Catalytic conversion and DFT analysis of post DDBD-catalysis system for degradation of toluene,ethyl acetate and acetone with different metal-oxides catalysts

A series of multiphase metal-oxide catalysts(MnOx/γ-Al_(2)O_(3),CuOx/γ-Al_(2)O_(3),FeO_(x/γ)-Al_(2)O_(3),CeO_(x)/γ-Al_(2)O_(3)and LaOx/γ-Al_(2)O_(3))were prepared for plasma-catalyst degradation of multicomponent volatile organic compounds(VOCs,such as toluene,acetone and ethyl acetate).The results reveal that the degradation efficiency(DE)of acetone,toluene and ethyl acetate in the DDBD system can be arranged as follows:Mn_(2)O_(3)/γ-Al_(2)O_(3)>Fe2O3/γ-Al_(2)O_(3)>CuO_(/γ)-Al_(2)O_(3)>CeO_(2)/γ-Al_(2)O_(3)>La_(2)O_(3)/γ-Al_(2)O_(3)>γ-Al_(2)O_(3),and the highest DE(49.5%for acetone,93.3%for toluene and 79.8%for ethyl acetate)is obtained in Mn_(2)O_(3)/γ-Al_(2)O_(3)+double dielectric barrier discharge(DDBD)system at specific input energy(SIE)of 700 J/L.Compared with the other catalysts,Mn_(2)O_(3)/γ-Al_(2)O_(3)also exhibits the most significant inhibitory effect on the production of ozone(O3).On the other hand,CeO_(2)/γ-Al_(2)O_(3)and La_(2)O_(3)/γ-Al_(2)O_(3)catalysts display different catalytic selectivity.Both catalysts can slightly raise the DE of VOCs and remarkably facilitate VOCs’mineralization.The carbon balance(CB)is increased by 30.2%and 38.8%,and the CO_(2)selectivity(SCO_(2))is raised by 70.5%and 11.9%in the CeO_(2)/γ-Al_(2)O_(3)+DDBD system and La_(2)O_(3)/γ-Al_(2)O_(3)+DDBD system at SIE of 700 J/L,respectively.To further understand the catalytic effect of the catalysts,the adsorption of O3on different catalysts was simulated by a DFT model.According to the results of the DFT model,it is found that the adsorption energy of other metal oxides seems to be used as a reference for catalytic effect to a certain extent except CeO_(2).The higher the absolute values of adsorption energy,the higher the improvement of VOCs degradation efficiency by catalyst.

Light-stimulated adaptive artificial synapse based on nanocrystalline metal-oxide film

Artificial synapses utilizing spike signals are essential elements of new generation brain-inspired computers.In this paper,we realize light-stimulated adaptive artificial synapse based on nanocrystalline zinc oxide film.The artificial synapse photoconductivity shows spike-type signal response,long and short-term memory(LTM and STM),STM-to-LTM transition and paired-pulse facilitation.It is also retaining the memory of previous exposures and demonstrates spike-frequency adaptation properties.A way to implement neurons with synaptic depression,tonic excitation,and delayed accelerating types of response under the influence of repetitive light signals is discussed.The developed artificial synapse is able to become a key element of neuromorphic chips and neuromorphic sensorics systems.

New Horizon in stabilization of single atoms on metal-oxide supports for CO_(2) reduction

Elecrochemical CO_(2) reduction is a promising route to convert CO_(2) into the value added chemicals,and to control the increasing accumulation of 002 in the atmosphere.The CO_(2) molecule is stable and chemically inert,so a highly efficient electrocatalyst is required for CO_(2) reduction.The single atoms with metal oxdde support is a new fronder in CO_(2) reduction.The supported single atoms contain disperse isolated atoms with an appropriate support maxcimize the atom efficiency of metals for boosting the catalytc perfomance.In this review,we had discussed state-of-the-art research on the synthestis of single atoms supported on the metal oxdde for boosting catalytic activity for CO_(2) reduction and special emphasis is placed on the influence of single atoms supported on metal oxdde on the CO_(2) reduction.Futhermore,we had discussed the challenges,and opportunities for paving the development of single atoms with metal support and their application in ecrocatalytic CO_(2) reduction.

