We present a mechanism for double transparency in an optomechanical system. This mechanism is based on the coupling of a moving cavity mirror to a second mechanical oscillator. Due to the purely mechanical coupling an...We present a mechanism for double transparency in an optomechanical system. This mechanism is based on the coupling of a moving cavity mirror to a second mechanical oscillator. Due to the purely mechanical coupling and the radiation pressure, three pathways are established for excitations of the probe photons into the cavity photons. Destructive interference occurs at two different frequencies, leading to double transparency to the probe field, It is the coupling strength between the mechanical oscillators that determines the locations of the transparency windows. Moreover, the normal splitting appears for the generated Stokes field and the four-wave mixing process is inhibited on resonance.展开更多
High content of asphaltenes and waxes leads to the high pour point and the poor flowability of heavy oil,which is adverse to its efficient development and its transportation in pipe.Understanding the interaction mecha...High content of asphaltenes and waxes leads to the high pour point and the poor flowability of heavy oil,which is adverse to its efficient development and its transportation in pipe.Understanding the interaction mechanism between asphaltene-wax is crucial to solve these problems,but it is still unclear.In this paper,molecular dynamics simulation was used to investigate the interaction between asphaltenewax and its effects on the crystallization behavior of waxes in heavy oil.Results show that molecules in pure wax are arranged in a paralleled geometry.But wax molecules in heavy oil,which are close to the surface of asphaltene aggregates,are bent and arranged irregularly.When the mass fraction of asphaltenes in asphaltene-wax system(ω_(asp))is 0-25 wt%,the attraction among wax molecules decreases and the bend degree of wax molecules increases with the increase ofω_(asp).Theω_(asp)increases from 0 to 25 wt%,and the attraction between asphaltene-wax is stronger than that among waxes.This causes that the wax precipitation point changes from 353 to 333 K.While theω_(asp)increases to 50 wt%,wax molecules are more dispersed owing to the steric hindrance of asphaltene aggregates,and the interaction among wax molecules transforms from attraction to repulsion.It causes that the ordered crystal structure of waxes can't be formed at normal temperature.Simultaneously,the asphaltene,with the higher molecular weight or the more hetero atoms,has more obvious inhibition to the formation of wax crystals.Besides,resins also have an obvious inhibition on the wax crystal due to the formation of asphalteneresin aggregates with a larger radius.Our results reveal the interaction mechanism between asphaltene-wax,and provide useful guidelines for the development of heavy oil.展开更多
The safety and durability of lithium-ion batteries under mechanical constraints depend significantly on electrochemical,thermal,and mechanical fields in applications.Characterizing and quantifying the multi-field coup...The safety and durability of lithium-ion batteries under mechanical constraints depend significantly on electrochemical,thermal,and mechanical fields in applications.Characterizing and quantifying the multi-field coupling behaviors requires interdisciplinary efforts.Here,we design experiments under mechanical constraints and introduce an in-situ analytical framework to clarify the complex interaction mechanisms and coupling degrees among multi-physics fields.The proposed analytical framework integrates the parameterization of equivalent models,in-situ mechanical analysis,and quantitative assessment of coupling behavior.The results indicate that the significant impact of pressure on impedance at low temperatures results from the diffusion-controlled step,enhancing kinetics when external pressure,like 180 to 240 k Pa at 10℃,is applied.The diversity in control steps for the electrochemical reaction accounts for the varying impact of pressure on battery performance across different temperatures.The thermal expansion rate suggests that the swelling force varies by less than 1.60%per unit of elevated temperature during the lithiation process.By introducing a composite metric,we quantify the coupling correlation and intensity between characteristic parameters and physical fields,uncovering the highest coupling degree in electrochemical-thermal fields.These results underscore the potential of analytical approaches in revealing the mechanisms of interaction among multi-fields,with the goal of enhancing battery performance and advancing battery management.展开更多
The mass communication model and interactive ritual chain theory,which serve as communication paradigms in the new media era,facilitate and enhance the synergy between the fields of social history of medicine and heal...The mass communication model and interactive ritual chain theory,which serve as communication paradigms in the new media era,facilitate and enhance the synergy between the fields of social history of medicine and health communication.This study employs a comprehensive framework based on the five elements of the mass communication model:information source,communication subject,communication object,message content,and post-communication feedback.Additionally,it incorporates the interactive ritual chain theory to examine the evolving dynamics and developmental trajectory of research in the social history of medicine during the new media era.Conclusively,this paper acknowledges the existing interaction gaps in the interaction between health communication and the social history of medicine research while outlining the challenges for fostering collaboration and proposing strategic optimizations for effective integration.展开更多
The existence of specific biorhythms and the role of geomagnetic and/or solar magnetic activities are well-established by appropriate correlations in chronobiology. From a physical viewpoint, there are two different a...The existence of specific biorhythms and the role of geomagnetic and/or solar magnetic activities are well-established by appropriate correlations in chronobiology. From a physical viewpoint, there are two different accesses to biorhythms to set up connections to molecular processes: quantum mechanical perturbation theoretical methods and their resonance dominators to characterize specific interactions between constituents. These methods permit the treatment of molecular processes by circuits with characteristic resonances and “beat-frequencies”, which result from primarily fast physical processes. As examples, the tunneling processes between DNA base pairs (H bonds), the ATP decomposition and the irradiation of tumor cells are accounted for.展开更多
