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Analysis on the Effect of Yiqi Huoxue Decoction Combined with Neuromuscular Electrical Stimulation in Improving ICU-Acquired Debility in Mechanically Ventilated Patients
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作者 Fan Jiang 《Journal of Clinical and Nursing Research》 2024年第2期206-211,共6页
Objective:To investigate the effect of Yiqi Huoxue decoction combined with neuromuscular electrical stimulation on improving intensive care unit(ICU)acquired debility in mechanically ventilated patients.Methods:50 pat... Objective:To investigate the effect of Yiqi Huoxue decoction combined with neuromuscular electrical stimulation on improving intensive care unit(ICU)acquired debility in mechanically ventilated patients.Methods:50 patients who were admitted to the ICU and received mechanical ventilation treatment in our hospital from June 2022 to June 2023 and were complicated with ICU-acquired neurasthenia were selected,and randomly grouped using the randomized envelope method into two groups:control group with 25 patients who received neuromuscular electrical stimulation alone;observation group with 25 patients who received the traditional Chinese medicine Yiqi Huoxue decoction.Comparison indexes:treatment efficiency,degree of emotional recovery(APACHEⅡscore),muscle strength status(MRC score),motor status(FAC rating),and self-care ability(BI index score).Results:The treatment efficiency of patients in the observation group patients was higher as compared to those in the control group(P<0.05).There was no significant difference in the comparison of the results of the scores(ratings)of each index between the two groups before treatment(P>0.05).After the treatment,the APACHEⅡscores of patients in the observation group were significantly lower as compared to those in the control group,while the MRC scores,FAC ratings,and BI index scores were higher in the observation group than those of the control group patients(P<0.05).Conclusion:The combined application of Yiqi Huoxue decoction and neuromuscular electrical stimulation in the treatment of patients with ICU-acquired neurasthenia complicated by mechanical ventilation significantly enhanced the clinical efficacy,the patient’s muscle strength,motor status,and ability of self-care.Hence,it has high application value and is worthy to be popularized. 展开更多
关键词 Yiqi huoxue decoction Neuromuscular electrical stimulation mechanical ventilation ICU-acquired neurasthenia
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An Improved Solov2 Based on Attention Mechanism and Weighted Loss Function for Electrical Equipment Instance Segmentation
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作者 Junpeng Wu Zhenpeng Liu +2 位作者 Xingfan Jiang Xinguang Tao Ye Zhang 《Computers, Materials & Continua》 SCIE EI 2024年第1期677-694,共18页
The current existing problem of deep learning framework for the detection and segmentation of electrical equipment is dominantly related to low precision.Because of the reliable,safe and easy-to-operate technology pro... The current existing problem of deep learning framework for the detection and segmentation of electrical equipment is dominantly related to low precision.Because of the reliable,safe and easy-to-operate technology provided by deep learning-based video surveillance for unmanned inspection of electrical equipment,this paper uses the bottleneck attention module(BAM)attention mechanism to improve the Solov2 model and proposes a new electrical equipment segmentation mode.Firstly,the BAM attention mechanism is integrated into the feature extraction network to adaptively learn the correlation between feature channels,thereby improving the expression ability of the feature map;secondly,the weighted sum of CrossEntropy Loss and Dice loss is designed as the mask loss to improve the segmentation accuracy and robustness of the model;finally,the non-maximal suppression(NMS)algorithm to better handle the overlap problem in instance segmentation.Experimental results show that the proposed method achieves an average segmentation accuracy of mAP of 80.4% on three types of electrical equipment datasets,including transformers,insulators and voltage transformers,which improve the detection accuracy by more than 5.7% compared with the original Solov2 model.The segmentation model proposed can provide a focusing technical means for the intelligent management of power systems. 展开更多
关键词 Deep learning electrical equipment attention mechanism weighted loss function
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Electrically controllable spin filtering in zigzag phosphorene nanoribbon based normal–antiferromagnet–normal junctions
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作者 李锐岗 刘军丰 汪军 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期666-670,共5页
