Geochemistry, zircon U–Pb geochronology, and Hf isotopes of S-type granite in the Baoshan block, constraints on the age and evolution of the Proto-Tethys

Geochemistry, zircon U–Pb geochronology, and Hf isotope data for the Early Paleozoic granites in the Baoshan Block reveal the Early Paleozoic tectonic evolution of the Proto-Tethys. The samples are high-K, calcalkaline, strongly peraluminous rocks with A/CNK values of 1.37–1.46, are enriched in SiO2, K2O, and Rb, and are depleted in Nb, P, Ti, Eu, and heavy rare earth elements,which indicates the crystallization fractionation of the granitic magma. Zircon U–Pb dating indicates that they formed in ca. 480 Ma. The Nansa granites have εHf(t) values ranging from-16.04 to 4.36 with corresponding TC DMages of 2.10–0.81 Ga, which suggests the magmas derived from the partial melting of ancient metasedimentary with minor involvement of mantle-derived components. A synthesis of data for the Early Paleozoic igneous rocks in the Baoshan block and adjacent(Tengchong,Qiangtang, Sibumasu, Himalaya, etc.) blocks indicates that these blocks were all aligned along the proto-Tethyan margin of East Gondwana in the Early Paleozoic. The Early Paleozoic S-type granites from Nansa were generated in a high-temperature and low-pressure(HTLP) extensional tectonic setting, which resulted from Andean-type orogeny instead of the final assembly of Gondwana or crustal extension in a non-arc environment. In certain places, an expanding environment may exist in opposition to the tectonic backdrop of the lithosphere’s thickening and shortening, leading the crust to melt and decompress,mantle-derived materials to mix, and a small quantity of peraluminous granite to emerge.

皖南伏岭A型花岗岩的成因——地球化学、锆石U-Pb年龄及Lu—Hf同位素特征

伏岭花岗岩体,位于江南造山带东段的皖浙相邻区,岩浆岩沿着近北东向的宁国—绩溪深大断裂断分布。笔者等对伏岭岩体鱼龙川(γ_(5)^(3-2))单元花岗岩开展了系统的全岩岩石地球化学、LA-ICPMS锆石U-Pb同位素年龄和锆石原位Lu—Hf同位素地球化学研究,结果表明,花岗岩的侵位年龄为131.8±0.9 Ma,富硅、富碱、贫钙、贫铁,具有较高的Rb、Th、U、Ga、Zr和Y含量,较低的Sr、Ba和Nb含量,稀土配分曲线呈现典型的“海鸥式”分布特征,显示强烈的负Eu异常;微量元素原始地幔标准化蛛网图显示明显的Ba、Sr、Nb的负异常。其高SiO_(2)含量和Rb/Sr值、低Ba、Sr含量具备江南造山带东段皖南地区A型花岗岩的典型特征。岩体具有同源岩浆演化特征,源区可能存在磷灰石、钛铁矿的分离结晶作用,而辉石类的分离较少。伏岭岩体主要来源于地壳中镁铁质岩石的部分熔融,其地球化学特征继承于源岩。锆石ε_(Hf)(t)变化范围较小,均在-7.0~-4.6之间,二阶段模式年龄(TDM2)为1478~1630 Ma,伏岭花岗岩可能由中元古代古老下地壳部分熔融形成。伏岭岩体的形成可能受到碰撞作用的影响,岩体形成于后碰撞期,中元古代的基底岩石被大范围的熔融,从而产生了伏岭A型花岗岩。

青海沟里地区斜长角闪岩锆石U-Pb年代学、Lu-Hf同位素特征及其指示意义

东昆仑造山带金水口群的沉积和变质时代一直存在争议。本文利用LA-ICP-MS技术对青海省都兰县沟里地区金水口群中的斜长角闪岩进行了锆石U-Pb年代学、Lu-Hf同位素研究。结果显示:斜长角闪岩中6个测点的碎屑锆石年龄集中在2.1~2.0 Ga之间,碎屑锆石最小年龄为1829 Ma,变质锆石的上交点年龄为(1905±300)Ma,误差较大,但暗示金水口群沉积时间漫长,沉积时代不晚于中元古代早期,故本文认为金水口群沉积时代在1800 Ma左右;年龄集中于2100 Ma的碎屑锆石具有麻粒岩相变质锆石特征。变质锆石年龄集中于450~420 Ma之间,12个点的加权平均年龄为(444.3±5.3)Ma,为早古生代,该年龄与东昆仑造山带响应原特提斯洋俯冲拼合并发生区域深熔作用的年龄基本一致;锆石^(176)Lu/^(177)Hf值较低,变质锆石ε_(Hf)(t)值为-35.41~-3.75,T_(DM2)介于3641~1666 Ma之间,源岩物质为古老地壳再循环的产物;古元古代碎屑锆石ε_(Hf)(t)值为-2.98~25.58,T_(DM2)介于2833~920 Ma之间,源区为来源于亏损地幔的陆壳,与太古宙TTG岩系相似,暗示阿尔金地块的TTG岩系为金水口群提供了部分物质来源。金水口群沉积于活动大陆边缘或初始裂谷盆地,上部沉积盖层冰沟群与万宝沟群沉积于浅海陆棚,沉积过程具有连续性。

