Emission of matter-wave jets from a parametrically driven condensate has attracted significant experimental and theoretical attention due to the appealing visual effects and potential metrological applications.In this...Emission of matter-wave jets from a parametrically driven condensate has attracted significant experimental and theoretical attention due to the appealing visual effects and potential metrological applications.In this work,we investigate the collective particle emission from a Bose-Einstein condensate confined in a one-dimensional lattice with periodically modulated interparticle interactions.We give the regimes for discrete modes,and find that the emission can be distinctly suppressed.The configuration induces a broad band,but few particles are ejected due to the interference of the matter waves.We further qualitatively model the emission process and demonstrate the short-time behaviors.This engineering provides a way to manipulate the propagation of particles and the corresponding dynamics of condensates in lattices,and may find application in the dynamical excitation control of other nonequilibrium problems with time-periodic driving.展开更多
Recently,soft decision modulations become the highlight of parallel combinatory spread spectrum ( PCSS) system. Existing soft decision BPSK and APK modulations are given and compared in the thesis. In order to apply s...Recently,soft decision modulations become the highlight of parallel combinatory spread spectrum ( PCSS) system. Existing soft decision BPSK and APK modulations are given and compared in the thesis. In order to apply soft decision QPSK modulation based on PCSS system,the correlation of superposition PN sequences is discussed. A weighted summation algorithm is adopted in QPSK demodulation to recover the whole orthogonal correlation of the superposition sequences; meanwhile the bit error rate of weighting soft decision QPSK modulation is simulated. The simulation results show that the bit error rate performance of proposed soft decision QPSK modulation based on PCSS system is better than that of hard decision modulation. The method proposed can be widely adopted in engineering application.展开更多
The particle modulations to turbulence in round jets were experimentally studied by means of two-phase velocity measurements with Phase Doppler Anemometer (PDA). Laden with very large particles, no significant atten...The particle modulations to turbulence in round jets were experimentally studied by means of two-phase velocity measurements with Phase Doppler Anemometer (PDA). Laden with very large particles, no significant attenuations of turbulence intensities were measured in the farfields, due to small two-phase slip velocities and particle Reynolds number. The gas-phase turbulence is enhanced by particles in the near-fields, but it is significantly attenuated by the small particles in the far-fields. The smaller particles have a more profound effect on the attenuation of turbulence intensities. The enhancements or attenuations of turbulence intensities in the far-fields depends on the energy production, transport and dissipation mechanisms between the two phases, which are determined by the particle prop- erties and two-phase velocity slips. The non-dimensional parameter CTI is introduced to represent the change of turbulence intensity.展开更多
To promote reliable and secure communications in the cognitive radio network,the automatic modulation classification algorithms have been mainly proposed to estimate a single modulation.In this paper,we address the cl...To promote reliable and secure communications in the cognitive radio network,the automatic modulation classification algorithms have been mainly proposed to estimate a single modulation.In this paper,we address the classification of superimposed modulations dedicated to 5G multipleinput multiple-output(MIMO)two-way cognitive relay network in realistic channels modeled with Nakagami-m distribution.Our purpose consists of classifying pairs of users modulations from superimposed signals.To achieve this goal,we apply the higher-order statistics in conjunction with the Multi-BoostAB classifier.We use several efficiency metrics including the true positive(TP)rate,false positive(FP)rate,precision,recall,F-Measure and receiver operating characteristic(ROC)area in order to evaluate the performance of the proposed algorithm in terms of correct superimposed modulations classification.Computer simulations prove that our proposal allows obtaining a good probability of classification for ten superimposed modulations at a low signal-to-noise ratio,including the worst case(i.e.,m=0.5),where the fading distribution follows a one-sided Gaussian distribution.We also carry out a comparative study between our proposal usingMultiBoostAB classifier with the decision tree(J48)classifier.Simulation results show that the performance of MultiBoostAB on the superimposed modulations classifications outperforms the one of J48 classifier.In addition,we study the impact of the symbols number,path loss exponent and relay position on the performance of the proposed automatic classification superimposed modulations in terms of probability of correct classification.展开更多
The highest occupied molecular orbital(HOMO) energies of fullerenes are found by quantitative first-principles calculations to be raised by negative charging, and the rising rate rank of the fullerenes is C60 >C7...The highest occupied molecular orbital(HOMO) energies of fullerenes are found by quantitative first-principles calculations to be raised by negative charging, and the rising rate rank of the fullerenes is C60 >C70 >C80 >C90>C100 >C180. Then we compare fullerenes with carbon nanotubes(CNTs) and graphene sheets(GSs) and find that the increase of the HOMO energy of a fullerene is much faster than that of CNTs and graphene sheets with the same number of C atoms. The rising rate rank is fullerene>CNT>GS, which holds no matter what the number of C atoms is or which structure the fullerene isomer is. This work paves a new path for developing all-carbon devices with low-dimensional carbon nanomaterials as different functional elements.展开更多