The cyclic plastic straining electrode technique has been used to investigate the transient electrochemical behaviour of Fe-26Cr1Mo stainless steel in 1M H2SO4 solution at a passive potential.The influence of plastic ...The cyclic plastic straining electrode technique has been used to investigate the transient electrochemical behaviour of Fe-26Cr1Mo stainless steel in 1M H2SO4 solution at a passive potential.The influence of plastic strain amplitude and plastic strain rate on the dissolution current response was analysed. The experimental results showed that the transient current was dependent on the competitive process of the surface film rupture and repassivation of the new surface. The high plastic strain amplitude and the high plastic strain rate caused a change of electrochemical activity of specimen surface. In the condition of low strain amplitude and strain rate, the characteristics of current response was mainly relative tp the process of new surface repassivation.The competition kinetics has been analysed through the comparison of plastic strain rate and repassivating rate展开更多
Bimolecular interactions play crucial roles in lignin pyrolysis.The tautomerization of key intermediates has a significant impact on the formation of stable products,whereas bimolecular tautomerization has been rarely...Bimolecular interactions play crucial roles in lignin pyrolysis.The tautomerization of key intermediates has a significant impact on the formation of stable products,whereas bimolecular tautomerization has been rarely clarified.In the present work,the bimolecular tautomerization mechanism induced by both concerted and radical interactions was proposed and carefully confirmed.A characteristicβ-O-4 lignin dimer,2-phenoxy-1-phenylethanol(α-OH-PPE),was used as the model compound to reveal two representative keto-phenol and enol-keto tautomerism mechanisms,based on theoretical calculations combined with pyrolysis experiments.The results indicate that the unimolecular tautomerism as the rate-determining step limits product generation,due to fairly high energy barriers.While the free hydroxy compounds and radicals derived from initial pyrolysis can further initiate bimolecular tautomerism reactions through the one-step concerted hydroxyl-assisted hydrogen transfer(hydroxylAHT)and two-step radical hydrogen abstraction interactions,respectively.By alleviating and even avoiding the large ring tension of tautomerism,the unstable tautomers(2,4-cyclohexadienone and1-hydroxy styrene)can be rapidly tautomerized into stable phenol and acetophenone with the help of intermolecular interaction.Benefitting from the significant advantage of retro-ene fragmentation in breaking theβ-O-4 bond to form tautomers,a large amount of stable phenolic and ketone products can be generated following bimolecular tautomerization in the pyrolysis ofβ-O-4 linked lignin.展开更多
Understanding the in situ stress state is crucial in many engineering problems and earth science research.The present article presents new insights into the interaction mechanism between the stress state and faults.In...Understanding the in situ stress state is crucial in many engineering problems and earth science research.The present article presents new insights into the interaction mechanism between the stress state and faults.In situ stresses can be influenced by various factors,one of the most important being the existence of faults.A fault could significantly affect the value and direction of the stress components.Reorientation and magnitude changes in stresses exist adjacent to faults and stress jumps/discontinuities across the fault.By contrast,the change in the stress state may lead to the transformation of faulting type and potential fault reactivation.Qualitative fault reactivation assessment using characteristic parameters under the current stress environment provides a method to assess the slip tendency of faults.The correlation between in situ stresses and fault properties enhances the ability to predict the fault slip tendency via stress measurements,which can be used to further refine the assessment of the fault reactivation risk.In the future,stress measurements at greater depths and long-term continuous real-time stress monitoring near/on key parts of faults will be essential.In addition,much attention needs to be paid to distinguishing the genetic mechanisms of abnormal stress states and the type and scale of stress variations and exploring the mechanisms of pre-faulting anomaly and fault reactivation.展开更多
In order to explore the effect mechanism of solvent on the synthesis of the metal organic framework materials, the microscopic interaction between solvent and framework and the effects of N,N-dimethyl-formamide(DMF) o...In order to explore the effect mechanism of solvent on the synthesis of the metal organic framework materials, the microscopic interaction between solvent and framework and the effects of N,N-dimethyl-formamide(DMF) or N-methyl- 2-pyrrolidone(NMP) on solvothermal synthesis of [Zn4O(BDC)3]8 were investigated through a combined DFT and experimental study. XRD and SEM showed that the absorbability of NMP in the pore of [Zn4O(BDC)3]8 was weaker than that of DMF. The thermal decomposition temperature of [Zn4O(BDC)3]8 synthesized in DMF was higher than that in NMP according to TG and FT-IR. In addition, the nitrogen sorption isotherms indicated that NMP improved gas sorption property of [Zn4O(BDC)3]8. The COSMO optimized calculations indicated that the total energy of Zn4O(BDC)3 in NMP was higher than that in DMF, and compared with non-solvent system, the charge of zinc atoms decreased and the charge value was the smallest in NMP. Furthermore, the interaction of DMF, NMP or DEF in [Zn4O(BDC)3]8 crystal model was calculated by DFT method. The results suggested that NMP should be easier to be removed from pore of materials than DMF from the point of view of energy state. It can be concluded that NMP was a favorable solvent to synthesize [Zn4O(BDC)3]8 and the microscopic mechanism was that the binding force between Zn4O(BDC)3 and NMP molecule was weaker than DMF.展开更多