胶西北大泽山岩体地球化学、锆石U-Pb年代学及Lu-Hf同位素特征

胶东金矿集区是我国最重要的金矿集区,大规模金成矿作用发生于125~110 Ma。本文选择了与成矿作用同期的早白垩世晚期大泽山岩体为研究对象,通过详细的岩相学、岩石地球化学、锆石LA-ICP-MS U-Pb年代学研究,识别出中粒二长花岗岩和细粒二长花岗岩两种主要的侵入岩类型,它们具有相似的岩相学和岩石地球化学特征,呈现同源岩浆演化特征。定年结果表明,中粒二长花岗岩中锆石U-Pb年龄分别为119.8±0.8 Ma和119.3±0.9 Ma,细粒二长花岗岩中锆石U-Pb年龄分别为109.2±0.7 Ma和109.9±0.7 Ma。岩石地球化学研究表明,二长花岗岩具有高的全碱(K_(2)O+Na_(2)O=8.14%~8.72%),高的Al_(2)O_(3)(12.42%~15.32%),属过铝质高钾钙碱性系列,轻稀土(LREE)富集、重稀土(HREE)相对亏损(LREE/HREE=8.46~18.87),具明显的稀土元素分馏((La/Yb)_(N)=8.52~24.08)和较强的Eu负异常(δEu=0.33~0.58)。大泽山岩体锆石ε_(Hf)(t)值为-26.4~-16.2,亏损地幔二阶段模式年龄(T_(DM2))为2812~2173 Ma,物源主要是古元古代和新太古代陆壳的部分熔融,有少量幔源物质的加入。大泽山岩体成岩期与胶东金矿的主成矿期一致,暗示岩浆活动与金成矿具有统一的地球动力学背景。

贵州北部马鬃岭铝土矿床中富锂铝质粘土岩碎屑锆石U-Pb年龄、Lu-Hf同位素特征及其对锂源的制约

为研究贵州北部马鬃岭铝土矿床中富锂铝质粘土岩的物源体系及其锂的来源,对出露于大竹园组顶部的该类岩石进行了锆石U-Pb定年、Lu-Hf同位素及锆石微量元素分析。分析结果表明富锂铝质粘土岩中碎屑锆石普遍发育岩浆振荡环带,为造山作用/弧作用相关的岩浆岩类锆石。碎屑锆石U-Pb年龄从早泥盆世到太古宙(411~3001 Ma)均有分布,具627~879 Ma和925~1018 Ma两个主峰及539~602 Ma一个次峰。ε_(Hf)(t)值为-27.61~7.03之间,二阶段模式年龄(t_(DM2))分布在1242~3387 Ma之间。结合碎屑锆石U-Pb-Hf同位素、微量元素特征及区域地质对比,认为富锂铝质粘土岩中碎屑锆石最主要的初始物源区为南岭-云开地体、江南造山带西段新元古代岩浆岩,其锂可能来源于江南造山带西段桂北-黔东地区860~750 Ma的基性岩。

Zircon U-Pb geochronology,Hf isotopes,and geochemistry constraints on the age and tectonic affinity of the basement granitoids from the Qiongdongnan Basin,northern South China Sea

Studies in the northern South China Sea(SCS)basement remain important for understanding the evolution of the Southeast Asian continental margin.Due to a thick cover of sediments and scarce borehole penetration,little is known about the age and tectonic affinity of this basement.In this study,an integrated study of zircon U-Pb geochronology,Hf isotopes,and whole-rock major and trace elements on seven basement granitoids from seven boreholes of Qiongdongnan Basin has been carried out.New zircon U-Pb results for these granitoids present middle-late Permian((270.0±1.2)Ma;(253±3.4)Ma),middle to late Triassic((246.2±3.4)Ma;(239.3±0.96)Ma;(237.9±0.99)Ma;(228.9±1.0)Ma)and Late Cretaceous ages((120.6±0.6)Ma).New data from this study,in combination with the previous dataset,indicates that granitoid ages in northern SCS basement vary from 270 Ma to 70.5 Ma,with three age groups of 270–196 Ma,162–142 Ma,and 137–71 Ma,respectively.Except for the late Paleozoic-Mesozoic rocks in the basement of the northern SCS,a few old zircon grains with the age of(2708.1±17)Ma to(2166.6±19)Ma provide clues to the existence of the pre-Proterozoic components.The geochemical signatures indicate that the middle Permian-early Cretaceous granitoids from the Qiongdongnan Basin are I-type granites formed in a volcanic arc environment,which were probably related to the subduction of the Paleo-Pacific Plate.

