Improving the performance of arylamine-based hole transporting materials in perovskite solar cells： Extending π-conjugation length or increasing the number of side groups？

In this work, we prepared three simple arylamine-based hole transporting materials from commercially available starting materials. The effect of extending z-conjugation length or increasing the number of side groups compared with reference compound on the photophysical, electrochemical, hole mobility properties and performance in perovskite solar cells were further studied. It is noted that these two kinds of molecular modifications can significantly lower the HOMO level and improve the hole mobility, thus improving the hole injection from valence band of perovskite. On the other hand, the compound with more side groups showed higher hole injection efficiency due to lower HOMO level and higher hole mo- bility compared with the compound with extending π-conjugation length. The perovskite solar cells with the modified molecules as hole transporting materials showed a higher efficiency of 15.40% and 16.95%, respectively, which is better than that of the reference compound （13.18%）. Moreover, the compound with increasing number of side groups based devices showed comparable photovoltaic performance with that of conventional spiro-OMeTAD （16.87%）.

Self-assembled donor-acceptor hole contacts for inverted perovskite solar cells with an efficiency approaching 22%: The impact of anchoring groups

Self-assembled molecules(SAMs) have shown great potential in replacing bulk charge selective contact layers in high-performance perovskite solar cells(PSCs) due to their low material consumption and simple processing. Herein, we design and synthesize a series of donor-acceptor(D-A) type SAMs(MPA-BTCA, MPA-BT-BA, and MPA-BT-RA, where MPA is 4-methoxy-N-(4-methoxyphenyl)-N-phenylaniline;BT is benzo[c][1,2,5]-thiadiazole;CA is 2-cyanoacrylic acid, BA is benzoic acid, RA is rhodanine-3-propionic acid) with distinct anchoring groups, which show dramatically different properties. MPA-BTCA with CA anchoring groups exhibited stronger dipole moments and formed a homogeneous monolayer on the indium tin oxide(ITO) surface by adopting an upstanding self-assembling mode. However, the MPA-BT-RA molecules tend to aggregate severely in solid state due to the sp~3 hybridization of the carbon atom on the RA group, which is not favorable for achieving a long-range ordered self-assembled layer.Consequently, benefiting from high dipole moment, as well as dense and uniform self-assembled film,the device based on MPA-BT-CA yielded a remarkable power conversion efficiency(PCE) of 21.81%.Encouragingly, an impressive PCE approaching 20% can still be obtained for the MPA-BT-CA-based PSCs as the device area is increased to 0.80 cm^(2). Our work sheds light on the design principles for developing hole selecting SAMs, which will pave a way for realizing highly efficient, flexible, and large-area PSCs.

Decorating hole transport material with −CF_(3) groups for highly efficient and stable perovskite solar cells

The hole transport material (HTM) plays an extremely important role to determine the power conversion efficiency (PCE) and the stability of perovskite solar cells (PSCs). Herein, we report an effective strategy to improve the performance of HTMs by introducing −CF_(3) groups via the rational decorative mode. Upon direct attachment or nonconjugated alkoxyl bridging of −CF_(3) groups on the terminal diphenylamines, the resulting molecular HTMs, i.e., 2,7-BCzA4CF_(3) and 2,7-BCzA4OCCF_(3), show distinct properties. Compared with 2,7-BCzA4CF_(3), the nonconjugated alkoxyl bridging −CF_(3) group-based 2,7-BCzA4OCCF_(3) exhibits better thermal stability, hydrophobicity, and a dramatically upgraded hole mobility by 135.7-fold of magnitude to 1.71 × 10^(−4) cm^(2) V^(−1) S^(−1). The PSCs with 2,7-BCzA4OCCF_(3) as HTM exhibit an PCE of up to 20.53% and excellent long-term stability, maintaining 92.57% of their performance for 30 days in air with humidity of 30% without encapsulation. This work provides beneficial guidelines for the design of new HTMs for efficient and stable PSCs.

