Although great advancements have been successfully achieved in ligand-assisted reprecipitation strategy(LARP)towards lead halide perovskite nano crystals(NCs)syn thesis,it still remains challe nging to develop bright ...Although great advancements have been successfully achieved in ligand-assisted reprecipitation strategy(LARP)towards lead halide perovskite nano crystals(NCs)syn thesis,it still remains challe nging to develop bright and stable iodide-based perovskite NC via facile LARP.Herein,striki ngly bright MAPbl3 NCs with photoluminesce nee qua ntum yield(PLQY)as high as 79%are synthesized via replacing the raw material(MAI and Pbh)with MAPbl3 crystal powder during LARP procedure.It has been found that crystal powder derived MAPbl3 NCs are more iodide-rich compared with that based on raw material,which is favorable to passivate the surface trap state.Accordingly,femtosecond transient absorption spectroscopies and space charge limited current measurements have corroborated that the trap density is much less in crystal powder resulted MAPbl3 NCs.Further analyses indicate stronger solvation with reduced precursor colloid size has been observed in crystal powder derived precursor solution probably due to the formation of MAPbl3-DMF.This work has provided a facile but valid method to enhance the photoluminesce nee of perovskite NC via modulati ng the beginning precursor solution.展开更多
基金The authors acknowledge the financial supports from the National Natural Science Foundation of China(No.21875288)the GDUPS(2016)and Fundamental Research Funds for the Central Universities.
文摘Although great advancements have been successfully achieved in ligand-assisted reprecipitation strategy(LARP)towards lead halide perovskite nano crystals(NCs)syn thesis,it still remains challe nging to develop bright and stable iodide-based perovskite NC via facile LARP.Herein,striki ngly bright MAPbl3 NCs with photoluminesce nee qua ntum yield(PLQY)as high as 79%are synthesized via replacing the raw material(MAI and Pbh)with MAPbl3 crystal powder during LARP procedure.It has been found that crystal powder derived MAPbl3 NCs are more iodide-rich compared with that based on raw material,which is favorable to passivate the surface trap state.Accordingly,femtosecond transient absorption spectroscopies and space charge limited current measurements have corroborated that the trap density is much less in crystal powder resulted MAPbl3 NCs.Further analyses indicate stronger solvation with reduced precursor colloid size has been observed in crystal powder derived precursor solution probably due to the formation of MAPbl3-DMF.This work has provided a facile but valid method to enhance the photoluminesce nee of perovskite NC via modulati ng the beginning precursor solution.
