We describe the new mineral species titanium, ideally Ti, found in the podiform chromitites of the Luobusha ophiolite in Tibet, People's Republic of China. The irregular crystals range from 0.1 to 0.6 mm in diameter ...We describe the new mineral species titanium, ideally Ti, found in the podiform chromitites of the Luobusha ophiolite in Tibet, People's Republic of China. The irregular crystals range from 0.1 to 0.6 mm in diameter and form an intergrowth with coesite and kyanite. Titanium is silver grey in colour, the luster is metallic, it is opaque, the streak is grayish black, and it is non-fluorescent. The mineral is malleable, has a rough to hackly fracture and has no apparent cleavage. The estimated Mohs hardness is 4, and the calculated density is 4.503 g/cm3. The composition is Ti 99.23-100.00 wt%. The mineral is hexagonal, space group P6flmmc. Unit-cell parameters are a 2.950 (2) ~, c 4.686 (1) A,V 35.32 (5) A3, Z = 2. The five strongest powder diffraction lines [d in A (hkl) (I/I0)] are: 2.569 (010) (32), 2.254(011) (100), 1.730 (012) (16), 1.478 (110) (21), and 0.9464 (121) (8). The species and name were approved by the CNMNC (IMA 2010-044).展开更多
A new mineral species, named naquite(FeSi), is found in the podiform chromitites of the Luobusha ophiolite in Qusong County, Tibet, China. The detailed composition is Fe 65.65, Si 32.57 and Al 1.78 wt%. The mineral ...A new mineral species, named naquite(FeSi), is found in the podiform chromitites of the Luobusha ophiolite in Qusong County, Tibet, China. The detailed composition is Fe 65.65, Si 32.57 and Al 1.78 wt%. The mineral is cubic, space group P213. The irregular crystals range from 15 to 50 μm in diameter and form an intergrowth with luobusaite. Naquite is steel grey in color, opaque, with a metallic lustre and gives a grayish-black streak. The mineral is brittle, has a conchoidal fracture and no apparent cleavage. The estimated Mohs hardness is 6.5, and the calculated density is 6.128 g/cm3. Unit-cell parameters are a 4.486 (4) A, V 90.28 (6)A^3, Z=4. The five strongest powder diffraction lines [d inA(hkl) (I/I0)] are: 3.1742 (110) (40), 2.5917(111) (43), 2.0076 (210) (100), 1.8307 (211) (65), and 1.1990 (321) (36). Originally called 'fersilicite', the species and new name have now been approved by the CNMNC (IMA 2010-010).展开更多
Diamond was found in podiform chromitites of ophiolite and harzburgite from Luobusha, Tibet. There are silicate inclusions in some diamond grains from this area. In the present work, the CCD (charge coupled detector) ...Diamond was found in podiform chromitites of ophiolite and harzburgite from Luobusha, Tibet. There are silicate inclusions in some diamond grains from this area. In the present work, the CCD (charge coupled detector) technology of X-ray powder diffraction was applied to the study of the inclusion in diamond from the ophiolite of Tibet. Diffraction patterns are obtained even though the inclusion is only 20 μm in crystal size. The results show that the inclusion in diamond consists of talc and clinochrysotile. Therefore, it is clear that the diamond from the ophiolite of Luobusha, Tibet, is natural diamond rather than a synthetic one.展开更多
讨论了在温度为300 K 条件下西藏罗布莎铬铁矿穆斯堡尔谱的特征。根据谱形将全谱分解成三套双峰,其中第Ⅰ、第Ⅱ套是由四面体中的Fe2+ 产生的,第Ⅲ套是由八面体中Fe3+ 产生的;总结出了中心位移值(δ)与铬铁矿平衡压力以及四级分裂值(QS...讨论了在温度为300 K 条件下西藏罗布莎铬铁矿穆斯堡尔谱的特征。根据谱形将全谱分解成三套双峰,其中第Ⅰ、第Ⅱ套是由四面体中的Fe2+ 产生的,第Ⅲ套是由八面体中Fe3+ 产生的;总结出了中心位移值(δ)与铬铁矿平衡压力以及四级分裂值(QS)、铬铁矿平衡温度之间的关系;探讨了铬铁矿的成因。研究结果表明,铬铁矿穆斯堡尔谱的两个重要参数δ和QS在铬铁矿成矿预测中可以作为矿物学标型特征来推测矿床的成因,参数的质量达到了铬铁矿床成矿预测之要求。展开更多
Yarlongite occurs in ophiolitic chromitite at the Luobusha mine (29°5′N 92°5′E, about 200 km ESE of Lhasa), Qusum County, Shannan Prefecture, Tibet Autonomous Region, People's Republic of China. Associa...Yarlongite occurs in ophiolitic chromitite at the Luobusha mine (29°5′N 92°5′E, about 200 km ESE of Lhasa), Qusum County, Shannan Prefecture, Tibet Autonomous Region, People's Republic of China. Associated minerals are: diamond, moissanite, wiistite, iridium ("osmiridium"), osmium ("iridosmine"), periclase, chromite, native iron, native nickel, native chromium, forsterite, Cr-rich diopside, intermetallic compounds Ni-Fe-Cr, Ni-Cr, Cr-C, etc. Yarlongite and