Research on Key Techniques of Condition Monitoring and Fault Diagnosing Systems of Machine Groups

This paper describes the development of the condition monitoring and faultdiagnosing system of a group of rotating machinery. The data management is performed by means ofdouble redundant data bases stored simultaneously in both the analyzing server and monitoringclient. In this way, high reliability of the storage of data is guaranteed. Condensation of trenddata releases much space resource of the hard disk. Diagnosing strategies orientated to differenttypical faults of rotating machinery are developed and incorporated into the system. Experimentalverification shows that the system is suitable and effective for condition monitoring and faultdiagnosing for a rotating machine group.

Aquifer Test求群孔抽水试验水文地质参数

在水文地质条件复杂的地区,往往采用大型的群孔抽水试验充分揭露含水层特征,获取水文地质参数。用Aquifer Test软件求解水文地质参数,则方便实用、简捷高效,可快速输出拟合图形和求参结果。Aquifer Test提供了丰富的求参方案,求参必须结合当地当时的水文地质条件实际情况考虑,选择适合的方案和时空数据求取水文地质参数。

C≡N-based carbazole-arylamine hole transporting materials for perovskite solar cells: Substitution position matters

Hole transporting materials(HTMs)containing passivating groups for perovskite materials have attracted much attention for efficient and stable perovskite solar cells(PSCs).Among them,C≡N-based molecules have been proved as efficient HTMs.Herein,a series of novel C≡N functionalized carbazole-arylamine derivatives with variable C≡N substitution positions(para,meta,and ortho)on benzene-carbazole skeleton(on the adjacent benzene of carbazole)were synthesized(p-HTM,m-HTM and o-HTM).The experimental results exhibit that the substitution positions of the Ctriple bondN unit on HTMs have minor difference on the HOMO energy level and hydrophobicity.m-HTM has a relatively lower glass transition temperature compared with that of p-HTM and o-HTM.The functional theory calculations show that the C≡N located on meta position exposed very well,and the exposure direction is also the same with the methoxy.Upon applying these molecules as HTMs in PSCs,their device performance is found to sensitively depend on the substitution position of the C≡N unit on the molecule skeleton.The devices using m-HTM and o-HTM exhibit better performance than that of p-HTM.Moreover,m-HTM-based devices exhibit better light-soaking performance and long-term stability,which could be resulted from better interaction with the perovskite according to DFT results.Moreover,we further prepared a HTM with two C≡N units on the symmetrical meta position of molecular skeleton(2m-HTM).Interestingly,2m-HTM-based devices exhibit relatively inferior performance compared with that of the m-HTM,which could be resulted from weak negative electrical character of C≡N unit on 2m-HTM.The results give some new insights for designing ideal HTM for efficient and stable PSCs.

A组煤底板灰岩地质异常体地震响应特征研究

淮南矿区A组煤的安全高效开采是保证华东地区能源供应的重要前提,准确掌握地下煤层的构造形态、发育情况是安全生产和减少事故发生的必要条件。以张集矿1613A工作面为工程背景,采用被动成像和噪声成像技术,对工作面顶底板的微地震监测资料进行分析,工作面已注浆治理的断层破碎带附近微地震事件较多,最深达到工作面下方约80 m的位置,有效验证了该断层破碎带的存在。通过反演的方法分析检波器中接收到的波形信号,获取工作面附近的波速场信息;利用西二、西三_(1)煤采区三维偏移数据体,计算了多种属性,研究了已揭示地质异常体的地震响应特征和属性特征,发现本区构造与地质异常体的研究需要特别注意蚂蚁体、最大曲率、最小曲率、局部异常、落差5个属性的指示作用。研究表明,以三维偏移数据体为基础,提取的各个属性对大断层均有显示,能够进行有效解释;对落差较小断层显示较好的属性是蚂蚁体属性和最大曲率、最小曲率、局部异常、落差属性。

A Triangular Model for Social Work Groups： Teaching the Forgotten Practice Modality

