The magnetic cooling utilizing magneto-caloric effect is recognized as promising energy efficiency and environmentally friendly technology.Here we report a systematical study on the microstructures,magnetic properties...The magnetic cooling utilizing magneto-caloric effect is recognized as promising energy efficiency and environmentally friendly technology.Here we report a systematical study on the microstructures,magnetic properties and cryogenic magneto-caloric performances of the Gd_(20)Ho_(20)Tm_(20)Cu_(20)Ni_(20) amorphous ribbons.It is found that the ribbons reveal a second-order phase transition and are accompanied by a table-shaped magneto-caloric effect.The calculated magneticentropy-change maximum |ΔSM|,temperature averaged entropy change(i.e.,TEC(10)),and refrigerant capacity reach 13.9 J/kg·K,13.84 J/kg-K and 740 J/kg with magnetic field change of 0-7 T,respectively,indicating that the present Gd_(20)Ho_(20)Tm_(20)Cu_(20)Ni_(20) amorphous ribbons are good candidates for magnetic cooling.展开更多
The magneto-caloric effect of Gd5 Si2Ge2 compounds produced by various techniques is investigated in terms of their magnetization behaviors in the magnetic field from 0 to 2.0 T.The studied materials include arc-melte...The magneto-caloric effect of Gd5 Si2Ge2 compounds produced by various techniques is investigated in terms of their magnetization behaviors in the magnetic field from 0 to 2.0 T.The studied materials include arc-melted, annealed and sintered alloys.The results demonstrate that the Gd5Si2Ge2 alloys obtained under different processing conditions possess distinct magneto-caloric effect due to their various microstructures.Proper annealing treatment can enhance the magneto-caloric effect of the alloy remarkably.While the sintered alloy bears relatively lower value of magnetic entropy change ( △ SM) than arc-melted one.The magnetic entropy change of the annealed Gd5 Si2Ge2 alloy arrives the arrives the maximum value of - △SM = 15.29 J· kg-1· K-1 for magnetic field change under 2.0 T in the present work.展开更多
Outstanding magneto-calorie properties of a Gd60Ni37Co3 amorphous alloy are reported. The magnetic entropy change peak（-△Sm^peak）near the Curie temperature （Tc=135 K） of the amorphous alloy under 5 T is about 10....Outstanding magneto-calorie properties of a Gd60Ni37Co3 amorphous alloy are reported. The magnetic entropy change peak（-△Sm^peak）near the Curie temperature （Tc=135 K） of the amorphous alloy under 5 T is about 10.42J·kg^-1K^-1 and the refrigeration capacity （RC） under 5 T is about 860J·kg^-1, both of which are almost the highest among the amorphous alloys with Tc above I00 K. The magneto-caloric behaviors and the mechanism for the rather high magneto-caloric effect of the Gd6oNi37Co3 metallic glass are investigated.展开更多
The magneto-caloric effect （MCE） of a Gd55Co25Al18Sn2 bulk metallic glass （BMG） is investigated. The Gd55Co25AllsSn2 as-cast rod prepared by a water-cooled copper mold suction casting method exhibits typi- cal amo...The magneto-caloric effect （MCE） of a Gd55Co25Al18Sn2 bulk metallic glass （BMG） is investigated. The Gd55Co25AllsSn2 as-cast rod prepared by a water-cooled copper mold suction casting method exhibits typi- cal amorphous characteristics. The maximum magnetic entropy change （--ASPmeak） and the magnetic refrigerant capacity （Re） of the BMG under a field of 5 T are about 9.32 J.kg-X.K 1 and 832 J.kg-1, respectively, both of which are larger than the values of the Gd55 Co25A120 BMG. The mechanism for the improved MCE by minor Sn addition is studied and the field dependence of - magneto-caloric behaviors of Gd55Co25Al18Sn2 BMG ASPmeak is investigated for a better understanding on the展开更多
A low cost Gd_(34)Ni_(33)Al_(33) metallic glass with excellent magnetocaloric properties was successfully prepared in the present work.The magnetic properties of the ribbons were measured by constructing the relations...A low cost Gd_(34)Ni_(33)Al_(33) metallic glass with excellent magnetocaloric properties was successfully prepared in the present work.The magnetic properties of the ribbons were measured by constructing the relationship of magnetic entropy change(-ΔS_(m)) on temperature as well as magnetic field.The amorphous alloy shows typical magnetocaloric behaviors,large maximum-ΔS_(m)(11.06 J/(kg·K) under 5 T)and adiabatic temperature rise(4.3 K under 5 T) near 40 K,indicating that the low cost Gd_(34)Ni_(33)Al_(33) metallic glass is a good candidate material for low temperature magnetic refrigeration.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant No.52071197)the Science and Technology Committee of Shanghai(Grant No.19ZR1418300)+2 种基金the Independent Research and Development Project of State Key Laboratory of Advanced Special SteelShanghai Key Laboratory of Advanced Ferrometallurgy,Shanghai University(Grant No.SKLASS 2019-Z003)the Science and Technology Commission of Shanghai Municipality(Grant No.19DZ2270200)。