U-Pb Age and Hf Isotope Study of Detrital Zircons from the Wanzi Supracrustals:Constraints on the Tectonic Setting and Evolution of the Fuping Complex,Trans-North China Orogen

Located in the middle segment of the Trans-North China Orogen, the Fuping Complex is considered as a critical area in understanding the evolution history of the North China Craton （NCC）. The complex is composed of various high-grade and multiply deformed rocks, including gray gneiss, basic granulite, amphibolite, fine-grained gneiss and marble, metamorphosed to upper amphibolite or granulite facies. It can be divided into four rock units： the Fuping TTG gneisses, Longquanguan augen gneisses, Wanzi supracrustals, and Nanying granitic gneisses. U-Pb age and Hf isotope compositions of about 200 detrital zircons from the Wanzi supracrustals of the Fuping Complex have been analyzed. The data on metamorphic zircon rims give ages of 1.82-1.84 Ga, corresponding to the final amalgamation event of the NCC, whereas the data for igneous zircon cores yield two age populations at -2.10 and -2.51 Ga, with some inherited ages scattering between 2.5 and 2.9 Ga. These results suggest that the Wanzi supracrustals were derived from the Fuping TTG gneisses （-2.5 Ga） and the Nanying granitic gneisses （2.0-2.1 Ga） and deposited between 2.10 and 1.84 Ga. All zircons with -2.51 Ga age have positive initial εHf values from ＋1.4 to ＋10.9, suggesting an important crustal growth event at -2.5 Ga through the addition of juvenile materials from the mantle. The Hf isotope data for the detrital zircons further imply that the 2.8 Ga rocks are important components in the lower crust, which is consistent with a suggestion from Nd isotope data for the Eastern Block. The zircons of 2.10 Ga population have initial εHf values of-4.9 to ＋6.1, interpreted as mixing of crustal re-melt with minor juvenile material contribution at 2.1 Ga. These results are distinct from that for the Western Block, supporting that the Fuping Complex was emplaced in a tectonic active environment at the western margin of the Eastern Block.

In Situ Analyses of Trace Elements, U–Pb and Lu–Hf Isotopes in Zircons from the Tongshankou Granodiorite Porphyry in Southeast Hubei Province, Middle-Lower Yangtze River Metallogenic Belt, China

The Tongshankou Cu-Mo deposit, located in southeast Hubei province, is a typical skarn–porphyry type ore deposit closely related to the Tongshankou granodiorite porphyry, characterized by a high Sr/Y ratio.Detailed in situ analyses of the trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry were performed.Scarcely any inherited zircons were observed, and the analyzed zircons yielded highly concordant results with a weighted mean 206Pb/238 U age of 143.5 ± 0.45 Ma（n=20, mean square weighted deviation was 0.75）, which was interpreted to represent the crystallization age of the Tongshankou granodiorite porphyry.The chondrite-normalized rare-earth element pattern was characterized by a slope that steeply rises from the light-group rare-earth elements（LREE） to the heavy-group rare-earth elements（HREE） with a positive Ce-anomaly and inconspicuous Eu-anomaly, which was coincident with the pattern of the zircons from the Chuquicamata West porphyry, Chile.The analyzed zircons also had relatively low 176Hf/177 Hf ratios of 0.282526–0.282604.Assuming t=143 Ma, the corresponding calculated initial Hf isotope compositions（εHf（t）） ranged from-5.6 to-2.9.The results of the in situ analysis of trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry suggest that a deep-seated process involving a thickened-crust/enriched-mantle interaction may play an important role in the generation of high Sr/Y-ratio magma and potentially in the generation of porphyry Cu-Mo systems.

