Effect of Waste Marble Powder on Physical and Mechanical Properties of Concrete

The emission of greenhouse gases from cement production is an obstacle for sustainable development of construction industry.The use of waste materials in constructions instead of cement could be a feasible solution to green construction.Waste marble powder with good cementing property can be used in concrete partially replace cement.In this research,the effects of using waste marble powder on the physical and mechanical properties of concrete have been studied.Three groups of particle size and five levels of replacement ratio(5%,10%,15%,20%,25%)for each group have been designed.During the different stage of hydration process,the microstructure,phase composition and thermal properties of marble-cement paste have been investigated,the influence of particle size of marble powder on these properties has been discussed.The compressive strength and stressstrain relation were tested for different series prepared by partially replacing cement at proportions of 5%–25%separately.From the data analysis,it was observed that the using of waste marble powder would affect the hydration products and further affect the mechanical properties of concrete,the addition of marble powder that partially replace the cement at particular proportions in concrete is feasible.

Chlorination roasting-coupled water leaching process for potash recovery from waste mica scrap using dry marble sludge powder and sodium chloride

The present paper reports the effective utilization of marble sludge powder(MSP)for the recovery of potash values from waste mica scrap using chlorination roasting-water leaching method.Characterization studies indicated the presence of dolomite as the major mineral phase in MSP,whereas muscovite and quartz were observed in the mica sample.The acid leaching studies suggest a maximum of 22%potash recovery under conditions:4 M H2SO4 acid,particle size of^100μm,stirring speed of 600 r/min,leaching temperature of 75℃,and leaching time of 90 min.The chlorination roasting-water leaching process was adopted to achieve the lowest level of 80%-90%potash recovery.The optimum conditions for the recovery of^93%potash from mica(~8.6wt%K2O)requires 900℃ roasting temperature,30 min roasting time,and 1:1:0.75 mass ratio of mica:MSP:NaCl.The roasting temperature and amount of NaCl are found to be the most important factors for the recovery process.The reaction mechanism suggests the formation of different mineral phases,including sylvite(KCl),wollastonite,kyanite,and enstatite,during roasting,which were confirmed by X-ray diffraction(XRD)analyses and scanning electron microscopy(SEM)morphologies.The MSP-blended NaCl additive is more effective for potash recovery compared with the other reported commercial roasting additives.