 Manavalan Satyanarayanan Hilda Joao Virsen Gaikwad PB Ramamurty 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2024年第2期111-119,共9页
The tephra layers in multiple sediment cores from the offshore region of the Mahanadi basin in the northern Bay of Bengal were investigated for possible volcanic sources. The glass shards from those tephra layers were... The tephra layers in multiple sediment cores from the offshore region of the Mahanadi basin in the northern Bay of Bengal were investigated for possible volcanic sources. The glass shards from those tephra layers were studied for size distribution, texture, and elemental geochemistry to establish chronostratigraphic markers for regional and global Quaternary correlation. The textural features of fine-grained(silty) volcanic glasses suggest the distal source of these tephra deposits. Major element composition with elevated SiO_(2) contents ranging between75%–76% and dominance of K_(2)O(> 4.5%) over CaO(< 0.9%) suggest ashes have originated from siliceous rhyolitic melts, similar to the petrographic composition of tephra from the Toba volcano. The bulk trace element compositions of the same glass shards were comparable with those reported in the youngest Toba tephra reported elsewhere. Likewise, the LREE-dominated chondrite normalized REE profiles of tephra from the Mahanadi basin closely resemble the characteristic REE patterns in Toba ash from other parts of the Indian Ocean and thus confirmed the contribution of the youngest Toba super-eruption for this ash layers. 展开更多
关键词 Mahanadi basin Bay of Bengal volcanic glass glass morphology glass-chemistry
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Mixed Alkali-zinc Effects on Thermo-mechanical Properties in Borosilicate Glasses
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作者 XIAO Guanzhou TAO Yunhang +3 位作者 ZHOU Hemin ZHENG Qingshuang QIAO Ang TAO Haizheng 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第5期1093-1099,共7页
A series of mixed alkali-zinc borosilicate glasses with various r values(r=molar ratio of[ZnO]/([R^(2)O]+[ZnO]))from 0.00 to 1.00 were fabricated to probe the mixed alkali-zinc effects on thermo-mechanical properties.... A series of mixed alkali-zinc borosilicate glasses with various r values(r=molar ratio of[ZnO]/([R^(2)O]+[ZnO]))from 0.00 to 1.00 were fabricated to probe the mixed alkali-zinc effects on thermo-mechanical properties.The nonlinear evolution of glass transition temperature(T_(g))with the addition of ZnO is ascribed to the competition of two converse factors,i e,the T_(g)depression as one of the colligative properties for a solution,on the one hand,and the enhancement of T_(g)due to the higher field strength of zinc cations compared to that of alkali ions.However,the nonlinear evolution of elastic moduli and coefficients of thermal expansion with r is attributed to the variance of intermediate-range clusters,which is confirmed by infrared and Raman scattering spectra.These findings are very helpful in tailoring the performance of borosilicate glasses. 展开更多
关键词 glass transition temperature elastic moduli coefficient of thermal expansion borosilicate glass
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Solid-state NMR reveals that oxygen tri-clusters make glass highly crackresistant
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作者 Zhiwu Yu 《Magnetic Resonance Letters》 2024年第2期77-78,共2页
In a recent paper,advanced solid-state nuclear magnetic resonance(SSNMR)technology was employed to reveal the underlying mechanism contributing to the high hardness and exceptional resistance to fragmentation observed... In a recent paper,advanced solid-state nuclear magnetic resonance(SSNMR)technology was employed to reveal the underlying mechanism contributing to the high hardness and exceptional resistance to fragmentation observed in certain special glasses[1].This study utilized SSNMR to analyze the atomic-scale internal structure of glass,enabling the quantification of the fraction of three-coordinated oxygen([^((3))O]).The research findings demonstrate a quantitative relationship between[^((3))O]and the resistance of glass to crack initiation. 展开更多