文摘The magnetic cooling utilizing magneto-caloric effect is recognized as promising energy efficiency and environmentally friendly technology.Here we report a systematical study on the microstructures,magnetic properties and cryogenic magneto-caloric performances of the Gd_(20)Ho_(20)Tm_(20)Cu_(20)Ni_(20) amorphous ribbons.It is found that the ribbons reveal a second-order phase transition and are accompanied by a table-shaped magneto-caloric effect.The calculated magneticentropy-change maximum |ΔSM|,temperature averaged entropy change(i.e.,TEC(10)),and refrigerant capacity reach 13.9 J/kg·K,13.84 J/kg-K and 740 J/kg with magnetic field change of 0-7 T,respectively,indicating that the present Gd_(20)Ho_(20)Tm_(20)Cu_(20)Ni_(20) amorphous ribbons are good candidates for magnetic cooling.
文摘The magneto-caloric effect of Gd5 Si2Ge2 compounds produced by various techniques is investigated in terms of their magnetization behaviors in the magnetic field from 0 to 2.0 T.The studied materials include arc-melted, annealed and sintered alloys.The results demonstrate that the Gd5Si2Ge2 alloys obtained under different processing conditions possess distinct magneto-caloric effect due to their various microstructures.Proper annealing treatment can enhance the magneto-caloric effect of the alloy remarkably.While the sintered alloy bears relatively lower value of magnetic entropy change ( △ SM) than arc-melted one.The magnetic entropy change of the annealed Gd5 Si2Ge2 alloy arrives the arrives the maximum value of - △SM = 15.29 J· kg-1· K-1 for magnetic field change under 2.0 T in the present work.
基金Supported by the National Natural Science Foundation of China under Grant Nos 51271103 and 51671119
文摘Outstanding magneto-calorie properties of a Gd60Ni37Co3 amorphous alloy are reported. The magnetic entropy change peak（-△Sm^peak）near the Curie temperature （Tc=135 K） of the amorphous alloy under 5 T is about 10.42J·kg^-1K^-1 and the refrigeration capacity （RC） under 5 T is about 860J·kg^-1, both of which are almost the highest among the amorphous alloys with Tc above I00 K. The magneto-caloric behaviors and the mechanism for the rather high magneto-caloric effect of the Gd6oNi37Co3 metallic glass are investigated.
基金Supported by the National Natural Science Foundation of China under Grant Nos 51171100 and 51271103
文摘The magneto-caloric effect （MCE） of a Gd55Co25Al18Sn2 bulk metallic glass （BMG） is investigated. The Gd55Co25AllsSn2 as-cast rod prepared by a water-cooled copper mold suction casting method exhibits typi- cal amorphous characteristics. The maximum magnetic entropy change （--ASPmeak） and the magnetic refrigerant capacity （Re） of the BMG under a field of 5 T are about 9.32 J.kg-X.K 1 and 832 J.kg-1, respectively, both of which are larger than the values of the Gd55 Co25A120 BMG. The mechanism for the improved MCE by minor Sn addition is studied and the field dependence of - magneto-caloric behaviors of Gd55Co25Al18Sn2 BMG ASPmeak is investigated for a better understanding on the
基金the National Natural Science Foundation of China(51671119,51701003,51871139)。
文摘A low cost Gd_(34)Ni_(33)Al_(33) metallic glass with excellent magnetocaloric properties was successfully prepared in the present work.The magnetic properties of the ribbons were measured by constructing the relationship of magnetic entropy change(-ΔS_(m)) on temperature as well as magnetic field.The amorphous alloy shows typical magnetocaloric behaviors,large maximum-ΔS_(m)(11.06 J/(kg·K) under 5 T)and adiabatic temperature rise(4.3 K under 5 T) near 40 K,indicating that the low cost Gd_(34)Ni_(33)Al_(33) metallic glass is a good candidate material for low temperature magnetic refrigeration.
