Al2O3 powders with different morphologies,namely fibrous,sheet-like,and spherical,were prepared by the hydrothermal-thermolysis method.Subsequently,polycrystalline,transparent cerium doped lutetium aluminum garnet(Lu...Al2O3 powders with different morphologies,namely fibrous,sheet-like,and spherical,were prepared by the hydrothermal-thermolysis method.Subsequently,polycrystalline,transparent cerium doped lutetium aluminum garnet(Lu3Al5O(12):Ce^3+)green phosphors were synthesized by high temperature solidstate method using commercial lutetium(III)oxide,cerium(III)oxide,and as-prepared Al2O3 powders with different morphologies.The phases,morphologies,and photoluminescent properties of the prepared phosphors were investigated by X-ray diffraction(XRD),scanning electron microscopy(SEM),and photoluminescence spectroscopy(PL).Moreover,the influences of the morphologies ofα-Al2O3 on the types of crystal structure,morphologies,and photoluminescent properties of LuAG:Ce^3+green phosphors were investigated.The results indicated that the morphologies and particle sizes of theα-Al2O3 powders could be controlled by the additives and parameters.Notably,the sphericalα-Al2O3 powders with good dispersibility were found to be the excellent base materials of LuAG:Ce^3+green phosphors for white light emitting diodes.展开更多
基金Funded by Shan’xi Educational Committee(No.17JK0395)
文摘Al2O3 powders with different morphologies,namely fibrous,sheet-like,and spherical,were prepared by the hydrothermal-thermolysis method.Subsequently,polycrystalline,transparent cerium doped lutetium aluminum garnet(Lu3Al5O(12):Ce^3+)green phosphors were synthesized by high temperature solidstate method using commercial lutetium(III)oxide,cerium(III)oxide,and as-prepared Al2O3 powders with different morphologies.The phases,morphologies,and photoluminescent properties of the prepared phosphors were investigated by X-ray diffraction(XRD),scanning electron microscopy(SEM),and photoluminescence spectroscopy(PL).Moreover,the influences of the morphologies ofα-Al2O3 on the types of crystal structure,morphologies,and photoluminescent properties of LuAG:Ce^3+green phosphors were investigated.The results indicated that the morphologies and particle sizes of theα-Al2O3 powders could be controlled by the additives and parameters.Notably,the sphericalα-Al2O3 powders with good dispersibility were found to be the excellent base materials of LuAG:Ce^3+green phosphors for white light emitting diodes.