In this work,the Permian Longtan marine-continental transitional shale in the southeast of Sichuan Basin was taken as study object.Through petrology and geochemical analysis,lithofacies types of the marine-continental...In this work,the Permian Longtan marine-continental transitional shale in the southeast of Sichuan Basin was taken as study object.Through petrology and geochemical analysis,lithofacies types of the marine-continental transitional shale were classified,key controlling factors of physical properties and gas content of the different shale lithofacies were analyzed.The research results show that the Longtan Formation marine-continental transitional shale in the study area has four types of lithofacies,namely,organic-lean calcareous shale,organic-lean mixed shale,organic-lean argillaceous shale,and organic-rich argillaceous shale,among which the organic-rich argillaceous shale is the most favorable lithofacies of the study area.The pore types of different lithofacies vary significantly and the clay mineral-related pore is the dominant type of the pore system in the study area.The main controlling factor of the physical properties is clay mineral content,and the most important factor affecting gas content is TOC content.Compared with marine shale,the marine-continental transitional shale has low average values,wide distribution range,and strong heterogeneity in TOC content,porosity,and pore structure parameters,but still contains some favorable layers with high physical properties and gas contents.The organic-rich clay shale deposited in tidal flat-lagoon system is most likely to form shale gas sweet spots,so it should be paid more attention in shale gas exploration.展开更多
Based on core description,thin section identification,X-ray diffraction analysis,scanning electron microscopy,low-temperature gas adsorption and high-pressure mercury intrusion porosimetry,the shale lithofacies of Sha...Based on core description,thin section identification,X-ray diffraction analysis,scanning electron microscopy,low-temperature gas adsorption and high-pressure mercury intrusion porosimetry,the shale lithofacies of Shan23 sub-member of Permian Shanxi Formation in the east margin of Ordos Basin was systematically analyzed in this study.The Shan23 sub-member has six lithofacies,namely,low TOC clay shale(C-L),low TOC siliceous shale(S-L),medium TOC siliceous shale(S-M),medium TOC hybrid shale(M-M),high TOC siliceous shale(S-H),and high TOC clay shale(C-H).Among them,S-H is the best lithofacies,S-M and M-M are the second best.The C-L and C-H lithofacies,mainly found in the upper part of Shan23 sub-member,generally developed in tide-dominated delta facies;the S-L,S-M,S-H and M-M shales occurring in the lower part of Shan23 sub-member developed in tide-dominated estuarine bay facies.The S-H,S-M and M-M shales have good pore struc-ture and largely organic matter pores and mineral interparticle pores,including interlayer pore in clay minerals,pyrite inter-crystalline pore,and mineral dissolution pore.C-L and S-L shales have mainly mineral interparticle pores and clay mineral in-terlayer pores,and a small amount of organic matter pores,showing poorer pore structure.The C-H shale has organic mi-cro-pores and a small number of interlayer fissures of clay minerals,showing good micro-pore structure,and poor meso-pore and macro-pore structure.The formation of favorable lithofacies is jointly controlled by depositional environment and diagen-esis.Shallow bay-lagoon depositional environment is conducive to the formation of type II2 kerogen which can produce a large number of organic cellular pores.Besides,the rich biogenic silica is conducive to the preservation of primary pores and en-hances the fracability of the shale reservoir.展开更多
Using the typical characteristics of multi-layered marine and continental transitional gas reservoirs as a basis,a model is developed to predict the related well production rate.This model relies on the fractal theory...Using the typical characteristics of multi-layered marine and continental transitional gas reservoirs as a basis,a model is developed to predict the related well production rate.This model relies on the fractal theory of tortuous capillary bundles and can take into account multiple gas flow mechanisms at the micrometer and nanometer scales,as well as the flow characteristics in different types of thin layers(tight sandstone gas,shale gas,and coalbed gas).Moreover,a source-sink function concept and a pressure drop superposition principle are utilized to introduce a coupled flow model in the reservoir.A semi-analytical solution for the production rate is obtained using a matrix iteration method.A specific well is selected for fitting dynamic production data,and the calculation results show that the tight sandstone has the highest gas production per unit thickness compared with the other types of reservoirs.Moreover,desorption and diffusion of coalbed gas and shale gas can significantly contribute to gas production,and the daily production of these two gases decreases rapidly with decreasing reservoir pressure.Interestingly,the gas production from fractures exhibits an approximately U-shaped distribution,indicating the need to optimize the spacing between clusters during hydraulic fracturing to reduce the area of overlapping fracture control.The coal matrix water saturation significantly affects the coalbed gas production,with higher water saturation leading to lower production.展开更多
