C/SiC/MoSi_2-SiC-Si multilayer coating for oxidation protection of carbon/carbon composites

C/SiC/MoSi2-SiC-Si oxidation protective multilayer coating for carbon/carbon （C/C） composites was prepared by pack cementation and slurry method. The microstructure, element distribution and phase composition of the as-received coating were analyzed by scanning electron microscopy （SEM）, energy dispersive X-ray spectroscopy （EDS） and X-ray diffraction （XRD）. The results show that the multilayer coating was composed of MoSi2, SiC and Si. It could effectively protect C/C composites against oxidation for 200 h with the mass loss of 3.25% at 1873 K in static air. The mass loss of the coated C/C composites results from the volatilization of SiO2 and the formation of cracks and bubble holes in the coating.

Self-propagating high temperature synthesis of MoSi_2 matrix composites

MoSi2 is presently regarded as the most important material for electrical heating and as one with huge potential for high temperature structural uses. MoSi2 and MoSi2 matrix composites were prepared by self-propagating high temperature synthesis （SHS）. Pure MoSi2 was obtained and a compound of MoSi2 and WSi2was synthesized in the form of predominant solid solution （Mo,W）Si2. By adding aluminum of 5.5 at.% to Mo-Si, the crystal structure of MoSi2 changed into a mixture of tetragonal Cllb MoSi2and hexagonal C40 Mo（Si,Al）2. The （Mo,W）Si2-Mo（Si,Al）2-W（Si,Al）2 composite materials were synthesized by adding aluminum of 5.5 at.% to Mo-W-Si. However, if the amount of the added aluminum was not larger than 2.5 at.%, it did not have any significant effect. SHS is an effective technology for synthesis of MoSi2 and MoSi2 matrix composites.

Microstructure, sintering behavior and mechanical properties of SiC/MoSi_2 composites by spark plasma sintering

SiC/MoSi2 composites were synthesized at different temperatures by spark plasma sintering using Mo, Si and SiC powders as raw materials. The phase composition, microstructure and mechanical properties of the as-prepared composites were investigated and the sintering behavior was also discussed. Results show that SiC/MoSi2 composites are composed of MoSi2, SiC and trace amount of Mo4.8Si3C0.6 phase and exhibit a fine-grain texture. During the synthesis process, there was an evolution from solid phase sintering to liquid phase sintering. When sintered at 1600 °C, the SiC/MoSi2 composites present the most favorable mechanical properties, the Vickers hardness, bending strength and fracture toughness are 13.4 GPa, 674 MPa and 5.1 MPa·m^1/2, respectively, higher 44%, 171%, 82% than those of monolithic MoSi2. SiC can withstand the applied stress as hard phase and retard the rapid propagation of cracks as second phase, which are beneficial to the improved mechanical properties of Si C/MoSi2 composites.

MoSi_2-WSi_2复合体系的自蔓延燃烧合成

利用自蔓延燃烧合成法制备了 Mo Si2 - WSi2 复合粉体 ,并对合成产物进行了 X射线衍射分析。研究表明 ,通过自蔓延燃烧合成反应既可实现 Mo Si2 与 WSi2 的复合 ,又可通过调整反应物 Mo,W,Si的比例 ,在 Mo Si2 中引入 WSi2的同时还能引入足够量的 Mo5 Si3- W5 Si3相。W量的增加使体系的绝热温度降低 ,对自蔓延燃烧合成反应产生影响。研究还表明 Mo Si2 - WSi2 和 Mo5 Si3- W5 Si3均以固溶体的形式存在。

自蔓延热爆合成MoSi_2-WSi_2复合粉末

以Mo、W和Si粉为原料,采用自蔓延热爆合成制备了不同组分的MoSi2WSi2复合粉末,并利用X射线衍射仪和扫描电镜对合成产物进行了相组成和产物形貌分析。结果表明:热爆反应产物纯净,MoSi2WSi2复合粉末中只有MoSi2和WSi2两相存在;颗粒的大小取决于体系的摩尔生成焓,摩尔生成焓越大,颗粒长大越显著;热爆合成反应以Si的熔化为先导,反应机制为熔化溶解析出长大机制。

Fabrication and fracture analysis of MoSi_2 matrix composites by mechanical alloying

Four composites, MoSi 2+ZrO 2, MoSi 2+ZrO 2(Y 2O 3), MoSi 2+ZrO 2+SiC and MoSi 2+ZrO 2(Y 2O 3)+SiC are fabricated by mechanical alloying. It is clear that cracks produced on the MoSi 2 matrix composites during hardness testing belong to the Palmquist crack system. The value of highest fracture toughness of MoSi 2+ZrO 2+SiC composite is 7.58?MPa·m 1/2 , which is nearly three times that of monolithic MoSi 2. This can be attributed to well distributed ZrO 2 and SiC particles along the boundaries of very fine MoSi 2 grains.