its associated minerals were handpicked from a large heavy mineral sample of chromitite. The metallic carbides associated with yarlongite are cohenite, tongbaite, khamrabaevite and qusongite (IMA2007-034). Yarlongite occurs as irregular grains, with a size between 0.02 and 0.06 mm, steel-grey colour, H Mohs: 5^1/2-6. Tenacity: brittle. Cleavage: (0 0 1) perfect. Fracture: conchoidal. Chemical formula: (Cr4Fe4Ni)29C4, or (Cr,Fe,Ni)29C4, Crystal system: Hexagonal, Space Group: P63/mc, a = 18.839(2) A, c = 4.4960 (9) A, V = 745.7(2) A^3, Z = 6, Density (calc.) = 7.19 g/cm3 (with simplified formula). Yariongite has been approved as a new mineral by the CNMNC (IMA2007-035). Holotype material is deposited at the Geological Museum of China (No. Ml1650).展开更多
(Fe4Cr4Ni)9C4 is a metal carbide mineral formed by combination of Fe, Cr and Ni with C. It occurs in a chromite deposit in the Luobusha ophiolite, Tibet. Based on the determina- tion of its crystal structure, the empi...(Fe4Cr4Ni)9C4 is a metal carbide mineral formed by combination of Fe, Cr and Ni with C. It occurs in a chromite deposit in the Luobusha ophiolite, Tibet. Based on the determina- tion of its crystal structure, the empirical formula is (Fe4.12Cr3.84Ni0.96)8.92C3.70 and the simplified formula is (Fe4Cr4Ni)4C9. The mineral is hexagonal with a = 1.38392(2) nm, c = 0.44690(9) nm, space group P63 m c, Z=6 and the calculated specific gravity Dx = 7.089 g/cm3. Fe, Cr and Ni occupy different crystallographic sites and their coordination numbers are approximately 12, forming an alternate stacking sequence of flat and puckered layers along the c axis. Some me- tallic atoms have a defect structure. The interatomic distances of Fe, Cr and Ni are 0.2525— 0.2666 nm, and the distances between Fe, Cr, Ni and C are 0.1893—0.2169 nm. The coordina- tion number of carbon is 6. It occurs in interstices of the metallic atoms Fe, Cr and Ni to form trigonal-prismatically coordinated polyhedra. These coordination polyhedra are linked with each other via shared corners or shared edges into a new type of metal carbide structure.展开更多
基金supported by the National Natural Science Foundation of China (40472025, 40620120098,40872043)
文摘We describe the new mineral species titanium, ideally Ti, found in the podiform chromitites of the Luobusha ophiolite in Tibet, People's Republic of China. The irregular crystals range from 0.1 to 0.6 mm in diameter and form an intergrowth with coesite and kyanite. Titanium is silver grey in colour, the luster is metallic, it is opaque, the streak is grayish black, and it is non-fluorescent. The mineral is malleable, has a rough to hackly fracture and has no apparent cleavage. The estimated Mohs hardness is 4, and the calculated density is 4.503 g/cm3. The composition is Ti 99.23-100.00 wt%. The mineral is hexagonal, space group P6flmmc. Unit-cell parameters are a 2.950 (2) ~, c 4.686 (1) A,V 35.32 (5) A3, Z = 2. The five strongest powder diffraction lines [d in A (hkl) (I/I0)] are: 2.569 (010) (32), 2.254(011) (100), 1.730 (012) (16), 1.478 (110) (21), and 0.9464 (121) (8). The species and name were approved by the CNMNC (IMA 2010-044).
基金supported financially by the National Natural Science Foundation of China (Grant No. 40472025, 40620120098,40872043)
文摘A new mineral species, named naquite(FeSi), is found in the podiform chromitites of the Luobusha ophiolite in Qusong County, Tibet, China. The detailed composition is Fe 65.65, Si 32.57 and Al 1.78 wt%. The mineral is cubic, space group P213. The irregular crystals range from 15 to 50 μm in diameter and form an intergrowth with luobusaite. Naquite is steel grey in color, opaque, with a metallic lustre and gives a grayish-black streak. The mineral is brittle, has a conchoidal fracture and no apparent cleavage. The estimated Mohs hardness is 6.5, and the calculated density is 6.128 g/cm3. Unit-cell parameters are a 4.486 (4) A, V 90.28 (6)A^3, Z=4. The five strongest powder diffraction lines [d inA(hkl) (I/I0)] are: 3.1742 (110) (40), 2.5917(111) (43), 2.0076 (210) (100), 1.8307 (211) (65), and 1.1990 (321) (36). Originally called 'fersilicite', the species and new name have now been approved by the CNMNC (IMA 2010-010).