Based on 10 shale samples collected from 4 wells in Qinshui Basin,we investigate the full-sized pore structure and fractal characteristics of Marine-Continental transitional shale by performing organic geochemistry,mi...Based on 10 shale samples collected from 4 wells in Qinshui Basin,we investigate the full-sized pore structure and fractal characteristics of Marine-Continental transitional shale by performing organic geochemistry,mineralogical composition,Nitrogen gas adsorption(N2 adsorption)and Nuclear Magnetic Resonance(NMR)measurements and fractal analysis.Results show that the TOC content of the shale samples is relatively high,with an average value of 2.44wt%,and the thermal evolution is during the mature-over mature stage.The NMR T2 spectrum can be used to characterize the fullsized pore structure characteristics of shale.By combining N2 adsorption pore structure parameters and NMR T2 spectrums,the surface relaxivity of samples are calculated to be between 1.7877 um/s and 5.2272 um/s.On this basis,the T2 spectrums are converted to full-sized pore volume and surface area distribution curves.The statistics show that the pore volume is mainly provided by mesopore,followed by micropore,and the average percentages are 65.04%and 30.83%respectively;the surface area is mainly provided by micropore,followed by mesopore,and the average percentages are 60.8004%and 39.137%respectively;macropore contributes little to pore volume and surface area.The pore structure characteristics of shale have no relationship with TOC,but strong relationships with clay minerals content.NMR fractal dimensions Dmicro and Dmeso have strong positive relationships with the N2 adsorption fractal dimensions D1 and D2 respectively,indicating that Dmicro can be used to characterize the fractal characteristics of pore surface,and Dmeso can be used to characterize the fractal characteristics of pore structure.The shale surface relaxivity is controlled by multiple factors.The increasing of clay mineral content,pore surface area,pore surface fractal dimension and the decreasing of average pore size,will all lead to the decreasing of shale surface relaxivity.展开更多
Objective At present, there is controversy regarding the existence of marine-terrestrial transitional facies that can act as a source of shale gas. This detailed study of Carboniferous-Permian age geological data from...Objective At present, there is controversy regarding the existence of marine-terrestrial transitional facies that can act as a source of shale gas. This detailed study of Carboniferous-Permian age geological data from the northern Shaanxi area （China） provides new insight for this type of shale gas. In addition, a new deposition and accumulation pattern for this type of shale gas is established.展开更多
The organic-rich shale of the Shanxi and Taiyuan Formation of the Lower Permian deposited in a marinecontinental transitional environment are well developed in the Ordos Basin,NW China,which is considered to contain a...The organic-rich shale of the Shanxi and Taiyuan Formation of the Lower Permian deposited in a marinecontinental transitional environment are well developed in the Ordos Basin,NW China,which is considered to contain a large amount of shale hydrocarbon resources.This study takes the Lower Permian Shanxi and Taiyuan shale collected from well SL~# in the Ordos Basin,NW China as an example to characterize the transitional shale reservoir.Based on organic geochemistry data,X-ray diffraction(XRD)analysis,field-emission scanning electron microscopy(FE-SEM)observations,the desorbed gas contents of this transitional shale were systematically studied and the shale gas potential was investigated.The results indicate that the Lower Permian Shanxi and Taiyuan shale has a relatively high total organic carbon(TOC)(average TOC of 4.9%)and contains type III kerogen with a high mature to over mature status.XRD analyses show that an important characteristic of the shale is that clay and brittle minerals of detrital origin comprise the major mineral composition of the marine-continental transitional shale samples,while the percentages of carbonate minerals,pyrite and siderite are relatively small.FE-SEM observations reveal that the mineral matrix pores are the most abundant in the Lower Permian shale samples,while organic matter(OM)pores are rarely developed.Experimental analysis suggests that the mineral compositions mainly govern the macropore development in the marine-continental transitional shale,and mineral matrix pores and microfractures are considered to provide space for gas storage and migration.In addition,the desorption experiments demonstrated that the marine-continental transitional shale in the Ordos Basin has a significantly potential for shale gas exploration,ranging from 0.53 to 2.86 m^3/t with an average value of 1.25m^3/t,which is in close proximity to those of terrestrial shale(1.29 m^3/t)and marine shale(1.28 m^3/t).In summary,these results demonstrated that the Lower Permian marine-continental transitional shale in the Ordos Basin has a significantly potential for shale gas exploration.展开更多
