The Hesar pluton in the northern Urumieh-Dokhtar magmatic arc hosts numerous mafic-microgranular enclaves(MMEs).Whole rock geochemistry,mineral chemistry,zircon U-Pb and Sr-Nd isotopes were measured.It is suggested th...The Hesar pluton in the northern Urumieh-Dokhtar magmatic arc hosts numerous mafic-microgranular enclaves(MMEs).Whole rock geochemistry,mineral chemistry,zircon U-Pb and Sr-Nd isotopes were measured.It is suggested that the rocks are metaluminous(A/CNK=1.32-1.45),subduction-related I-type calc-alkaline gabbro to diorite with similar mineral assemblages and geochemical signatures.The host rocks yielded an U-Pb crystallization age of 37.3±0.4 Ma for gabbro-diorite.MMEs have relatively low SiO_(2) contents(52.9-56.6 wt%)and high Mg^(#)(49.8-58.7),probably reflecting a mantle-derived origin.Chondrite-and mantle-normalized trace element patterns are characterized by LREE and LILE enrichment,HREE and HFSE depletion with slight negative Eu anomalies(Eu/Eu^(*)=0.86-1.03).The host rocks yield(^(87)Sr/^(86)Sr)_(i) ratios of 0.70492-0.70510,positive ε_(Nd)(t)values of+1.55-+2.06 and T_(DM2)of 707-736 Ma,which is consistent with the associated mafic microgranular enclaves((^(87)Sr/^(86)Sr)_(i)=0.705014,ε_(Nd)(t)=+1.75,T_(DM2)=729 Ma).All data suggest magma-mixing for enclave and host rock formation,showing a complete equilibration between mixed-mafic and felsic magmas,followed by rapid diffusion.The T_(DM1)(Nd)and T_(DM2)(Nd)model ages and U-Pb dating indicate that the host pluton was produced by partial melting of the lower continental crust and subsequent mixing with injected lithospheric mantlederived magmas in a pre-collisional setting of Arabian-Eurasian plates.Clinopyroxene composition indicates a crystallization temperature of~1000℃ and a depth of~9 km.展开更多
Magmatic Ni-Cu-(PGE) sulfide and Fe-Ti oxide deposits in plume-related large igneous provinces(LIPs)are commonly related to low-Ti and high-Ti series magmas, respectively, but the major factors that control such a rel...Magmatic Ni-Cu-(PGE) sulfide and Fe-Ti oxide deposits in plume-related large igneous provinces(LIPs)are commonly related to low-Ti and high-Ti series magmas, respectively, but the major factors that control such a relationship of metallogenic types and magma compositions are unclear. Magma fOcontrols sulfur status and relative timing of Fe-Ti oxide saturation in mafic magmas, which may help clarify this issue. Taking the Emeishan LIP as a case, we calculated the magma fOof the high-Ti and low-Ti picrites based on the olivine-spinel oxygen barometer, and the partitioning of V in olivine. The obtained fOof the high-Ti series magma(FMQ + 1.1 to FMQ + 2.6) is higher than that of the low-Ti series magma(FMQ-0.5to FMQ + 0.5). The magma fOof the high-Ti and low-Ti picrites containing Fo > 90 olivine reveals that the mantle source of the high-Ti series is likely more oxidized than that of the low-Ti series. The results using the ’lambda REE’ approach show that the high-Ti series may have been derived from relatively oxidized mantle with garnet pyroxenite component. The S contents at sulfide saturation(SCSS) of the two series magmas were calculated based on liquid compositions obtained from the alpha Melts modeling, and the results show that the low-Ti series magma could easily attain the sulfide saturation as it has low fOwith S being dominantly as S. In contrast, the oxidized high-Ti series magma is difficult to attain the sulfide saturation, but could crystallize Fe-Ti oxides at magma MgO content of ~7.0 wt.%. Thus, contrasting magma fOof low-Ti and high-Ti series in plume-related LIPs may play an important role in producing two different styles of metallogeny.展开更多
Ten rock samples consisting of one pyroclastic density current(PDC1)deposit,seven lava flows(LF1–7),and two summit lava domes(LD1,2)were studied to understand the petrogenesis and magma dynamics at Mt.Sumbing.The str...Ten rock samples consisting of one pyroclastic density current(PDC1)deposit,seven lava flows(LF1–7),and two summit lava domes(LD1,2)were studied to understand the petrogenesis and magma dynamics at Mt.Sumbing.The stratigraphy is arranged as LF1,PDC1,LF2,LF3,LF4,LF5,LF6,LF7,LD1,and LD2;furthermore,these rocks were divided into two types.TypeⅠ,observed in the oldest(LF1)sample,has poor MgO and high Ba/Nb,Th/Yb and Sr.The remaining samples(PDC1–LD2)represent typeⅡ,characterized by high MgO and low Ba/Nb,Th/Yb and Sr values.We suggest that type I is derived from AOC(altered oceanic crust)-rich melts that underwent significant crustal assimilation,while typeⅡoriginates from mantle-rich melts with less significant crustal assimilation.The early stage of typeⅡmagma(PDC1–LF3)was considered a closed system,evolving basaltic andesite into andesite(55.0–60.2 wt%SiO_(2))with a progressively increasing phenocryst(0.30–0.48φ_(PC))and decreasing crystal size distribution(CSD)slope(from-3.9 to-2.9).The evidence of fluctuating silica and phenocryst contents(between 55.9–59.7 wt%and 0.25–0.41φ_(PC),respectively),coupled with the kinked and steep(from-5.0 to-3.3)CSD curves imply the interchanging condition between open(i.e.,magma mixing)and closed magmatic systems during the middle stage(LF4–LF6).Finally,it underwent to closed system again during the final stage(LF7–LD2)because the magma reached dacitic composition(at most 68.9 wt%SiO_(2))with abundant phenocryst(0.38–0.45φ_(PC))and gentle CSD slope(from-4.1 to-1.2).展开更多