To make the modulation classification system more suitable for signals in a wide range of signal to noise rate (SNR), a feature extraction method based on signal wavelet packet transform modulus maxima matrix (WPT...To make the modulation classification system more suitable for signals in a wide range of signal to noise rate (SNR), a feature extraction method based on signal wavelet packet transform modulus maxima matrix (WPTMMM) and a novel support vector machine fuzzy network (SVMFN) classifier is presented. The WPTMMM feature extraction method has less computational complexity, more stability, and has the preferable advantage of robust with the time parallel moving and white noise. Further, the SVMFN uses a new definition of fuzzy density that incorporates accuracy and uncertainty of the classifiers to improve recognition reliability to classify nine digital modulation types (i.e. 2ASK, 2FSK, 2PSK, 4ASK, 4FSK, 4PSK, 16QAM, MSK, and OQPSK). Computer simulation shows that the proposed scheme has the advantages of high accuracy and reliability (success rates are over 98% when SNR is not lower than 0dB), and it adapts to engineering applications.展开更多
We compare the transport properties of electrons in monolayer graphene by modulating the Fermi velocity inside the barrier. A critical transmission angle is found only when the Fermi velocity in the barriers is larger...We compare the transport properties of electrons in monolayer graphene by modulating the Fermi velocity inside the barrier. A critical transmission angle is found only when the Fermi velocity in the barriers is larger than the one outside the barriers. It is shown that the transmission exhibits periodicity with the incident angle below the critical transmission angle, and attenuates exponentially in the opposite situation. For both situations, peak splitting occurs in the transmission as the number of the velocity barriers increases, and the characteristics of the transmission suggest an interesting application of an excellent band-pass filter. The dependence of the conductance on the Fermi energy through an identical velocity- modulation structure differs wildly with different Fermi velocities of the barrier. The counterpart of the peak splitting is the sharp oscillations in the conductance profile. Furthermore, some oscillations for the multiple barriers are so sharp that the structure may be used as an excellent sensor.展开更多
To make the modulation classification system more suitable for signals in a wide range of signal to noise ratios (SNRs), a novel adaptive modulation classification scheme is presented in this paper. Differ-ent from ...To make the modulation classification system more suitable for signals in a wide range of signal to noise ratios (SNRs), a novel adaptive modulation classification scheme is presented in this paper. Differ-ent from traditional schemes, the proposed scheme employs a new SNR estimation algorithm for small samples before modulation classification, which makes the modulation classifier work adaptively according to estimated SNRs. Furthermore, it uses three efficient features and support vector machines (SVM) in modulation classification. Computer simulation shows that the scheme can adaptively classify ten digital modulation types (i.e. 2ASK, 4ASK, 2FSK, 4FSK, 2PSK, 4PSK, 16QAM, TFM, π/4QPSK and OQPSK) at SNRS ranging from 0dB to 25dB and success rates are over 95% when SNR is not lower than 3dB. Accuracy, efficiency and simplicity of the proposed scheme are obviously improved, which make it more adaptive to engineering applications.展开更多
Transmission electron microscopy (TEM) study of SrPt2As2 reveals two incommensurate modulations appearing in the charge-density-wave (CDW) state below TCDW ≈ 470 K. These two structural modulations can be well ex...Transmission electron microscopy (TEM) study of SrPt2As2 reveals two incommensurate modulations appearing in the charge-density-wave (CDW) state below TCDW ≈ 470 K. These two structural modulations can be well explained in terms of condensations of two-coupled phonon modes with wave vectors of q1=0.62a* on the a*-b* plane and q2 = 0.23a* on the a*-c* plane. The atomic displacements occur along the b-axis direction for q1 and along the c-axis direction for q2, respectively. Moreover, the correlation between ql and q2 can be generally written as q1 = (q2 + a*)/2 in the CDW state, suggesting the presence of essential coupling between q1 and q2. A small fraction of Ir doping on the Pt site in Sr(Pt1-xIrx)2As2 (x ≤ 0.06) could moderately change these CDW modulations and also affect their superconductivities.展开更多
This paper explores the potential to use accurate but outdated channel estimates for adaptive modulation. The work is novel in that the research is conditioned on block by block adaptation. First,we define a new quant...This paper explores the potential to use accurate but outdated channel estimates for adaptive modulation. The work is novel in that the research is conditioned on block by block adaptation. First,we define a new quantity,the Tolerable Average Use Delay (TAUD),which can indicate the ability of an adaptation scheme to tolerate the delay of channel estimation results. We find that for the variable-power schemes,TAUD is a constant and dependent on the target Bit Error Rate (BER),average power and Doppler frequency; while for the constant-power schemes,it depends on the ad-aptation block length as well. At last,we investigate the relation between the delay tolerating per-formance and the spectral efficiency and give the system design criterion. The delay tolerating per-formance is improved at the price of lower data rate.展开更多
Photochromic materials with multicolor upconversion reversible modulations are attractive in optical switching devices.Herein,the fabricated YNbO_(4):Er^(3+)/Tm^(3+)/Yb^(3+) materials exhibit excellent photochromism a...Photochromic materials with multicolor upconversion reversible modulations are attractive in optical switching devices.Herein,the fabricated YNbO_(4):Er^(3+)/Tm^(3+)/Yb^(3+) materials exhibit excellent photochromism and multicolor upconversion properties from green,red to near infrared(NIR) emissions with increasing Yb concentrations.Reversible multiband upconversion modulations are achieved by alternating light(365 and 405 nm) or thermal stimuli.After 365 nm irradiation,the luminescence color changes from yellow to red,the luminescent photoswitching contrast reaches up to 86.21%(green),82.12%(red) and 77.38%(NIR) in the Y_(0.83)Er_(0.01)Tm_(0.01)NbO_(4):0.15 Yb sample.Besides,the upconversion emission intensity before and after photochromic reaction shows remarkable change in a wide temperature range of 298-718 K.These results indicate that the Er^(3+)/Tm^(3+)/Yb^(3+) tri-doped YNbO_(4) materials can be a good candidate in optical switching and data storage applications.展开更多