China is home to shales of three facies:Marine shale,continental shale,and marine-continental transitional shale.Different types of shale gas are associated with significantly different formation conditions and major ...China is home to shales of three facies:Marine shale,continental shale,and marine-continental transitional shale.Different types of shale gas are associated with significantly different formation conditions and major controlling factors.This study compared the geological characteristics of various shales and analyzed the influences of different parameters on the formation and accumulation of shale gas.In general,shales in China’s several regions exhibit high total organic carbon(TOC)contents,which lays a sound material basis for shale gas generation.Marine strata generally show high degrees of thermal evolution.In contrast,continental shales manifest low degrees of thermal evolution,necessitating focusing on areas with relatively high degrees of thermal evolution in the process of shale gas surveys for these shales.The shales of the Wufeng and Silurian formations constitute the most favorable shale gas reservoirs since they exhibit the highest porosity among the three types of shales.These shales are followed by those in the Niutitang and Longtan formations.In contrast,the shales of the Doushantuo,Yanchang,and Qingshankou formations manifest low porosities.Furthermore,the shales of the Wufeng and Longmaxi formations exhibit high brittle mineral contents.Despite a low siliceous mineral content,the shales of the Doushantuo Formation feature a high carbonate mineral content,which can increase the shales’brittleness to some extent.For marine-continental transitional shales,where thin interbeds of tight sandstone with unequal thicknesses are generally found,it is recommended that fracturing combined with drainage of multiple sets of lithologic strata should be employed to enhance their shale gas production.展开更多
Organic matter(OM)nanopores developed in transitional facies shales,i.e.,the Upper Permian Longtan and Dalong Formations in the Yangtze Platform,China,were investigated to determine the corre-sponding influence of the...Organic matter(OM)nanopores developed in transitional facies shales,i.e.,the Upper Permian Longtan and Dalong Formations in the Yangtze Platform,China,were investigated to determine the corre-sponding influence of thermal maturity and OM types within the geological conditions.A suite of 16 core samples were taken from Type-Ⅲ Longtan shales and Type-Ⅱ Dalong shales from two wells covering a ma-turity(Ro,vitrinite reflectance)ranging from 1.22%to 1.43%and 2.62%to 2.97%,respectively.Integrated analysis of the shale samples was carried out,including field-emission scanning electron microscopy(FESEM),low-pressure N2 and CO2 adsorption,high-pressure CH4 adsorption,and mercury intrusion capillary pressure(MICP)analysis.The fluid inclusions of liquid and gas hydrocarbons trapped in calcite vein samples in Dalong shales of two wells were studied using laser Raman and fluorescence spectroscopy.FE-SEM images indicated that OM pores in different formations varied substantially in terms of shape,size,and distribution density.OM pores in Type-Ⅱ Dalong shales of Well XY1 were mainly micropore,sparsely distributed in the gas-prone kerogen with a spot-like and irregular shape,while bitumen rarely developed observable pores.In contrast,the morphology of OM pores in Type-Ⅲ Longtan shales were significantly different,which was due to differences in the OM type.The primary OM pores in some terrestrial woody debris in Longtan shales had a relatively larger pore diameter,ranging from hundreds of nanometers to a few micrometers and were al-most all rounded in shape,which might be one of the factors contributing to larger pore volume and gas adsorption capacity than Dalong shales of Well XY1.Comparing Dalong shales of Well XY1 with relatively lower thermal maturity,there were abundant spongy-like pores,densely developed in the pyrobitumen in Type-Ⅱ Dalong shales of Well EY1,with an irregular shape and diameter ranging from several to hundreds of nanometers.Many blue fluorescent oil inclusions and a small number of CH4 inclusions mixed with C2H6 could be observed within calcite veins in Dalong shales of Well XY1,whereas only CH4 inclusions could be identified within calcite veins in Dalong shales of Well EJ1.Therefore,thermal maturity not only controlled the type of hydrocarbons generated,but also makes a significant contribution to the formation of OM pores,resulting in larger pore volumes and adsorption capacity of Type-Ⅱ shale samples in the dry gas window.展开更多
基金Supported by the National Natural Science Foundation (U19B6003).