The crack-closure effect is a crucial factor that affects the crack growth rate and should be considered in simulation analysis and testing.A mixed-mode I+II loading fatigue crack growth test was performed using EA4T ...The crack-closure effect is a crucial factor that affects the crack growth rate and should be considered in simulation analysis and testing.A mixed-mode I+II loading fatigue crack growth test was performed using EA4T axle steel specimens.The variation of the plastic-induced crack closure(PICC)effect and the roughness-induced crack closure(RICC)effect during crack deflection in the mixed-mode is examined in this study.The results show that the load perpendicular to the crack propagation direction hinders the slip effect caused by the load parallel to the crack propagation direction under mixed-mode loading,and the crack deflection is an intuitive manifestation of the interaction between the PICC and RICC.The proportion of the RA value change on the crack side caused by contact friction was reduced by the interaction between PICC and RICC.The roughness of the crack surface before and after the crack deflection is different,and the spatial torsion crack surface is formed during the crack propagation process.With the increase of the crack length,the roughness of the fracture surface increases.During the crack deflection process,the PICC value fluctuates around 0.2,and the RICC value is increased to 0.15.展开更多
This study was aimed to analyze the effect of procyanidin B2(PC)and tannin acid(TA)on the activities of cholesterol esterase(CEase)and the inhibitory mechanisms of enzymatic activity.The interaction mechanisms were in...This study was aimed to analyze the effect of procyanidin B2(PC)and tannin acid(TA)on the activities of cholesterol esterase(CEase)and the inhibitory mechanisms of enzymatic activity.The interaction mechanisms were investigated by enzymatic kinetics,multi-spectroscopy methods,thermodynamics analysis,molecular docking,and dynamic simulations.PC and TA could bind with CEase and inhibit the activity of enzyme in a mixed-competitive manner and non-competitive manner,which was verified by molecular docking simulations and dynamics simulations.Also,PC and TA showed the synergistic inhibition with orlistat.Fluorescence,UVvis and the thermodynamic analysis revealed that the complexes were formed from CEase and inhibitors by noncovalent interaction.As revealed by the circular dichroism results,both PC and TA decreased enzymatic activities by altering the conformations of CEase.The inhibition of PC and TA on CEase might be one mechanism for its cholesterol-lowering effect.展开更多
Artificial intelligence(AI)can sometimes resolve difficulties that other advanced technologies and humans cannot.In medical diagnostics,AI has the advantage of processing figure recognition,especially for images with ...Artificial intelligence(AI)can sometimes resolve difficulties that other advanced technologies and humans cannot.In medical diagnostics,AI has the advantage of processing figure recognition,especially for images with similar characteristics that are difficult to distinguish with the naked eye.However,the mechanisms of this advanced technique should be well-addressed to elucidate clinical issues.In this letter,regarding an original study presented by Takayama et al,we suggest that the authors should effectively illustrate the mechanism and detailed procedure that artificial intelligence techniques processing the acquired images,including the recognition of non-obvious difference between the normal parts and pathological ones,which were impossible to be distinguished by naked eyes,such as the basic constitutional elements of pixels and grayscale,special molecules or even some metal ions which involved into the diseases occurrence.展开更多
The mechanism of interaction relation between the rare-earth element Ce and elements Pb and Bi in Ag-based filler metal has been studied. The results show that the compounds CePb and CeBi with high melting point can b...The mechanism of interaction relation between the rare-earth element Ce and elements Pb and Bi in Ag-based filler metal has been studied. The results show that the compounds CePb and CeBi with high melting point can be easily produced between these three elements in the filler metal, which greatly limited the formation of the isolated phase Pb or Bi and also eliminated the bad effect of impurity elements Pb and Bi on the spreading property of Ag-based filler metal. The metallurgical and quantum-mechanical bond formation analysis show that a strong chemical affinity was existed between the rare-earth element Ce and impurity elements Pb and Bi, which was proved by the XRD analysis results.展开更多
Objective Shale gas is as an important kind of unconventional natural gas,with a great resource potential,and its exploration and development has attracted much attention around the world.Organic matter(OM)pores are...Objective Shale gas is as an important kind of unconventional natural gas,with a great resource potential,and its exploration and development has attracted much attention around the world.Organic matter(OM)pores are a common constituent in shales and form the dominant pore network of many shale gas systems.展开更多
Research of interaction mechanism between Chlorella vulgaris and two bacterial strains(Z-QD08 and Z-QS01) were conducted under laboratory conditions.Growth rates of bacteria and C.vulgaris were tested under co-cultu...Research of interaction mechanism between Chlorella vulgaris and two bacterial strains(Z-QD08 and Z-QS01) were conducted under laboratory conditions.Growth rates of bacteria and C.vulgaris were tested under co-culture conditions to evaluate the effects of concentrations of C.vulgaris and bacteria on their interactions.To test whether the availability of inorganic nutrients,vitamins and trace metals affects the interactions between C.vulgaris and bacteria,experiments were performed with or without the culture medium filtrate of C.vulgaris or bacteria.The results showed that the growth of C.vulgaris was promoted at low concentrations of bacteria(5×106cells/ml),and expressed a positive correlation with the bacteria density,whereas opposite trend was observed for treatments with high bacteria density(10×106cells/ml and 20×106cells/ml).The growth rate of bacteria decreased with the increasing concentrations of C.vulgaris.The growth of bacteria Z-QD08 was inhibited by C.vulgaris through interference competition,while the mechanism for interaction between bacteria Z-QS01 and C.vulgaris was resource competition.The influence of cell density on the interaction between microalgae and bacteria was also discussed.These experiments confirm some elements of published theory on interactions between heterotrophic bacteria and microalgae and suggest that heterotrophic bacteria play an important role in the development of blooms in natural waters.展开更多
