The title compound (Me2SiSiMe2)[(η5-1-indenyl)Fe(CO)]2(μ-CO)2 was preparedby the reaction of 1 .2-bis(1-indenyl)tetramethyldisilane and Fe(CO)5 in retluxing heptane inrefluxing xylene can be converted into [Me2Si(...The title compound (Me2SiSiMe2)[(η5-1-indenyl)Fe(CO)]2(μ-CO)2 was preparedby the reaction of 1 .2-bis(1-indenyl)tetramethyldisilane and Fe(CO)5 in retluxing heptane inrefluxing xylene can be converted into [Me2Si(η5-1-indenyl ) Fe(CO)2]2.The pure transisomer 2t was obtained and its crystal and molecular structure was determined by X-raydiffraction.展开更多
文摘The title compound (Me2SiSiMe2)[(η5-1-indenyl)Fe(CO)]2(μ-CO)2 was preparedby the reaction of 1 .2-bis(1-indenyl)tetramethyldisilane and Fe(CO)5 in retluxing heptane inrefluxing xylene can be converted into [Me2Si(η5-1-indenyl ) Fe(CO)2]2.The pure transisomer 2t was obtained and its crystal and molecular structure was determined by X-raydiffraction.