We investigated the electric controllable spin-filtering effect in a zigzag phosphorene nanoribbon(ZPNR) based normal–antiferromagnet–normal junction. Two ferromagnets are closely coupled to the edges of the nanorib... We investigated the electric controllable spin-filtering effect in a zigzag phosphorene nanoribbon(ZPNR) based normal–antiferromagnet–normal junction. Two ferromagnets are closely coupled to the edges of the nanoribbon and form the edge-to-edge antiferromagnetism. Under an in-plane electric field, the two degenerate edge bands of the edge-to-edge antiferromagnet split into four spin-polarized sub-bands and a 100% spin-polarized current can be easily induced with the maximal conductance 2e~2/h. The spin polarization changes with the strength of the electric field and the exchange field,and changes sign at opposite electric fields. The spin-polarized current switches from one edge to the other by reversing the direction of the electric field. The edge current can also be controlled spatially by changing the electric potential of the scattering region. The manipulation of edge current is useful in spin-transfer-torque magnetic random-access memory and provides a practical way to develop controllable spintronic devices. 展开更多
关键词 zigzag phosphorene electrically controllable spin filter quantum transport
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Recent Advances in Mechanistic Understanding of Metal-Free Carbon Thermocatalysis and Electrocatalysis with Model Molecules
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作者 Wei Guo Linhui Yu +2 位作者 Ling Tang Yan Wan Yangming Lin 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第7期74-97,共24页
Metal-free carbon,as the most representative heterogeneous metal-free catalysts,have received considerable interests in electro-and thermo-catalytic reac-tions due to their impressive performance and sustainability.Ov... Metal-free carbon,as the most representative heterogeneous metal-free catalysts,have received considerable interests in electro-and thermo-catalytic reac-tions due to their impressive performance and sustainability.Over the past decade,well-designed carbon catalysts with tunable structures and heteroatom groups coupled with various characterization techniques have proposed numerous reaction mechanisms.However,active sites,key intermediate species,precise structure-activity relationships and dynamic evolution processes of carbon catalysts are still rife with controversies due to the monotony and limitation of used experimental methods.In this Review,we sum-marize the extensive efforts on model catalysts since the 2000s,particularly in the past decade,to overcome the influences of material and structure limitations in metal-free carbon catalysis.Using both nanomolecule model and bulk model,the real contribution of each alien species,defect and edge configuration to a series of fundamentally important reactions,such as thermocatalytic reactions,electrocatalytic reactions,were systematically studied.Combined with in situ techniques,isotope labeling and size control,the detailed reaction mechanisms,the precise 2D structure-activity relationships and the rate-determining steps were revealed at a molecular level.Furthermore,the outlook of model carbon catalysis has also been proposed in this work. 展开更多
关键词 Metal-free carbon catalysts Model catalyst electrOCATALYSIS Active site Reaction mechanisms
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An Image Fingerprint and Attention Mechanism Based Load Estimation Algorithm for Electric Power System
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作者 Qing Zhu Linlin Gu Huijie Lin 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第7期577-591,共15页
With the rapid development of electric power systems,load estimation plays an important role in system operation and planning.Usually,load estimation techniques contain traditional,time series,regression analysis-base... With the rapid development of electric power systems,load estimation plays an important role in system operation and planning.Usually,load estimation techniques contain traditional,time series,regression analysis-based,and machine learning-based estimation.Since the machine learning-based method can lead to better performance,in this paper,a deep learning-based load estimation algorithm using image fingerprint and attention mechanism is proposed.First,an image fingerprint construction is proposed for training data.After the data preprocessing,the training data matrix is constructed by the cyclic shift and cubic spline interpolation.Then,the linear mapping and the gray-color transformation method are proposed to form the color image fingerprint.Second,a convolutional neural network(CNN)combined with an attentionmechanism is proposed for training performance improvement.At last,an experiment is carried out to evaluate the estimation performance.Compared with the support vector machine method,CNN method and long short-term memory method,the proposed algorithm has the best load estimation performance. 展开更多
关键词 Load estimation deep learning attention mechanism image fingerprint construction