There are two factors,source composition and magmatic differentiation,potentially controlling W-Sn mineralization.Which one is more important is widely debated and may need to be determined for each individual deposit...There are two factors,source composition and magmatic differentiation,potentially controlling W-Sn mineralization.Which one is more important is widely debated and may need to be determined for each individual deposit.The Xitian granite batholith located in South China is a natural laboratory for investigating the above problem.It consists essentially of two separate components,formed in the Triassic at ca.226 Ma and Jurassic at ca.152 Ma,respectively.The Triassic and Jurassic rocks are both composed of porphyritic and fine-grained phases.The latter resulted from highlydifferentiated porphyritic ones but they have similar textural characteristics and mineral assemblages,indicating that they reached a similar degree of crystal fractionation.Although both fine-grained phases are highly differentiated with elevated rare metal contents,economic W–Sn mineralization is rare in the Triassic granitoids and this can be attributed to less fertile source materials than their Jurassic counterparts,with a slightly more enriched isotopic signature and whole-rockεNd(226 Ma)of−10.4 to−9.2(2σ=0.2)compared withεNd(152 Ma)of−9.2 to−8.2(2σ=0.2)for the Jurassic rocks.The initial W-Sn enrichment was derived from the metasedimentary rocks and strongly enhanced by reworking of the continental crust,culminating in the Jurassic.展开更多
Porphyry Cu(Mo-Au)deposit is one of the most important types of copper deposit and usually formed under magmatic arc-related settings,whilst the Mujicun porphyry Cu-Mo deposit in North China Craton uncommonly generate...Porphyry Cu(Mo-Au)deposit is one of the most important types of copper deposit and usually formed under magmatic arc-related settings,whilst the Mujicun porphyry Cu-Mo deposit in North China Craton uncommonly generated within intra-continental settings.Although previous studies have focused on the age,origin and ore genesis of the Mujicun deposit,the ore-forming age,magma source and tectonic evolution remain controversial.Here,this study targeted rutile(TiO_(2))in the ore-hosting diorite porphyry from the Mujicun Cu-Mo deposit to conduct in situ U-Pb dating and trace element composition studies,with major views to determine the timing and magma evolution and to provide new insights into porphyry Cu-Mo metallogeny.Rutile trace element data show flat-like REE patterns characterized by relatively enrichment LREEs and depleted HREEs,which could be identified as magmatic rutile.Rutile U-Pb dating yields lower intercept ages of 139.3–138.4 Ma,interpreted as post magmatic cooling timing below about 500℃,which are consistent or slightly postdate with the published zircon U-Pb ages of diorite porphyry(144.1–141.7 Ma)and skarn(146.2 Ma;139.9 Ma)as well as the molybdenite Re-Os ages of molybdenum ores(144.8–140.0 Ma).Given that the overlap between the closure temperature of rutile U-Pb system and ore-forming temperature of the Mujicun deposit,this study suggests that the ore-forming ages of the Mujicun deposit can be constrained at 139.3–138.4 Ma,with temporal links to the late large-scale granitic magmatism at 138–126 Ma in the Taihang Orogen.Based on the Mg and Al contents in rutile,the magma of ore-hosting diorite porphyry was suggested to be derived from crust-mantle mixing components.In conjunction with previous studies in Taihang Orogen,this study proposes that the far-field effect and the rollback of the subducting Paleo-Pacific slab triggered lithospheric extension,asthenosphere upwelling,crust-mantle interaction and thermo-mechanical erosion,which jointly facilitated the formation of dioritic magmas during the Early Cretaceous.Subsequently,the dioritic magmas carrying crust-mantle mixing metallic materials were emplaced and precipitated at shallow positions along NNE-trending ore-controlling faults,eventually resulting in the formation of the Mujicun Cu-Mo deposit within an intracontinental extensional setting.展开更多
The mafic enclaves from Paleoproterozoic domain are considered to be the results of large-scale crust-mantle interaction and magma mixing. In this paper, petrography, mineralogy and geochemistry were jointly used to d...The mafic enclaves from Paleoproterozoic domain are considered to be the results of large-scale crust-mantle interaction and magma mixing. In this paper, petrography, mineralogy and geochemistry were jointly used to determine the origin of the mafic enclaves and their relationship with the host granitoids of the Kan granite-gneiss complex. This study also provides new information on crust-mantle interactions. The mafic enclaves of the Kan vary in shape and size and have intermediate chemical compositions. The diagrams used show a number of similarities in the major elements (and often in the trace elements) between the mafic enclaves and the host granitoids. Geochemical show that the Kan rock are metaluminous, enriched in silica, medium to high-K calc-alkaline I-type granite. The similarities reflect a mixing of basic and acid magma. Mafic enclaves have a typical magmatic structure, which is characterized by magma mixing. The genesis of these rocks is associated with the context of subduction. They result from the mixing of a mafic magma originating from the mantle and linked to subduction, and a granitic magma (type I granite) that arises from the partial melting of the crust.展开更多
