Two novel zinc（Ⅱ） coordination polymers, [Zn2（BCB）（CH3OH）（μ3-OH）]n（1） and {[Zn2（BCB）（μ3-OH）（H2O）2]·CH3OH}n （2）, have been constructed from 3,5-bis（2-carboxylphenoxy）benzoic acid（H3BCB） an...Two novel zinc（Ⅱ） coordination polymers, [Zn2（BCB）（CH3OH）（μ3-OH）]n（1） and {[Zn2（BCB）（μ3-OH）（H2O）2]·CH3OH}n （2）, have been constructed from 3,5-bis（2-carboxylphenoxy）benzoic acid（H3BCB） and characterized by elemental analysis（EA）, IR, powder X-ray diffraction（PXRD）, and thermogravimetric（TG） analyses. Structural analysis reveals that complexes 1 and 2 are both 1D polymeric chains with unprecedented tetranuclear {Zn4（COO）4（μ3-OH）2} clusters, which were further expanded into a 2D structure. Fluorescence measurements show that 1 and 2 have highly selective and sensitive detection of nitrobenzene.展开更多
A phenoxazine based molecule termed SP has been synthesized and used as selective sensor for halogenated solvents. This molecule shows selective fast response towards halogenated solvent via naked-eye detectable chrom...A phenoxazine based molecule termed SP has been synthesized and used as selective sensor for halogenated solvents. This molecule shows selective fast response towards halogenated solvent via naked-eye detectable chromism. SP shows colorless solution when dissolved in most solvents initially but changes to blue color in chloroform under UV irradiation(λ = 365 nm) within 5 s. The luminescence spectra of SP in halogenated solvent show a large bathochromic shift(> 100 nm) with 60-fold enhanced emission intensity compared to that in halogen-free solvents. It is also worth mentioning that the photoinduced reaction between SP molecule and the halogenated solvents occurred. Based on the detailed NMR, fluorescence and mass spectra, the possible radical reaction mechanism was proposed.Different from the majority of solvatochromic sensors that based on the polarity of solvents for detection of halogenated solvents, our sensor system worked in a special展开更多
基金supported by the Foundation of State Key Laboratory of Coal Conversion(No.J17-18-611)the National Natural Science Foundation of China(No.21676258)
文摘Two novel zinc（Ⅱ） coordination polymers, [Zn2（BCB）（CH3OH）（μ3-OH）]n（1） and {[Zn2（BCB）（μ3-OH）（H2O）2]·CH3OH}n （2）, have been constructed from 3,5-bis（2-carboxylphenoxy）benzoic acid（H3BCB） and characterized by elemental analysis（EA）, IR, powder X-ray diffraction（PXRD）, and thermogravimetric（TG） analyses. Structural analysis reveals that complexes 1 and 2 are both 1D polymeric chains with unprecedented tetranuclear {Zn4（COO）4（μ3-OH）2} clusters, which were further expanded into a 2D structure. Fluorescence measurements show that 1 and 2 have highly selective and sensitive detection of nitrobenzene.
基金the Natural Science Foundation of Shandong Province (Nos. BS2014CL042, ZR2014EEP021, ZR2017MB033)the Key Research and Development Program of Shandong Province, China (Nos. 2016GSF116014 and 2017CXGC1113)+1 种基金the Start-up Grant of Shandong Jiaotong University and the National Undergraduate Innovation Training Program (No. 201611510109)the financial support from the government of Shandong Province for visiting abroad
文摘A phenoxazine based molecule termed SP has been synthesized and used as selective sensor for halogenated solvents. This molecule shows selective fast response towards halogenated solvent via naked-eye detectable chromism. SP shows colorless solution when dissolved in most solvents initially but changes to blue color in chloroform under UV irradiation(λ = 365 nm) within 5 s. The luminescence spectra of SP in halogenated solvent show a large bathochromic shift(> 100 nm) with 60-fold enhanced emission intensity compared to that in halogen-free solvents. It is also worth mentioning that the photoinduced reaction between SP molecule and the halogenated solvents occurred. Based on the detailed NMR, fluorescence and mass spectra, the possible radical reaction mechanism was proposed.Different from the majority of solvatochromic sensors that based on the polarity of solvents for detection of halogenated solvents, our sensor system worked in a special
