Hierarchical sea-urchin-shaped manganese oxide microspheres were synthesized via a facile method based on the reaction between KMnO4 and MnSO4 in HNO3 solution at 50℃. The average diameter of the microspheres is -850...Hierarchical sea-urchin-shaped manganese oxide microspheres were synthesized via a facile method based on the reaction between KMnO4 and MnSO4 in HNO3 solution at 50℃. The average diameter of the microspheres is -850 nm. The microspheres consist of a core of diameter of -800 nm and nanorods of width -50 nm. The nanorods exist at the edge of the core, The Brunauer-Emmett-Teller surface area of the sea-urchin-shaped microspheres is 259.4 m^2/g. A possible formation mechanism of the hierarchical sea-urchin-shaped microspheres is proposed. The temperature for 90% conversion of benzene （T90%） on the hierarchical urchin-shaped MnO2 microspheres is about 218 ℃.展开更多
基金supported by the National High Technology Research and Development Program 863 of China,No.2010AA064903National Natural Science Foundation of China(NSFC) No. 51002154
文摘Hierarchical sea-urchin-shaped manganese oxide microspheres were synthesized via a facile method based on the reaction between KMnO4 and MnSO4 in HNO3 solution at 50℃. The average diameter of the microspheres is -850 nm. The microspheres consist of a core of diameter of -800 nm and nanorods of width -50 nm. The nanorods exist at the edge of the core, The Brunauer-Emmett-Teller surface area of the sea-urchin-shaped microspheres is 259.4 m^2/g. A possible formation mechanism of the hierarchical sea-urchin-shaped microspheres is proposed. The temperature for 90% conversion of benzene （T90%） on the hierarchical urchin-shaped MnO2 microspheres is about 218 ℃.