Currently,dual atomic catalysts(DACs)with neighboring active sites for oxygen reduction reaction(ORR)still meet lots of challenges in the synthesis,especially the construction of atomic pairs of elements from differen...Currently,dual atomic catalysts(DACs)with neighboring active sites for oxygen reduction reaction(ORR)still meet lots of challenges in the synthesis,especially the construction of atomic pairs of elements from different blocks of the periodic table.Herein,a“rare earth(Ce)-metalloid(Se)”non-bonding heteronuclear diatomic electrocatalyst has been constructed for ORR by rational coordination and carbon support defect engineering.Encouraging,the optimized Ce-Se diatomic catalysts(Ce-Se DAs/NC)displayed a half-wave potential of 0.886 V vs.reversible hydrogen electrode(RHE)and excellent stability,which surpass those of separate Ce or Se single atoms and most single/dual atomic catalysts ever reported.In addition,a primary zinc-air battery constructed using Ce-Se DAs/NC delivers a higher peak power density(209.2 mW·cm^(−2))and specific capacity(786.4 mAh·gZn^(−1))than state-of-the-art noble metal catalysts Pt/C.Theoretical calculations reveal that the Ce-Se DAs/NC has improved the electroactivity of the Ce-N_(4)region due to the electron transfer towards the nearby Se specific activity(SA)sites.Meanwhile,the more electron-rich Se sites promote the adsorptions of key intermediates,which results in the optimal performances of ORR on Ce-Se DAs/NC.This work provides new perspectives on electronic structure modulations via non-bonded long-range coordination micro-environment engineering in DACs for efficient electrocatalysis.展开更多
The present research employs artificial intelligence to come up with an automatic solution for the modulation's classification of various radio signal varieties.As a result,the work we performed involved selecting...The present research employs artificial intelligence to come up with an automatic solution for the modulation's classification of various radio signal varieties.As a result,the work we performed involved selecting the database required for supervised deep learning,evaluating the performance of current techniques on unprocessed communication signals,and suggesting a deep learning networkbased method that would enable the classification of modulation types with the best possible ratio between computation time and accuracy.We started by examining the automatic classification models that are currently in usage.In light of the difficulty of forecasting in low Signal Noise Ratio(SNR)situations,we suggested an ensemble learning strategy based on adjusted Res Net and Transformer Neural Network,which is effective at extracting multi-scale features from the raw I/Q sequence data.Finally,we produced an architecture that is simple to use and apply to communication signals.The architecture of this solution is strong and optimal,enabling it to determine the type of modulation with up to 95%accuracy automatically.展开更多
Two-dimensional(2D)materials have attracted considerable research interest,leading to significant advances in energy applications in recent years,such as lithium batteries,catalysis,electronics,and thermoelectrics,owi...Two-dimensional(2D)materials have attracted considerable research interest,leading to significant advances in energy applications in recent years,such as lithium batteries,catalysis,electronics,and thermoelectrics,owing to their rich controllable properties and excellent performances.Recently,pressure has been successfully employed as an effective method for property modulation of 2D materials,through tuning electronic orbitals and bonding patterns.In this review,we summarize recent progresses in the pressure-driven property modulations and elucidate the underlying mechanism of the pressure modulation of 2D materials.Further,we identify the remaining challenges and opportunities in this new,vibrant area of research for energy conversion and utilization.Among the different property modulation strategies,the in situ application of high pressure is systematically identified as a promising knob for 2D materials.This review is expected to inspire further research on the fundamental understanding and practical applications of high-pressure modulation in 2D materials.展开更多
This paper investigates the bit-interleaved coded generalized spatial modulation(BICGSM) with iterative decoding(BICGSM-ID) for multiple-input multiple-output(MIMO) visible light communications(VLC). In the BICGSM-ID ...This paper investigates the bit-interleaved coded generalized spatial modulation(BICGSM) with iterative decoding(BICGSM-ID) for multiple-input multiple-output(MIMO) visible light communications(VLC). In the BICGSM-ID scheme, the information bits conveyed by the signal-domain(SiD) symbols and the spatial-domain(SpD) light emitting diode(LED)-index patterns are coded by a protograph low-density parity-check(P-LDPC) code. Specifically, we propose a signal-domain symbol expanding and re-allocating(SSER) method for constructing a type of novel generalized spatial modulation(GSM) constellations, referred to as SSERGSM constellations, so as to boost the performance of the BICGSM-ID MIMO-VLC systems.Moreover, by applying a modified PEXIT(MPEXIT) algorithm, we further design a family of rate-compatible P-LDPC codes, referred to as enhanced accumulate-repeat-accumulate(EARA) codes,which possess both excellent decoding thresholds and linear-minimum-distance-growth property. Both analysis and simulation results illustrate that the proposed SSERGSM constellations and P-LDPC codes can remarkably improve the convergence and decoding performance of MIMO-VLC systems. Therefore, the proposed P-LDPC-coded SSERGSM-mapped BICGSMID configuration is envisioned as a promising transmission solution to satisfy the high-throughput requirement of MIMO-VLC applications.展开更多
Hydrogen,meeting the requirements of sustainable development,is regarded as the ultimate energy in the 21st century.Due to the inexhaustible and feasible of solar energy,solar water splitting is an immensely promising...Hydrogen,meeting the requirements of sustainable development,is regarded as the ultimate energy in the 21st century.Due to the inexhaustible and feasible of solar energy,solar water splitting is an immensely promising strategy for environmental-friendly hydrogen production,which not only overcomes the fluctuation and intermittency but also contributes to achieving the mission of global“Carbon Neutrality and Carbon Peaking”.However,there is still a lack of a comprehensive overview focusing on hydrogen progress with a discussion of development from solar energy to solar cells.Herein,we emphasize several solar-to-hydrogen pathways from the basic concepts and principles and focus on photovoltaic-electrolysis and photoelectrochemical/photovoltaic systems,which have achieved solar-to-hydrogen(STH)efficiency of over 10%and have extremely promising for large-scale application.In addition,we summarize the challenges and opportunities faced in this field including configuration design,electrode materials,and performance evaluation.Finally,perspectives on the potential commercial application and scientific research for the further development of solar-to-hydrogen are analyzed and presented.展开更多