High-voltage super-junction lateral double-diffused metal-oxide semiconductor with a partial lightly doped pillar

A novel super-junction lateral double-diffused metal-oxide semiconductor （SJ-LDMOS） with a partial lightly doped P pillar （PD） is proposed. Firstly, the reduction in the partial P pillar charges ensures the charge balance and suppresses the substrate-assisted depletion effect. Secondly, the new electric field peak produced by the P/P junction modulates the surface electric field distribution. Both of these result in a high breakdown voltage （BV）. In addition, due to the same conduction paths, the specific on-resistance （Ron,sp） of the PD SJ-LDMOS is approximately identical to the conventional SJ-LDMOS. Simulation results indicate that the average value of the surface lateral electric field of the PD SJ-LDMOS reaches 20 V/μm at a 15 μm drift length, resulting in a BV of 300 V.

Wet thermal annealing effect on TaN/HfO_2/Ge metal-oxide-semiconductor capacitors with and without a GeO_2 passivation layer

Wet thermal annealing effects on the properties of TaN/HfO2/Ge metal-oxide-semiconductor （MOS） structures with and without a GeO2 passivation layer are investigated. The physical and the electrical properties are characterized by X-ray photoemission spectroscopy, high-resolution transmission electron microscopy, capacitance-voltage （C-V） and current-voltage characteristics. It is demonstrated that wet thermal annealing at relatively higher temperature such as 550 ℃ can lead to Ge incorporation in HfO2 and the partial crystallization of HfO2, which should be responsible for the serious degradation of the electrical characteristics of the TaN/HfO2/Ge MOS capacitors. However, wet thermal annealing at 400 ℃ can decrease the GeOx interlayer thickness at the HfO2/Ge interface, resulting in a significant reduction of the interface states and a smaller effective oxide thickness, along with the introduction of a positive charge in the dielectrics due to the hydrolyzable property of GeOx in the wet ambient. The pre-growth of a thin GeO2 passivation layer can effectively suppress the interface states and improve the C V characteristics for the as-prepared HfO2 gated Ge MOS capacitors, but it also dissembles the benefits of wet thermal annealing to a certain extent.

Reconstruction model for temperature and concentration profiles of soot and metal-oxide nanoparticles in a nanofluid fuel flame by using a CCD camera

This paper presents a numerical study on the simultaneous reconstruction of temperature and volume fraction fields of soot and metal-oxide nanoparticles in an axisymmetric nanofluid fuel sooting flame based on the radiative energy images captured by a charge-coupled device（CCD） camera. The least squares QR decomposition method was introduced to deal with the reconstruction inverse problem. The effects of ray numbers and measurement errors on the reconstruction accuracy were investigated. It was found that the reconstruction accuracies for volume fraction fields of soot and metaloxide nanoparticles were easily affected by the measurement errors for radiation intensity, whereas only the metal-oxide volume fraction field reconstruction was more sensitive to the measurement error for the volume fraction ratio of metaloxide nanoparticles to soot. The results show that the temperature, soot volume fraction, and metal-oxide nanoparticles volume fraction fields can be simultaneously and accurately retrieved for exact and noisy data using a single CCD camera.

Tuning the Electrochemical Property of the Ultrafine Metal-oxide Nanoclusters by Iron Phthalocyanine as Efficient Catalysts for Energy Storage and Conversion

Nanoclusters(NCs)have been demonstrated of outstanding performance in electrochemical energy storage and conversion technologies due to their strong quantum confinement effects and strong interaction with supports.Here,we developed a class of ultrafine metal-oxide(MOx,M=Fe,Co and Ni)NCs incorporated with iron phthalocyanine(FePc),MOx/FePc-G,supported on graphene as high-performance catalysts for oxygen reduction reaction(ORR),oxygen evolution reaction(OER),and carbon dioxide reduction(CO2RR).The high activities for ORR and OER are attributed to the electron donation and accepting ability of the highly redox active of FePc-G that could tune the properties of MOx.The FeOx/FePc-G exhibits an extremely positive half-wave potential(E1/2)of 0.888 and 0.610 V for ORR in alkaline and neutral conditions,respectively,which is around 60 mV more positive than that of Pt/C.And NiOx/FePc-G shows similar OER activity with the state-of-the-art catalysts,Ir/C,and better performance than NiFeO NCs supported on graphene.Remarkably,the CoOx/FePc-G and NiOx/FePc-G show high activity and selectivity to reduce CO2 into CO with a low onset potential of-0.22 V(overpotential is 0.11 V).

Low-temperature metal–oxide thin-film transistor technologies for implementing flexible electronic circuits and systems

Here we review two 300℃metal–oxide(MO)thin-film transistor(TFT)technologies for the implementation of flexible electronic circuits and systems.Fluorination-enhanced TFTs for suppressing the variation and shift of turn-on voltage(VON),and dual-gate TFTs for acquiring sensor signals and modulating VON have been deployed to improve the robustness and performance of the systems in which they are deployed.Digital circuit building blocks based on fluorinated TFTs have been designed,fabricated,and characterized,which demonstrate the utility of the proposed low-temperature TFT technologies for implementing flexible electronic systems.The construction and characterization of an analog front-end system for the acquisition of bio-potential signals and an active-matrix sensor array for the acquisition of tactile images have been reported recently.