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Application Strategies of BIM Technology in Highway Electromechanical Engineering
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作者 Li Liu 《Journal of World Architecture》 2024年第2期123-128,共6页
The transportation system is vital for social and economic development.With the rapid economic development,the demand for highways has been increasing.Mechanical and electrical engineering is a crucial part of highway... The transportation system is vital for social and economic development.With the rapid economic development,the demand for highways has been increasing.Mechanical and electrical engineering is a crucial part of highway construction,affecting the expressway’s later use.Applying building information modeling(BIM)technology in highway electromechanical engineering allows for the visibility and simulation of mechanical and electrical engineering construction,providing scientific guidance for construction.In this research,the author analyzes the advantages of BIM technology in highway electromechanical engineering and the basic composition of electromechanical engineering.The research proposes strategies and cases for applying BIM technology in highway electromechanical engineering.The ultimate goal of this research is to improve the construction of highways in terms of electromechanical engineering. 展开更多
关键词 BIM technology HIGHWAY mechanical and electrical engineering
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Construction Safety Management of Mechanical and Electrical Installation Projects
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作者 Honglou Chi 《Journal of Architectural Research and Development》 2024年第2期50-54,共5页
Various industries today rely on the support of electromechanical equipment,expanding its scope of application and leading to an increase in electromechanical installation projects.However,due to the high level of exp... Various industries today rely on the support of electromechanical equipment,expanding its scope of application and leading to an increase in electromechanical installation projects.However,due to the high level of expertise required and the potential risks involved,it is crucial to emphasize safety management during construction.This paper delves into the significance of construction safety management for electromechanical installation projects,identifies common problems encountered during construction,and proposes solutions.This analysis aims to provide relevant personnel with essential guidance and references for managing electromechanical installation projects safely. 展开更多
关键词 Construction safety mechanical and electrical installation Installation engineering Engineering projects Safety management
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Recent advances in cobalt phosphide-based materials for electrocatalytic water splitting:From catalytic mechanism and synthesis method to optimization design
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作者 Rongrong Deng Mengwei Guo +1 位作者 Chaowu Wang Qibo Zhang 《Nano Materials Science》 EI CAS CSCD 2024年第2期139-173,共35页
Electrochemical water splitting has long been considered an effective energy conversion technology for trans-ferring intermittent renewable electricity into hydrogen fuel,and the exploration of cost-effective and high... Electrochemical water splitting has long been considered an effective energy conversion technology for trans-ferring intermittent renewable electricity into hydrogen fuel,and the exploration of cost-effective and high-performance electrocatalysts is crucial in making electrolyzed water technology commercially viable.Cobalt phosphide(Co-P)has emerged as a catalyst of high potential owing to its high catalytic activity and durability in water splitting.This paper systematically reviews the latest advances in the development of Co-P-based materials for use in water splitting.The essential effects of P in enhancing the catalytic performance of the hydrogen evolution reaction and oxygen evolution reaction are first outlined.Then,versatile synthesis techniques for Co-P electrocatalysts are summarized,followed by advanced strategies to enhance the electrocatalytic performance of Co-P materials,including heteroatom doping,composite construction,integration with well-conductive sub-strates,and structure control from the viewpoint of experiment.Along with these optimization strategies,the understanding of the inherent mechanism of enhanced catalytic performance is also discussed.Finally,some existing challenges in the development of highly active and stable Co-P-based materials are clarified,and pro-spective directions for prompting the wide commercialization of water electrolysis technology are proposed. 展开更多
关键词 Co-P electrocatalysts Water splitting Hydrogen production Catalytic mechanism Synthesis technique Optimization design
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Review of Power Supply and Distribution Construction Technology for Highway Electromechanical Engineering