In this paper, the tropical air-sea interaction is discussed by using a simple air-sea coupled model, in which the inertia-gravity waves are filtered off and only the equatorial Rossby waves are reserved in both the a...In this paper, the tropical air-sea interaction is discussed by using a simple air-sea coupled model, in which the inertia-gravity waves are filtered off and only the equatorial Rossby waves are reserved in both the atmosphere and the ocean. There exist two kinds of air-sea interaction waves in the coupled model, that is, the high-frequency fast waves and the low-frequency slow waves. The phase speed of the fast waves is westward and the frequencies are close to those of the equatorial Rossby waves in the atmosphere. The slow waves propagate westward in the part of short wavelengths and eastward in that of long wavelengths. There exist instabilities for both the westward and eastward propagating slow waves. If the fast waves are filtered off, there is little effect on the slow waves which have great influence on the long range process in the tropical air-sea coupled system. According to the tropical air-sea interaction waves we obtain here, a possible explanation to the propagating process of ENSO events is given.展开更多
The interaction mechanism and phase evolution of ammonium polyphosphate(APP)mixed with muscovite(APP/muscovite)were studied by TG,XRD and SEM,respectively,during heating.When the temperature is not higher than 300...The interaction mechanism and phase evolution of ammonium polyphosphate(APP)mixed with muscovite(APP/muscovite)were studied by TG,XRD and SEM,respectively,during heating.When the temperature is not higher than 300 ℃,muscovite has no effect on the thermaldecomposition of APP,and the initialdecomposition temperature of APP/muscovite at 283 ℃ is basically the same as the APP at 295 ℃,and the main thermaldecomposition products are polyphosphoric acid and NH_4H_2PO_4 at 300 ℃.The polyphosphoric acid,the decomposition products of APP,can enable K and Siout of muscovite and interact with muscovite chemically to generate Al_2O_3·2SiO_2,α-SiO_2 and phosphates(AlPO_4 and K_5P_3O_(10))compounds during 400 ℃-800 ℃,which own obvious adhesive phenomenon and porous structure with the apparent porosity of 58.4%.Further reactions between phosphates other than reactions among Al_2O_3·2SiO_2 and α-SiO_2 can generate KAlP_2O_7 at 1 000 ℃ and the density of residualproduct is improved by low melting point phosphate filling pore to form relatively dense structure and decrease the apparent porosity to 44.4%.The flame resistant and self-supported ceramic materials are expected to enhance the fire-retarding synergistic effect between APP and muscovite.展开更多
Human immunodeficiency virus(HIV) and tuberculosis(TB) coinfection is a serious public health problem. HIV and TB promote each other, accelerating development of HIV to acquired immunodeficiency syndrome(AIDS) and hei...Human immunodeficiency virus(HIV) and tuberculosis(TB) coinfection is a serious public health problem. HIV and TB promote each other, accelerating development of HIV to acquired immunodeficiency syndrome(AIDS) and heightening TB mortality. Determining interaction mechanism between HIV and Mycobacterium tuberculosis can lead to development of effective treatments. This study summarizes prevalence status of AIDS and TB coinfection and research advances concerning their interaction mechanism.展开更多
Carboxylmethyl cellulose(CMC) has become a commercial organic binder in agglomeration of iron ore concentrates. The relative molecular mass and degree of substitution(DS) of CMC have a large impact on its binding perf...Carboxylmethyl cellulose(CMC) has become a commercial organic binder in agglomeration of iron ore concentrates. The relative molecular mass and degree of substitution(DS) of CMC have a large impact on its binding performance. The interaction mechanism between CMC and iron ore particles was analyzed through Zeta potential measurements, adsorption measurements and infrared spectra. The results show that the interaction is chemical adsorption-oriented and the CMC's adsorption performance is related to the properties of CMC as well as the type of iron oxides. CMC has a greater affinity to Fe2O3 than Fe3O4, and CMC with higher relative molecular mass shows a higher adsorption isotherm. Pelletization of practical iron ore concentrates added with CMC further illustrates that CMC with higher relative molecular mass or DS exhibits a better binding performance, which is consistent with the results of adsorption tests.展开更多
An investigation is undertaken of an integrated mechanical-electromagnetic coupling system consisting of a rigid vehicle with heave, roll, and pitch motions, four electromagnetic energy harvesters and four tires subje...An investigation is undertaken of an integrated mechanical-electromagnetic coupling system consisting of a rigid vehicle with heave, roll, and pitch motions, four electromagnetic energy harvesters and four tires subject to uneven road excitations in order to improve the passengers' riding comfort and harvest the lost engine energy due to uneven roads. Following the derived mathematical formulations and the proposed solution approaches, the numerical simulations of this interaction system subject to a continuous sinusoidal road excitation and a single ramp impact are completed. The simulation results are presented as the dynamic response curves in the forms of the frequency spectrum and the time history, which reveals the complex interaction characteristics of the system for vibration reductions and energy harvesting performance. It has addressed the coupling effects on the dynamic characteristics of the integrated system caused by: (1) the natural modes and frequencies of the vehicle; (2) the vehicle rolling and pitching motions; (3) different road excitations on four wheels; (4) the time delay of a road ramp to impact both the front and rear wheels, etc., which cannot be tackled by an often used quarter vehicle model. The guidelines for engineering applications are given. The developed coupling model and the revealed concept provide a means with analysis idea to investigate the details of four energy harvester motions for electromagnetic suspension designs in order to replace the current passive vehicle isolators and to harvest the lost engine energy. Potential further research directions are suggested for readers to consider in the future.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.61178021,11474118,and 11204099)the National Basic Research Program of China(Grant No.2012CB921604)
文摘We present a mechanism for double transparency in an optomechanical system. This mechanism is based on the coupling of a moving cavity mirror to a second mechanical oscillator. Due to the purely mechanical coupling and the radiation pressure, three pathways are established for excitations of the probe photons into the cavity photons. Destructive interference occurs at two different frequencies, leading to double transparency to the probe field, It is the coupling strength between the mechanical oscillators that determines the locations of the transparency windows. Moreover, the normal splitting appears for the generated Stokes field and the four-wave mixing process is inhibited on resonance.
