Metamaterials(MTM)can enhance the properties of microwaves and also exceed some limitations of devices used in technical practice.Note that the antenna is the element for realizing a microwave imaging(MWI)system since...Metamaterials(MTM)can enhance the properties of microwaves and also exceed some limitations of devices used in technical practice.Note that the antenna is the element for realizing a microwave imaging(MWI)system since it is where signal transmission and absorption occur.Ultra-Wideband(UWB)antenna superstrates with MTM elements to ensure the signal transmitted from the antenna reaches the tumor and is absorbed by the same antenna.The lack of conventional head imaging techniques,for instance,Magnetic Resonance Imaging(MRI)and Computerized Tomography(CT)-scan,has been demonstrated in the paper focusing on the point of failure of these techniques for prompt diagnosis and portable systems.Furthermore,the importance ofMWIhas been addressed elaborately to portray its effectiveness and aptness for a primary tumor diagnosis.Other than that,MTM element designs have been discussed thoroughly based on their performances towards the contributions to the better image resolution of MWI with detailed reasonings.This paper proposes the novel design of a Zeroindex Split RingResonator(SRR)MTMelement superstrate with a UWB antenna implemented in MWI systems for detecting tumor.The novel design of the MTM enables the realization of a high gain of a superstrate UWB antenna with the highest gain of 5.70 dB.Besides that,the MTM imitates the conduct of the zeroreflection phase on the resonance frequency,which does not exist.An antenna with an MTM unit is of a 7×4 and 10×5 Zero-index SRR MTM element that acts as a superstrate plane to the antenna.Apart from that,Rogers(RT5880)substrate material is employed to fabricate the designed MTM unit cell,with the following characteristics:0.51mm thickness,the loss tangent of 0.02,as well as the relative permittivity of 2.2,with Computer Simulation Technology(CST)performing the simulation and design.Both MTM unit cells of 7×4 and 10×5 attained 0°with respect to the reflection phase at the 2.70 GHz frequency band.The first design,MTM Antenna Design 1,consists of a 7×4 MTM unit cell that observed a rise of 5.70 dB with a return loss(S11)−20.007 dB at 2.70 GHz frequency.The second design,MTM Antenna Design 2,consists of 10×5 MTM unit cells that recorded a gain of 5.66 dB,having the return loss(S11)−19.734 dB at 2.70 GHz frequency.Comparing these two MTM elements superstrates with the antenna,one can notice that the 7×4 MTM element shape has a low number of the unit cell with high gain and is a better choice than the 10×5 MTM element in realizing MTM element superstrates antenna for MWI.展开更多
Nitration of aromatic Compounds is triggered by Vilsmeier-Haack reagent (DMF/POCl3) or (DMF/SOCl2) in the presence of KNO3 or NaNO2 under conventional and non-conventional conditions. The reactions af- forded correspo...Nitration of aromatic Compounds is triggered by Vilsmeier-Haack reagent (DMF/POCl3) or (DMF/SOCl2) in the presence of KNO3 or NaNO2 under conventional and non-conventional conditions. The reactions af- forded corresponding Nitro derivatives in very good yield with high regioselectivity. The results obtained in non-conventional methods (Micro wave irradiation, Grinding, Sonication) are comparable with those ob- tained under conventional conditions, but the reaction times of former conditions are substantially shorter than that of the latter.展开更多
The microwave absorption efficiency, which is relevant to magnet field and its distribution, is a major parameter of the microwave ion source (MWIS) for the intense neutron tube. Based on previous work, the relations ...The microwave absorption efficiency, which is relevant to magnet field and its distribution, is a major parameter of the microwave ion source (MWIS) for the intense neutron tube. Based on previous work, the relations between microwave absorption efficiency and plasma chamber structure and thickness of the microwave introduction window are studied. The microwave absorption efficiency reaches to 100% when plasma chamber is 100mm long and the window thickness is 30mm. The microwave absorption efficiency as a function of pressure is also presented.展开更多
A facile, high yielding green chemical synthetic protocol adaptable to the parallel synthesis of a library of potentially bioactive 2-amino-4-arylthiazoles is reported herein. The methodology involves the condensation...A facile, high yielding green chemical synthetic protocol adaptable to the parallel synthesis of a library of potentially bioactive 2-amino-4-arylthiazoles is reported herein. The methodology involves the condensation of various aracyl bromides with N-arylthioureas under MWI using water as solvent, to yield pure products (81%-97%) in very short reaction times (1-20 min).展开更多
In order to increase the evaluating precision of mesh reflection wave, the mesh wave impedance (MWI) is extended to the non-uniform mesh in 1-D and 2-D cases for the first time on the basis of the Yee's positional...In order to increase the evaluating precision of mesh reflection wave, the mesh wave impedance (MWI) is extended to the non-uniform mesh in 1-D and 2-D cases for the first time on the basis of the Yee's positional relation for electromagnetic field components. Lots of characteristics are obtained for different mesh sizes and frequencies. Then the reflection coefficient caused by the non-uniform mesh can be calculated according to the theory of equivalent transmission line. By comparing it with that calculated by MWI in the uniform mesh, it is found that the evaluating error can be largely reduced and is in good agreement with that directly computed by FDTD method. And this extension of MWI can be used in the error analysis of complex mesh.展开更多
A series of pyrido[2,3-d]pyrimidines derivatives have been prepared by one-pot three-component reaction of 4(6)-aminouracil, malononitrile and aromatic aldehydes. This efficient synthesis was done under microwave irra...A series of pyrido[2,3-d]pyrimidines derivatives have been prepared by one-pot three-component reaction of 4(6)-aminouracil, malononitrile and aromatic aldehydes. This efficient synthesis was done under microwave irradiation conditions (method A) and also using catalytic amount of diammonium hydrogen phosphate [(NH4)2HPO4] (DAHP) in aqueous media (method B). This procedure has the advantages of good yields, easy work-up, and benign environmentally friendly character. Reaction could proceed via domino Knoevenagel-Michael-cyclization reactions.展开更多
基金the Fundamental Research Grant Scheme (FRGS/1/2018/ICT06/UNIMAP/02/1)of the Ministry of Higher Education of Malaysia.