Social Work students typically enroll in the required practice methods courses that are specified by the Council on Social Work Education. At least in the majority of BSW Programs, these practice methods courses are divided into micro-level and macro-level sequences. Individual and family systems are covered in the former sequence, while communities and organizations are the systems of focus in the latter sequence. The group system is often minimized and/or completely ignored in the process, even though there may be some reference made to groups in both practice methods sequences. Consequently, the mezzo-level system of groups is only given ＂lip-service＂ in the dyadic division of micro and macro-level practice. Furthermore, students often do not have the opportunity to practice in group settings, much less, develop competency in these professional venues. This paper describes a teaching format used in a BSW Program in an effort to ensure student competency as required in a Groups Practice course. The triangular model includes： （1） Classroom teaching of theory; （2） Practice of group dynamics; and （3） Supervision by instructors and MSW students.

Some Group Runs Based Multivariate Control Charts for Monitoring the Process Mean Vector

In this article, we propose two control charts namely, the “Multivariate Group Runs’ (MV-GR-M)” and the “Multivariate Modified Group Runs’ (MV-MGR-M)” control charts, based on the multivariate normal processes, for monitoring the process mean vector. Methods to obtain the design parameters and operations of these control charts are discussed. Performances of the proposed charts are compared with some existing control charts. It is verified that, the proposed charts give a significant reduction in the out-of-control “Average Time to Signal” (ATS) in the zero state, as well in the steady state compared to the Hotelling’s T2 and the synthetic T2 control charts.

基于Fluent-Simulink协同仿真的EVAP系统泄漏监测中压力场分析

本文旨在分析使用负压衰减法对汽车燃油蒸发控制系统进行泄漏监测时,泄漏孔位置对系统气相空间内的压力和流场特性的影响。首先通过建立气相空间的总压模型得到瞬态模型边界条件,然后采用1 mm泄漏孔的上方泄漏和侧向泄漏的瞬态模型进行分析,最后进行1 mm标准孔泄漏验证试验。结果表明:在衰减时间30-39 s内,气相空间内除泄漏孔与管路附近外,其余各处压力基本相等;阀管路中的最大压力高于循环管中的最大压力;上方泄漏时的气相空间负压衰减速率高于侧向泄漏;衰减时间30-39 s为较佳的监测时段。

金沙江结合带巴塘段滑坡群InSAR探测识别与形变特征

金沙江结合带结构破碎,软弱岩层发育,流域性特大高位地质灾害频繁发生。针对该区域开展大范围滑坡调查与监测研究,对减灾防灾具有重要意义。以金沙江结合带巴塘段为试验区,采用堆叠InSAR技术分别利用升轨、降轨Sentinel-1A卫星数据对该区域滑坡隐患开展了调查研究。在此基础上,以中心绒乡滑坡群为重点研究区,利用多维小基线子集技术获取了区域二维形变速率(水平东西向和垂直向)及二维时间序列结果。通过对4处典型滑坡体的形变时间序列结果进行分析,发现在两年时间段内安里克米滑坡、仁娘村滑坡、贡伙村滑坡1和贡伙村滑坡2水平方向累积位移量分别达到44.3、-26.6、65.3和-77.1 mm,垂直向累积位移量分别达到-30.2、-88.3、-80.9和-56.9 mm,且这4处滑坡呈现缓慢蠕滑变形趋势。通过对贡伙村滑坡2的形变监测二维时间序列与降雨数据分析发现,强降雨对滑坡变形有一定短暂影响。由于滑坡群处于地质条件脆弱地区,构造活动强烈,在强降雨条件下极易导致滑坡失稳,建议对其进行持续监测,同时该研究成果对流域内其他区域的滑坡调查与监测研究具有参考意义。

Comparative Analysis of Group Sequential Designs Tests for Randomized Controlled Clinical Trials: A Model Study on Two-Sided Tests for Comparing Two Treatments