Geochemistry, geochronology and Hf isotope of granitoids in the Chinese Altai: Implications for Paleozoic tectonic evolution of the Central Asian Orogenic Belt

The Chinese Altai in northwestern Xinjiang has numerous outcrops of granitoids which provide critical information on accretionary orogenic processes and crustal growth of the Central Asian Orogenic Belt.Zircon U-Pb ages, Hf-isotopic compositions and whole-rock geochemistry of monzogranite and granodiorites in the Qinghe County are employed to elucidate Paleozoic tectonics of the Chinese Altai. Granodiorites have crystallization ages of 424.6 ± 3.1 Ma(MSWD = 0.23) and 404.0 ± 3.4 Ma(MSWD = 0.18);monzogranite was emplaced in the early Permian with a crystallization age of 293.7 ± 4.6 Ma(MSWD = 1.06). Both granodiorites and monzogranite are I-type granites with A/CNK ratios of 0.92 -0.97 and 1.03 -1.06, respectively. They also show similar geochemical features of high HREE and Y contents, low Sr contents and Sr/Y ratios, as well as enrichment of Cs, Rb, Th and U, and depletion of Nb, Ta, P and Ti.These geochemical features indicate that the monzogranite and granodiorites were formed in an arc setting related to subduction. The gneissic monzogranites display high SiO_2 and K_2 O contents, and belong to the high-K calc-alkaline series. In the chondrite normalized REE distribution pattern, the monzogranite samples exhibit enrichment of LREE with strong negative Eu anomalies(σE u =0.44 -0.53), zircon εHf(t) values from +7.24 to +12.63 and two-stage Hf model ages of 463 -740 Ma. This suggests that the monzogranite was generated from the mixing of pelitic and mantle material. The granodiorite samples are calc-alkaline granites with lower contents of Si O_2 and Na_2 O + K_2 O, higher contents of TiO_2, Fe_2O_3~t, MgO and CaO compared to the monzogranite samples. They also show enrichment of LREE and moderate negative Eu anomalies(σE u= 0.54 =0.81), as well as slightly higher differentiation of LREE than that of HREE. The425 Ma granodiorite has zircon εHf(t) values from -0.51 to +1.98 and two-stage Hf model ages of 1133 -1240 Ma, whereas the 404 Ma granodiorite displays those of +2.52 to +7.50 and 816 -1071 Ma.Geochemistry and zircon Hf isotopic compositions indicate that granodiorites were formed by partial melting of juvenile lower crust. Together with regional geology and previous data, the geochemical and geochronological data of the monzogranite and granodiorites from this study suggest long-lived subduction and accretion along the Altai Orogen during ca. 425 -294 Ma.

Precambrian Tectonic Affinity of the Southern Langshan Area, Northeastern Margin of the Alxa Block: Evidence from Zircon U-Pb Dating and Lu-Hf Isotopes

The Alxa Block is the westernmost part of the North China Craton(NCC), and is regarded as one of the basement components of the NCC. Its geological evolution is of great significance for the understanding of the NCC.However, the Precambrian basement of the Alxa Block is still poorly studied. In this study, we present new in situ LA-ICPMS zircon U-Pb and Lu-Hf isotope data from the Diebusige Metamorphic Complex(DMC) which located in the eastern Alxa Block. Field and petrological studies show that the DMC consists mainly of metamorphic supracrustal rocks and minor metamorphic plutonic rocks and has experienced amphibolite-granulite facies metamorphism. Zircon U-Pb dating results suggested that the amphibolite sample yields a crystallization age of 2636 ± 14 Ma and metamorphic ages of 2517–2454 Ma and 1988–1952 Ma, proving the existence of exposed Archean rocks in the Langshan area and indicating that late Neoarchean to Paleoproterozoic metamorphic events existed in the Alxa Block. Two paragneiss samples show that the magmatic detrital zircons from the DMC yield 207Pb/206Pb ages ranging from 2.48 Ga to 2.10 Ga with two youngest peaks at 2.13 Ga and 2.16 Ga, respectively, and they were also overprinted by metamorphic events at 1.97–1.90 Ga and 1.89–1.79Ga. Compilation of U-Pb ages of magmatic detrital and metamorphic zircons suggested that the main part of the DMC may have been formed at 2.1–2.0 Ga. Zircon Lu-Hf isotope data show that the source materials of the main part of the DMC were originated from the reworking of ancient Archean crust(3.45–2.78 Ga). The Hf isotope characteristics and the tectonothermal event records exhibit different evolution history with the Khondalite Belt and the Yinshan Block and the other basements of the Alxa Block, indicating that the Langshan was likely an independent terrain before the middle Paleoproterozoic and was subjected to the middle to late Paleoproterozoic tectonothermal events with the Khondalite Belt as a whole.

