Ultrasonic-assisted extraction(UAE)combined with medium pressure liquid chromatography(MPLC)was designed for carbazole separation from anthracene slag(AS).The effects of liquid/solid ratio,temperature,and extraction t...Ultrasonic-assisted extraction(UAE)combined with medium pressure liquid chromatography(MPLC)was designed for carbazole separation from anthracene slag(AS).The effects of liquid/solid ratio,temperature,and extraction times on carbazole separation were investigated.When using CC14 and ethyl acetate as extraction solvents and combining with MPLC,carbazole recovery and purity are 75.1%and 95.4%,respectively.The mechanism for carbazole separation were presumed by examining intermolecular interactions such as N-H…π,π-π,and C-Cl…πinteractions.These results demonstrate that UAE/MPLC has a considerable potential as a green and promising strategy for separating and purifying carbazole and other chemicals from AS.展开更多
Synergistic extraction of cerium（IV） from sulfuric acid medium using mixture of 2-ethylhexyl phosphonic acid mono 2-ethylhexyl ester（HEH/EHP, HL） and Di-（2-ethyl hexyl） phosphoric acid（HDEHP, HA） as extractant...Synergistic extraction of cerium（IV） from sulfuric acid medium using mixture of 2-ethylhexyl phosphonic acid mono 2-ethylhexyl ester（HEH/EHP, HL） and Di-（2-ethyl hexyl） phosphoric acid（HDEHP, HA） as extractant was investigated.The results indicated that the maximum synergistic enhancement coefficients were obtained at the mole fraction of HEH/EHP=0.6, and cerium（IV） was extracted into organic phase in the form of Ce（SO4）0.5HL2A2.A cation exchange mechanism was proposed for the synergistic extraction of Ce（IV）.The equilibrium constants and thermodynamic functions such as △G, △H, and △S were determined in the extraction of Ce（IV） from sulfuric medium using mixture of HEH/EHP and HDEHP.展开更多
项目供热面积约1.14×10^(5)m^(2),总热负荷7000 k W,采用中深层地热供热,平均热负荷为4859.09 kW,项目年耗热量为62959.68 GJ。热源为1口水热型地热井,按照“一采一灌、同层回灌、取热不耗水”的模式进行建设,配套回灌井1口。利用...项目供热面积约1.14×10^(5)m^(2),总热负荷7000 k W,采用中深层地热供热,平均热负荷为4859.09 kW,项目年耗热量为62959.68 GJ。热源为1口水热型地热井,按照“一采一灌、同层回灌、取热不耗水”的模式进行建设,配套回灌井1口。利用中深层地热水作为供热热源,冬季提供45℃/40℃采暖循环水,采用“板换直供+热泵机组调峰”的方式为项目供热。按照30年运行期测算,中深层地热方案相比于天然气锅炉方案可节省费用1.127738×10^(8)元。展开更多
基金Supported by the Key Project of Joint Fund for the research on Coal-Based Low Carbon Technology from National Natural Science Foundation of China and the Government of Shanxi(U1610223)Coal-based Key Scientific and Technological Projects of Shanxi Province(MJH2014-15)the National Key Research and Development Program of China(2018YFB0604602).
文摘Ultrasonic-assisted extraction(UAE)combined with medium pressure liquid chromatography(MPLC)was designed for carbazole separation from anthracene slag(AS).The effects of liquid/solid ratio,temperature,and extraction times on carbazole separation were investigated.When using CC14 and ethyl acetate as extraction solvents and combining with MPLC,carbazole recovery and purity are 75.1%and 95.4%,respectively.The mechanism for carbazole separation were presumed by examining intermolecular interactions such as N-H…π,π-π,and C-Cl…πinteractions.These results demonstrate that UAE/MPLC has a considerable potential as a green and promising strategy for separating and purifying carbazole and other chemicals from AS.
基金support by the High Technology Research and Development Programme (2006AA06Z123) National Key Technology Research and Development Programme (2006BAC02A06) of China
文摘Synergistic extraction of cerium（IV） from sulfuric acid medium using mixture of 2-ethylhexyl phosphonic acid mono 2-ethylhexyl ester（HEH/EHP, HL） and Di-（2-ethyl hexyl） phosphoric acid（HDEHP, HA） as extractant was investigated.The results indicated that the maximum synergistic enhancement coefficients were obtained at the mole fraction of HEH/EHP=0.6, and cerium（IV） was extracted into organic phase in the form of Ce（SO4）0.5HL2A2.A cation exchange mechanism was proposed for the synergistic extraction of Ce（IV）.The equilibrium constants and thermodynamic functions such as △G, △H, and △S were determined in the extraction of Ce（IV） from sulfuric medium using mixture of HEH/EHP and HDEHP.
文摘项目供热面积约1.14×10^(5)m^(2),总热负荷7000 k W,采用中深层地热供热,平均热负荷为4859.09 kW,项目年耗热量为62959.68 GJ。热源为1口水热型地热井,按照“一采一灌、同层回灌、取热不耗水”的模式进行建设,配套回灌井1口。利用中深层地热水作为供热热源,冬季提供45℃/40℃采暖循环水,采用“板换直供+热泵机组调峰”的方式为项目供热。按照30年运行期测算,中深层地热方案相比于天然气锅炉方案可节省费用1.127738×10^(8)元。