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作者 Li Liu 《Journal of Electronic Research and Application》 2024年第2期27-32,共6页
In recent years,China has made significant progress in the construction of highways,resulting in an improved highway network that has provided robust support for economic and social development.However,the rapid expan... In recent years,China has made significant progress in the construction of highways,resulting in an improved highway network that has provided robust support for economic and social development.However,the rapid expansion of highway construction,power supply,and distribution has led to several challenges in mechanical and electrical engineering technology.Ensuring the safe,stable,and cost-effective operation of the power supply and distribution system to meet the diverse requirements of highway operations has become a pressing issue.This article takes an example of a highway electromechanical engineering power supply and distribution construction project to provide insight into the construction process of highway electromechanical engineering power supply and distribution technology. 展开更多
关键词 HIGHWAY mechanical and electrical engineering Power supply and distribution construction technology Construction process
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A new review of single-ion conducting polymer electrolytes in the light of ion transport mechanisms
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作者 Yuqi Luo Lu Gao Weimin Kang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期543-556,I0012,共15页
With the depletion of fossil fuels and the demand for high-performance energy storage devices,solidstate lithium metal batteries have received widespread attention due to their high energy density and safety advantage... With the depletion of fossil fuels and the demand for high-performance energy storage devices,solidstate lithium metal batteries have received widespread attention due to their high energy density and safety advantages.Among them,the earliest developed organic solid-state polymer electrolyte has a promising future due to its advantages such as good mechanical flexibility,but its poor ion transport performance dramatically limits its performance improvement.Therefore,single-ion conducting polymer electrolytes(SICPEs)with high lithium-ion transport number,capable of improving the concentration polarization and inhibiting the growth of lithium dendrites,have been proposed,which provide a new direction for the further development of high-performance organic polymer electrolytes.In view of this,lithium ions transport mechanisms and design principles in SICPEs are summarized and discussed in this paper.The modification principles currently used can be categorized into the following three types:enhancement of lithium salt anion-polymer interactions,weakening of lithium salt anion-cation interactions,and modulation of lithium ion-polymer interactions.In addition,the advances in single-ion conductors of conventional and novel polymer electrolytes are summarized,and several typical highperformance single-ion conductors are enumerated and analyzed in what way they improve ionic conductivity,lithium ions mobility,and the ability to inhibit lithium dendrites.Finally,the advantages and design methodology of SICPEs are summarized again and the future directions are outlined. 展开更多
关键词 Lithium metal batteries Single-ion conductor Polymer electrolytes Ion transport mechanism Li-ion transport number
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Role of methoxy and C_(α)-based substituents in electrochemical oxidation mechanisms and bond cleavage selectivity of β-O-4 lignin model compounds
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作者 Yang Zhou Qiang Zeng +3 位作者 Hongyan He Kejia Wu Fuqiao Liu Xuehui Li 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第1期114-125,共12页
In order to better understand the specific substituent effects on the electrochemical oxidation process of β-O-4 bond, a series of methoxyphenyl type β-O-4 dimer model compounds with different localized methoxyl gro... In order to better understand the specific substituent effects on the electrochemical oxidation process of β-O-4 bond, a series of methoxyphenyl type β-O-4 dimer model compounds with different localized methoxyl groups, including 2-(2-methoxyphenoxy)-1-phenylethanone, 2-(2-methoxyphenoxy)-1-phenylethanol, 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)ethanone, 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)ethanol, 2-(2,6-dimethoxyphenoxy)-1-(4-methoxyphenyl)ethanone, 2-(2,6-dimethoxyphenoxy)-1-(4-methoxyphenyl)ethanol have been selected and their electrochemical properties have been studied experimentally by cyclic voltammetry, and FT-IR spectroelectrochemistry. Combining with electrolysis products distribution analysis and density functional theory calculations, oxidation mechanisms of all six model dimers have been explored. In particular, a total effect from substituents of both para-methoxy(on the aryl ring closing to Cα) and Cα-OH on the oxidation mechanisms has been clearly observed, showing a significant selectivity on the Cα-Cβbond cleavage induced by electrochemical oxidations. 展开更多