基金financially supported by the Project funded by China Postdoctoral Science Foundation (NO.2022M723500)the National Natural Science Foundation of China (NO.52204069)the Sinopec Science and Technology Project of China (NO.P22015)。
文摘High content of asphaltenes and waxes leads to the high pour point and the poor flowability of heavy oil,which is adverse to its efficient development and its transportation in pipe.Understanding the interaction mechanism between asphaltene-wax is crucial to solve these problems,but it is still unclear.In this paper,molecular dynamics simulation was used to investigate the interaction between asphaltenewax and its effects on the crystallization behavior of waxes in heavy oil.Results show that molecules in pure wax are arranged in a paralleled geometry.But wax molecules in heavy oil,which are close to the surface of asphaltene aggregates,are bent and arranged irregularly.When the mass fraction of asphaltenes in asphaltene-wax system(ω_(asp))is 0-25 wt%,the attraction among wax molecules decreases and the bend degree of wax molecules increases with the increase ofω_(asp).Theω_(asp)increases from 0 to 25 wt%,and the attraction between asphaltene-wax is stronger than that among waxes.This causes that the wax precipitation point changes from 353 to 333 K.While theω_(asp)increases to 50 wt%,wax molecules are more dispersed owing to the steric hindrance of asphaltene aggregates,and the interaction among wax molecules transforms from attraction to repulsion.It causes that the ordered crystal structure of waxes can't be formed at normal temperature.Simultaneously,the asphaltene,with the higher molecular weight or the more hetero atoms,has more obvious inhibition to the formation of wax crystals.Besides,resins also have an obvious inhibition on the wax crystal due to the formation of asphalteneresin aggregates with a larger radius.Our results reveal the interaction mechanism between asphaltene-wax,and provide useful guidelines for the development of heavy oil.
基金supported by the National Science Fund for Excellent Youth Scholars of China(52222708)the National Natural Science Foundation of China(51977007)。
文摘The safety and durability of lithium-ion batteries under mechanical constraints depend significantly on electrochemical,thermal,and mechanical fields in applications.Characterizing and quantifying the multi-field coupling behaviors requires interdisciplinary efforts.Here,we design experiments under mechanical constraints and introduce an in-situ analytical framework to clarify the complex interaction mechanisms and coupling degrees among multi-physics fields.The proposed analytical framework integrates the parameterization of equivalent models,in-situ mechanical analysis,and quantitative assessment of coupling behavior.The results indicate that the significant impact of pressure on impedance at low temperatures results from the diffusion-controlled step,enhancing kinetics when external pressure,like 180 to 240 k Pa at 10℃,is applied.The diversity in control steps for the electrochemical reaction accounts for the varying impact of pressure on battery performance across different temperatures.The thermal expansion rate suggests that the swelling force varies by less than 1.60%per unit of elevated temperature during the lithiation process.By introducing a composite metric,we quantify the coupling correlation and intensity between characteristic parameters and physical fields,uncovering the highest coupling degree in electrochemical-thermal fields.These results underscore the potential of analytical approaches in revealing the mechanisms of interaction among multi-fields,with the goal of enhancing battery performance and advancing battery management.
基金University of Science and Technology of China Quality Project History of Medicine(2023YCZX02)Digital Museum Construction Project of Chinese Centre for Disease Control and Prevention(BB2110240080)The National Key R&D project granted by the Ministry of Science and Technology(2018YFA0902400).
文摘The mass communication model and interactive ritual chain theory,which serve as communication paradigms in the new media era,facilitate and enhance the synergy between the fields of social history of medicine and health communication.This study employs a comprehensive framework based on the five elements of the mass communication model:information source,communication subject,communication object,message content,and post-communication feedback.Additionally,it incorporates the interactive ritual chain theory to examine the evolving dynamics and developmental trajectory of research in the social history of medicine during the new media era.Conclusively,this paper acknowledges the existing interaction gaps in the interaction between health communication and the social history of medicine research while outlining the challenges for fostering collaboration and proposing strategic optimizations for effective integration.
文摘The existence of specific biorhythms and the role of geomagnetic and/or solar magnetic activities are well-established by appropriate correlations in chronobiology. From a physical viewpoint, there are two different accesses to biorhythms to set up connections to molecular processes: quantum mechanical perturbation theoretical methods and their resonance dominators to characterize specific interactions between constituents. These methods permit the treatment of molecular processes by circuits with characteristic resonances and “beat-frequencies”, which result from primarily fast physical processes. As examples, the tunneling processes between DNA base pairs (H bonds), the ATP decomposition and the irradiation of tumor cells are accounted for.