关键词 CRACK resistance glass
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Design and characterization of biodegradable Mg-Zn-Ag metallic glasses
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作者 Jian WANG Chen WANG +1 位作者 Wei-feng RAO In-ho JUNG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第9期2814-2827,共14页
In order to develop the Mg-Zn-Ag metallic glasses(MGs)for biodegradable implant applications,the glass formation ability(GFA)and biocompatibility of Mg-Zn-Ag alloys were investigated using a combination of the calcula... In order to develop the Mg-Zn-Ag metallic glasses(MGs)for biodegradable implant applications,the glass formation ability(GFA)and biocompatibility of Mg-Zn-Ag alloys were investigated using a combination of the calculation of phase diagrams(CALPHAD)and experimental measurements.High GFA potentiality of two alloy series,specifically Mg_(96-x)Zn_xAg_(4)and Mg_(94-x)Zn_xAg_6(x=17,20,23,26,29,32,35),was predicted theoretically and then substantiated through experimental testing.X-ray diffraction(XRD)and differential scanning calorimetry(DSC)techniques were used to evaluate the crystallinity,GFA,and crystallization characteristics of these alloys.The results showed that compositions between Mg_(73)Zn_(23)Ag_(4)and Mg_(64)Zn_(32)Ag_(4)for Mg_(96-x)Zn_xAg_4,Mg_(66)Zn_(28)Ag_(6)and Mg_(63)Zn_(31)Ag_(6for)Mg_(94-x)Zn_xAg_(6)displayed a superior GFA.Notably,the GFA of the Mg_(96-x)Zn_xAg_(4)series was better than that of the Mg_(94-x)Zn_xAg_(6)series.Furthermore,the Mg_(70)Zn_(26)Ag_4,Mg_(74)Zn_(20)Ag_6,and Mg_(71)Zn_(23)Ag_(6)alloys showed acceptable corrosion rates,good cytocompatibility,and positive effects on cell proliferation.These characteristics make them suitable for applications in medical settings,potentially materials as biodegradable implants. 展开更多
关键词 glass forming ability calculation phase diagram(CALPHAD) Mg−Zn−Ag metallic glasses CYTOCOMPATIBILITY
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Influence of Al_(2)O_(3)/SiO_(2) Ratio on the Structure and Properties of Na^(+)/K^(+)Ion Exchange Na_(2)O-MgO-Al_(2)O_(3)-SiO_(2) Glasses
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作者 吴建磊 CHEN Junzhu +4 位作者 TIAN Xiaokun LI Jiahao GAO Wenkai YUE Yunlong 康俊峰 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第3期606-612,共7页
In this work,the structure,viscosity and ion-exchange process of Na_(2)O-MgO-Al_(2)O_(3)-SiO_(2) glasses with different Al_(2)O_(3)/SiO_(2) molar ratios were investigated.The results showed that,with increasing Al_(2)... In this work,the structure,viscosity and ion-exchange process of Na_(2)O-MgO-Al_(2)O_(3)-SiO_(2) glasses with different Al_(2)O_(3)/SiO_(2) molar ratios were investigated.The results showed that,with increasing Al_(2)O_(3)/SiO_(2) ratio,the simple structural units Q_(1) and Q_(2) transformed into highly aggregated structural units Q_(3) and Q_(4),indicating the increase of polymerization degree of glass network.Meanwhile,the coefficient of thermal expansion decreased from 9.23×10^(-6)℃^(-1) to 8.88×10^(-6)℃^(-1).The characteristic temperatures such as melting,forming,softening and glass transition temperatures increased with the increase of Al_(2)O_(3)/SiO_(2) ratio,while the glasses working temperature range became narrow.The increasing Al_(2)O_(3)/SiO_(2) ratio and prolonging ion-exchange time enhanced the surface compressive stress(CS)and depth of stress layer(DOL).However,the increase of ion exchange temperature increased the DOL and decreased the CS affected by stress relaxation.There was a good linear relationship between stress relaxation and surface compressive stress.Chemical strengthening significantly improved the hardness of glasses,which reached the maximum value of(622.1±10)MPa for sample with Al_(2)O_(3)/SiO_(2) ratio of 0.27 after heat treated at 410℃for 2 h. 展开更多
关键词 network structure viscosity ion exchange aluminosilicate glass
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Structural color of metallic glass through picosecond laser