The presented research illustrates the applicability and productiveness of the systematic literature review methodology, a non-empirical methodology in the geological sciences, particularly volcanology. The systematic...The presented research illustrates the applicability and productiveness of the systematic literature review methodology, a non-empirical methodology in the geological sciences, particularly volcanology. The systematic literature review methodology is a replicable, rigorous, and transparent methodology for synthesizing existing literature to answer questions on a specific topic. The synthesis allows for knowledge consolidation, such as identifying knowledge gaps. In our illustration of this methodology, we focused on the expanding knowledge about the magma pathway at Mount Cameroon, one of Africa’s active volcanoes. Our synthesis of the relevant international geoscience research literature is based on the framework of knowledge about the magma pathway beneath a typical basaltic volcano. The framework has three primary components: magma supply, storage, and transport to erupting vents. Across these components is a total of twelve secondary components. The result is a previously non-existent and fragmented overall understanding of the magma pathway at Mount Cameroon. The gaps in the understanding (such as in the magma supply rates, timescales of chamber processes, and magma ascent rates) may be addressed in future research. Another key implication of the presented research lies in the proof of concept of the systematic literature review methodology as an applicable qualitative research methodology in the study of volcanoes.展开更多
The three most crucial factors for the formation of large and super-large magmatic sulfide deposits are: (1) a large volume of mantle-derived mafic-ultramafic magmas that participated in the formation of the deposi...The three most crucial factors for the formation of large and super-large magmatic sulfide deposits are: (1) a large volume of mantle-derived mafic-ultramafic magmas that participated in the formation of the deposits; (2) fractional crystallization and crustal contamination, particularly the input of sulfur from crustal rocks, resulting in sulfide immiscibility and segregation; and (3) the timing of sulfide concentration in the intrusion. The super-large magmatic Ni-Cu sulfide deposits around the world have been found in small mafic-ultramafic intrusions, except for the Sudbury deposit. Studies in the past decade indicated that the intrusions hosting large and super-large magmatic sulfide deposits occur in magma conduits, such as those in China, including Jinchuan (Gansu), Yangliuping (Sichuan), Kalatongke (Xinjiang), and Hongqiling (Jilin). Magma conduits as open magma systems provide a perfect environment for extensive concentration of immiscible sulfide melts, which have been found to occur along deep regional faults. The origin of many mantle-derived magmas is closely associated with mantle plumes, intracontinental rifts, or post-collisional extension. Although it has been confirmed that sulfide immiscibility results from crustal contamination, grades of sulfide ores are also related to the nature of the parental magmas, the ratio between silicate magma and immiscible sulfide melt, the reaction between the sulfide melts and newly injected silicate magmas, and fractionation of the sulfide melt. The field relationships of the ore-bearing intrusion and the sulfide ore body are controlled by the geological features of the wall rocks. In this paper, we attempt to demonstrate the general characteristics, formation mechanism,tectonic settings, and indicators of magmatic sulfide deposits occurring in magmatic conduits which would provide guidelines for further exploration.展开更多
Magma mingling has been identified within the continental margin of southeastern China.This study focuses on the relationship between mafic and felsic igneous rocks in composite dikes and plutons in this area,and uses...Magma mingling has been identified within the continental margin of southeastern China.This study focuses on the relationship between mafic and felsic igneous rocks in composite dikes and plutons in this area,and uses this relationship to examine the tectonic and geodynamic implications of the mingling of mafic and felsic magmas.Mafic magmatic enclaves(MMEs) show complex relationships with the hosting Xiaocuo granite in Fujian area,including lenticular to rounded porphyritic microgranular enclaves containing abundant felsic/mafic phenocrysts,elongate mafic enclaves,and back-veining of the felsic host granite into mafic enclaves.LA-ICP-MS zircon U-Pb analyses show crystallization of the granite and dioritic mafic magmatic enclave during ca.132 and 116 Ma.The host granite and MMEs both show zircon growth during repeated