文摘In this work,the Permian Longtan marine-continental transitional shale in the southeast of Sichuan Basin was taken as study object.Through petrology and geochemical analysis,lithofacies types of the marine-continental transitional shale were classified,key controlling factors of physical properties and gas content of the different shale lithofacies were analyzed.The research results show that the Longtan Formation marine-continental transitional shale in the study area has four types of lithofacies,namely,organic-lean calcareous shale,organic-lean mixed shale,organic-lean argillaceous shale,and organic-rich argillaceous shale,among which the organic-rich argillaceous shale is the most favorable lithofacies of the study area.The pore types of different lithofacies vary significantly and the clay mineral-related pore is the dominant type of the pore system in the study area.The main controlling factor of the physical properties is clay mineral content,and the most important factor affecting gas content is TOC content.Compared with marine shale,the marine-continental transitional shale has low average values,wide distribution range,and strong heterogeneity in TOC content,porosity,and pore structure parameters,but still contains some favorable layers with high physical properties and gas contents.The organic-rich clay shale deposited in tidal flat-lagoon system is most likely to form shale gas sweet spots,so it should be paid more attention in shale gas exploration.
基金China National Science and Technology Major Project(2017ZX05035).
文摘Based on core description,thin section identification,X-ray diffraction analysis,scanning electron microscopy,low-temperature gas adsorption and high-pressure mercury intrusion porosimetry,the shale lithofacies of Shan23 sub-member of Permian Shanxi Formation in the east margin of Ordos Basin was systematically analyzed in this study.The Shan23 sub-member has six lithofacies,namely,low TOC clay shale(C-L),low TOC siliceous shale(S-L),medium TOC siliceous shale(S-M),medium TOC hybrid shale(M-M),high TOC siliceous shale(S-H),and high TOC clay shale(C-H).Among them,S-H is the best lithofacies,S-M and M-M are the second best.The C-L and C-H lithofacies,mainly found in the upper part of Shan23 sub-member,generally developed in tide-dominated delta facies;the S-L,S-M,S-H and M-M shales occurring in the lower part of Shan23 sub-member developed in tide-dominated estuarine bay facies.The S-H,S-M and M-M shales have good pore struc-ture and largely organic matter pores and mineral interparticle pores,including interlayer pore in clay minerals,pyrite inter-crystalline pore,and mineral dissolution pore.C-L and S-L shales have mainly mineral interparticle pores and clay mineral in-terlayer pores,and a small amount of organic matter pores,showing poorer pore structure.The C-H shale has organic mi-cro-pores and a small number of interlayer fissures of clay minerals,showing good micro-pore structure,and poor meso-pore and macro-pore structure.The formation of favorable lithofacies is jointly controlled by depositional environment and diagen-esis.Shallow bay-lagoon depositional environment is conducive to the formation of type II2 kerogen which can produce a large number of organic cellular pores.Besides,the rich biogenic silica is conducive to the preservation of primary pores and en-hances the fracability of the shale reservoir.
文摘Using the typical characteristics of multi-layered marine and continental transitional gas reservoirs as a basis,a model is developed to predict the related well production rate.This model relies on the fractal theory of tortuous capillary bundles and can take into account multiple gas flow mechanisms at the micrometer and nanometer scales,as well as the flow characteristics in different types of thin layers(tight sandstone gas,shale gas,and coalbed gas).Moreover,a source-sink function concept and a pressure drop superposition principle are utilized to introduce a coupled flow model in the reservoir.A semi-analytical solution for the production rate is obtained using a matrix iteration method.A specific well is selected for fitting dynamic production data,and the calculation results show that the tight sandstone has the highest gas production per unit thickness compared with the other types of reservoirs.Moreover,desorption and diffusion of coalbed gas and shale gas can significantly contribute to gas production,and the daily production of these two gases decreases rapidly with decreasing reservoir pressure.Interestingly,the gas production from fractures exhibits an approximately U-shaped distribution,indicating the need to optimize the spacing between clusters during hydraulic fracturing to reduce the area of overlapping fracture control.The coal matrix water saturation significantly affects the coalbed gas production,with higher water saturation leading to lower production.