Boosting hydrogen production of ammonia decomposition via the construction of metal-oxide interfaces

The ammonia decomposition for the production of carbon-free hydrogen has triggered great attention yet still remains challenging due to its sluggish kinetics,posting the importance of precise design of efficient catalysts for ammonia decomposition under low temperatures.Constructing the metal-support interaction and interface is one of the most important strategies for promoting catalysts.In this work,by coating ceria onto the Ni nanoparticles(NPs),we discover that the Ni-CeO_(2)interfaces create an exceptional effect to enhance the catalytic decomposition of ammonia by over 10 folds,compared with the pristine Ni.The kinetic analysis demonstrates that the recombinative N2 desorption is the rate-determining step(RDS)and the Ni-CeO_(2)interface greatly increases the RDS.Based on these understandings,a strategy to fabricate the Ni/CeO_(2)catalyst with abundant Ni-Ce-O interfaces via one-pot sol-gel method was employed(hereafter denoted to s-Ni/CeO_(2)).The s-Ni/CeO_(2)catalyst shows a high activity for ammonia decomposition,achieving a H_(2)formation rate of 10.5 mmol gcat1 min^(-1)at 550℃.Combined with a series of characterizations,the relationship between the catalyst structure and the performance was investigated for further understanding the effect of metal-oxide interfaces.

Analysis of recoverable and permanent components of threshold voltage shift in NBT stressed p-channel power VDMOSFET

In this study we investigate the dynamic recovery effects in IRF9520 commercial p-channel power vertical double diffused metal-oxide semiconductor field-effect transistors（VDMOSFETs） subjected to negative bias temperature（NBT）stressing under the particular pulsed bias. Particular values of the pulsed stress voltage frequency and duty cycle are chosen in order to analyze the recoverable and permanent components of stress-induced threshold voltage shift in detail. The results are discussed in terms of the mechanisms responsible for buildup of oxide charge and interface traps. The partial recovery during the low level of pulsed gate voltage is ascribed to the removal of recoverable component of degradation, i.e., to passivation/neutralization of shallow oxide traps that are not transformed into the deeper traps（permanent component）.Considering the value of characteristic time constant associated with complete removal of the recoverable component of degradation, it is shown that by selecting an appropriate combination of the frequency and duty cycle, the threshold voltage shifts induced under the pulsed negative bias temperature stress conditions can be significantly reduced, which may be utilized for improving the device lifetime in real application circuits.

Interface-related switching behaviors of amorphous Pr_(0.67)Sr_(0.33)MnO_3-based memory cells

The resistive switching properties in amorphous Pr0.67Sr0.33MnO3 films deposited by pulsed laser deposition are investigated.Reproducible and bipolar counter-8-shape and 8-shape switching behaviours of Au/Pr0.67Sr0.33MnO3 /F：SnO2 junctions are obtained at room temperature.Dramatically,the coexistence of two switching polarities could be reversibly adjusted by an applied voltage range.The results allocated those two switching types to areas of different defect densities beneath the same electrode.The migration of oxygen vacancies and the trapping effect of electrons under an applied electric field play an important role.An interface-effect-related resistance switching is proposed in an amorphous Pr0.67Sr0.33MnO3-based memory cell.

A unified charge-based model for SOI MOSFETs applicable from intrinsic to heavily doped channel

A unified charge-based model for fully depleted silicon-on-insulator （SOI） metal oxide semiconductor field-effect transistors （MOSFETs） is presented. The proposed model is accurate and applicable from intrinsic to heavily doped channels with various structure parameters. The framework starts from the one-dimensional Poisson Boltzmann equa- tion, and based on the full depletion approximation, an accurate inversion charge density equation is obtained. With the inversion charge density solution, the unified drain current expression is derived, and a unified terminal charge and intrinsic capacitance model is also derived in the quasi-static case. The validity and accuracy of the presented analytic model is proved by numerical simulations.