thermal events at-210 Ma and 160-180 Ma.Samples from the magma mingling zone generally contain felsic-derived zircons with well-developed growth zoning and aspect ratios of 2-3,and maficderived zircons with no obvious oscillatory zoning and with higher aspect ratios of 5-10.However,these two groups of zircons show no obvious trace element or age differences.The Hf-isotope compositions show that the host granite and MMEs have similar ε(Hf)(t) values from negative to positive which suggest a mixed source from partial melting of the Meso-Neoproterozoic with involvement of enriched mantlederived magmas or juvenile components.The lithologies,mineral associations,and geochemical characteristics of the mafic and felsic rocks in this study area indicate that both were intruded together,suggesting Early Cretaceous mantle—crustal interactions along the southeastern China continental margin.The Early Cretaceous magma mingling is correlated to subduction of Paleo-Pacific plate.展开更多
For skarn type deposits , there are two lands of skarns , skarn formed by filtrating-diffusing metasomatism and vein skarn formed by filling . The vein skarn , discussed this paper and considered to be magmatic genesi...For skarn type deposits , there are two lands of skarns , skarn formed by filtrating-diffusing metasomatism and vein skarn formed by filling . The vein skarn , discussed this paper and considered to be magmatic genesis , is characterized by: (1) occurring as vein with distinct boundaries with country rocks , yet just the same even in marble easy to be replaced ; (2) composed of a mineral assemblage similar to that of granite ,containing pegmatite as wen as coarse skarn mineral pockets ,and sometimes transited with dike rocks ; (3) dear crystalline feature of deposition ; (4) sideronitic texture ; (5) stowing vesicular, bean-like and flow structures ; (6) very common liquid immiscibility; (7) vertical zoning of gravitational differentiation caused by volatile concentration upwards; (8) associated and transited with non-copper ore bodies of magmatic genesis and tungsten-bearing quartz veins of silicate magmatic genesis rich in volatile ; (9) melt inclusions . Two origins of skam magma . originated by assimilation of silicate magma at its emplacemeot or below it and generated owe to assimilation of deep magma ,corrosion of carbonate strata and liquation , are presented .展开更多
Petro Gram is an Excel?based magmatic petrology program that generates numerical and graphical models.Petro Gram can model the magmatic processes such as melting,crystallization,assimilation and magma mixing based on ...Petro Gram is an Excel?based magmatic petrology program that generates numerical and graphical models.Petro Gram can model the magmatic processes such as melting,crystallization,assimilation and magma mixing based on the trace element and isotopic data.The program can produce both inverse and forward geochemical models for melting processes(e.g.forward model for batch,fractional and dynamic melting,and inverse model for batch and dynamic melting).However,the program uses a forward modeling approach for magma differentiation processes such as crystallization(EC:Equilibruim Crystallization,FC:Fractional Crystallization,IFC:Imperfect Fractional Crystallization and In-situ Crystallization),assimilation(AFC:Assimilation Fractional Crystallization,Decoupled FC-A:Decoupled Fractional Crystallization and Assimillation,A-IFC:Assimilation and Imperfect Fractional Crystallization)and magma mixing.One of the most important advantages of the program is that the melt composition obtained from any partial melting model can be used as a starting composition of the crystallization,assimilation and magma mixing.In addition,Petro Gram is able to carry out the classification,tectonic setting,multi-element(spider)and isotope correlation diagrams,and basic calculations including Mg^#,Eu/Eu^*,εSrandεNdwidely used in magmatic petrology.展开更多
The contents of major element composition of the phenocrysts and the matrix glass as well as the spinel inclusions and the melt inclusion in the phenocrysts of the basalt dredged from Station 133 of the Okinawa Trough...The contents of major element composition of the phenocrysts and the matrix glass as well as the spinel inclusions and the melt inclusion in the phenocrysts of the basalt dredged from Station 133 of the Okinawa Trough are determined by electron microprobe. The results show that the basalt is a dor- galite consisting of phenocrysts of bytownite, chrysolite, clinopyroxene and magnetite as well as labradorite microcrystal, matrix glass and a few bits of broken vein quartz. Glassy melt inclusion and chromohercynite or chrompleonaste exist in bytownite and chrysolite. The formation of the spinels is re- lated to partial melting of mantle. The melt inclusions stand for a primary alkali dorgalitic magma, whose composition corresponds to olivine gabbro. The basaltic magma was generated from partial melting of spinel-lherzolite of the upper mantle and evolved in a process of 'alkali dorgalitic magma-trachy- basaltic magma-basdaltic trachytic magma-trachytic magma'. Assimilation and hybridization of crustal material may exist during magma upwelling in every evolutionary stage.展开更多