文摘Metamaterials(MTM)can enhance the properties of microwaves and also exceed some limitations of devices used in technical practice.Note that the antenna is the element for realizing a microwave imaging(MWI)system since it is where signal transmission and absorption occur.Ultra-Wideband(UWB)antenna superstrates with MTM elements to ensure the signal transmitted from the antenna reaches the tumor and is absorbed by the same antenna.The lack of conventional head imaging techniques,for instance,Magnetic Resonance Imaging(MRI)and Computerized Tomography(CT)-scan,has been demonstrated in the paper focusing on the point of failure of these techniques for prompt diagnosis and portable systems.Furthermore,the importance ofMWIhas been addressed elaborately to portray its effectiveness and aptness for a primary tumor diagnosis.Other than that,MTM element designs have been discussed thoroughly based on their performances towards the contributions to the better image resolution of MWI with detailed reasonings.This paper proposes the novel design of a Zeroindex Split RingResonator(SRR)MTMelement superstrate with a UWB antenna implemented in MWI systems for detecting tumor.The novel design of the MTM enables the realization of a high gain of a superstrate UWB antenna with the highest gain of 5.70 dB.Besides that,the MTM imitates the conduct of the zeroreflection phase on the resonance frequency,which does not exist.An antenna with an MTM unit is of a 7×4 and 10×5 Zero-index SRR MTM element that acts as a superstrate plane to the antenna.Apart from that,Rogers(RT5880)substrate material is employed to fabricate the designed MTM unit cell,with the following characteristics:0.51mm thickness,the loss tangent of 0.02,as well as the relative permittivity of 2.2,with Computer Simulation Technology(CST)performing the simulation and design.Both MTM unit cells of 7×4 and 10×5 attained 0°with respect to the reflection phase at the 2.70 GHz frequency band.The first design,MTM Antenna Design 1,consists of a 7×4 MTM unit cell that observed a rise of 5.70 dB with a return loss(S11)−20.007 dB at 2.70 GHz frequency.The second design,MTM Antenna Design 2,consists of 10×5 MTM unit cells that recorded a gain of 5.66 dB,having the return loss(S11)−19.734 dB at 2.70 GHz frequency.Comparing these two MTM elements superstrates with the antenna,one can notice that the 7×4 MTM element shape has a low number of the unit cell with high gain and is a better choice than the 10×5 MTM element in realizing MTM element superstrates antenna for MWI.
文摘Nitration of aromatic Compounds is triggered by Vilsmeier-Haack reagent (DMF/POCl3) or (DMF/SOCl2) in the presence of KNO3 or NaNO2 under conventional and non-conventional conditions. The reactions af- forded corresponding Nitro derivatives in very good yield with high regioselectivity. The results obtained in non-conventional methods (Micro wave irradiation, Grinding, Sonication) are comparable with those ob- tained under conventional conditions, but the reaction times of former conditions are substantially shorter than that of the latter.
基金Innovation Fund for Technology-based Small Firms (99C26212210085)
文摘The microwave absorption efficiency, which is relevant to magnet field and its distribution, is a major parameter of the microwave ion source (MWIS) for the intense neutron tube. Based on previous work, the relations between microwave absorption efficiency and plasma chamber structure and thickness of the microwave introduction window are studied. The microwave absorption efficiency reaches to 100% when plasma chamber is 100mm long and the window thickness is 30mm. The microwave absorption efficiency as a function of pressure is also presented.
文摘A facile, high yielding green chemical synthetic protocol adaptable to the parallel synthesis of a library of potentially bioactive 2-amino-4-arylthiazoles is reported herein. The methodology involves the condensation of various aracyl bromides with N-arylthioureas under MWI using water as solvent, to yield pure products (81%-97%) in very short reaction times (1-20 min).
文摘In order to increase the evaluating precision of mesh reflection wave, the mesh wave impedance (MWI) is extended to the non-uniform mesh in 1-D and 2-D cases for the first time on the basis of the Yee's positional relation for electromagnetic field components. Lots of characteristics are obtained for different mesh sizes and frequencies. Then the reflection coefficient caused by the non-uniform mesh can be calculated according to the theory of equivalent transmission line. By comparing it with that calculated by MWI in the uniform mesh, it is found that the evaluating error can be largely reduced and is in good agreement with that directly computed by FDTD method. And this extension of MWI can be used in the error analysis of complex mesh.
文摘A series of pyrido[2,3-d]pyrimidines derivatives have been prepared by one-pot three-component reaction of 4(6)-aminouracil, malononitrile and aromatic aldehydes. This efficient synthesis was done under microwave irradiation conditions (method A) and also using catalytic amount of diammonium hydrogen phosphate [(NH4)2HPO4] (DAHP) in aqueous media (method B). This procedure has the advantages of good yields, easy work-up, and benign environmentally friendly character. Reaction could proceed via domino Knoevenagel-Michael-cyclization reactions.