Clinical trials are usually long term studies and it seems impossible to reach all required subjects at the same time. Performing interim analyses and monitoring results may provide early termination of trial after obtaining significant results. The aim of this study is comparing group sequential tests in respect to advantage of sample size reduction and early termination. In this study, 4 test types used in group sequential designs were compared with fixed sample size design test and each other. Comparisons were done according to two-sided tests for comparing two treatments. In this sense, 1080 models were performed. In models, 2 different Type I errors, 2 different powers, 5 different analysis groups, 6 different effect sizes and 9 different variances selections were considered. All test types increased the maximum sample size in different manner, compared with fixed sample size design. Each test had different critical values to reject H0 hypothesis, at the same type I error rate and number of analyses conditions. Selection of test type used in group sequential designs depends on a few characteristics, as reducing sample size, early termination and detecting minimal effect size. Test performance is highly related with selected Type I error rate, power and number of analyses. In addition to these statistical characteristics, researchers should decide test type with respect to other trial conditions as the issue of trial, reaching subjects easy or not and importance of early termination.

Evaluation of Hydrogeology of the Lower Son Valley Based on Remote Sensing Data

Remote sensing, one of the most important reconnaissance and feature identifying tools generally applied for surface and groundwater investigation, was used for water resources mapping for the lower Son Valley in this study. The mapping was done with the help of Indian Remote Sensing (IRS) satellite imagery IRS-LISS- 1-B1 for January 29, 1991 obtained during the day transit time. The area under study comprises adjoining parts of Uttar Pradesh and Bihar states of India and extends over the seven districts, namely Bhojpur, Rohtas, Patna, Jahanabad, Aurangabad, Ballia and Chapra. Geology of the study area is quite complex, tectonically disturbed and shows four major cycles of depositions after erosions during last one billion years (since Cretaceous). Two lineaments mapped by GSI (Geological Survey of India) in western side of river Son in the Bhojpur district can also be identified by the satellite imagery. In the present study, apart from these lineaments, two new lineaments have been investigated, which run almost parallel to river Ganga in northwest parts of the area in Ballia district. The lineaments may play a very vital role in groundwater monitoring in the area. The detailed study of geomorphology, vegetation and geology of the Lower Son valley on the basis of photo-interpretation techniques for surface features, drainage pattern and density, and drainage texture has been carried out to determine alluvial type, permeability, tributary, etc. These studies and Darcy velocity analysis show that the prospect of water is very good for entire lower Son valley. The Bhojpur district is most prospective for groundwater exploitation.

基于北斗/GNSS与InSAR的水库群坝体表面变形监测体系

面向城市水库群安全监测的需求,提出基于北斗/GNSS与InSAR技术构建城市水库群坝体表面变形监测体系的概念,利用InSAR技术大范围、高精度的优势,研究实现水库群坝体表面变形监测高效率的方法,同时提出基于北斗/GNSS基准网实现区域内测点实时和应急监测的策略。通过2种技术手段的结合,可形成自动、高效、经济、综合的水库坝体表面变形监测作业新模式,实现对城市水库群高时间分辨率和高空间分辨率,普查性监测和重点在线监测的有机统一。

基于LoRa和GPRS的山区输电线路监测信号无线传输方案

文中针对偏远山区输电线路状态监测系统巡检与维修难度较大的现状,提出一种基于LoRa的山区输电线路在线监测方案。根据LoRa无线传输的特性以及山区监测环境,设计了基于GPRS和LoRa的山区输电线路传输架构。利用多目标优化算法优化山区输电线路线型拓扑结构中的LoRa传输分组并平衡传输模块的通信延时与传输能耗。仿真实验结果表明,监测系统数据传输成功率最高可达99%。与国内外现有输电线路状态监测系统相比,所提方案具有高可靠性传输、低成本以及长期监测的优点,适用于山区输电线路监测信号。