基金supported by the National Natural Science Foundation of China grants 4997203 and 49872019.
文摘Diamond was found in podiform chromitites of ophiolite and harzburgite from Luobusha, Tibet. There are silicate inclusions in some diamond grains from this area. In the present work, the CCD (charge coupled detector) technology of X-ray powder diffraction was applied to the study of the inclusion in diamond from the ophiolite of Tibet. Diffraction patterns are obtained even though the inclusion is only 20 μm in crystal size. The results show that the inclusion in diamond consists of talc and clinochrysotile. Therefore, it is clear that the diamond from the ophiolite of Luobusha, Tibet, is natural diamond rather than a synthetic one.
文摘讨论了在温度为300 K 条件下西藏罗布莎铬铁矿穆斯堡尔谱的特征。根据谱形将全谱分解成三套双峰,其中第Ⅰ、第Ⅱ套是由四面体中的Fe2+ 产生的,第Ⅲ套是由八面体中Fe3+ 产生的;总结出了中心位移值(δ)与铬铁矿平衡压力以及四级分裂值(QS)、铬铁矿平衡温度之间的关系;探讨了铬铁矿的成因。研究结果表明,铬铁矿穆斯堡尔谱的两个重要参数δ和QS在铬铁矿成矿预测中可以作为矿物学标型特征来推测矿床的成因,参数的质量达到了铬铁矿床成矿预测之要求。
基金supported by the National Natural Science Foundation of China(Grant 40472025,40672030 and 40872043).
文摘Yarlongite occurs in ophiolitic chromitite at the Luobusha mine (29°5′N 92°5′E, about 200 km ESE of Lhasa), Qusum County, Shannan Prefecture, Tibet Autonomous Region, People's Republic of China. Associated minerals are: diamond, moissanite, wiistite, iridium ("osmiridium"), osmium ("iridosmine"), periclase, chromite, native iron, native nickel, native chromium, forsterite, Cr-rich diopside, intermetallic compounds Ni-Fe-Cr, Ni-Cr, Cr-C, etc. Yarlongite and its associated minerals were handpicked from a large heavy mineral sample of chromitite. The metallic carbides associated with yarlongite are cohenite, tongbaite, khamrabaevite and qusongite (IMA2007-034). Yarlongite occurs as irregular grains, with a size between 0.02 and 0.06 mm, steel-grey colour, H Mohs: 5^1/2-6. Tenacity: brittle. Cleavage: (0 0 1) perfect. Fracture: conchoidal. Chemical formula: (Cr4Fe4Ni)29C4, or (Cr,Fe,Ni)29C4, Crystal system: Hexagonal, Space Group: P63/mc, a = 18.839(2) A, c = 4.4960 (9) A, V = 745.7(2) A^3, Z = 6, Density (calc.) = 7.19 g/cm3 (with simplified formula). Yariongite has been approved as a new mineral by the CNMNC (IMA2007-035). Holotype material is deposited at the Geological Museum of China (No. Ml1650).
基金supported by the National Natural Science Foundati on of China(Grant Nos.4024201 3 and 40472075)
文摘(Fe4Cr4Ni)9C4 is a metal carbide mineral formed by combination of Fe, Cr and Ni with C. It occurs in a chromite deposit in the Luobusha ophiolite, Tibet. Based on the determina- tion of its crystal structure, the empirical formula is (Fe4.12Cr3.84Ni0.96)8.92C3.70 and the simplified formula is (Fe4Cr4Ni)4C9. The mineral is hexagonal with a = 1.38392(2) nm, c = 0.44690(9) nm, space group P63 m c, Z=6 and the calculated specific gravity Dx = 7.089 g/cm3. Fe, Cr and Ni occupy different crystallographic sites and their coordination numbers are approximately 12, forming an alternate stacking sequence of flat and puckered layers along the c axis. Some me- tallic atoms have a defect structure. The interatomic distances of Fe, Cr and Ni are 0.2525— 0.2666 nm, and the distances between Fe, Cr, Ni and C are 0.1893—0.2169 nm. The coordina- tion number of carbon is 6. It occurs in interstices of the metallic atoms Fe, Cr and Ni to form trigonal-prismatically coordinated polyhedra. These coordination polyhedra are linked with each other via shared corners or shared edges into a new type of metal carbide structure.