Combined U-Pb SHRIMP and Hf isotope study of the Late Paleozoic Yaminue Complex,Rio Negro Province,Argentina:Implications for the origin and evolution of the Patagonia composite terrane

We have carried out zircon U-Pb SHRIMP dating and Hf isotope determinations on a biotite paraschist and on a tonalitic orthogneiss of the Yaminué Complex, and re-evaluate this complex in the broader context of the tectonic evolution of the Patagonia composite terrane. In the metasedimentary unit （msuYC）, the youngest detrital zircon dated at 318 ± 5 Ma （Mississippian/Pennsylvanian boundary） indicates a Pennsylvanian （or younger） depositional age. The three main age populations peak at 474, 454 and 374 Ma. Preliminary Hf isotope data for two detrital zircons （447 and 655 Ma） yielded ε（Hf） values of -0.32 and 0.48, indicating that their primary sources contained small amounts of recycled crustal components （of Calymmian age; TDM 1.56 Ga）. Zircons from the orthogneiss （miuYC; intrusive into msuYC） show a crystallization age of 261.3 - 2.7 Ma （Capitanian; late middle Permian） which is broadly coeval with deformation, and Neoarchean-Paleoproterozoic inheritance. Meaningful core-rim relationship between Neoarchean zircon cores and late Permian rims is well defined, indicating the occurrence of Archean crust in this sector of Patagonia. Hf TDM of Permian zircons is mainly Meso-Paleoarchean （2.97-3.35 Ga）, with highly negative e（Hf） values （ca, -33）. Hf TDM of inherited Neoarchean zircon cores is also Meso-Paleoarchean （3.14-3.45 Ga） but more juvenile （ε（Hf） = -0.3）. Hf isotopes reinforce the presence of unexposed ancient crust in this area. Combining geological and isotope data, as well as geophysical models, we identify the Yaminué Complex within the La Esperanza-Yaminué crustal block flanked by two other, distinct crustal blocks： the Eastern block which forms part of the Patagonia terrane sensu stricto, located in the eastern Patagonian region, and the Western block forming part of the Southern Patagonia terrane. Their origins and timing of amalgamation to form the Patagonia composite terrane are also discussed.

Geochemistry,geochronology and Hf isotope of granitoids in the northern Alxa region:Implications for the Late Paleozoic tectonic evolution of the Central Asian Orogenic Belt

The tectonic setting of the northern Alxa region during the Late Paleozoic is highly controversial.The key to resolve this controversy is to recognize the Late Paleozoic magmatic processes in the northern Alxa.In this paper,we present new zircon U-Pb ages,Hf-isotopic compositions and whole-rock geochemical data of four granitoids along the Zhusileng-Hangwula Tectonic Belt in the northern Alxa region that could provide critical information about the tectonic evolution of this region.The zircon U-Pb data could be grouped as two phases:Late Devonian granite and diorite(ca.373-360 Ma),and Late Carboniferous granodiorite(ca.318 Ma).The Late Devonian granites and diorites are metaluminous to slightly peraluminous,with A/CNK and A/NK ratios of 0.90-1.11 and0.95-2.19,respectively.The Late Devonian diorites are characterized by high MgO,Cr and Ni contents and MgO#values,together with variableεHf(t)values from-1.0 to+1.3 and old TDM2 ages varied from 1283 Ma to 1426 Ma,indicating the primary magma was potentially derived from magma mixing of depleted mantle with Mesoproterozoic continental crust.Even though the Late Devonian granites yielded most positive and minor negative eHf(t)values between-1.1 to+5.7(three grains are negative)with two-stage model ages(TDM2)of 1003-1438 Ma,they display low MgO,Cr and Ni contents and MgO#values,suggesting that they were mainly derived from juvenile crustal materials,mixed with a small amount of ancient crust.The Late Carboniferous granitoids are metaluminous and medium-K calc-alkaline series,with A/CNK and A/NK ratios ranging from 0.88 to 0.95 and1.75 to 1.90,respectively.These rocks were potentially derived from juvenile crustal materials mixed with depleted mantle,as evidenced by their highεHf(t)values(+11.6 to+14.1)and young TDM2 ages(427 Ma to 586 Ma),as well as high Mg#values,and MgO,Ni and Cr contents.Our data,along with available sedimentary evidence and previous researches,indicate that the Late Devonian and Late Carboniferous rocks are arc-related granitoids under the subduction setting.The identification of arc-related granitoids in the northern Alxa region not only reveals the Late Paleozoic magmatic process in response to the subduction of Paleo Asian Ocean,but also provide significant constrains to the tectonic evolution of the Central Asian Orogenic Belt.