文摘The cyclic plastic straining electrode technique has been used to investigate the transient electrochemical behaviour of Fe-26Cr1Mo stainless steel in 1M H2SO4 solution at a passive potential.The influence of plastic strain amplitude and plastic strain rate on the dissolution current response was analysed. The experimental results showed that the transient current was dependent on the competitive process of the surface film rupture and repassivation of the new surface. The high plastic strain amplitude and the high plastic strain rate caused a change of electrochemical activity of specimen surface. In the condition of low strain amplitude and strain rate, the characteristics of current response was mainly relative tp the process of new surface repassivation.The competition kinetics has been analysed through the comparison of plastic strain rate and repassivating rate
基金the National Natural Science Foundation of China(52276189,52106241)Natural Science Foundation of Jiangsu Province(BK20221248)for financial support。
文摘Bimolecular interactions play crucial roles in lignin pyrolysis.The tautomerization of key intermediates has a significant impact on the formation of stable products,whereas bimolecular tautomerization has been rarely clarified.In the present work,the bimolecular tautomerization mechanism induced by both concerted and radical interactions was proposed and carefully confirmed.A characteristicβ-O-4 lignin dimer,2-phenoxy-1-phenylethanol(α-OH-PPE),was used as the model compound to reveal two representative keto-phenol and enol-keto tautomerism mechanisms,based on theoretical calculations combined with pyrolysis experiments.The results indicate that the unimolecular tautomerism as the rate-determining step limits product generation,due to fairly high energy barriers.While the free hydroxy compounds and radicals derived from initial pyrolysis can further initiate bimolecular tautomerism reactions through the one-step concerted hydroxyl-assisted hydrogen transfer(hydroxylAHT)and two-step radical hydrogen abstraction interactions,respectively.By alleviating and even avoiding the large ring tension of tautomerism,the unstable tautomers(2,4-cyclohexadienone and1-hydroxy styrene)can be rapidly tautomerized into stable phenol and acetophenone with the help of intermolecular interaction.Benefitting from the significant advantage of retro-ene fragmentation in breaking theβ-O-4 bond to form tautomers,a large amount of stable phenolic and ketone products can be generated following bimolecular tautomerization in the pyrolysis ofβ-O-4 linked lignin.
基金financially supported by the National Natural Science Foundation of China (No.52204084)the Interdisciplinary Research Project for Young Teachers of USTB (the Fundamental Research Funds for the Central Universities,No.FRF-IDRY-20-013)+3 种基金the Fundamental Research Funds for the Central Universities and the Youth Teacher International Exchange and Growth Program (No.QNXM20220009)the Fundamental Research Funds for the Central Universities (No.FRF-TP-20-041A1)the China Postdoctoral Science Foundation (No.2021M700388)the National Key R&D Program of China (Nos.2022YFC2905600 and 2022YFC3004601)。
文摘Understanding the in situ stress state is crucial in many engineering problems and earth science research.The present article presents new insights into the interaction mechanism between the stress state and faults.In situ stresses can be influenced by various factors,one of the most important being the existence of faults.A fault could significantly affect the value and direction of the stress components.Reorientation and magnitude changes in stresses exist adjacent to faults and stress jumps/discontinuities across the fault.By contrast,the change in the stress state may lead to the transformation of faulting type and potential fault reactivation.Qualitative fault reactivation assessment using characteristic parameters under the current stress environment provides a method to assess the slip tendency of faults.The correlation between in situ stresses and fault properties enhances the ability to predict the fault slip tendency via stress measurements,which can be used to further refine the assessment of the fault reactivation risk.In the future,stress measurements at greater depths and long-term continuous real-time stress monitoring near/on key parts of faults will be essential.In addition,much attention needs to be paid to distinguishing the genetic mechanisms of abnormal stress states and the type and scale of stress variations and exploring the mechanisms of pre-faulting anomaly and fault reactivation.
基金Project(51104185)supported by the National Natural Science Foundation of ChinaProject(2010QZZD003)supported by the Key Project of Central South University of Fundamental Research Funds for the Central Universities of China
文摘In order to explore the effect mechanism of solvent on the synthesis of the metal organic framework materials, the microscopic interaction between solvent and framework and the effects of N,N-dimethyl-formamide(DMF) or N-methyl- 2-pyrrolidone(NMP) on solvothermal synthesis of [Zn4O(BDC)3]8 were investigated through a combined DFT and experimental study. XRD and SEM showed that the absorbability of NMP in the pore of [Zn4O(BDC)3]8 was weaker than that of DMF. The thermal decomposition temperature of [Zn4O(BDC)3]8 synthesized in DMF was higher than that in NMP according to TG and FT-IR. In addition, the nitrogen sorption isotherms indicated that NMP improved gas sorption property of [Zn4O(BDC)3]8. The COSMO optimized calculations indicated that the total energy of Zn4O(BDC)3 in NMP was higher than that in DMF, and compared with non-solvent system, the charge of zinc atoms decreased and the charge value was the smallest in NMP. Furthermore, the interaction of DMF, NMP or DEF in [Zn4O(BDC)3]8 crystal model was calculated by DFT method. The results suggested that NMP should be easier to be removed from pore of materials than DMF from the point of view of energy state. It can be concluded that NMP was a favorable solvent to synthesize [Zn4O(BDC)3]8 and the microscopic mechanism was that the binding force between Zn4O(BDC)3 and NMP molecule was weaker than DMF.