关键词 Lignin model compounds β-O-4 dimers electrochemical oxidation Oxidation mechanisms Substituent effect
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Mechanical Properties and Electronic Structures of M(M=Ti,V,Cr,Mn and Fe)Dopedβ-Si_(3)N_(4) from First-Principle
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作者 龙敏 黄福祥 +4 位作者 XU Liangyu LI Xuemei YANG Zhou LENG Yue MEI Shini 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第3期639-644,共6页
The structures,mechanical properties and electronic structures of M metals(M=Ti,V,Cr,Mn and Fe)dopedβ-Si_(3)N_(4) were investigated by First-principles calculations within CASTEP.The calculated lattice parameters of... The structures,mechanical properties and electronic structures of M metals(M=Ti,V,Cr,Mn and Fe)dopedβ-Si_(3)N_(4) were investigated by First-principles calculations within CASTEP.The calculated lattice parameters ofβ-Si_(3)N_(4) were consistent with previous date.The cohesive energy and formation enthalpy show that initialβ-Si_(3)N_(4) has the highest structural stability.The calculated elastic constant and the Voigt-Reuss-Hill approximation indicate that elastic moduli ofβ-Si_(3)N_(4) are slightly reduced by M doping.Based on Poisson’s and Pugh’s ratio,β-Si_(3)N_(4) is a ductile material and the toughness ofβ-Si_(3)N_(4) increases with M doping,and Fe doping exhibited the best toughness.The results of density of states,charge distributions and overlapping populations indicate thatβ-Si_(3)N_(4) has the strong covalent and ionic bond strength between N and Si. 展开更多
关键词 first-principles β-Si_(3)N_(4) mechanical properties electronic structure
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Electrostatic Attraction and Repulsion Explained and Modelled Mathematically Using Classical Physics—A Detailed Mechanism Based on Particle Wave Functions
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作者 Declan Traill 《Journal of Applied Mathematics and Physics》 2024年第4期1050-1062,共13页
The phenomenon of electrical attraction and repulsion between charged particles is well known, and described mathematically by Coulomb’s Law, yet until now there has been no explanation for why this occurs. There has... The phenomenon of electrical attraction and repulsion between charged particles is well known, and described mathematically by Coulomb’s Law, yet until now there has been no explanation for why this occurs. There has been no mechanistic explanation that reveals what causes the charged particles to accelerate, either towards or away from each other. This paper gives a detailed explanation of the phenomena of electrical attraction and repulsion based on my previous work that determined the exact wave-function solutions for both the Electron and the Positron. It is revealed that the effects are caused by wave interactions between the wave functions that result in Electromagnetic reflections of parts of the particle’s wave functions, causing a change in their momenta. 展开更多
关键词 electrOSTATIC electron POSITRON COULOMB Force ATTRACTION REPULSION Wave Function electric Magnetic Radiation Pressure Shell THEOREM 3D Computer Model Quantum
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Reform of the Comprehensive Practical Course System for Mechanical and Electronic Engineering Majors Under the Background of New Engineering
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作者 Yali Yu Keyi Wang Yong Yang 《Journal of Contemporary Educational Research》 2024年第2期85-90,共6页
Under the background of new engineering,the reform of the comprehensive practical course system for mechanical and electronic engineering majors actively responds to the challenges posed by the new round of technologi... Under the background of new engineering,the reform of the comprehensive practical course system for mechanical and electronic engineering majors actively responds to the challenges posed by the new round of technological revolution and industrial transformation to higher education,cultivating top-notch innovative intellectuals with comprehensive engineering qualities,meeting the requirements of being able to solve complex engineering problems rather than just cognitive capabilities,forming two core courses through reconstructing and reshaping the core courses of the major.The core courses include Drive,Measurement,and Control I and Drive,Measurement,and Control II,which highlight the comprehensive framework of mechanical and electronic engineering professional knowledge,continuing the comprehensive practical course system based on the unity of knowledge and practice,following the trend of new engineering,highlighting the practicality of professional innovation,assisting engineering education reform,and promoting high-quality development of new engineering professionals cultivation. 展开更多
