An experiment facility has been set up for the study of metal cluster compounds in our laboratory, which consists of a nano-electrospray ionization source, an ion transmission and focus system, and a reflectron time-o...An experiment facility has been set up for the study of metal cluster compounds in our laboratory, which consists of a nano-electrospray ionization source, an ion transmission and focus system, and a reflectron time-of-fight mass spectrometer. Taking advantage of the nano-electrospray ionization source, polyvalent ions are usually produced in the ＂ionization＂ process and the obtained mass resolution of the equipment is over 8000. The molecular ion peaks of metal cluster compounds [Au20（PPhpy2）10Cl2]（SbF6）4, where PPhpy2=bis（2- pyridyl）phenylphosphine, and [AuaAg2（C）L6]（BF4）4, where L=2-（diphenylphosphino）-5- methylpyridine, are distinguished in the respective mass spectrum, accompanied by some fragment ion peaks. In addition, the mass-to-charge ratios of the parent ions are determi- nated. Preliminary results suggest that the device is a powerful tool for the study of metal cluster compounds. It turns out that the information obtained by the instrumentation serves as an essential supplement to single crystal X-ray diffraction for structure characterization of metal cluster compounds.展开更多
The special design of magnetic analyzer for a 400 keV ion implanter is described. An asymmetric double-focusing condition is used in the design. The transverse object point is real and the vertical object is virtual. ...The special design of magnetic analyzer for a 400 keV ion implanter is described. An asymmetric double-focusing condition is used in the design. The transverse object point is real and the vertical object is virtual. The electrostatic doublet is taken to realize the beam optics matching between the ion source, initial focusing system and magnetic analyzer. By this design the magnetic analyzer has been cut in size, and the mass resolution enhanced. The desired mass resolution equals 200, such that six mercury isotopes can be separated. The measured results for the mass resolution is in good agreement with the calculated values. This manifests the successful theoretical calculation.展开更多
A new electron impact storage ion source has been designed for time of flight mass spectrometers with a high mass resolving power and high sensitivity. Because of the storage and compressing focus of the source, the o...A new electron impact storage ion source has been designed for time of flight mass spectrometers with a high mass resolving power and high sensitivity. Because of the storage and compressing focus of the source, the overall performance of the instrument has been improved greatly with a mass resolving power up to 3 500. The conditions of the second order of the focus are given and the storage ability is proved. The competer simulations and experiment results are given, too.展开更多
文摘An experiment facility has been set up for the study of metal cluster compounds in our laboratory, which consists of a nano-electrospray ionization source, an ion transmission and focus system, and a reflectron time-of-fight mass spectrometer. Taking advantage of the nano-electrospray ionization source, polyvalent ions are usually produced in the ＂ionization＂ process and the obtained mass resolution of the equipment is over 8000. The molecular ion peaks of metal cluster compounds [Au20（PPhpy2）10Cl2]（SbF6）4, where PPhpy2=bis（2- pyridyl）phenylphosphine, and [AuaAg2（C）L6]（BF4）4, where L=2-（diphenylphosphino）-5- methylpyridine, are distinguished in the respective mass spectrum, accompanied by some fragment ion peaks. In addition, the mass-to-charge ratios of the parent ions are determi- nated. Preliminary results suggest that the device is a powerful tool for the study of metal cluster compounds. It turns out that the information obtained by the instrumentation serves as an essential supplement to single crystal X-ray diffraction for structure characterization of metal cluster compounds.
文摘The special design of magnetic analyzer for a 400 keV ion implanter is described. An asymmetric double-focusing condition is used in the design. The transverse object point is real and the vertical object is virtual. The electrostatic doublet is taken to realize the beam optics matching between the ion source, initial focusing system and magnetic analyzer. By this design the magnetic analyzer has been cut in size, and the mass resolution enhanced. The desired mass resolution equals 200, such that six mercury isotopes can be separated. The measured results for the mass resolution is in good agreement with the calculated values. This manifests the successful theoretical calculation.
文摘A new electron impact storage ion source has been designed for time of flight mass spectrometers with a high mass resolving power and high sensitivity. Because of the storage and compressing focus of the source, the overall performance of the instrument has been improved greatly with a mass resolving power up to 3 500. The conditions of the second order of the focus are given and the storage ability is proved. The competer simulations and experiment results are given, too.