基金Supported by National Natural Science Foundation of China (Grant No.52375159)National Railway Administration of China (Grant No.KF2023-025)the Independent Research Project of the State Key Laboratory of Traction Power (Grant No.2022TPL_T03)。
文摘The crack-closure effect is a crucial factor that affects the crack growth rate and should be considered in simulation analysis and testing.A mixed-mode I+II loading fatigue crack growth test was performed using EA4T axle steel specimens.The variation of the plastic-induced crack closure(PICC)effect and the roughness-induced crack closure(RICC)effect during crack deflection in the mixed-mode is examined in this study.The results show that the load perpendicular to the crack propagation direction hinders the slip effect caused by the load parallel to the crack propagation direction under mixed-mode loading,and the crack deflection is an intuitive manifestation of the interaction between the PICC and RICC.The proportion of the RA value change on the crack side caused by contact friction was reduced by the interaction between PICC and RICC.The roughness of the crack surface before and after the crack deflection is different,and the spatial torsion crack surface is formed during the crack propagation process.With the increase of the crack length,the roughness of the fracture surface increases.During the crack deflection process,the PICC value fluctuates around 0.2,and the RICC value is increased to 0.15.
基金supported by the National Basic Research Program of China(‘973’program,2013CB127106)。
文摘This study was aimed to analyze the effect of procyanidin B2(PC)and tannin acid(TA)on the activities of cholesterol esterase(CEase)and the inhibitory mechanisms of enzymatic activity.The interaction mechanisms were investigated by enzymatic kinetics,multi-spectroscopy methods,thermodynamics analysis,molecular docking,and dynamic simulations.PC and TA could bind with CEase and inhibit the activity of enzyme in a mixed-competitive manner and non-competitive manner,which was verified by molecular docking simulations and dynamics simulations.Also,PC and TA showed the synergistic inhibition with orlistat.Fluorescence,UVvis and the thermodynamic analysis revealed that the complexes were formed from CEase and inhibitors by noncovalent interaction.As revealed by the circular dichroism results,both PC and TA decreased enzymatic activities by altering the conformations of CEase.The inhibition of PC and TA on CEase might be one mechanism for its cholesterol-lowering effect.
基金Supported by the Dean Responsible Project of Gansu Medical College,No.GY-2023FZZ01University Teachers Innovation Fund Project of Gansu Province,No.2023A-182and Key Research Project of Pingliang Science and Technology,No.PL-STK-2021A-004.
文摘Artificial intelligence(AI)can sometimes resolve difficulties that other advanced technologies and humans cannot.In medical diagnostics,AI has the advantage of processing figure recognition,especially for images with similar characteristics that are difficult to distinguish with the naked eye.However,the mechanisms of this advanced technique should be well-addressed to elucidate clinical issues.In this letter,regarding an original study presented by Takayama et al,we suggest that the authors should effectively illustrate the mechanism and detailed procedure that artificial intelligence techniques processing the acquired images,including the recognition of non-obvious difference between the normal parts and pathological ones,which were impossible to be distinguished by naked eyes,such as the basic constitutional elements of pixels and grayscale,special molecules or even some metal ions which involved into the diseases occurrence.
文摘The mechanism of interaction relation between the rare-earth element Ce and elements Pb and Bi in Ag-based filler metal has been studied. The results show that the compounds CePb and CeBi with high melting point can be easily produced between these three elements in the filler metal, which greatly limited the formation of the isolated phase Pb or Bi and also eliminated the bad effect of impurity elements Pb and Bi on the spreading property of Ag-based filler metal. The metallurgical and quantum-mechanical bond formation analysis show that a strong chemical affinity was existed between the rare-earth element Ce and impurity elements Pb and Bi, which was proved by the XRD analysis results.
基金supported by the National Natural Science Foundation of China(grant No.41202103)China Postdoctoral Science Foundation(grant No. 2016M591350)
文摘Objective Shale gas is as an important kind of unconventional natural gas,with a great resource potential,and its exploration and development has attracted much attention around the world.Organic matter(OM)pores are a common constituent in shales and form the dominant pore network of many shale gas systems.
基金Key Projects of Applied Basic and Frontier Technology Research of Tianjin under contract No.13JCZDJC29300scientific research plan program of Tianjin Agricultural University under contract No.2009D005the National Natural Science Foundation of China under contract No.31200400
文摘Research of interaction mechanism between Chlorella vulgaris and two bacterial strains(Z-QD08 and Z-QS01) were conducted under laboratory conditions.Growth rates of bacteria and C.vulgaris were tested under co-culture conditions to evaluate the effects of concentrations of C.vulgaris and bacteria on their interactions.To test whether the availability of inorganic nutrients,vitamins and trace metals affects the interactions between C.vulgaris and bacteria,experiments were performed with or without the culture medium filtrate of C.vulgaris or bacteria.The results showed that the growth of C.vulgaris was promoted at low concentrations of bacteria(5×106cells/ml),and expressed a positive correlation with the bacteria density,whereas opposite trend was observed for treatments with high bacteria density(10×106cells/ml and 20×106cells/ml).The growth rate of bacteria decreased with the increasing concentrations of C.vulgaris.The growth of bacteria Z-QD08 was inhibited by C.vulgaris through interference competition,while the mechanism for interaction between bacteria Z-QS01 and C.vulgaris was resource competition.The influence of cell density on the interaction between microalgae and bacteria was also discussed.These experiments confirm some elements of published theory on interactions between heterotrophic bacteria and microalgae and suggest that heterotrophic bacteria play an important role in the development of blooms in natural waters.