基金support from the National Science and Technology Major Project of China (Grant No. 2016ZX05034)
文摘Based on 10 shale samples collected from 4 wells in Qinshui Basin,we investigate the full-sized pore structure and fractal characteristics of Marine-Continental transitional shale by performing organic geochemistry,mineralogical composition,Nitrogen gas adsorption(N2 adsorption)and Nuclear Magnetic Resonance(NMR)measurements and fractal analysis.Results show that the TOC content of the shale samples is relatively high,with an average value of 2.44wt%,and the thermal evolution is during the mature-over mature stage.The NMR T2 spectrum can be used to characterize the fullsized pore structure characteristics of shale.By combining N2 adsorption pore structure parameters and NMR T2 spectrums,the surface relaxivity of samples are calculated to be between 1.7877 um/s and 5.2272 um/s.On this basis,the T2 spectrums are converted to full-sized pore volume and surface area distribution curves.The statistics show that the pore volume is mainly provided by mesopore,followed by micropore,and the average percentages are 65.04%and 30.83%respectively;the surface area is mainly provided by micropore,followed by mesopore,and the average percentages are 60.8004%and 39.137%respectively;macropore contributes little to pore volume and surface area.The pore structure characteristics of shale have no relationship with TOC,but strong relationships with clay minerals content.NMR fractal dimensions Dmicro and Dmeso have strong positive relationships with the N2 adsorption fractal dimensions D1 and D2 respectively,indicating that Dmicro can be used to characterize the fractal characteristics of pore surface,and Dmeso can be used to characterize the fractal characteristics of pore structure.The shale surface relaxivity is controlled by multiple factors.The increasing of clay mineral content,pore surface area,pore surface fractal dimension and the decreasing of average pore size,will all lead to the decreasing of shale surface relaxivity.
基金funded by the Geological Survey Project of China Geological Survey(No.1212011085516)Geological Survey Level 2 Project(No.121201103000150011)Basic Research Professional Expenses of CAGS(No. YYWF201609)
文摘Objective At present, there is controversy regarding the existence of marine-terrestrial transitional facies that can act as a source of shale gas. This detailed study of Carboniferous-Permian age geological data from the northern Shaanxi area （China） provides new insight for this type of shale gas. In addition, a new deposition and accumulation pattern for this type of shale gas is established.
基金This work was financially supported by the Chinese Academy of Sciences Key Project(Grant No.XDB10030404)the National key R&D Program of China(Grant No.2017YFA0604803)+1 种基金the National Natural Science Foundation of China(Grant Nos.41831176,41572350 and 41503049)the Key Laboratory Project of Gansu(Grant No.1309RTSA041).
文摘The organic-rich shale of the Shanxi and Taiyuan Formation of the Lower Permian deposited in a marinecontinental transitional environment are well developed in the Ordos Basin,NW China,which is considered to contain a large amount of shale hydrocarbon resources.This study takes the Lower Permian Shanxi and Taiyuan shale collected from well SL~# in the Ordos Basin,NW China as an example to characterize the transitional shale reservoir.Based on organic geochemistry data,X-ray diffraction(XRD)analysis,field-emission scanning electron microscopy(FE-SEM)observations,the desorbed gas contents of this transitional shale were systematically studied and the shale gas potential was investigated.The results indicate that the Lower Permian Shanxi and Taiyuan shale has a relatively high total organic carbon(TOC)(average TOC of 4.9%)and contains type III kerogen with a high mature to over mature status.XRD analyses show that an important characteristic of the shale is that clay and brittle minerals of detrital origin comprise the major mineral composition of the marine-continental transitional shale samples,while the percentages of carbonate minerals,pyrite and siderite are relatively small.FE-SEM observations reveal that the mineral matrix pores are the most abundant in the Lower Permian shale samples,while organic matter(OM)pores are rarely developed.Experimental analysis suggests that the mineral compositions mainly govern the macropore development in the marine-continental transitional shale,and mineral matrix pores and microfractures are considered to provide space for gas storage and migration.In addition,the desorption experiments demonstrated that the marine-continental transitional shale in the Ordos Basin has a significantly potential for shale gas exploration,ranging from 0.53 to 2.86 m^3/t with an average value of 1.25m^3/t,which is in close proximity to those of terrestrial shale(1.29 m^3/t)and marine shale(1.28 m^3/t).In summary,these results demonstrated that the Lower Permian marine-continental transitional shale in the Ordos Basin has a significantly potential for shale gas exploration.