Active control of terahertz(THz)waves is attracting tremendous attentions in terahertz communications and active photonic devices.Perovskite,due to its excellent photoelectric conversion performance and simple manufac...Active control of terahertz(THz)waves is attracting tremendous attentions in terahertz communications and active photonic devices.Perovskite,due to its excellent photoelectric conversion performance and simple manufacturing process,has emerged as a promising candidate for optoelectronic applications.However,the exploration of perovskites in optically controlled THz modulators is still limited.In this work,the photoelectric properties and carrier dynamics of FA_(0.4)MA_(0.6)PbI_(3)perovskite films were investigated by optical pumped terahertz probe(OPTP)system.The ultrafast carrier dynamics reveal that FA_(0.4)MA_(0.6)PbI_(3)thin film exhibits rapid switching and relaxation time within picosecond level,suggesting that FA_(0.4)MA_(0.6)PbI_(3)is an ideal candidate for active THz devices with ultrafast response.Furthermore,as a proof of concept,a FA_(0.4)MA_(0.6)PbI_(3)-based metadevice with integrating plasma-induced transparency(PIT)effect was fabricated to achieve ultrafast modulation of THz wave.The experimental results demonstrated that the switching time of FA_(0.4)MA_(0.6)PbI_(3)-based THz modulator is near to 3.5 ps,and the threshold of optical pump is as low as 12.7μJ cm^(-2).The simulation results attribute the mechanism of ultrafast THz modulation to photo-induced free carriers in the FA_(0.4)MA_(0.6)PbI_(3)layer,which progressively shorten the capacitive gap of PIT resonator.This study not only illuminates the potential of FA_(0.4)MA_(0.6)PbI_(3)in THz modulation,but also contributes to the field of ultrafast photonic devices.展开更多
Hepatocellular carcinoma(HCC)is a prevalent and aggressive liver malignancy.The interplay between bile acids(BAs)and the gut microbiota has emerged as a critical factor in HCC development and progression.Under normal ...Hepatocellular carcinoma(HCC)is a prevalent and aggressive liver malignancy.The interplay between bile acids(BAs)and the gut microbiota has emerged as a critical factor in HCC development and progression.Under normal conditions,BA metabolism is tightly regulated through a bidirectional interplay between gut microorganisms and BAs.The gut microbiota plays a critical role in BA metabolism,and BAs are endogenous signaling molecules that help maintain liver and intestinal homeostasis.Of note,dysbiotic changes in the gut microbiota during pathogenesis and cancer development can disrupt BA homeostasis,thereby leading to liver inflammation and fibrosis,and ultimately contributing to HCC development.Therefore,understanding the intricate interplay between BAs and the gut microbiota is crucial for elucidating the mechanisms underlying hepatocarcinogenesis.In this review,we comprehensively explore the roles and functions of BA metabolism,with a focus on the interactions between BAs and gut microorganisms in HCC.Additionally,therapeutic strategies targeting BA metabolism and the gut microbiota are discussed,including the use of BA agonists/antagonists,probiotic/prebiotic and dietary interventions,fecal microbiota transplantation,and engineered bacteria.In summary,understanding the complex BA-microbiota crosstalk can provide valuable insights into HCC development and facilitate the development of innovative therapeutic approaches for liver malignancy.展开更多
The laminated transition metal disulfides(TMDs),which are well known as typical two-dimensional(2D)semiconductive materials,possess a unique layered structure,leading to their wide-spread applications in various field...The laminated transition metal disulfides(TMDs),which are well known as typical two-dimensional(2D)semiconductive materials,possess a unique layered structure,leading to their wide-spread applications in various fields,such as catalysis,energy storage,sensing,etc.In recent years,a lot of research work on TMDs based functional materials in the fields of electromagnetic wave absorption(EMA)has been carried out.Therefore,it is of great significance to elaborate the influence of TMDs on EMA in time to speed up the application.In this review,recent advances in the development of electromagnetic wave(EMW)absorbers based on TMDs,ranging from the VIB group to the VB group are summarized.Their compositions,microstructures,electronic properties,and synthesis methods are presented in detail.Particularly,the modulation of structure engineering from the aspects of heterostructures,defects,morphologies and phases are systematically summarized,focusing on optimizing impedance matching and increasing dielectric and magnetic losses in the EMA materials with tunable EMW absorption performance.Milestones as well as the challenges are also identified to guide the design of new TMDs based dielectric EMA materials with high performance.展开更多
基金supported by the China Scholarship Council(Grant No.201906130092)the Natural Science Research Start-up Foundation of Recruiting Talents of Nanjing University of Posts and Telecommunications(Grant No.NY223065)the Natural Science Foundation of Sichuan Province(Grant No.2023NSFSC1330).
文摘Emission of matter-wave jets from a parametrically driven condensate has attracted significant experimental and theoretical attention due to the appealing visual effects and potential metrological applications.In this work,we investigate the collective particle emission from a Bose-Einstein condensate confined in a one-dimensional lattice with periodically modulated interparticle interactions.We give the regimes for discrete modes,and find that the emission can be distinctly suppressed.The configuration induces a broad band,but few particles are ejected due to the interference of the matter waves.We further qualitatively model the emission process and demonstrate the short-time behaviors.This engineering provides a way to manipulate the propagation of particles and the corresponding dynamics of condensates in lattices,and may find application in the dynamical excitation control of other nonequilibrium problems with time-periodic driving.