The Tafresh granitoids are located at the central part of the Urumieh-Dokhtar Magmatic Arc(UDMA)in Iran.These rocks,mainly consisting of diorite and granodiorite,were emplaced during the Early Miocene.They are compose...The Tafresh granitoids are located at the central part of the Urumieh-Dokhtar Magmatic Arc(UDMA)in Iran.These rocks,mainly consisting of diorite and granodiorite,were emplaced during the Early Miocene.They are composed of varying proportions of plagioclase+K-feldspar+hornblende±quartz±biotite.Discrimination diagrams and chemical indices of amphibole phases reveal a calc-alkaline affinity and fall clearly in the crust-mantle mixed source field.The estimated pressure,derived from Al in amphibole barometry,is approximately 3 Kb.The granitoids are I-type,metaluminous and belong to the calc-alkaline series.They are all enriched in light rare earth elements and large ion lithophile elements,depleted in high field strength elements and display geochemical features typical of subduction-related calc-alkaline arc magmas.Most crystal size distribution(CSD)line patterns from the granitoids show a non-straight trend which points to the effect of physical processes during petrogenesis.The presence of numerous mafic enclaves,sieve texture and oscillatory zoning along with the CSD results show that magma mixing in the magma chamber had an important role in the petrogenesis of Tafresh granitoids.Moreover,the CSD analysis suggests that the plagioclase crystals were crystallized in a time span of less than 1000 years,which is indicative of shallow depth magma crystallization.展开更多
基金supported by the Iran National Science Foundation(INSF)(Grant No.98012578)projects from the National Natural Science Foundation of China(Grant Nos.41473033,41673031)。
文摘The Hesar pluton in the northern Urumieh-Dokhtar magmatic arc hosts numerous mafic-microgranular enclaves(MMEs).Whole rock geochemistry,mineral chemistry,zircon U-Pb and Sr-Nd isotopes were measured.It is suggested that the rocks are metaluminous(A/CNK=1.32-1.45),subduction-related I-type calc-alkaline gabbro to diorite with similar mineral assemblages and geochemical signatures.The host rocks yielded an U-Pb crystallization age of 37.3±0.4 Ma for gabbro-diorite.MMEs have relatively low SiO_(2) contents(52.9-56.6 wt%)and high Mg^(#)(49.8-58.7),probably reflecting a mantle-derived origin.Chondrite-and mantle-normalized trace element patterns are characterized by LREE and LILE enrichment,HREE and HFSE depletion with slight negative Eu anomalies(Eu/Eu^(*)=0.86-1.03).The host rocks yield(^(87)Sr/^(86)Sr)_(i) ratios of 0.70492-0.70510,positive ε_(Nd)(t)values of+1.55-+2.06 and T_(DM2)of 707-736 Ma,which is consistent with the associated mafic microgranular enclaves((^(87)Sr/^(86)Sr)_(i)=0.705014,ε_(Nd)(t)=+1.75,T_(DM2)=729 Ma).All data suggest magma-mixing for enclave and host rock formation,showing a complete equilibration between mixed-mafic and felsic magmas,followed by rapid diffusion.The T_(DM1)(Nd)and T_(DM2)(Nd)model ages and U-Pb dating indicate that the host pluton was produced by partial melting of the lower continental crust and subsequent mixing with injected lithospheric mantlederived magmas in a pre-collisional setting of Arabian-Eurasian plates.Clinopyroxene composition indicates a crystallization temperature of~1000℃ and a depth of~9 km.
基金supported by grants from the National Natural Science Foundation of China (Nos. 41902077, 41730423 and 41921003)China Postdoctoral Science Foundation Grant (No. 2019M653103)Science and Technology Planning of Guangdong Province, China (2020B1212060055)。
文摘Magmatic Ni-Cu-(PGE) sulfide and Fe-Ti oxide deposits in plume-related large igneous provinces(LIPs)are commonly related to low-Ti and high-Ti series magmas, respectively, but the major factors that control such a relationship of metallogenic types and magma compositions are unclear. Magma fOcontrols sulfur status and relative timing of Fe-Ti oxide saturation in mafic magmas, which may help clarify this issue. Taking the Emeishan LIP as a case, we calculated the magma fOof the high-Ti and low-Ti picrites based on the olivine-spinel oxygen barometer, and the partitioning of V in olivine. The obtained fOof the high-Ti series magma(FMQ + 1.1 to FMQ + 2.6) is higher than that of the low-Ti series magma(FMQ-0.5to FMQ + 0.5). The magma fOof the high-Ti and low-Ti picrites containing Fo > 90 olivine reveals that the mantle source of the high-Ti series is likely more oxidized than that of the low-Ti series. The results using the ’lambda REE’ approach show that the high-Ti series may have been derived from relatively oxidized mantle with garnet pyroxenite component. The S contents at sulfide saturation(SCSS) of the two series magmas were calculated based on liquid compositions obtained from the alpha Melts modeling, and the results show that the low-Ti series magma could easily attain the sulfide saturation as it has low fOwith S being dominantly as S. In contrast, the oxidized high-Ti series magma is difficult to attain the sulfide saturation, but could crystallize Fe-Ti oxides at magma MgO content of ~7.0 wt.%. Thus, contrasting magma fOof low-Ti and high-Ti series in plume-related LIPs may play an important role in producing two different styles of metallogeny.