Geochronology, Geochemistry and Sr-Nd-Pb-Hf Isotopes of No. I Complex from the Shitoukengde Ni–Cu Sulfide Deposit in the Eastern Kunlun Orogen, Western China: Implications for the Magmatic Source, Geodynamic Setting and Genesis

The Shitoukengde Ni-Cu deposit, located in the Eastern Kunlun Orogen, comprises three mafic-ultramafic complexes, with the No. I complex hosting six Ni-Cu orebodies found recently. The deposit is hosted in the small ultramafic bodies intruding Proterozoic metamorphic rocks. Complexes at Shitoukengde contain all kinds of mafic-ultramafic rocks, and olivine websterite and pyroxene peridotite are the most important Ni-Cu-hosted rocks. Zircon U-Pb dating suggests that the Shitoukengde Ni-Cu deposit formed in late Silurian （426-422 Ma）, and their zircons have ~Hf（t） values of-9.4 to 5.9 with the older TDMm ages （0.80-1.42 Ga）. Mafic-ultramafic rocks from the No. I complex show the similar rare earth and trace element patterns, which are enriched in light rare earth elements and large ion iithophile elements （e.g., K, Rb, Th） and depleted in heavy rare earth elements and high field strength elements （e.g., Ta, Nb, Zr, Ti）. Sulfides from the deposit have the slightly higher ~34S values of 1.9-4.3%o than the mantle （0 ~ 2%o）. The major and trace element characteristics, and Sr-Nd-Pb and Hf, S isotopes indicate that their parental magmas originated from a metasomatised, asthenospheric mantle source which had previously been modified by subduction-related fluids, and experienced significant crustal contamination both in the magma chamber and during ascent triggering S oversaturation by addition of S and Si, that resulted in the deposition and enrichment of sulfides. Combined with the tectonic evolution, we suggest that the Shitoukengde Ni-Cu deposit formed in the post-collisional, extensional regime related to the subducted oceanic slab break-off after the Wanbaogou oceanic basalt plateau collaged northward to the Qaidam Block in late Silurian.

Zircon U-Pb chronology, geochemistry and Lu-Hf isotope constraints on genesis of monzonitic granite from Harizha area in eastern section of East Kunlun region

The Harizha area is located in the eastern section of East Kunlun orogenic belt. The petrology, the zircon LA-ICP-MS U-Pb chronology and the petrogeochemistry of the monzonitic granite in the area were studied. The results show that the formation age of the monzonitic granite in the Harizha area is 237.4±1.4 Ma, which belongs to Middle Triassic. The content of SiO_2 in the rock is 61.29%--63.30%,(K_2O+Na_2O) is 5.41%--5.84%, Al_2O_3 is 14.80%--15.99%, the Mg~# value is 46.33--48.33, and the aluminum saturation index A/CNK is 0.87--0.91. Therefore, it can be concluded that the rock belongs to the I-type granite of quasi-aluminous high potassium Ca-alkaline series. The total REE content of the rock is 118.82×10^(-6)--164.54×10^(-6), and the La/Yb ratios range from 7.77 to 10.13. Meanwhile, the rock does not show obvious Eu anomalies(δEu=0.61--0.75) and is characterized by enrichment of LREE and LILE such as Rb and K, relative depletion of HREE and HFSE such as Nb, Ti and Ta. Zircon Hf isotopic dating exhibits that the average ε_(Hf)(t) is-2.4 and the average of two-stage model age(t_(DM2)) is 1 417 Ma, indicating that the source rocks are mainly crustal materials. It can be concluded from research findings and regional geological structural analysis that the monzonitic granite in the Harizha area originated from partial melting of the Mesoproterozoic mafic lower crust in the later stage of the subduction of the Paleo-Tethys Ocean.