基金supported by the project of the China Geological Survey for shale gas in Southern China(DD20221852)the National Natural Science Foundation of China(42242010,U2244208)。
文摘China is home to shales of three facies:Marine shale,continental shale,and marine-continental transitional shale.Different types of shale gas are associated with significantly different formation conditions and major controlling factors.This study compared the geological characteristics of various shales and analyzed the influences of different parameters on the formation and accumulation of shale gas.In general,shales in China’s several regions exhibit high total organic carbon(TOC)contents,which lays a sound material basis for shale gas generation.Marine strata generally show high degrees of thermal evolution.In contrast,continental shales manifest low degrees of thermal evolution,necessitating focusing on areas with relatively high degrees of thermal evolution in the process of shale gas surveys for these shales.The shales of the Wufeng and Silurian formations constitute the most favorable shale gas reservoirs since they exhibit the highest porosity among the three types of shales.These shales are followed by those in the Niutitang and Longtan formations.In contrast,the shales of the Doushantuo,Yanchang,and Qingshankou formations manifest low porosities.Furthermore,the shales of the Wufeng and Longmaxi formations exhibit high brittle mineral contents.Despite a low siliceous mineral content,the shales of the Doushantuo Formation feature a high carbonate mineral content,which can increase the shales’brittleness to some extent.For marine-continental transitional shales,where thin interbeds of tight sandstone with unequal thicknesses are generally found,it is recommended that fracturing combined with drainage of multiple sets of lithologic strata should be employed to enhance their shale gas production.
基金We would like to thank the National Key R&D program of China(No.2017YFE0103600)the National Natural Science Foundation of China(Nos.41830431,41672139)the China National Science and Technology Major Projects(No.2016ZX05034002-003)for financial assistance to this research.
文摘Organic matter(OM)nanopores developed in transitional facies shales,i.e.,the Upper Permian Longtan and Dalong Formations in the Yangtze Platform,China,were investigated to determine the corre-sponding influence of thermal maturity and OM types within the geological conditions.A suite of 16 core samples were taken from Type-Ⅲ Longtan shales and Type-Ⅱ Dalong shales from two wells covering a ma-turity(Ro,vitrinite reflectance)ranging from 1.22%to 1.43%and 2.62%to 2.97%,respectively.Integrated analysis of the shale samples was carried out,including field-emission scanning electron microscopy(FESEM),low-pressure N2 and CO2 adsorption,high-pressure CH4 adsorption,and mercury intrusion capillary pressure(MICP)analysis.The fluid inclusions of liquid and gas hydrocarbons trapped in calcite vein samples in Dalong shales of two wells were studied using laser Raman and fluorescence spectroscopy.FE-SEM images indicated that OM pores in different formations varied substantially in terms of shape,size,and distribution density.OM pores in Type-Ⅱ Dalong shales of Well XY1 were mainly micropore,sparsely distributed in the gas-prone kerogen with a spot-like and irregular shape,while bitumen rarely developed observable pores.In contrast,the morphology of OM pores in Type-Ⅲ Longtan shales were significantly different,which was due to differences in the OM type.The primary OM pores in some terrestrial woody debris in Longtan shales had a relatively larger pore diameter,ranging from hundreds of nanometers to a few micrometers and were al-most all rounded in shape,which might be one of the factors contributing to larger pore volume and gas adsorption capacity than Dalong shales of Well XY1.Comparing Dalong shales of Well XY1 with relatively lower thermal maturity,there were abundant spongy-like pores,densely developed in the pyrobitumen in Type-Ⅱ Dalong shales of Well EY1,with an irregular shape and diameter ranging from several to hundreds of nanometers.Many blue fluorescent oil inclusions and a small number of CH4 inclusions mixed with C2H6 could be observed within calcite veins in Dalong shales of Well XY1,whereas only CH4 inclusions could be identified within calcite veins in Dalong shales of Well EJ1.Therefore,thermal maturity not only controlled the type of hydrocarbons generated,but also makes a significant contribution to the formation of OM pores,resulting in larger pore volumes and adsorption capacity of Type-Ⅱ shale samples in the dry gas window.