MoSi_2-WSi_2复合材料自蔓延热爆合成反应热力学

对Mo-W-Si三元体系自蔓延热爆合成MoSi2-WSi2复合材料的反应吉布斯自由能、反应生成焓和绝热温度进行了理论分析和实验研究,并利用X射线衍射分析和扫描电镜及微区成分分析(EDAX)技术对产物进行了相组成和微区成分分析。结果表明:在1685K(Si熔点)时,MoSi2和WSi2的反应生成焓最大,分别为234.645kJ/mol和195.670kJ/mol。当初始温度为1685K时,体系所有产物均完全熔融。利用自蔓延热爆合成可制备纯净的MoSi2-WSi2复合材料。MoSi2和WSi2以固溶体(Mox,W1-x)Si2的形式存在,但每个晶粒内的成分并不均匀。

Properties of CNTs/MoSi2 composites prepared by spark plasma sintering

Molybdenum disilicide(MoSi_2) based composites with various contents of carbon nanotubes(CNTs) were fabricated by spark plasma sintering(SPS) in vacuum under a pressure of 25 MPa.The composites obtained under a sintering temperature of 1500 °C and time of 10 min exhibited optimum mechanical properties at room temperature in terms of fracture toughness and transverse rupture strength.MoSi_2 based composite with 6.0% CNTs(volume fraction) had the highest fracture toughness,transverse rupture strength and hardness,which were improved by about 25.7%,51.5% and 24.4% respectively,as compared with pure MoSi_2.A Mo_(4.8)Si_3C_(0.6) phase was detected in CNTs/MoSi_2 composites by both X-ray diffraction(XRD) method and microstructure analysis with scanning electron microscopy(SEM).It is believed that the fine grains and well dispersed small Mo_(4.8)Si_3C_(0.6) particles had led to a higher hardness and strength of CNTs/MoSi_2 composites because of their particle pullout,crack deflection and micro-bridging effects.

Fabrication of MoSi_2-SiC Composites by a Spark Plasma Sintering Method

MolybdenUmdisilicidepeoSi,)hashighmeltingpoint（2293K）,relativelylowdensity（6.249/cm3）,abrittle-to-ductiletemper;tabout1173K[l]andoutstandingoxidationresistance[2M].Forthisreason,thedisilicidematrixcompositesarebeingconsideredasoneofthemoStPromisingc...

Effect of MoSi_2 content on dielectric and mechanical properties of MoSi_2/Al_2O_3 composite coatings

Molybdenum disilicide （MoSi2） sheath and aluminum oxide （Al2O3） core blended powders were fabricated by spray drying. A derived coating material was produced for the application as microwave absorbers using the as prepared powders by atmospheric plasma spray （APS） technology. The effects of MoSi2/Al2O3 mass ratio on the dielectric and physical mechanical properties of the composite coatings were investigated. When the MoSi2 content of the composites increases from 0 to 45%, the flexure strength and fracture toughness improve from 198 to 324 MPa and 3.05 to 4.82 MPa-m1/2 then decline to 310 MPa and 4.67 MPa-m1/2, respectively. The dielectric loss tangent increases with increasing MoSi2 content, and the real part of permittivity decreases conversely over the frequency range of 8.2-12.4 GHz. These effects are due to the agglomeration of early molten MoSi2 particles and the increase of the electrical conductivity with increasing MoSi2 content.

TOUGHENING OF IN SITU SYNTHESIZED MoSi_2-SiC COMPOSITE AT ROOM TEMPERATURE

The in situ synthesized MoSi2-SiC composite is proved to be of higher fracture toughness than the monolithic MoSi2. The TEM and HREM study reveals that the interface between MoSi2/SiC is of direct atomic bonding without any amorphous glassy phase, such the SiO2 structure. Based on the fractography and the observation of crack propagation path from indentation, it is concluded that the toughening of such composite at room temperature can be attributed to the high interfacial binding energy, the refinement of the MoSi2 matrix and the deflection and bridging behavior in the crack propagation.

High temperature creep behavior of in-situ synthesized MoSi_2-30%SiC composite

The compressive creep behavior at 1?200 ～ 1?400?℃ of an in situ synthesized MoSi 2 30%SiC (volume fraction) composite and a traditional PM MoSi 2 30%SiC (volume fraction) composite is investigated. The creep rate of the in situ synthesized MoSi 2 30%SiC (volume fraction) composite is about 10 -7 s -1 under stress of 60 ～ 120?MPa, and significantly lower than that made by PM method above 1?300?℃. The reason is that the interface between SiC particle and MoSi 2 matrix in in situ synthesized SiC p/MoSi 2 is of direct atomic bonding without any amorphous glassy phase, such as SiO 2 structure. Creep deformation occurs primarily by dislocation motion and the dislocations have Burgers vectors of the type of <110> and <100>.