基金Sponsored by the National Natural Science Foundation of China(Grant No.61271263)
文摘Recently,soft decision modulations become the highlight of parallel combinatory spread spectrum ( PCSS) system. Existing soft decision BPSK and APK modulations are given and compared in the thesis. In order to apply soft decision QPSK modulation based on PCSS system,the correlation of superposition PN sequences is discussed. A weighted summation algorithm is adopted in QPSK demodulation to recover the whole orthogonal correlation of the superposition sequences; meanwhile the bit error rate of weighting soft decision QPSK modulation is simulated. The simulation results show that the bit error rate performance of proposed soft decision QPSK modulation based on PCSS system is better than that of hard decision modulation. The method proposed can be widely adopted in engineering application.
基金supported by the National Natural Science Foundation of China (50876053 and 50706021).
文摘The particle modulations to turbulence in round jets were experimentally studied by means of two-phase velocity measurements with Phase Doppler Anemometer (PDA). Laden with very large particles, no significant attenuations of turbulence intensities were measured in the farfields, due to small two-phase slip velocities and particle Reynolds number. The gas-phase turbulence is enhanced by particles in the near-fields, but it is significantly attenuated by the small particles in the far-fields. The smaller particles have a more profound effect on the attenuation of turbulence intensities. The enhancements or attenuations of turbulence intensities in the far-fields depends on the energy production, transport and dissipation mechanisms between the two phases, which are determined by the particle prop- erties and two-phase velocity slips. The non-dimensional parameter CTI is introduced to represent the change of turbulence intensity.
文摘To promote reliable and secure communications in the cognitive radio network,the automatic modulation classification algorithms have been mainly proposed to estimate a single modulation.In this paper,we address the classification of superimposed modulations dedicated to 5G multipleinput multiple-output(MIMO)two-way cognitive relay network in realistic channels modeled with Nakagami-m distribution.Our purpose consists of classifying pairs of users modulations from superimposed signals.To achieve this goal,we apply the higher-order statistics in conjunction with the Multi-BoostAB classifier.We use several efficiency metrics including the true positive(TP)rate,false positive(FP)rate,precision,recall,F-Measure and receiver operating characteristic(ROC)area in order to evaluate the performance of the proposed algorithm in terms of correct superimposed modulations classification.Computer simulations prove that our proposal allows obtaining a good probability of classification for ten superimposed modulations at a low signal-to-noise ratio,including the worst case(i.e.,m=0.5),where the fading distribution follows a one-sided Gaussian distribution.We also carry out a comparative study between our proposal usingMultiBoostAB classifier with the decision tree(J48)classifier.Simulation results show that the performance of MultiBoostAB on the superimposed modulations classifications outperforms the one of J48 classifier.In addition,we study the impact of the symbols number,path loss exponent and relay position on the performance of the proposed automatic classification superimposed modulations in terms of probability of correct classification.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11374174,51390471,51527803,and 51701143the National Basic Research Program of China under Grant No 2015CB654902+4 种基金the National Key Research and Development Program under Grant No 2016YFB0700402the Foundation for the Author of National Excellent Doctoral Dissertation under Grant No 201141the National Program for Thousand Young Talents of China,the Tianjin Municipal Education Commissionthe Tianjin Municipal Science and Technology Commissionthe Fundamental Research Fund of Tianjin University of Technology
文摘The highest occupied molecular orbital(HOMO) energies of fullerenes are found by quantitative first-principles calculations to be raised by negative charging, and the rising rate rank of the fullerenes is C60 >C70 >C80 >C90>C100 >C180. Then we compare fullerenes with carbon nanotubes(CNTs) and graphene sheets(GSs) and find that the increase of the HOMO energy of a fullerene is much faster than that of CNTs and graphene sheets with the same number of C atoms. The rising rate rank is fullerene>CNT>GS, which holds no matter what the number of C atoms is or which structure the fullerene isomer is. This work paves a new path for developing all-carbon devices with low-dimensional carbon nanomaterials as different functional elements.
文摘To make the modulation classification system more suitable for signals in a wide range of signal to noise rate (SNR), a feature extraction method based on signal wavelet packet transform modulus maxima matrix (WPTMMM) and a novel support vector machine fuzzy network (SVMFN) classifier is presented. The WPTMMM feature extraction method has less computational complexity, more stability, and has the preferable advantage of robust with the time parallel moving and white noise. Further, the SVMFN uses a new definition of fuzzy density that incorporates accuracy and uncertainty of the classifiers to improve recognition reliability to classify nine digital modulation types (i.e. 2ASK, 2FSK, 2PSK, 4ASK, 4FSK, 4PSK, 16QAM, MSK, and OQPSK). Computer simulation shows that the proposed scheme has the advantages of high accuracy and reliability (success rates are over 98% when SNR is not lower than 0dB), and it adapts to engineering applications.
基金Project supported by the National Natural Science Foundation of China (Grant No. 11104156)the Postdoctoral Science Foundation of China (CPSF) (Grant No. 2012M510405)+1 种基金the Independent Research and Development Fund of Tsinghua University (Grant No. 20121087948)Beijing Key Laboratory of Fine Ceramics Opening Fund (Grant No. 2012200110)
文摘We compare the transport properties of electrons in monolayer graphene by modulating the Fermi velocity inside the barrier. A critical transmission angle is found only when the Fermi velocity in the barriers is larger than the one outside the barriers. It is shown that the transmission exhibits periodicity with the incident angle below the critical transmission angle, and attenuates exponentially in the opposite situation. For both situations, peak splitting occurs in the transmission as the number of the velocity barriers increases, and the characteristics of the transmission suggest an interesting application of an excellent band-pass filter. The dependence of the conductance on the Fermi energy through an identical velocity- modulation structure differs wildly with different Fermi velocities of the barrier. The counterpart of the peak splitting is the sharp oscillations in the conductance profile. Furthermore, some oscillations for the multiple barriers are so sharp that the structure may be used as an excellent sensor.