关键词 Comprehensive engineering quality mechanical and electronic Engineering Practical course system New engineering
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SOLIDWORKS Electrical在通过式脚踏封口机自动化改造设计中的应用
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作者 董改花 赵家硕 +1 位作者 王晓兰 郭秀华 《工业控制计算机》 2024年第6期90-92,共3页
小型企业塑封工艺中通过式脚踏封口机应用广泛,但在塑封重型工件时,工人操作非常费力且次品率高,无法保障塑封质量,为此对其进行机构优化与软硬件设计自动化改造。利用SOLIDWORKS Electrical快速建立3D虚拟电气配盘与生成各类BOM清单,... 小型企业塑封工艺中通过式脚踏封口机应用广泛,但在塑封重型工件时,工人操作非常费力且次品率高,无法保障塑封质量,为此对其进行机构优化与软硬件设计自动化改造。利用SOLIDWORKS Electrical快速建立3D虚拟电气配盘与生成各类BOM清单,大大缩短了研发周期,安装人员还可以根据虚拟电气装配路径进行准确安装。最终设计出结构合理,满足生产工艺要求的自动化装置,企业以极少改造成本提质增效,为机电一体化装置自动化设计提供了一个高效开发途径。 展开更多
关键词 脚踏封口机 自动化改造 SOLIDWORKS electrical
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A Review of In‑Situ Techniques for Probing Active Sites and Mechanisms of Electrocatalytic Oxygen Reduction Reactions 被引量:3
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作者 Jinyu Zhao Jie Lian +2 位作者 Zhenxin Zhao Xiaomin Wang Jiujun Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第2期61-113,共53页
Electrocatalytic oxygen reduction reaction(ORR)is one of the most important reactions in electrochemical energy technologies such as fuel cells and metal–O2/air batteries,etc.However,the essential catalysts to overco... Electrocatalytic oxygen reduction reaction(ORR)is one of the most important reactions in electrochemical energy technologies such as fuel cells and metal–O2/air batteries,etc.However,the essential catalysts to overcome its slow reaction kinetic always undergo a complex dynamic evolution in the actual catalytic process,and the concomitant intermediates and catalytic products also occur continuous conversion and reconstruction.This makes them difficult to be accurately captured,making the identification of ORR active sites and the elucidation of ORR mechanisms difficult.Thus,it is necessary to use extensive in-situ characterization techniques to proceed the real-time monitoring of the catalyst structure and the evolution state of intermediates and products during ORR.This work reviews the major advances in the use of various in-situ techniques to characterize the catalytic processes of various catalysts.Specifically,the catalyst structure evolutions revealed directly by in-situ techniques are systematically summarized,such as phase,valence,electronic transfer,coordination,and spin states varies.In-situ revelation of intermediate adsorption/desorption behavior,and the real-time monitoring of the product nucleation,growth,and reconstruction evolution are equally emphasized in the discussion.Other interference factors,as well as in-situ signal assignment with the aid of theoretical calculations,are also covered.Finally,some major challenges and prospects of in-situ techniques for future catalysts research in the ORR process are proposed. 展开更多
关键词 Oxygen reduction reaction Catalysts In-situ techniques Active sites mechanISMS
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Harvesting Environment Mechanical Energy by Direct Current Triboelectric Nanogenerators 被引量:2
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作者 Chuncai Shan Kaixian Li +1 位作者 Yuntao Cheng Chenguo Hu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第8期381-404,共24页
As hundreds of millions of distributed devices appear in every corner of our lives for information collection and transmission in big data era,the biggest challenge is the energy supply for these devices and the signa... As hundreds of millions of distributed devices appear in every corner of our lives for information collection and transmission in big data era,the biggest challenge is the energy supply for these devices and the signal transmission of sensors.Triboelectric nanogenerator(TENG)as a new energy technology meets the increasing demand of today’s distributed energy supply due to its ability to convert the ambient mechanical energy into electric energy.Meanwhile,TENG can also be used as a sensing system.Direct current triboelectric nanogenerator(DC-TENG)can directly supply power to electronic devices without additional rectification.It has been one of the most important developments of TENG in recent years.Herein,we review recent progress in the novel structure designs,working mechanism and corresponding method to improve the output performance for DC-TENGs from the aspect of mechanical rectifier,tribovoltaic effect,phase control,mechanical delay switch and air-discharge.The basic theory of each mode,key merits and potential development are discussed in detail.At last,we provide a guideline for future challenges of DC-TENGs,and a strategy for improving the output performance for commercial applications. 展开更多
关键词 Triboelectric nanogenerators Direct current Working mechanism
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Radical and(photo)electron transfer induced mechanisms for lignin photo-and electro-catalytic depolymerization 被引量:1
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作者 Kejia Wu Minglong Cao +1 位作者 Qiang Zeng Xuehui Li 《Green Energy & Environment》 SCIE EI CSCD 2023年第2期383-405,共23页