碳/碳复合材料 MoSi_2 涂层的防氧化研究

研究了碳／碳复合材料ＭｏＳｉ２防氧化涂层的性能。结果表明，ＭｏＳｉ２涂层系统具有１５００℃长时间防氧化作用，在１５００℃时，带涂层的碳／碳复合材料长时间氧化失重速率稳定在２．４３×１０－５ｇ／ｍ２·ｓ，２４２小时的氧化失重为０．５７％，该质量损失表现为涂层系统自身蒸发损耗；同时。

防止 C/C 复合材料氧化的 MoSi_2/SiC 双相涂层系统的研究

由固相扩散—浸渗处理制备了防止碳／碳复合材料氧化的ＭｏＳｉ２／ＳｉＣ双相涂层。通过对涂层的结构、成份以及氧化机理的研究表明，ＭｏＳｉ２／ＳｉＣ双相涂层由内层为β－ＳｉＣ和外层为ＭｏＳｉ２／ＳｉＣ双相层构成，具有优异的高温抗氧化性能。

Nb增韧MoSi_2基复合材料的研究进展

从增韧机理、增强体形态对材料性能的影响、界面反应等方面阐述了 Nb增韧 Mo Si2 复合材料的研究进展 ,指出 Mo Si2 -

激光涂覆制备原位自生MoSi_2/SiC陶瓷复合涂层的研究

为了在碳钢表面获得耐磨、耐蚀、抗热疲劳等综合性能优良的陶瓷基复合涂层 ,利用 3kW连续波快速轴流CO2 激光器进行了一系列的激光表面涂覆试验 ,光斑直径3～5mm ,扫描速度 3～ 10mm/s。试验结果表明 ,利用激光表面涂覆技术和粉末预置法 ,可以在碳钢表面直接原位合成SiC颗粒增韧的MoSi2 陶瓷基复合涂层 ,涂层与基体呈良好的冶金结合 ,涂层宏观质量完好 ,无裂纹和气孔等缺陷。球状SiC颗粒尺寸为 1～ 5 μm ,均匀分布于MoSi2 基体内。涂层显微硬度达 10 0 0HV0 2 ,是基材显微硬度的 4

WSi_2/MoSi_2复合材料的摩擦磨损特性

选用 MM- 2 0 0型摩擦磨损试验机测定了不同载荷条件下 WSi2 /Mo Si2 复合材料与 45 #钢配副的干摩擦磨损性能 ,采用扫描电子显微镜和 X射线衍射仪分析讨论了其磨损机理 .结果表明 :WSi2 /Mo Si2 复合材料在高于 80 N载荷条件下具有比较稳定的摩擦磨损性能 ;在 85～ 1 3 5 N范围内其摩擦磨损性能优于 Mo Si2 材料 .WSi2 /Mo Si2

WSi_2/MoSi_2复合材料的低温氧化特征

通过热重分析法研究了WSi2 /MoSi2 复合材料在 4 0 0～ 70 0℃的氧化性能 ,采用X 射线和SEM分析了表面氧化相的组成和表面形貌。结果表明 :WSi2 /MoSi2 复合材料具有较低的低温抗氧化性 ,5 0 0～ 70 0℃氧化会发生“PEST”现象 ;6 0 0和 70 0℃氧化时的质量增重与时间近似于线性关系 ;大量MoO3 和WO3 等挥发性氧化相的形成 ,破坏了连续致密保护性SiO2 膜的形成 ,促进了裂纹的产生与扩展 ,导致颗粒分离 ,成为“PEST”

原位技术在 MoSi_2 基复合材料制备中的应用与发展

从复合材料增强相的原位引入和原位涂层两个方面，对制备ＭｏＳｉ２基复合材料的燃烧合成、固态置换反应、机械合金化、反应浸渗和反应喷雾沉积等原位复合技术的现状和发展作了概述。

Al/MoSi_2复合材料的低温氧化行为

通过热重量分析法研究了Al/MoSi2 复合材料在 40 0～ 70 0℃的氧化性能 ,采用SEM和X射线衍射仪观察与测定了其表面形貌和相组成。结果表明 :Al/MoSi2 复合材料在 40 0 ,6 0 0和 70 0℃氧化时 ,质量变化较少 ,归因于表面形成较连续的 3Al3 O2 ·2SiO2 保护膜 ;而它在 5 0 0℃氧化过程中 ,大量生成挥发性MoO3 相 ,破坏了 3Al3 O2 ·2SiO2 保护性膜的形成 ,导致了PEST现象的发生。