Homogeneous interface-type resistance switching in Au/La_(0.67)Ca_(0.33)MnO_3/SrTiO_3/F:SnO_2 heterojunction memories

La0.67Ca0.33MnO3 thin films are fabricated on fluorine-doped tin oxide conducting glass substrates by a pulsed laser deposition technique with SrTiO3 used as a buffer layer. The current-voltage characteristics of the heterojunetions exhibit an asymmetric and resistance switching behaviour. A homogeneous interface-type conduction mechanism is also reported using impedance spectroscopy. The spatial homogeneity of the charge carrier distribution leads to field- induced potential-barrier change at the Au-La0.67Ca0.33MnO3 interface and a concomitant resistance switching effect. The ratio of the high resistance state to the low resistance state is found to be as high as 1.3 x 10^4% by simulating the AC electric field. This colossal resistance switching effect will greatly improve the signal-to-noise ratio in nonvolatile memory applications.

Electrochemical Characterization of Surface-modified LiMn_2O_4 Cathode Materials for Li-ion Batteries

To improve the performance, the surface of 12Mn2O4 was coated with very fine MgO , Al2O3 and ZnO by solgel method, respectively. The structure and morphology of the coated materials were investigated by X-ray diffraction （ XRD ）, X-ray photoelectron spectroscopy （ XPS ） and scanning electron microscopy （SEM）. The charge and discharge performance of uncoated and surfnce modified 12Mn2O4 spinel at 25℃ and 55 ℃ were tested, using a voltage window of 3.0-4.35 V and a current deasity of 0. 1 C rate. There is a slight decrease in the initial discharge capacity relative to that of uncoated UMn2 O4, bat the cycle ability of 12 12Mn2O4 coated by metal-oxide has remarkably been improved. The EIS measuremeuts of uncoated and Al2O3 -coated 12Mn2O4 were carried out by a model 273 A potentiostatl galvanistat controUed by a computer using M270 software, and using a freqnency response analyzer （ Zsimpwin ） combined with a potentiostate （ PAR 273）. Coaseqnently, the reason for the improved cycle properties is that the surface modification reduces the dissolution of Mn , which results from the suppression of the electrolyte decomposition, and suppresses the formation of passivation film that acts as an electronic insulating layer. In conclusion, the use of surface modification is an effective way to improve the electrochemical performance of 12Mn2O4 cathode material for lithium batteries.

Current status and development of CMOS SiPM for scintillator-based radiation detectors toward all-digital sensors[Invited]

Modern scintillator-based radiation detectors require silicon photomultipliers(Si PMs)with photon detection efficiency higher than 40%at 420 nm,possibly extended to the vacuum ultraviolet(VUV)region,single-photon time resolution(SPTR)<100 ps,and dark count rate(DCR)<150 kcps/mm^(2).To enable single-photon time stamping,digital electronics and sensitive microcells need to be integrated in the same CMOS substrate,with a readout frame rate higher than 5 MHz for arrays extending over a total area up to 4 mm×4 mm.This is challenging due to the increasing doping concentrations at low CMOS scales,deep-level carrier generation in shallow trench isolation fabrication,and power consumption,among others.The advances at 350 and 110 nm CMOS nodes are benchmarked against available Si PMs obtained in CMOS and commercial customized technologies.The concept of digital multithreshold Si PMs with a single microcell readout is finally reported,proposing a possible direction toward fully digital scintillator-based radiation detectors.

Advancements on metal oxide semiconductor photocatalysts in photo-electrochemical conversion of carbon dioxide into fuels and other useful products

Due to its fascinating and tunable optoelectronic properties,semiconductor nanomaterials are the best choices for multidisciplinary applications.Particularly,the use of semiconductor photocatalysts is one of the promising ways to harness solar energy for useful applications in the field of energy and environment.In recent years,metal oxide-based tailored semiconductor photocatalysts have extensively been used for photocatalytic conversion of carbon dioxide(CO_(2))into fuels and other useful products utilizing solar energy.This is very significant not only from renewable energy consumption but also from reducing global warming point of view.Such current research activities are promising for a better future of society.The present mini-review is focused on recent developments(2–3 years)in metal oxide semiconductor hybrid photocatalysts-based photo-electrochemical conversion of CO_(2)into fuels and other useful products.First,general mechanism of photo-electrochemical conversion of CO_(2)into fuels or other useful products has been discussed.Then,various metal oxide-based emerging hybrid photocatalysts including tailoring of their morphological,compositional,and optoelectronic properties have been discussed with emphasis on their role in enhancing photoelectrochemical efficienty.Afterwards,mechanism of their photo-electrochemical reactions and applications in CO_(2)conversion into fuels/other useful products have been discussed.Finally,challenges and future prospects have been discussed followed by a summary.

