3D reticulated ceramics (3DRCs) with the composition containing SrFe12O19-SiC-TiO2 were prepared by a replication process with polyurethane sponges as the template in ceramic slurry. The electrical conductivity, diele...3D reticulated ceramics (3DRCs) with the composition containing SrFe12O19-SiC-TiO2 were prepared by a replication process with polyurethane sponges as the template in ceramic slurry. The electrical conductivity, dielectric and magnetic parameters of 3D reticulated ceramics (3DRCs) were measured with changes in cell size of the sponges, contents in the slurry and sintering temperature in this paper. Discussions about the influential factors of those parameters were focused on their electrical conductivity. The experimental results indicated that the electrical conductivity of 3DRCs raised with the increase of cell size, SiC/SrO 6Fe2O3 with weight ratio and sintering temperature. X-ray diffractions and SEM were used to investigate the relationship between electrical conductivity and sintering temperature. Deoxidizing reactions of SrO 6Fe2O3 caused the increasing electrical conductivity. The real part of permittivity (ε') and imaginary part of permeability (μ') raised with the increase of electrical conductivity (σ). The imaginary part of permittivity (ε') has a maximum at 10o S/cm with the increase of a, and the real part of permeability (μ') changes slightly with the increase of a. When a is at the range of 10-4 S/cm to 10o S/cm (a semi conductive state), both the imagine part of permittivity and permeability raises with increasing a, therefore, the 3DRCs present their high electromagnetic loss properties.展开更多
直流气体绝缘输电管道(direct current gas insulated lines,DC-GIL)电场分布受温度梯度、运行电压、金属微粒等诸多因素影响,具有非常大的不确定性,给绝缘设计和运行稳定性带来挑战。非线性电导材料能够自适应地调控直流设备电场分布,...直流气体绝缘输电管道(direct current gas insulated lines,DC-GIL)电场分布受温度梯度、运行电压、金属微粒等诸多因素影响,具有非常大的不确定性,给绝缘设计和运行稳定性带来挑战。非线性电导材料能够自适应地调控直流设备电场分布,有望突破DC-GIL绝缘子设计瓶颈。为了兼顾电场调节作用和损耗特性,建立100 kV直流GIL仿真模型,对比研究运行工况下传统绝缘子、表层电导非线性(surface nonlinear conductivity,SNC)绝缘子和体电导非线性(bulk nonlinear conductivity,BNC)绝缘子的电场分布及损耗功率。通过分析非线性电导(nonlinear conductivity,NC)参数对气固沿面电场调控作用和损耗特性的影响规律,发现SNC绝缘子的电场畸变率先随着欧姆区电导率和非线性系数的增大而快速下降,而后趋于平稳。理想情况下,SNC绝缘子的NC参数应处于电场调节作用的"饱和临界线",且欧姆区电导率最低。而BNC绝缘子的电场调节作用仅依赖于非线性系数,降低欧姆区电导率可降低绝缘子功率损耗。缩比绝缘子实验结果证实了SNC绝缘子非线性参数直接影响DC-GIL沿面闪络电压。展开更多
文摘3D reticulated ceramics (3DRCs) with the composition containing SrFe12O19-SiC-TiO2 were prepared by a replication process with polyurethane sponges as the template in ceramic slurry. The electrical conductivity, dielectric and magnetic parameters of 3D reticulated ceramics (3DRCs) were measured with changes in cell size of the sponges, contents in the slurry and sintering temperature in this paper. Discussions about the influential factors of those parameters were focused on their electrical conductivity. The experimental results indicated that the electrical conductivity of 3DRCs raised with the increase of cell size, SiC/SrO 6Fe2O3 with weight ratio and sintering temperature. X-ray diffractions and SEM were used to investigate the relationship between electrical conductivity and sintering temperature. Deoxidizing reactions of SrO 6Fe2O3 caused the increasing electrical conductivity. The real part of permittivity (ε') and imaginary part of permeability (μ') raised with the increase of electrical conductivity (σ). The imaginary part of permittivity (ε') has a maximum at 10o S/cm with the increase of a, and the real part of permeability (μ') changes slightly with the increase of a. When a is at the range of 10-4 S/cm to 10o S/cm (a semi conductive state), both the imagine part of permittivity and permeability raises with increasing a, therefore, the 3DRCs present their high electromagnetic loss properties.
