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Dynamic response mechanism and precursor characteristics of gneiss rockburst under different initial burial depths
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作者 LIU Dongqiao SUN Jie +4 位作者 MENG Wen HE Manchao ZHANG Chongyuan LI Ran CAO Binghao 《Journal of Mountain Science》 SCIE CSCD 2024年第3期1004-1018,共15页
To investigate the influence mechanism of geostress on rockburst characteristics,three groups of gneiss rockburst experiments were conducted under different initial geostress conditions.A high-speed photography system... To investigate the influence mechanism of geostress on rockburst characteristics,three groups of gneiss rockburst experiments were conducted under different initial geostress conditions.A high-speed photography system and acoustic emission(AE)monitoring system were used to monitor the entire rockburst process in real time.The experimental results show that when the initial burial depth increases from 928 m to 1320 m,the proportion of large fracture scale in rockburst increases by 154.54%,and the AE energy increases by 565.63%,reflecting that the degree and severity of rockburst increase with the increase of burial depth.And then,two mechanisms are proposed to explain this effect,including(i)the increase of initial geostress improves the energy storage capacity of gneiss,and then,the excess energy which can be converted into kinetic energy of debris ejection increases,consequently,a more pronounced violent ejection phenomenon is observed at rockburst;(ii)the increase of initial geostress causes more sufficient plate cracks of gneiss after unloading ofσh,which provides a basis for more severe ejection of rockburst.What’s more,a precursor with clear physical meaning for rockburst is proposed under the framework of dynamic response process of crack evolution.Finally,potential value in long term rockburst warning of the precursor obtained in this study is shown via the comparison of conventional precursor. 展开更多
关键词 Traffic Engineering Gneiss Rockburst Crack propagation Excess energy precursor characteristic
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Investigation of granite failure precursor under axial load using modified LSTM framework
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作者 WANG Ya-lei XU Jin-ming 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第8期2930-2943,共14页
Granite is usually composed of quartz,biotite,feldspar,and cracks,and the variation characteristics of these components could reflect the deformation and failure process of rock well.Taking granite as an example,the v... Granite is usually composed of quartz,biotite,feldspar,and cracks,and the variation characteristics of these components could reflect the deformation and failure process of rock well.Taking granite as an example,the video camera was used to record the deformation and failure process of rock.The distribution of meso-components in video images was then identified.The meso-components of rock failure precursors were also discussed.Moreover,a modified LSTM(long short-term memory method)based on SSA(sparrow search algorithm)was proposed to estimate the change of meso-components of rock failure precursor.It shows that the initiation and expansion of cracks are mainly caused by feldspar and quartz fracture,and when the quartz and feldspar exit the stress framework,rock failure occurs;the second large increase of crack area and the second large decrease of quartz or feldspar area may be used as a precursor of rock failure;the precursor time of rock failure based on meso-scopic components is about 4 s earlier than that observed by the naked eye;the modified LSTM network has the strongest estimation ability for quartz area change,followed by feldspar and biotite,and has the worst estimation ability for cracks;when using the modified LSTM network to predict the precursors of rock instability and failure,quartz and feldspar could be given priority.The results presented herein may provide reference in the investigation of rock failure mechanism. 展开更多
关键词 GRANITE failure precursor axial load modified long short-term memory method
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Stabilizing perovskite precursors with the reductive natural amino acid for printable mesoscopic perovskite solar cells
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作者 Wenjing Hu Jian Yang +9 位作者 Chuang Yang Xufeng Xiao Chaoyang Wang Zhaozhen Cui Qiaojiao Gao Jianhang Qi Minghao Xia Yaqiong Su Anyi Mei Hongwei Han 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期32-39,I0003,共9页