胶西北地区钻孔揭露隐伏郭家岭期花岗岩的地球化学、锆石U-Pb年龄及Lu-Hf同位素特征

胶东矿集区是世界著名的金矿资源基地,截止2019年累计查明金资源储量达5000余吨,区内广泛分布的中生代花岗岩与金矿有着密切的时间、空间关系。前人利用高精度重磁、CSAMT等物探方法解译,认为焦家成矿带、招平成矿带深部可能有隐伏郭家岭期花岗岩存在。本文通过近几年勘查施工钻孔揭露的胶西北三条主要金成矿带隐伏郭家岭期花岗岩,表现为较高的Na2O+K2O(5.80%~11.27%)、Al2O3(14.01%~16.36%)含量,高的Sr含量(632×10^(-6)~1224×10^(-6))、Ba含量(1641×10^(-6)~3512×10^(-6))和高的Sr/Y比值(185~435),CaO(1.25%~2.44%)、TiO2(0.08%~0.23%)、MgO(0.17%~0.84%)、全Fe2O3(0.67%~1.94%)、Rb(46×10^(-6)~110×10^(-6)),属于高钾钙碱性-钙碱性系列。岩石的A/CNK为1.01~1.06,投点于弱过铝质区域。稀土配分模式为轻稀土富集,重稀土亏损的右倾模式,具有正铕异常,弱负铈异常。微量元素特征显示富集Ba、K、Rb、Sr、Pb等大离子亲石元素(LILE),亏损Ta、Nb、P、Ti等高场强元素(HSFE)。三山岛北部海域斑状中粒二长花岗岩和焦家金矿带斑状中粒二长花岗岩锆石SHRIMP U-Pb测年结果为126.10±1.00 Ma和127.59±0.85 Ma。岩浆锆石εHf(t)值为-27.94~-18.59,Hf同位素二阶段模式年龄tDM2为2.95~2.36 Ga(均值2.47 Ga),样品分布于球粒陨石演化线之下壳源区域,岩浆源区与郭家岭岩体落点一致。结合岩石地球化学认为,钻孔揭露的郭家岭期花岗岩既具有地壳物质来源特征,又有地幔物质的加入,是陆壳酸性岩浆与幔源基性岩浆混合作用的结果。通过已开展的钻探工程及脉岩提供的信息,认为胶西北三条主要控矿断裂带下盘有郭家岭期花岗岩存在,同时对胶西北三条主要控矿断裂带、栖霞一带、乳山市周围深部可能存在郭家岭期花岗岩范围进行推测。这对整个胶东地区郭家岭期花岗岩的分布格局有一个全新的认识,为进一步研究郭家岭期花岗岩与金矿成矿的内在联系提供基础。

Zircon U-Pb and Lu-Hf isotope constraints on Archean crustal evolution in Southeastern Guyana Shield

The southeastern Guyana Shield,northeast Amazonian Craton,in the north of Brazil,is part of a widespread orogenic belt developed during the Transamazonian orogenic cycle(2.26-1.95 Ga)that includes a large Archean continental landmass strongly reworked during the Transamazonian orogeny,named Amapa Block.It consists mainly of a high-grade metamorphic granulitic-migmatitic-gneiss complex,of Meso-to Neoarchean age and Rhyacian granitoids and supracrustal sequences.For the first time,coupled U-Pb and Lu-Hf isotope data were obtained on zircon by LA-ICP-MS from five tectono-stratigraphic units of the Archean basement and one Paleoproterozoic intrusive rock,in order to investigate the main episodes of crustal growth and reworking.Whole-rock Sm-Nd isotope data were compared to the zircon Lu-Hf data.Three main magmatic episodes were defined by U-Pb zircon dating,two in the Mesoarchean(~3.19 Ga and 2.85 Ga)and one in the Neoarchean(~2.69-2.65 Ga).SubchondriticεHf(t)values obtained for almost all investigated units indicate that crustal reworking processes were predominant during the formation of rocks that today make up the Amapa Block.Hf-TDMC model ages,ranging from2.99 Ga to 3.97 Ga,indicate that at least two important periods of mantle extraction and continental crust formation occurred during the Archean in southeastern Guyana Shield,an older one in the Eoarchean(~4.0 Ga)and a younger one in the Mesoarchean(~3.0-3.1 Ga).The latter is recognized as an important period of crustal accretion worldwide.The recognition of an Eoarchean episode to the southeastern most part of the Guyana Shield is unprecedented and was not recorded by whole-rock Sm-Nd data,which were restricted to the Meso-Paleoarchean(2.83 Ga to 3.51 Ga).This finding reveals t hat continental crust generation in the Amazonian Craton began at least 500 Ma earlier than previously suggested by the SmNd systematics.

Episodic crustal growth and reworking at the southeastern margin of the North China Craton: evidence from zircon U–Pb and Lu–Hf isotopes of Archean tonalite–trondhjemite–granodiorite gneisses in the Bengbu-Wuhe area