文摘In this paper, the tropical air-sea interaction is discussed by using a simple air-sea coupled model, in which the inertia-gravity waves are filtered off and only the equatorial Rossby waves are reserved in both the atmosphere and the ocean. There exist two kinds of air-sea interaction waves in the coupled model, that is, the high-frequency fast waves and the low-frequency slow waves. The phase speed of the fast waves is westward and the frequencies are close to those of the equatorial Rossby waves in the atmosphere. The slow waves propagate westward in the part of short wavelengths and eastward in that of long wavelengths. There exist instabilities for both the westward and eastward propagating slow waves. If the fast waves are filtered off, there is little effect on the slow waves which have great influence on the long range process in the tropical air-sea coupled system. According to the tropical air-sea interaction waves we obtain here, a possible explanation to the propagating process of ENSO events is given.
基金Funded by the National Natural Science Foundation of China(No.51472188)
文摘The interaction mechanism and phase evolution of ammonium polyphosphate(APP)mixed with muscovite(APP/muscovite)were studied by TG,XRD and SEM,respectively,during heating.When the temperature is not higher than 300 ℃,muscovite has no effect on the thermaldecomposition of APP,and the initialdecomposition temperature of APP/muscovite at 283 ℃ is basically the same as the APP at 295 ℃,and the main thermaldecomposition products are polyphosphoric acid and NH_4H_2PO_4 at 300 ℃.The polyphosphoric acid,the decomposition products of APP,can enable K and Siout of muscovite and interact with muscovite chemically to generate Al_2O_3·2SiO_2,α-SiO_2 and phosphates(AlPO_4 and K_5P_3O_(10))compounds during 400 ℃-800 ℃,which own obvious adhesive phenomenon and porous structure with the apparent porosity of 58.4%.Further reactions between phosphates other than reactions among Al_2O_3·2SiO_2 and α-SiO_2 can generate KAlP_2O_7 at 1 000 ℃ and the density of residualproduct is improved by low melting point phosphate filling pore to form relatively dense structure and decrease the apparent porosity to 44.4%.The flame resistant and self-supported ceramic materials are expected to enhance the fire-retarding synergistic effect between APP and muscovite.
文摘Human immunodeficiency virus(HIV) and tuberculosis(TB) coinfection is a serious public health problem. HIV and TB promote each other, accelerating development of HIV to acquired immunodeficiency syndrome(AIDS) and heightening TB mortality. Determining interaction mechanism between HIV and Mycobacterium tuberculosis can lead to development of effective treatments. This study summarizes prevalence status of AIDS and TB coinfection and research advances concerning their interaction mechanism.
基金Project(2012zzts101)supported by the Fundamental Research Funds for the Central Universities,China
文摘Carboxylmethyl cellulose(CMC) has become a commercial organic binder in agglomeration of iron ore concentrates. The relative molecular mass and degree of substitution(DS) of CMC have a large impact on its binding performance. The interaction mechanism between CMC and iron ore particles was analyzed through Zeta potential measurements, adsorption measurements and infrared spectra. The results show that the interaction is chemical adsorption-oriented and the CMC's adsorption performance is related to the properties of CMC as well as the type of iron oxides. CMC has a greater affinity to Fe2O3 than Fe3O4, and CMC with higher relative molecular mass shows a higher adsorption isotherm. Pelletization of practical iron ore concentrates added with CMC further illustrates that CMC with higher relative molecular mass or DS exhibits a better binding performance, which is consistent with the results of adsorption tests.
基金supporting S. Zhou to visit University of Southampton for one year to engage in this researchHarbin Engineering University for supporting J. T. Xing to visit Harbin Engineering University (Grant HEUCF160104)
文摘An investigation is undertaken of an integrated mechanical-electromagnetic coupling system consisting of a rigid vehicle with heave, roll, and pitch motions, four electromagnetic energy harvesters and four tires subject to uneven road excitations in order to improve the passengers' riding comfort and harvest the lost engine energy due to uneven roads. Following the derived mathematical formulations and the proposed solution approaches, the numerical simulations of this interaction system subject to a continuous sinusoidal road excitation and a single ramp impact are completed. The simulation results are presented as the dynamic response curves in the forms of the frequency spectrum and the time history, which reveals the complex interaction characteristics of the system for vibration reductions and energy harvesting performance. It has addressed the coupling effects on the dynamic characteristics of the integrated system caused by: (1) the natural modes and frequencies of the vehicle; (2) the vehicle rolling and pitching motions; (3) different road excitations on four wheels; (4) the time delay of a road ramp to impact both the front and rear wheels, etc., which cannot be tackled by an often used quarter vehicle model. The guidelines for engineering applications are given. The developed coupling model and the revealed concept provide a means with analysis idea to investigate the details of four energy harvester motions for electromagnetic suspension designs in order to replace the current passive vehicle isolators and to harvest the lost engine energy. Potential further research directions are suggested for readers to consider in the future.