Energy transfer among the co-doped activators is an efficient route to achieve color-tunable emission in inorganic phosphors.Herein,photoluminescence tuning from blue to cyan has been achieved in the Lu2MgAl4 SiO12;Eu...Energy transfer among the co-doped activators is an efficient route to achieve color-tunable emission in inorganic phosphors.Herein,photoluminescence tuning from blue to cyan has been achieved in the Lu2MgAl4 SiO12;Eu^2+,Ce^3+phosphors by varying the Ce^3+concentration with a fixed Eu^2+content.With the further introduction of a Mn^2+-Si^4+couple into the host lattice,the emission color can be tuned to red through the energy transfer of Eu^2+and Mn^2+.The luminescence properties and the energy transfer mechanism were studied in detail.The energy transfer from Eu^2+to Ce^3+is certified as a dipolequadrupole interaction with the energy transfer efficiency of 41.4%and Eu^2+to Mn^2+belongs to a dipole-dipole interaction with the energy transfer efficiency of 94.3%.The results imply that this singlephased Lu2MgAl4 SiO12:Eu^2+,Ce^3+,Mn^2+phosphor has a potential prospect for application in near-UV chip pumped white light emitting diodes.展开更多
基金Project supported by the National Natural Science Foundation of China(51972118,51722202,51572023)Natural Science Foundation of Beijing(2172036)Fundamental Research Funds for the Central Universities(FRF-TP-18-002C1)。
文摘Energy transfer among the co-doped activators is an efficient route to achieve color-tunable emission in inorganic phosphors.Herein,photoluminescence tuning from blue to cyan has been achieved in the Lu2MgAl4 SiO12;Eu^2+,Ce^3+phosphors by varying the Ce^3+concentration with a fixed Eu^2+content.With the further introduction of a Mn^2+-Si^4+couple into the host lattice,the emission color can be tuned to red through the energy transfer of Eu^2+and Mn^2+.The luminescence properties and the energy transfer mechanism were studied in detail.The energy transfer from Eu^2+to Ce^3+is certified as a dipolequadrupole interaction with the energy transfer efficiency of 41.4%and Eu^2+to Mn^2+belongs to a dipole-dipole interaction with the energy transfer efficiency of 94.3%.The results imply that this singlephased Lu2MgAl4 SiO12:Eu^2+,Ce^3+,Mn^2+phosphor has a potential prospect for application in near-UV chip pumped white light emitting diodes.