基金funded by the Faculty of Geography under the scheme of“Dana Hibah Penelitian Mandiri Dosen Tahun 2023 Tahap 1”。
文摘Ten rock samples consisting of one pyroclastic density current(PDC1)deposit,seven lava flows(LF1–7),and two summit lava domes(LD1,2)were studied to understand the petrogenesis and magma dynamics at Mt.Sumbing.The stratigraphy is arranged as LF1,PDC1,LF2,LF3,LF4,LF5,LF6,LF7,LD1,and LD2;furthermore,these rocks were divided into two types.TypeⅠ,observed in the oldest(LF1)sample,has poor MgO and high Ba/Nb,Th/Yb and Sr.The remaining samples(PDC1–LD2)represent typeⅡ,characterized by high MgO and low Ba/Nb,Th/Yb and Sr values.We suggest that type I is derived from AOC(altered oceanic crust)-rich melts that underwent significant crustal assimilation,while typeⅡoriginates from mantle-rich melts with less significant crustal assimilation.The early stage of typeⅡmagma(PDC1–LF3)was considered a closed system,evolving basaltic andesite into andesite(55.0–60.2 wt%SiO_(2))with a progressively increasing phenocryst(0.30–0.48φ_(PC))and decreasing crystal size distribution(CSD)slope(from-3.9 to-2.9).The evidence of fluctuating silica and phenocryst contents(between 55.9–59.7 wt%and 0.25–0.41φ_(PC),respectively),coupled with the kinked and steep(from-5.0 to-3.3)CSD curves imply the interchanging condition between open(i.e.,magma mixing)and closed magmatic systems during the middle stage(LF4–LF6).Finally,it underwent to closed system again during the final stage(LF7–LD2)because the magma reached dacitic composition(at most 68.9 wt%SiO_(2))with abundant phenocryst(0.38–0.45φ_(PC))and gentle CSD slope(from-4.1 to-1.2).
基金financially supported by the National Natural Science Foundation of China(Grant Nos.92162210,42172096 and 41773028).
文摘There are two factors,source composition and magmatic differentiation,potentially controlling W-Sn mineralization.Which one is more important is widely debated and may need to be determined for each individual deposit.The Xitian granite batholith located in South China is a natural laboratory for investigating the above problem.It consists essentially of two separate components,formed in the Triassic at ca.226 Ma and Jurassic at ca.152 Ma,respectively.The Triassic and Jurassic rocks are both composed of porphyritic and fine-grained phases.The latter resulted from highlydifferentiated porphyritic ones but they have similar textural characteristics and mineral assemblages,indicating that they reached a similar degree of crystal fractionation.Although both fine-grained phases are highly differentiated with elevated rare metal contents,economic W–Sn mineralization is rare in the Triassic granitoids and this can be attributed to less fertile source materials than their Jurassic counterparts,with a slightly more enriched isotopic signature and whole-rockεNd(226 Ma)of−10.4 to−9.2(2σ=0.2)compared withεNd(152 Ma)of−9.2 to−8.2(2σ=0.2)for the Jurassic rocks.The initial W-Sn enrichment was derived from the metasedimentary rocks and strongly enhanced by reworking of the continental crust,culminating in the Jurassic.
基金jointly supported by the National Natural Science Foundation of China(4220207742103025)+5 种基金the Opening Foundation of MNR Key Laboratory of Metallogeny and Mineral Assessment(ZS2209ZS2106)the Opening Foundation of Key Laboratory of Mineral Resources in Western China(Gansu Province)(MRWCGS-2021-01)the Natural Science Foundation of Gansu Province(22JR5RA440)the Fundamental Research Funds for the Central Universities(LZUJBKY-2022-42)the Guiding Special Funds of“Double First-Class(First-Class University&First-Class Disciplines)”(561119201)of Lanzhou University,China。
文摘Porphyry Cu(Mo-Au)deposit is one of the most important types of copper deposit and usually formed under magmatic arc-related settings,whilst the Mujicun porphyry Cu-Mo deposit in North China Craton uncommonly generated within intra-continental settings.Although previous studies have focused on the age,origin and ore genesis of the Mujicun deposit,the ore-forming age,magma source and tectonic evolution remain controversial.Here,this study targeted rutile(TiO_(2))in the ore-hosting diorite porphyry from the Mujicun Cu-Mo deposit to conduct in situ U-Pb dating and trace element composition studies,with major views to determine the timing and magma evolution and to provide new insights into porphyry Cu-Mo metallogeny.Rutile trace element data show flat-like REE patterns characterized by relatively enrichment LREEs and depleted HREEs,which could be identified as magmatic rutile.Rutile U-Pb dating yields lower intercept ages of 139.3–138.4 Ma,interpreted as post magmatic cooling timing below about 500℃,which are consistent or slightly postdate with the published zircon U-Pb ages of diorite porphyry(144.1–141.7 Ma)and skarn(146.2 Ma;139.9 Ma)as well as the molybdenite Re-Os ages of molybdenum ores(144.8–140.0 Ma).Given that the overlap between the closure temperature of rutile U-Pb system and ore-forming temperature of the Mujicun deposit,this study suggests that the ore-forming ages of the Mujicun deposit can be constrained at 139.3–138.4 Ma,with temporal links to the late large-scale granitic magmatism at 138–126 Ma in the Taihang Orogen.Based on the Mg and Al contents in rutile,the magma of ore-hosting diorite porphyry was suggested to be derived from crust-mantle mixing components.In conjunction with previous studies in Taihang Orogen,this study proposes that the far-field effect and the rollback of the subducting Paleo-Pacific slab triggered lithospheric extension,asthenosphere upwelling,crust-mantle interaction and thermo-mechanical erosion,which jointly facilitated the formation of dioritic magmas during the Early Cretaceous.Subsequently,the dioritic magmas carrying crust-mantle mixing metallic materials were emplaced and precipitated at shallow positions along NNE-trending ore-controlling faults,eventually resulting in the formation of the Mujicun Cu-Mo deposit within an intracontinental extensional setting.