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作者 Yue’e Zhang Xing Tong +3 位作者 Yuqiang Yan Shuo Cao Hai-Bo Ke Wei-Hua Wang 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第10期120-128,共9页
The alteration in surface color of metallic glasses(MGs)holds great significance in the context of microstructuredesign and commercial utility.It is essential to accurately describe the structures that are formed duri... The alteration in surface color of metallic glasses(MGs)holds great significance in the context of microstructuredesign and commercial utility.It is essential to accurately describe the structures that are formed during the laser and colorseparation processes in order to develop practical laser coloring applications.Due to the high oxidation sensitivity of Labasedmetallic glass,it can broaden the color range but make it more complex.Structure coloring by laser processing on thesurface of La-based metallic glass can be conducted after thermoplastic forming.It is particularly important to clarify therole of structure and composition in the surface coloring process.The aim is to study the relationship between amorphoussurface structural color,surface geometry,and oxide formation by laser processing in metallic glasses.The findings revealedthat the periodic structure primarily determines the surface color at laser energy densities below 1.0 J/mm^(2).In contrast,thesurface color predominantly depends on the proportion of oxides that are formed when energy densities exceed 1.0 J/mm^(2).Consequently,this study provides a novel concept for the fundamental investigation of laser coloring and establishes a newavenue for practical application. 展开更多
关键词 metallic glass picosecond laser periodic structure OXIDES
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Effect of Fe_(2)O_(3)on the Structure,Physical Properties and Crystallization of CaO-Al_(2)O_(3)-SiO_(2)Glass
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作者 张峰 XIONG Dehua +7 位作者 谢俊 张继红 HAN Jianjun CHEN Dequan WEN Zhongquan FAN Zhenhua CHEN Lina SUN Tengfei 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第4期954-961,共8页
The calcium aluminosilicate-based glasses(CaO-Al_(2)O_(3)-SiO_(2),CAS)with different Fe_(2)O_(3)content(0.10wt%,0.50wt%,0.90wt%,and 1.30wt%)were prepared by traditional melt-quenching method.The glass network structur... The calcium aluminosilicate-based glasses(CaO-Al_(2)O_(3)-SiO_(2),CAS)with different Fe_(2)O_(3)content(0.10wt%,0.50wt%,0.90wt%,and 1.30wt%)were prepared by traditional melt-quenching method.The glass network structure,thermal and mechanical properties,and crystallization behavior changes were investigated by nuclear magnetic resonance spectrometer,Fourier-transform infrared spectro-photometer,X-ray diffractometer,differential scanning calorimetry and field emission scanning electron microscope measurements.The change of Q^(n)in glass structures reveals the glass network connectivity decreases due to the increasing content of Fe_(2)O_(3)addition,resulting in the increasing of non-bridging number in glass structure.The glass densities slightly rise from 2.644 to 2.681 g/cm^(3),while Vickers’s hardness increases at first,from 6.469 to 6.901 GPa,then slightly drops to 6.745 GPa,with Fe_(2)O_(3)content increase.There is almost no thermal expansion coefficient change from different Fe_(2)O_(3)content.The glass transmittance in visible range gradually decreases with higher Fe_(2)O_(3)content,resulting from the strong absorption of Fe^(2+)and Fe^(3+)ions.The calculated activation energy from thermal analysis results first decreases from 282.70 to 231.18 kJ/mol,and then increases to 244.02 kJ/mol,with the Fe_(2)O_(3)content increasing from 0.10wt%to 1.30wt%.Meanwhile,the maximum Avrami constant of 2.33 means the CAS glasses exhibit two-dimensional crystallization.All of the CAS glass-ceramics samples contain main crystal phase of anorthite,the microstructure appears lamellar and columnar crystals. 展开更多
关键词 calcium aluminosilicate glass network structure physical properties CRYSTALLIZATION
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