The cratonization history of the North China Craton(NCC)and the nature of tectonothermal events are still highly controversial.Tonalite-trondhjemite-granodiorite(TTG)gneisses,as the dominant lithological assemblages in Archean metamorphic terranes,can provide significant clues to the magmatic and metamorphic evolution of Precambrian crust.This study presents zircon laser-ablation inductively-coupled-plasma mass spectrometry U–Pb ages,trace-element,and in-situ LA-MC-ICPMS zircon Hf isotope data for the TTG gneisses from the Bengbu-Wuhe area on the southeastern margin of the NCC.Cathodoluminescence images and trace elements indicated that magmatic zircons display the characteristics of euhedral-subhedral crystals with oscillatory growth zoning structures,high RREE contents,marked Ce positive anomalies,and Pr–Eu negative anomalies.The metamorphic zircons display the spherical-oval crystals with distinct core-rim structures,high and homogeneous luminescent intensity,lower RREE,Nb,Ta,Hf contents,relative flat REE patterns,weak Ce positive anomalies,and Pr-Eu negative anomalies.The Ti–in–zircon geothermometer data indicate that the crystallization temperature of the TTG gneiss ranged from 754 to 868℃.Zircon U–Pb ages indicate that the TTG gneisses formed at 2.79–2.77 Ga and 2.50 Ga and underwent metamorphism at 2.57–2.52 Ga.The Hf isotopic data indicate that the magmatic zircons exhibit high,positive eHf(t)values close to those of the coeval depleted mantle,whereas the metamorphic zircons exhibit negative or nil eHf(t)values.This implies that the TTG gneisses were derived from the partial melting of the~2.9–2.6 Ga juvenile crustal sources mixed with~3.0–2.8 Ga ancient crustal materials.Combined with the regional tectonic evolution,we propose that the metamorphic basement at the southeastern margin of the NCC underwent episodic crustal growth at~2.7 and~2.5 Ga and subsequently underwent crustal reworking or re-melting of the ancient crust during the Neoarchean.The Neoarchean TTG gneisses might have been derived from the partial melting of lower crustal materials related to plate subduction.

First Report of Zircon U-Pb Chronology and Hf Isotope Evidence of the Heluositan Group Granulite in West Kunlun, Xinjiang

Objective As the uplift belt on the southem margin of the Tarim block, the Tiekelike block consists mainly of a set of Precambrian metamorphic rocks with granulite and gneisses. The Heluositan group-complex is the most ancient rock series in the area, and is a key area for studying the formation and evolution of the Precambrian basement of the Tarim craton. LA-ICP-MS zircon U-Pb dating and Hf isotopic analysis of granulite in this area provide new evidence for revealing the formation and evolution of the Precambrian basement in the Tarim Basin.

Influence of Isotope Substitution Helium Atom on Partial Cross Sections in He-HF Collisions

在我们的以前的研究开发的靠近联合的方程和各向异性的潜力被用于 HF-3He (4He， 6He， 8He， 10He ) 碰撞系统，和在 40 兆电子伏的事件精力的部分生气的节(PCS ) 被计算。由分析这些 PCS 的差别，有部分波浪数字的增加，并且与同位素替换氦原子的团的变化的 PCS 的变化规则被获得。结果证明刺激 PCS 为碰撞精力和每这里考虑的系统比有弹性的 PCS 快收敛。另外，刺激 PCS 为高度激动的状态更快收敛。尾巴效果在有弹性的散布和低激动的状态然而并非处于高度激动的状态仅仅是在场的。随同位素替换氦原子的团的增加，集成橡皮的速度，全部无弹性，并且 state-to-state 刺激 PCS 慢下来，并且这些 PCS 的最大值经历一个常规变化。

赣南铁山垅钨矿田花岗斑岩地球化学特征、锆石U-Pb年龄及Hf同位素特征

赣南铁山垅钨矿田位于南岭钨锡多金属成矿带东段,已探获黑钨矿资源量超10万吨。铁山垅复式岩体包括主体似斑状黑云母花岗岩和补体细粒二云母花岗岩两部分,花岗斑岩呈脉状分布。矿田内花岗岩具有相似的地球化学特征,都属过铝质高钾钙碱性花岗岩类,表现出高硅、富铝、富碱、高钾、富成矿元素(W、Sn、Cu、Mo)和亏损Ba、Sr、Ti、P、REE、Eu,稀土配分曲线呈典型的“海鸥式”分布和M型四分组效应等特征。利用LA-ICP-MS锆石U-Pb定年方法获得花岗斑岩^(206)Pb/^(238)U年龄为146.7±0.5 Ma(MSDW=0.5),成岩时代属晚侏罗世。锆石的n(^(176)Lu)/n(^(177)Hf)=0.000973~0.001989,f_(Lu/Hf)=-0.97~-0.94,ε_(Hf)(t)=-17.9~-10.3,二阶段模式年龄(TDM2)为1.86~2.33 Ga,显示原岩为古元古代地壳。综合分析认为,铁山垅矿田岩浆活动可划分为170~155 Ma、155~150 Ma、150~145 Ma三个阶段,钨锡矿成矿主要集中在第二阶段,且第三阶段花岗斑岩与铜多金属矿成矿关系密切,推测铜岭矿区深部具有较大的找矿前景。