文摘To make the modulation classification system more suitable for signals in a wide range of signal to noise ratios (SNRs), a novel adaptive modulation classification scheme is presented in this paper. Differ-ent from traditional schemes, the proposed scheme employs a new SNR estimation algorithm for small samples before modulation classification, which makes the modulation classifier work adaptively according to estimated SNRs. Furthermore, it uses three efficient features and support vector machines (SVM) in modulation classification. Computer simulation shows that the scheme can adaptively classify ten digital modulation types (i.e. 2ASK, 4ASK, 2FSK, 4FSK, 2PSK, 4PSK, 16QAM, TFM, π/4QPSK and OQPSK) at SNRS ranging from 0dB to 25dB and success rates are over 95% when SNR is not lower than 3dB. Accuracy, efficiency and simplicity of the proposed scheme are obviously improved, which make it more adaptive to engineering applications.
基金Project supported by the National Basic Research Program of China(Grant Nos.2011CBA00101,2010CB923002,2012CB821404,and 2011CB921703)the National Natural Science Foundation of China(Grant Nos.11190022,11274368,and 51272277)the Funds from the Chinese Academy of Sciences
文摘Transmission electron microscopy (TEM) study of SrPt2As2 reveals two incommensurate modulations appearing in the charge-density-wave (CDW) state below TCDW ≈ 470 K. These two structural modulations can be well explained in terms of condensations of two-coupled phonon modes with wave vectors of q1=0.62a* on the a*-b* plane and q2 = 0.23a* on the a*-c* plane. The atomic displacements occur along the b-axis direction for q1 and along the c-axis direction for q2, respectively. Moreover, the correlation between ql and q2 can be generally written as q1 = (q2 + a*)/2 in the CDW state, suggesting the presence of essential coupling between q1 and q2. A small fraction of Ir doping on the Pt site in Sr(Pt1-xIrx)2As2 (x ≤ 0.06) could moderately change these CDW modulations and also affect their superconductivities.
基金Supported by the National Natural Science Foundation of China (No.60496311).
文摘This paper explores the potential to use accurate but outdated channel estimates for adaptive modulation. The work is novel in that the research is conditioned on block by block adaptation. First,we define a new quantity,the Tolerable Average Use Delay (TAUD),which can indicate the ability of an adaptation scheme to tolerate the delay of channel estimation results. We find that for the variable-power schemes,TAUD is a constant and dependent on the target Bit Error Rate (BER),average power and Doppler frequency; while for the constant-power schemes,it depends on the ad-aptation block length as well. At last,we investigate the relation between the delay tolerating per-formance and the spectral efficiency and give the system design criterion. The delay tolerating per-formance is improved at the price of lower data rate.
基金Project supported by the National Natural Science Foundation of China(52062042,51802164)the Natural Science Foundation of Inner Mongolia(2020MS05044)。
文摘Photochromic materials with multicolor upconversion reversible modulations are attractive in optical switching devices.Herein,the fabricated YNbO_(4):Er^(3+)/Tm^(3+)/Yb^(3+) materials exhibit excellent photochromism and multicolor upconversion properties from green,red to near infrared(NIR) emissions with increasing Yb concentrations.Reversible multiband upconversion modulations are achieved by alternating light(365 and 405 nm) or thermal stimuli.After 365 nm irradiation,the luminescence color changes from yellow to red,the luminescent photoswitching contrast reaches up to 86.21%(green),82.12%(red) and 77.38%(NIR) in the Y_(0.83)Er_(0.01)Tm_(0.01)NbO_(4):0.15 Yb sample.Besides,the upconversion emission intensity before and after photochromic reaction shows remarkable change in a wide temperature range of 298-718 K.These results indicate that the Er^(3+)/Tm^(3+)/Yb^(3+) tri-doped YNbO_(4) materials can be a good candidate in optical switching and data storage applications.
基金the support from the National Key R&D Program of China(No.2021YFA1501101)the National Natural Science Foundation of China(No.21971117)+12 种基金the National Natural Science Foundation of China/Research Grant Council of Hong Kong Joint Research Scheme(No.N_PolyU502/21)the National Natural Science Foundation of China/Research Grants Council(RGC)of Hong Kong Collaborative Research Scheme(No.CRS_PolyU504/22)the Functional Research Funds for the Central Nankai University(No.63186005)the Tianjin Key Lab for Rare Earth Materials and Applications(No.ZB19500202)the Open Funds(No.RERU2019001)the State Key Laboratory of Rare Earth Resource Utilization,the 111 Project(No.B18030)from Chinathe Beijing-Tianjin-Hebei Collaborative Innovation Project(No.19YFSLQY00030)the Outstanding Youth Project of Tianjin 21 Natural Science Foundation(No.20JCJQJC00130)the Key Project of Tianjin Natural Science Foundation(No.20JCZDJC00650)the funding for Projects of Strategic Importance of The Hong Kong Polytechnic University(Project Code:1-ZE2V)the Shenzhen Fundamental Research Scheme-General Program(No.JCYJ20220531090807017)the Natural Science Foundation of Guangdong Province(No.2023A1515012219)the Departmental General Research Fund(Project Code:ZVUL)from The Hong Kong Polytechnic University.