Requirement of ultra-high voltage GIS arrester to voltage gradient of metal-oxide varistor

The surge arrester with excellent protection characteristics would decrease the overvoltage level ap- plied on the power apparatus to reduce their insulation levels and manufacturing bottleneck. The arrester for the 1000-kV ultra-high voltage ac power transmission system is designed as tank-type structure. The field-circuit combination numerical method combining the three-dimensional finite element method with circuit is proposed to analyze the potential distribution of GIS arrester. By comparing several design schemes, the most effective method to improve the potential distribution along the varistor column is to increase the voltage gradient of the ZnO varistor. Synthesizing several influential factors, the suitable voltage gradient of ZnO varistor should be controlled to 435 V/mm, and the resulted nonuniform degree of the potential distribution along the varistor column inside the GIS arrester would be controlled smaller than 10%. The result in this paper provides the fundamental technical index for the study of the high voltage gradient ZnO varistors.

Benchmark evaluation of tomographic algorithms for simultaneous reconstruction of temperature and volume fraction fields of soot and metal-oxide nanoparticles in non-uniform flames

With the growing applications of nanofluid flame, the monitoring and controlling of its combustion process is of paramount importance. Thus, it is necessary to develop diagnosing methods which can simultaneously image important parameters such as temperature and volume fractions of soot, metal-oxide nanoparticles. Tomographic emission spectroscopy is an effective method which has been proposed for this purpose. However, the inversion process was only reported with least-squares QR decomposition(LSQR) so far and there are numerous well-established reconstruction algorithms which have not been utilized yet.Thus, this work aims to perform systematic comparative studies on several representative algorithms for the inversion process. In the simulative studies, algorithms including Tikhonov regularization, algebraic reconstruction technique(ART), LSQR,Landweber algorithm, maximum likelihood expectation maximization(MLEM), and ordered subset expectation maximization(OSEM) were discussed. The effects of the number of iterations, the signal-to-noise ratio, and the number of projections and the calibration error in projection angles on the performance of the algorithms were investigated. Advice on selecting the suitable algorithms under different application conditions is then provided according to the extensive numerical studies.

Quasi-two-dimensionalβ-Ga2O3 field effect transistors with large drain current density and low contact resistance via controlled formation of interfacial oxygen vacancies

Quasi-two-dimensi on al(2D)β-Ga2O3 is a rediscovered metal-oxide semiconductor with an ultra-wide bandgap of 4.6-4.9eV.It has been reported to be a promising material for next-generation power and radio frequency electronics.Field effect transistors(FETs)that can switch at high voltage are key compone nts in power and radio frequency devices,and reliable Ohmic con tacts are essential for high FET performance.However,obtaining low contact resistance onβ-Ga2O3 FETs is difficult since reactions betweenβ-Ga2O3 and metal contacts are not fully understood.Herein,we experimentally demonstrate the importanee of reactions at the metal/β-Ga2O3 interface and the corresponding effects of these reactions on FET performance.When Ti is employed as the metal contact,annealing ofβ-Ga2O3 FETs in argon can effectively transform Schottky contacts into Ohmic contacts and permit a large drain current density of-3.1 mA//μm.The contact resistance(Rcontact)between the Ti electrodes andβ-Ga2O3 decreased from^430 to^0.387Ω·mm after annealing.X-ray photoelectron spectroscopy(XPS)confirmed the formation of oxygen vacancies at the Ti/β-Ga2O3 interface after annealing,which is believed to cause the improved FET performance.The results of this study pave the way for greater application ofβ-Ga2O3 in electronics.

Effect of CeO_2 and Al_2O_3 on the activity of Pd/Co_3O_4/cordierite catalyst in the three-way catalysis reactions(CO/NO/C_nH_m)

The present article studies the effect of CeO2 and A1203 on the activity of Pd/Co304/cordierite catalyst in conversion of NO, CO, CnHm. The catalysts were characterized by temperature programmed reduction with hydrogen, X-ray diffraction, X-ray photoelectron spectroscopy and transmission electron microscopy. It is shown that the effect of CeO2 on the properties of Pd/C03 O4/cordierite catalyst depends on preparation method. The catalyst obtained by co-deposition of cerium and cobalt oxides has higher activity in CO oxidation （CO ＋ 02 and CO ＋ NO） and total hexane oxidation （C6H14 ＋ 02）. Such phenomenon is probably caused by more than stoichiometric amount of formed oxygen vacancies, an increase in both mobility of surface oxygen and dispersity of components in the catalytic composition. It is demonstrated that CeO2 addition promotes the SO2 resistance of Pd/C03 O4/cordierite. The second support decreases the activity of Pd/Co3Oa/cordierite catalyst in the reactions of CO and C6H14 with oxygen because of COA1204 formation.