As one of the three major components of woody biomass,lignin is a kind of natural organic polymer and the only abundant natural renewable resource with aromatic nucleus.Chemical catalysis induced depolymerization is a... As one of the three major components of woody biomass,lignin is a kind of natural organic polymer and the only abundant natural renewable resource with aromatic nucleus.Chemical catalysis induced depolymerization is an important and effective approach for lignin utilization.In particular,photocatalysis and electrocatalysis show great potential in accurately activating C-O/C-C bonds,which is a critical point of selective cleavage of lignin.In this contribution,we focus on radical and(photo)electron transfer induced reaction mechanisms of the photo(electro)catalytic depolymerization of lignin.Primarily,the general situation of Carbon-centered radicals and active oxygen species mediated lignin conversion has been discussed.Then the mechanisms for(photo)electron transfer mediated lignin depolymerization have been summarized.At the end of this review,the challenges and opportunities of photo(electro)catalysis in the applications of lignin valorization have been forecasted. 展开更多
关键词 LIGNIN Photocatalysis electrOCATALYSIS DEPOLYMERIZATION Reaction mechanism
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Single-atom electrocatalysts for lithium-sulfur chemistry:Design principle,mechanism,and outlook 被引量:1
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作者 Yingze Song Luwei Zou +2 位作者 Chaohui Wei Yu Zhou Yue Hu 《Carbon Energy》 SCIE CSCD 2023年第4期13-41,共29页
Lithium-sulfur batteries(LSBs)have been regarded as one of the promising candidates for the next-generation“lithium-ion battery beyond”owing to their high energy density and due to the low cost of sulfur.However,the... Lithium-sulfur batteries(LSBs)have been regarded as one of the promising candidates for the next-generation“lithium-ion battery beyond”owing to their high energy density and due to the low cost of sulfur.However,the main obstacles encountered in the commercial implementation of LSBs are the notorious shuttle effect,retarded sulfur redox kinetics,and uncontrolled dendrite growth.Accordingly,single-atom catalysts(SACs),which have ultrahigh catalytic efficiency,tunable coordination configuration,and light weight,have shown huge potential in the field of LSBs to date.This review summarizes the recent research progress of SACs applied as multifunctional components in LSBs.The design principles and typical synthetic strategies of SACs toward effective Li–S chemistry as well as the working mechanism promoting sulfur conversion reactions,inhibiting the lithium polysulfide shuttle effect,and regulating Li+nucleation are comprehensively illustrated.Potential future directions in terms of research on SACs for the realization of commercially viable LSBs are also outlined. 展开更多
关键词 design principle lithium-sulfur chemistry mechanISM single-atom electrocatalyst
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Dynamic mechanical characteristics of NdFeB in electromagnetic brake 被引量:1
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作者 Lei Li Guo-lai Yang Li-qun Wang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2023年第1期111-125,共15页
With the continuous development of artillery,the disadvantages of hydraulic recoil brakes gradually appear.At the same time,the appearance of high-performance Nd Fe B permanent magnet makes it possible to apply electr... With the continuous development of artillery,the disadvantages of hydraulic recoil brakes gradually appear.At the same time,the appearance of high-performance Nd Fe B permanent magnet makes it possible to apply electromagnetic braking technology to recoil mechanism.In this paper,prototype tests of a certain artillery were carried out to verify the feasibility of the electromagnetic brake(EMB)and obtain the electromagnetic braking force.Due to the brittleness of Nd Fe B,in order to eliminate the worry about the safety of EMB,SHPB experiments of Nd Fe B were carried out.Then,based on the assumption of uniform crack distribution,the law of crack propagation and damage accumulation was described theoretically,and the damage constitutive model suitable for brittle materials was proposed by combining the Zhu-Wang-Tang(ZWT)equation.Finally,the numerical simulation model of the artillery prototype was established and through calculation,the dynamic mechanical characteristics of Nd Fe B in the prototype were analyzed.The calculation results show that the strength of Nd Fe B can meet the requirements of the use in the working process.From the perspective of damage factor,the damage value of the permanent magnet on the far right is larger,and the damage value of the inner ring gradually decreases to the outer ring. 展开更多
关键词 electromagnetic brake Sintered NdFeB Damage constitutive Dynamic mechanical characteristics
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