文摘Currently,dual atomic catalysts(DACs)with neighboring active sites for oxygen reduction reaction(ORR)still meet lots of challenges in the synthesis,especially the construction of atomic pairs of elements from different blocks of the periodic table.Herein,a“rare earth(Ce)-metalloid(Se)”non-bonding heteronuclear diatomic electrocatalyst has been constructed for ORR by rational coordination and carbon support defect engineering.Encouraging,the optimized Ce-Se diatomic catalysts(Ce-Se DAs/NC)displayed a half-wave potential of 0.886 V vs.reversible hydrogen electrode(RHE)and excellent stability,which surpass those of separate Ce or Se single atoms and most single/dual atomic catalysts ever reported.In addition,a primary zinc-air battery constructed using Ce-Se DAs/NC delivers a higher peak power density(209.2 mW·cm^(−2))and specific capacity(786.4 mAh·gZn^(−1))than state-of-the-art noble metal catalysts Pt/C.Theoretical calculations reveal that the Ce-Se DAs/NC has improved the electroactivity of the Ce-N_(4)region due to the electron transfer towards the nearby Se specific activity(SA)sites.Meanwhile,the more electron-rich Se sites promote the adsorptions of key intermediates,which results in the optimal performances of ORR on Ce-Se DAs/NC.This work provides new perspectives on electronic structure modulations via non-bonded long-range coordination micro-environment engineering in DACs for efficient electrocatalysis.
文摘The present research employs artificial intelligence to come up with an automatic solution for the modulation's classification of various radio signal varieties.As a result,the work we performed involved selecting the database required for supervised deep learning,evaluating the performance of current techniques on unprocessed communication signals,and suggesting a deep learning networkbased method that would enable the classification of modulation types with the best possible ratio between computation time and accuracy.We started by examining the automatic classification models that are currently in usage.In light of the difficulty of forecasting in low Signal Noise Ratio(SNR)situations,we suggested an ensemble learning strategy based on adjusted Res Net and Transformer Neural Network,which is effective at extracting multi-scale features from the raw I/Q sequence data.Finally,we produced an architecture that is simple to use and apply to communication signals.The architecture of this solution is strong and optimal,enabling it to determine the type of modulation with up to 95%accuracy automatically.
基金The authors acknowledge the micro-fabrication center of National Laboratory of Solid State Microstructures(NLSSM)for technique supportProf.Jia Zhu acknowledges the support from the XPLORER PRIZE+3 种基金This work is jointly supported by the National Key Research and Development Program of China(No.2021YFA140070)the National Natural Science Foundation of China(Nos.61735008,51925204,12022403)Excellent Research Program of Nanjing University(ZYJH005)Carbon Peaking and Carbon Neutrality Science and Technology Innovation Fund of Jiangsu Province(BK20220035).
文摘Two-dimensional(2D)materials have attracted considerable research interest,leading to significant advances in energy applications in recent years,such as lithium batteries,catalysis,electronics,and thermoelectrics,owing to their rich controllable properties and excellent performances.Recently,pressure has been successfully employed as an effective method for property modulation of 2D materials,through tuning electronic orbitals and bonding patterns.In this review,we summarize recent progresses in the pressure-driven property modulations and elucidate the underlying mechanism of the pressure modulation of 2D materials.Further,we identify the remaining challenges and opportunities in this new,vibrant area of research for energy conversion and utilization.Among the different property modulation strategies,the in situ application of high pressure is systematically identified as a promising knob for 2D materials.This review is expected to inspire further research on the fundamental understanding and practical applications of high-pressure modulation in 2D materials.
基金supported in part by the NSF of China under Grant 62322106,62071131the Guangdong Basic and Applied Basic Research Foundation under Grant 2022B1515020086+2 种基金the International Collaborative Research Program of Guangdong Science and Technology Department under Grant 2022A0505050070in part by the Open Research Fund of the State Key Laboratory of Integrated Services Networks under Grant ISN22-23the National Research Foundation,Singapore University of Technology Design under its Future Communications Research&Development Programme“Advanced Error Control Coding for 6G URLLC and mMTC”Grant No.FCP-NTU-RG-2022-020.
文摘This paper investigates the bit-interleaved coded generalized spatial modulation(BICGSM) with iterative decoding(BICGSM-ID) for multiple-input multiple-output(MIMO) visible light communications(VLC). In the BICGSM-ID scheme, the information bits conveyed by the signal-domain(SiD) symbols and the spatial-domain(SpD) light emitting diode(LED)-index patterns are coded by a protograph low-density parity-check(P-LDPC) code. Specifically, we propose a signal-domain symbol expanding and re-allocating(SSER) method for constructing a type of novel generalized spatial modulation(GSM) constellations, referred to as SSERGSM constellations, so as to boost the performance of the BICGSM-ID MIMO-VLC systems.Moreover, by applying a modified PEXIT(MPEXIT) algorithm, we further design a family of rate-compatible P-LDPC codes, referred to as enhanced accumulate-repeat-accumulate(EARA) codes,which possess both excellent decoding thresholds and linear-minimum-distance-growth property. Both analysis and simulation results illustrate that the proposed SSERGSM constellations and P-LDPC codes can remarkably improve the convergence and decoding performance of MIMO-VLC systems. Therefore, the proposed P-LDPC-coded SSERGSM-mapped BICGSMID configuration is envisioned as a promising transmission solution to satisfy the high-throughput requirement of MIMO-VLC applications.