软土地层双洞口顶管接收井下沉力学特性研究

相较于常规沉井,顶管接收井几何形式的差异对结构受力、变形的影响规律尚不明确,亟待对此展开深入研究。以武汉市某排水顶管工程矩形接收井为依托,对沉井结构受力及下沉姿态开展现场监测,并利用数值模拟进行了对比验证和拓展研究。结果表明:预设顶管接收洞口引起的结构局部刚度降低,会导致结构在初沉阶段受弯效应增强,从而使接收洞口附近的内层钢筋压应力减小并使钢筋转向受拉状态,并且在下沉后期加剧该处钢筋应力变化幅度;因沉井外壁摩阻力增大而产生的附加应力叠加弯矩作用,使结构内、外层纵向钢筋沿井壁厚度方向的内力分布不均。对软土地层进行土体加固,有利于提高顶管接收井结构稳定性和顶管机头接收精度。

船闸深孔反弧门实时在线监测技术应用研究

针对船闸输水系统工作反弧门长期在深孔动水条件下频繁启闭,给船闸安全运行造成安全隐患,提出一种深孔反弧门实时在线监测技术方案。为掌握深孔反弧门运行情况,将已密封好的应变及倾角等传感器布置在闸门上,再利用钢丝网架胶管将采集信号输送至在线监测系统。监测系统实时进行反弧门在线监测与数据显示,并实时分析结构应力、运行姿态及启闭力,根据分析结果,给出不同等级报警信息及相应的处置建议,提示运行操作人员对反弧门采取对应措施。对广西大藤峡水利枢纽船闸反弧门实施实时在线监测,测试数据表明实施的反弧门实时在线监测系统是可靠稳定的,证明将实时在线监测技术应用于深孔且动水频繁启闭的闸门是可行的。

基于超星平台的飞机性能工程课程群线上教学质量监控指标研究

针对线上教学质量不均衡和难以监控的问题,有必要对混合式教学模式下的线上教学质量进行监控和评价。以飞机性能工程课程群为对象,开展学习效果和线上学习行为的关联性研究。基于超星平台4个学年的统计数据,初步形成6个一级指标、24个二级指标。首先通过数据预处理删除无效和共线性指标;然后通过描述性统计分析,得出样本数据的分布规律,删除异常指标;接着对15个指标进行相关性分析,得出影响期末考试成绩的相关性指标;最后对剩余指标进行主成分分析并进行排序,形成飞机性能工程课程群线上教学质量监控指标的依次为签到完成率(x_(8))、章节测验总均分(x_(24))、视频观看时长(x_(3))、章节测验参与均分(x_(23))、章节学习次数(x_(1))、任务完成率(x_(5))、章节测验参与率(x_(22))7个学生线上学习行为指标。

基于孔间直流电透视的煤层底板采动破坏电阻率时移变化规律与机理

煤层采动过程中,底板应力状态的改变会产生变形与破坏,而不同煤层采动过程中底板破坏具有一定的规律。目前基于直流电阻率法的煤层底板水害监测主要集中于底板变形与破坏的电阻率响应特征上。为了研究工作面回采过程中煤层底板的电性时移变化特征,采用孔间直流电透视观测系统和时移电阻率反射系数法,通过数值模拟和现场试验揭示了煤层底板采动破坏电阻率时移规律。首先,针对典型地电模型,对比单独反演和时移电阻率变化率的结果,验证了孔间直流电透视时移方法的可靠性。然后,针对煤层底板采动破坏,分析了采动过程中底板承压水导升与底板破坏带的电性响应规律与特征,并讨论了时移电阻率反射系数确定煤层底板破坏深度的可行性,为野外施工提供理论依据。最后,通过现场监测试验,获得工作面回采过程中煤层底板的电性变化特征,并采用时移电阻率反射系数R确定了工作面底板岩层的破坏深度为15 m。结果表明:利用孔间直流电透视法获得的煤层底板采动破坏电阻率时移特征可在一定程度上消除了监测数据中的地层因素和随机噪声影响,且时移电阻率反射系数可用来确定煤层底板破坏深度。该方法将探测目标从单一的研究地质异常转换到对煤层采动过程中工作面底板破坏的全生命周期动态监测,进而实现了工作面底板结构破坏的精细刻画。