Sulfide-melt inclusions in mantle xenoliths from the Changbaishan district,Jilin province,China

Mantle xenoliths are common in the Cenozoic basalts of the Changbaishan District,Jilin Province,China.Sulfide assemblages in mantle minerals can be divided into three types:isolated sulfide grains,sulfide-meh inclusions and filling sulfides in fractures.Sulfide-meh inclusions occur as single-phase sulfides,sulfide-silicate melt,and CO_2-sulfide-silicate melt inclusions. Isolated sulfide grains are mainly composed of pyrrhotite,but cubanite was found occasionally.Sulfide-meh inclusions are mainly composed of pontlandite and MSS,with small amounts of chalcopyrite and talnakhite.The calculated distribution coefficient K_(D3)for lherzolite are similar to that of mean experimental value.The bulk sulfides in lherzolite were in equilibrium with the enclosing minerals, indicating immiscible sulfide melts captured in partial melting of upper mantle.Sulfide in fractures has higher Ni/Fe and(Fe+Ni)/S than those of sulfide melt inclusions.They might represent later metasomatizing fluids in the mantle.Ni/Fe and(Fe+Ni)/S increase from isolated grains,sulfide inclusions to sulfides in fractures.These changes were not only affected by temperature and pressure,hut by geochemistry of Ni,Fe and Cu,and sulfur fugacity as well.

Study on Sulfide-melt Inclusions in Mantle Xenoliths of Xinchang, Zhejiang

In minerals of mantle xenoliths captured within Tertiary alkali-basalt from Xinchang, Zhejiang province, China, many sulfidemelt inclusions were found by the observation of polished thin section. Electron microprobe analysis has been applied to detect the components of sulfide-melt inclusions. The result shows that the sulfide phases of inclusions are mainly pentlandite, and secondarily pyrrho- tite, The molar ratio of Ni to Fe, r_Ni,/r_Fe, of mineral phases in sulfide inclusions is related to olivine contents in host mantle xenoliths. The r_Ni/r_Ni, of sulfides from Xinchang samples has a possitive correlation to r_(Fe+Ni),/r_S. The r_(Fe+Ni),/r_S, becomes higher with the increasing of r_Ni/r_Fe In single sulfide-melt inclusions, r_Ni,/r_Fe, r_(Fe+Ni),/r, and Ni contents increase from the center to edge, reflecting a result of different cooling speed in an inclusion. A comparison between the data from Hannuoba, West Eifel of Germany and Nograd-Gomor of east Europe suggests that the composition of the inclusions is different for each area, which indicated that a regional differentiation of sulfide in mantle fluids.

Sulfide-melt inclusions in mantle xenoliths of Hannuoba,China

Sulfide fluid incluision study on mantle xenoliths of Hannouba has been carried out by EPMA analysis. It is indicated that the Ni/Fe ratios of metal sulfides in sulfide-melt inclusions from Hannuoba seem to be related to host rocks. These data of lherzolite （pentlandite） are obviously higher than those of olivine pyroxenite （mainly pentlandite, partly pyrrhotine）. The LRM analysis shows that sulfur （H2S+SO2） occupies larger proportion in gas composition of CO2 fluid inclusions, generally more than mol 20 %. This may be related to sulfide inclusions which are frequently found.

地幔矿物中硫化物熔体包裹体的成因

中国东部新生代碱性玄武岩中产出的巨晶、辉石岩和橄榄岩等地幔捕虏体内硫化物熔体包裹体的矿物组成不尽相同，反映了它们成因上的差异巨晶中除有磁黄铁矿相的硫化物熔体包裹体外还有一些磁黄铁矿士黄铜矿上镍黄铁矿共生的硫化物熔体包裹体这反映它们是在成分接近于上地幔硫化物平均组成的硫化物液滴逐步冷却过程中形成，即首先在1000℃以上的高温晶出单硫化物固溶体（MSS），然后在大约850℃晶出黄铜矿（固溶体），最后在610—300℃下由MSS中溶离出镍黄铁矿辉石岩中硫化物熔体包裹体有磁黄铁矿和镍黄铁矿，而橄榄岩中主要为镍黄铁矿这表明地慢部分熔融造成残余的橄榄岩中硫化物包裹体富Ni，生成镍黄铁矿；而在部分熔融期间作为堆晶产出的辉石岩变得相对贫Ni，可以生成磁黄铁矿．另外，Ni在橄榄石和辉石矿物中分配系数的不同也许是另一个原因河北汉诺坝、福建明溪和闽清的二辉橄榄岩中出现的硫化物都是镍黄铁矿，也表明它们经历过地幔部分熔融.