基金financial support from the Sichuan Science and Technology Program(No.2022NSFSC0226)Open Fund(PLN2021–17)of State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation(Southwest Petroleum University)Science and Technology Project of Southwest Petroleum University(No.2021JBGS08).
文摘Hydrogen,meeting the requirements of sustainable development,is regarded as the ultimate energy in the 21st century.Due to the inexhaustible and feasible of solar energy,solar water splitting is an immensely promising strategy for environmental-friendly hydrogen production,which not only overcomes the fluctuation and intermittency but also contributes to achieving the mission of global“Carbon Neutrality and Carbon Peaking”.However,there is still a lack of a comprehensive overview focusing on hydrogen progress with a discussion of development from solar energy to solar cells.Herein,we emphasize several solar-to-hydrogen pathways from the basic concepts and principles and focus on photovoltaic-electrolysis and photoelectrochemical/photovoltaic systems,which have achieved solar-to-hydrogen(STH)efficiency of over 10%and have extremely promising for large-scale application.In addition,we summarize the challenges and opportunities faced in this field including configuration design,electrode materials,and performance evaluation.Finally,perspectives on the potential commercial application and scientific research for the further development of solar-to-hydrogen are analyzed and presented.
基金supported by the National Natural Science Foundation of China(U1930117,12204445)。
文摘Active control of terahertz(THz)waves is attracting tremendous attentions in terahertz communications and active photonic devices.Perovskite,due to its excellent photoelectric conversion performance and simple manufacturing process,has emerged as a promising candidate for optoelectronic applications.However,the exploration of perovskites in optically controlled THz modulators is still limited.In this work,the photoelectric properties and carrier dynamics of FA_(0.4)MA_(0.6)PbI_(3)perovskite films were investigated by optical pumped terahertz probe(OPTP)system.The ultrafast carrier dynamics reveal that FA_(0.4)MA_(0.6)PbI_(3)thin film exhibits rapid switching and relaxation time within picosecond level,suggesting that FA_(0.4)MA_(0.6)PbI_(3)is an ideal candidate for active THz devices with ultrafast response.Furthermore,as a proof of concept,a FA_(0.4)MA_(0.6)PbI_(3)-based metadevice with integrating plasma-induced transparency(PIT)effect was fabricated to achieve ultrafast modulation of THz wave.The experimental results demonstrated that the switching time of FA_(0.4)MA_(0.6)PbI_(3)-based THz modulator is near to 3.5 ps,and the threshold of optical pump is as low as 12.7μJ cm^(-2).The simulation results attribute the mechanism of ultrafast THz modulation to photo-induced free carriers in the FA_(0.4)MA_(0.6)PbI_(3)layer,which progressively shorten the capacitive gap of PIT resonator.This study not only illuminates the potential of FA_(0.4)MA_(0.6)PbI_(3)in THz modulation,but also contributes to the field of ultrafast photonic devices.
基金supported by Fujian Provincial Natural Science(2020J01122587)National Natural Science Foundation of China(82103355,82102255,and 82222901)+1 种基金RGC Theme-based Research Scheme(T12-703/19-R)Research grants Council-General Research Fund(14117422 and 14117123)。
文摘Hepatocellular carcinoma(HCC)is a prevalent and aggressive liver malignancy.The interplay between bile acids(BAs)and the gut microbiota has emerged as a critical factor in HCC development and progression.Under normal conditions,BA metabolism is tightly regulated through a bidirectional interplay between gut microorganisms and BAs.The gut microbiota plays a critical role in BA metabolism,and BAs are endogenous signaling molecules that help maintain liver and intestinal homeostasis.Of note,dysbiotic changes in the gut microbiota during pathogenesis and cancer development can disrupt BA homeostasis,thereby leading to liver inflammation and fibrosis,and ultimately contributing to HCC development.Therefore,understanding the intricate interplay between BAs and the gut microbiota is crucial for elucidating the mechanisms underlying hepatocarcinogenesis.In this review,we comprehensively explore the roles and functions of BA metabolism,with a focus on the interactions between BAs and gut microorganisms in HCC.Additionally,therapeutic strategies targeting BA metabolism and the gut microbiota are discussed,including the use of BA agonists/antagonists,probiotic/prebiotic and dietary interventions,fecal microbiota transplantation,and engineered bacteria.In summary,understanding the complex BA-microbiota crosstalk can provide valuable insights into HCC development and facilitate the development of innovative therapeutic approaches for liver malignancy.
基金This work was supported by the National Natural Science Foundation of China(52372289,52102368,52072192 and 51977009)Regional Joint Fund for Basic Research and Applied Basic Research of Guangdong Province(No.2020SA001515110905).
文摘The laminated transition metal disulfides(TMDs),which are well known as typical two-dimensional(2D)semiconductive materials,possess a unique layered structure,leading to their wide-spread applications in various fields,such as catalysis,energy storage,sensing,etc.In recent years,a lot of research work on TMDs based functional materials in the fields of electromagnetic wave absorption(EMA)has been carried out.Therefore,it is of great significance to elaborate the influence of TMDs on EMA in time to speed up the application.In this review,recent advances in the development of electromagnetic wave(EMW)absorbers based on TMDs,ranging from the VIB group to the VB group are summarized.Their compositions,microstructures,electronic properties,and synthesis methods are presented in detail.Particularly,the modulation of structure engineering from the aspects of heterostructures,defects,morphologies and phases are systematically summarized,focusing on optimizing impedance matching and increasing dielectric and magnetic losses in the EMA materials with tunable EMW absorption performance.Milestones as well as the challenges are also identified to guide the design of new TMDs based dielectric EMA materials with high performance.