文摘The mafic enclaves from Paleoproterozoic domain are considered to be the results of large-scale crust-mantle interaction and magma mixing. In this paper, petrography, mineralogy and geochemistry were jointly used to determine the origin of the mafic enclaves and their relationship with the host granitoids of the Kan granite-gneiss complex. This study also provides new information on crust-mantle interactions. The mafic enclaves of the Kan vary in shape and size and have intermediate chemical compositions. The diagrams used show a number of similarities in the major elements (and often in the trace elements) between the mafic enclaves and the host granitoids. Geochemical show that the Kan rock are metaluminous, enriched in silica, medium to high-K calc-alkaline I-type granite. The similarities reflect a mixing of basic and acid magma. Mafic enclaves have a typical magmatic structure, which is characterized by magma mixing. The genesis of these rocks is associated with the context of subduction. They result from the mixing of a mafic magma originating from the mantle and linked to subduction, and a granitic magma (type I granite) that arises from the partial melting of the crust.
文摘The presented research illustrates the applicability and productiveness of the systematic literature review methodology, a non-empirical methodology in the geological sciences, particularly volcanology. The systematic literature review methodology is a replicable, rigorous, and transparent methodology for synthesizing existing literature to answer questions on a specific topic. The synthesis allows for knowledge consolidation, such as identifying knowledge gaps. In our illustration of this methodology, we focused on the expanding knowledge about the magma pathway at Mount Cameroon, one of Africa’s active volcanoes. Our synthesis of the relevant international geoscience research literature is based on the framework of knowledge about the magma pathway beneath a typical basaltic volcano. The framework has three primary components: magma supply, storage, and transport to erupting vents. Across these components is a total of twelve secondary components. The result is a previously non-existent and fragmented overall understanding of the magma pathway at Mount Cameroon. The gaps in the understanding (such as in the magma supply rates, timescales of chamber processes, and magma ascent rates) may be addressed in future research. Another key implication of the presented research lies in the proof of concept of the systematic literature review methodology as an applicable qualitative research methodology in the study of volcanoes.
基金supported by 973 Program(2007CB411408)National Natural Science Foundation of China(NSFC) projects (40730420 and 40973038)Chinese Academy of Sciences(KZCX2-YW-Q04)
文摘The three most crucial factors for the formation of large and super-large magmatic sulfide deposits are: (1) a large volume of mantle-derived mafic-ultramafic magmas that participated in the formation of the deposits; (2) fractional crystallization and crustal contamination, particularly the input of sulfur from crustal rocks, resulting in sulfide immiscibility and segregation; and (3) the timing of sulfide concentration in the intrusion. The super-large magmatic Ni-Cu sulfide deposits around the world have been found in small mafic-ultramafic intrusions, except for the Sudbury deposit. Studies in the past decade indicated that the intrusions hosting large and super-large magmatic sulfide deposits occur in magma conduits, such as those in China, including Jinchuan (Gansu), Yangliuping (Sichuan), Kalatongke (Xinjiang), and Hongqiling (Jilin). Magma conduits as open magma systems provide a perfect environment for extensive concentration of immiscible sulfide melts, which have been found to occur along deep regional faults. The origin of many mantle-derived magmas is closely associated with mantle plumes, intracontinental rifts, or post-collisional extension. Although it has been confirmed that sulfide immiscibility results from crustal contamination, grades of sulfide ores are also related to the nature of the parental magmas, the ratio between silicate magma and immiscible sulfide melt, the reaction between the sulfide melts and newly injected silicate magmas, and fractionation of the sulfide melt. The field relationships of the ore-bearing intrusion and the sulfide ore body are controlled by the geological features of the wall rocks. In this paper, we attempt to demonstrate the general characteristics, formation mechanism,tectonic settings, and indicators of magmatic sulfide deposits occurring in magmatic conduits which would provide guidelines for further exploration.
基金supported by the Chinese NSF (41602213,90914004)China University of Geosciences(Beijing)(2011TDL001)the Guangzhou Marine Geological Survey (GZH20110205)
文摘Magma mingling has been identified within the continental margin of southeastern China.This study focuses on the relationship between mafic and felsic igneous rocks in composite dikes and plutons in this area,and uses this relationship to examine the tectonic and geodynamic implications of the mingling of mafic and felsic magmas.Mafic magmatic enclaves(MMEs) show complex relationships with the hosting Xiaocuo granite in Fujian area,including lenticular to rounded porphyritic microgranular enclaves containing abundant felsic/mafic phenocrysts,elongate mafic enclaves,and back-veining of the felsic host granite into mafic enclaves.LA-ICP-MS zircon U-Pb analyses show crystallization of the granite and dioritic mafic magmatic enclave during ca.132 and 116 Ma.The host granite and MMEs both show zircon growth during repeated thermal events at-210 Ma and 160-180 Ma.Samples from the magma mingling zone generally contain felsic-derived zircons with well-developed growth zoning and aspect ratios of 2-3,and maficderived zircons with no obvious oscillatory zoning and with higher aspect ratios of 5-10.However,these two groups of zircons show no obvious trace element or age differences.The Hf-isotope compositions show that the host granite and MMEs have similar ε(Hf)(t) values from negative to positive which suggest a mixed source from partial melting of the Meso-Neoproterozoic with involvement of enriched mantlederived magmas or juvenile components.The lithologies,mineral associations,and geochemical characteristics of the mafic and felsic rocks in this study area indicate that both were intruded together,suggesting Early Cretaceous mantle—crustal interactions along the southeastern China continental margin.The Early Cretaceous magma mingling is correlated to subduction of Paleo-Pacific plate.