幔源角闪石巨晶中硫化物熔融包裹体研究

硫化物熔融包裹体研究是认识硫化物矿床成矿元素来源和演化的重要手段,由于硫化物熔融包裹体的体积较小(粒径仅为10～20μm),其详细化学元素组分的难以获得一直是制约进一步研究的瓶颈。笔者在前人研究的基础上,借助于扫描电镜、电镜能谱和二次飞行时间离子探针(Tof-SIMS)对产于铜陵地区角闪石巨晶中的硫化物熔融包裹体进行了详细的研究,首次获得了一套精确的矿物化学资料和元素分布图。矿物学研究表明,角闪石巨晶在上地幔和下地壳均有结晶,温压区间分别为T:850～900℃(温度),P:0.70×109～0.82×109Pa(压力),对应深度D:23.10～27.06km;和T:900～950℃,P:1.09×109～1.17×109Pa,D:35.97～38.61km。元素分布图显示,硫化物熔融包裹体主要有两种元素组成体系:S-Fe-Mn-Ni-Rb-Sr-Ba和S-Fe-Cu-Sr,幔源硫化物体系中Mn、Ni、Rb、Ba等元素具有相似的性质特征可共溶,与Cu则表现出不混溶。在铜陵地区,上地幔的部分熔融形成了一套碱性玄武岩浆,后受岩浆底侵作用和壳幔相互作用影响,底侵进入下地壳深位岩浆房,发生结晶分异和同化混染作用,形成一套轻度演化的玄武岩浆,可能为辉长质。上地幔和下地壳的角闪石巨晶分别是由上地幔碱性玄武岩浆和下地壳轻度演化的玄武岩浆(辉长质)高压下结晶的产物。当上地幔碱性玄武岩浆上侵到下地壳深位岩浆房以后,发生结晶分异作用,又由于地壳硅镁层的混染作用,使得玄武岩浆中硫溶解度降低,促其熔离,从而释放大量的硫(S,以及Ni、Cu、Cr)。角闪石巨晶中的硫化物熔融包裹体正是在下地壳深位岩浆房中,由正在结晶的角闪石巨晶在结晶分异和轻度演化的玄武质岩浆中捕获的不混溶硫化物熔融液滴形成的。铜陵地区在中生代经历了一个长期的大规模的岩浆底侵作用和壳幔相互作用过程,由于下地壳硅镁层混染作用使得轻度演化的玄武岩浆释放大量硫,必然会在莫霍面附近形成大规模高浓度的硫富集区,这些组分在岩浆上侵作用、地壳减薄作用或者裂谷作用的影响下很容易再活化,进入区域岩浆-热液流体系统,最终参与形成区域大规模的硫化物矿床。

地幔岩中不同产状的流体-熔体包裹体及地幔流体交代作用

地幔捕虏体中存在不同产状的熔体包裹体和各种硅酸盐玻璃相,包括主矿物内部的蠕虫状、长圆形、圆形、不规则状包裹体(I型)、边部的连通的管状包裹体(T型)、主矿物边部和粒间的片状熔融体——“浆胞”(C型),三者可见明显过渡关系,它们是地幔流体交代地幔岩石过程中由交代重熔形成的,是研究地幔流体的特征和地幔交代作用的对象之一.从I型、T型到C型,其成分呈规律变化,其中S、Cu、Ni,K、Na含量呈明显的降低趋势.包裹体中玻璃相的成分较主矿物富Si、Al、S、Cu、Ni、K和Na,再加上CO2包裹体的发现,表明地幔流体的成分富碱金属、Si、Al、S、Cu、Ni和CO2.地幔交代作用可以使交代产物中Si、Al含量升高而形成中酸性岩浆,也可由于硫化物熔体聚集而形成矿浆.不同地区的地幔流体性质可能存在差异,这些不同性质的地幔流体可能与不同类型的地幔成矿作用有关.

大兴安岭北部诺敏河地幔金云母及钾质地幔熔体研究

在大兴安岭北部诺敏河第四纪钾质火山岩携带的地幔捕虏体中,发现少量金云母矿物和富钾地幔熔体。金云母颗粒大小1~5mm,呈网脉状充填在橄榄石和辉石、石榴子石等地幔矿物间隙。电子探针研究表明地幔橄榄石、单斜辉石、斜方辉石和石榴石等矿物几乎不含钾质成分(K2O<0.01%),而金云母矿物成分具有高钾(K2O^10%)、高钛(Ti O25.41%~7.74%)的特点,暗示区域地幔钾的富集与金云母矿物有密切关系。地幔金云母的成因往往与富钾地幔流体/熔体的交代作用有关,在地幔捕虏体矿物反应边的硅酸盐熔体(囊体)中,发现富硅、富钾的熔体,K2O 4%~8%。结合前人地幔熔体研究,认为区域地幔经历了多期、不同成分地幔熔体的富集作用,其中富钾熔体对地幔钾质成分的富集起到重要作用。诺敏钾质火山正是富钾地幔部分熔融的产物,钾质熔体成分的来源可能与俯冲再循环的壳源物质有关。

地幔岩中流体包裹体研究

地幔岩石中的流体包裹体代表地幔流体的样品。地幔流体包裹体可以存在从地幔来的金刚石,地幔捕虏体和岩浆碳酸岩中。研究这些岩石和矿物中的流体包裹体可以得出其所代表的地幔流体的温度、压力、成分和同位素。我们目前见到的这三类地幔岩石的包裹体主要可在橄榄石、辉石、金刚石、方解石和磷灰石中见到。这些包裹体可以粗略地分为 CO_2包裹体和硅酸盐熔融体包裹体。又可细分为四类包裹体:(1)富碳酸盐的硅酸盐熔融包裹体。这种包裹体在金刚石、地幔岩捕虏体和岩浆碳酸盐岩中见到,它又可分为结晶质熔融包裹体和玻璃包裹体。(2)CO_2包裹体。这种包裹体大多见于地幔捕虏体中,在金刚石和岩浆碳酸岩中也可见到。(3)含硫化物的包裹体。这种包裹体见于地幔捕虏体中,与纯 CO_2包裹体和含CO_2的熔融包裹体共存。(4)高密度的流体包裹体。这种包裹体见于金刚石中,是一种高盐度、高密度的含K、Cl 和 H_2O 的流体包裹体,又可分为高卤水包裹体和含卤水的富硅的碳酸盐岩浆包裹体。从对金刚石、地幔捕虏体和岩浆碳酸盐岩中流体包裹体的研究表明,地幔流体存在不均匀性和不混溶性。