文摘For skarn type deposits , there are two lands of skarns , skarn formed by filtrating-diffusing metasomatism and vein skarn formed by filling . The vein skarn , discussed this paper and considered to be magmatic genesis , is characterized by: (1) occurring as vein with distinct boundaries with country rocks , yet just the same even in marble easy to be replaced ; (2) composed of a mineral assemblage similar to that of granite ,containing pegmatite as wen as coarse skarn mineral pockets ,and sometimes transited with dike rocks ; (3) dear crystalline feature of deposition ; (4) sideronitic texture ; (5) stowing vesicular, bean-like and flow structures ; (6) very common liquid immiscibility; (7) vertical zoning of gravitational differentiation caused by volatile concentration upwards; (8) associated and transited with non-copper ore bodies of magmatic genesis and tungsten-bearing quartz veins of silicate magmatic genesis rich in volatile ; (9) melt inclusions . Two origins of skam magma . originated by assimilation of silicate magma at its emplacemeot or below it and generated owe to assimilation of deep magma ,corrosion of carbonate strata and liquation , are presented .
文摘Petro Gram is an Excel?based magmatic petrology program that generates numerical and graphical models.Petro Gram can model the magmatic processes such as melting,crystallization,assimilation and magma mixing based on the trace element and isotopic data.The program can produce both inverse and forward geochemical models for melting processes(e.g.forward model for batch,fractional and dynamic melting,and inverse model for batch and dynamic melting).However,the program uses a forward modeling approach for magma differentiation processes such as crystallization(EC:Equilibruim Crystallization,FC:Fractional Crystallization,IFC:Imperfect Fractional Crystallization and In-situ Crystallization),assimilation(AFC:Assimilation Fractional Crystallization,Decoupled FC-A:Decoupled Fractional Crystallization and Assimillation,A-IFC:Assimilation and Imperfect Fractional Crystallization)and magma mixing.One of the most important advantages of the program is that the melt composition obtained from any partial melting model can be used as a starting composition of the crystallization,assimilation and magma mixing.In addition,Petro Gram is able to carry out the classification,tectonic setting,multi-element(spider)and isotope correlation diagrams,and basic calculations including Mg^#,Eu/Eu^*,εSrandεNdwidely used in magmatic petrology.
基金This work was supported by the Youth Oceanic Science Foundation of State Oceanic Administration of China under contract!No. 94-2
文摘The contents of major element composition of the phenocrysts and the matrix glass as well as the spinel inclusions and the melt inclusion in the phenocrysts of the basalt dredged from Station 133 of the Okinawa Trough are determined by electron microprobe. The results show that the basalt is a dor- galite consisting of phenocrysts of bytownite, chrysolite, clinopyroxene and magnetite as well as labradorite microcrystal, matrix glass and a few bits of broken vein quartz. Glassy melt inclusion and chromohercynite or chrompleonaste exist in bytownite and chrysolite. The formation of the spinels is re- lated to partial melting of mantle. The melt inclusions stand for a primary alkali dorgalitic magma, whose composition corresponds to olivine gabbro. The basaltic magma was generated from partial melting of spinel-lherzolite of the upper mantle and evolved in a process of 'alkali dorgalitic magma-trachy- basaltic magma-basdaltic trachytic magma-trachytic magma'. Assimilation and hybridization of crustal material may exist during magma upwelling in every evolutionary stage.
文摘The Tafresh granitoids are located at the central part of the Urumieh-Dokhtar Magmatic Arc(UDMA)in Iran.These rocks,mainly consisting of diorite and granodiorite,were emplaced during the Early Miocene.They are composed of varying proportions of plagioclase+K-feldspar+hornblende±quartz±biotite.Discrimination diagrams and chemical indices of amphibole phases reveal a calc-alkaline affinity and fall clearly in the crust-mantle mixed source field.The estimated pressure,derived from Al in amphibole barometry,is approximately 3 Kb.The granitoids are I-type,metaluminous and belong to the calc-alkaline series.They are all enriched in light rare earth elements and large ion lithophile elements,depleted in high field strength elements and display geochemical features typical of subduction-related calc-alkaline arc magmas.Most crystal size distribution(CSD)line patterns from the granitoids show a non-straight trend which points to the effect of physical processes during petrogenesis.The presence of numerous mafic enclaves,sieve texture and oscillatory zoning along with the CSD results show that magma mixing in the magma chamber had an important role in the petrogenesis of Tafresh granitoids.Moreover,the CSD analysis suggests that the plagioclase crystals were crystallized in a time span of less than 1000 years,which is indicative of shallow depth magma crystallization.