Solution processability significantly advances the development of highly-efficient perovskite solar cells.However,the precursor solution tends to undergo irreversible degradation reactions,impairing the device perform... Solution processability significantly advances the development of highly-efficient perovskite solar cells.However,the precursor solution tends to undergo irreversible degradation reactions,impairing the device performance and reproducibility.Here,we utilize a reductive natural amino acid,Nacetylcysteine(NALC),to stabilize the precursor solution for printable carbon-based hole-conductorfree mesoscopic perovskite solar cells.We find that I_(2) can be generated in the aged solution containing methylammonium iodide(MI) in an inert atmosphere and speed up the MA-FA^(+)(formamidinium) reaction which produces large-size cations and hinders the formation of perovskite phase.NALC effectively stabilizes the precursor via its sulfhydryl group which reduces I_(2) back to I^(-)and provides H^(+).The NALC-stabilized precursor which is aged for 1440 h leads to devices with a power conversion efficiency equivalent to 98% of that for devices prepared with the fresh precursor.Furthermore,NALC improves the device power conversion efficiency from 16.16% to 18.41% along with enhanced stability under atmospheric conditions by modifying grain boundaries in perovskite films and reducing associated defects. 展开更多
关键词 Perovskite solar cells Perovskite precursor Degradation STABILIZATION Reductive natural amino acid
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Precursor engineering enables high-performance all-inorganic CsPbIBr_(2) perovskite solar cells with a record efficiency approaching 13%
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作者 Qingyan Chang Yidan An +8 位作者 Huaiman Cao Yuzhen Pan Liangyu Zhao Yulong Chen Yi We Sai-Wing Tsang Hin-Lap Yip Licheng Sun Ze Yu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期16-22,I0003,共8页
All-inorganic CsPbIBr_(2) perovskite has attracted widespread attention in photovoltaic and other optoelectronic devices because of its superior thermal stability.However,the deposition of high-quality solutionprocess... All-inorganic CsPbIBr_(2) perovskite has attracted widespread attention in photovoltaic and other optoelectronic devices because of its superior thermal stability.However,the deposition of high-quality solutionprocessed CsPbIBr_(2) perovskite films with large thicknesses remains challenging.Here,we develop a triple-component precursor(TCP) by employing lead bromide,lead iodide,and cesium bromide,to replace the most commonly used double-component precursor(DCP) consisting of lead bromide and cesium iodide.Remarkably,the TCP system significantly increases the solution concentration to 1.3 M,leading to a larger film thickness(~390 nm) and enhanced light absorption.The resultant CsPbIBr_(2) films were evaluated in planar n-i-p structured solar cells,which exhibit a considerably higher optimal photocurrent density of 11.50 mA cm^(-2) in comparison to that of DCP-based devices(10.69 mA cm^(-2)).By adopting an organic surface passivator,the maximum device efficiency using TCP is further boosted to a record efficiency of 12.8% for CsPbIBr_(2) perovskite solar cells. 展开更多
关键词 All-inorganic perovskite solar cells CsPbIBr_(2) precursor engineering Solubility High performance
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Disinfection Byproducts and Their Precursors in Drinking Water Sources:Origins,Influencing Factors,and Environmental Insights
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作者 Rong Xiao Yang Deng +1 位作者 Zuxin Xu Wenhai Chu 《Engineering》 SCIE EI CAS CSCD 2024年第5期36-50,共15页
Tracing the contamination origins in water sources and identifying the impacts of natural and human processes are essential for ecological safety and public health.However,current analysis approaches are not ideal,as ... Tracing the contamination origins in water sources and identifying the impacts of natural and human processes are essential for ecological safety and public health.However,current analysis approaches are not ideal,as they tend to be laborious,time-consuming,or technically difficult.Disinfection byproducts(DBPs)are a family of well-known secondary pollutants formed by the reactions of chemical disinfectants with DBP precursors during water disinfection treatment.Since DBP precursors have various origins(e.g.,natural,domestic,industrial,and agricultural sources),and since the formation of DBPs from different precursors in the presence of specific disinfectants is distinctive,we argue that DBPs and DBP precursors can serve as alternative indicators to assess the contamination in water sources and identify pollution origins.After providing a retrospective of the origins of DBPs and DBP precursors,as well as the specific formation patterns of DBPs from different precursors,this article presents an overview of the impacts of various natural and anthropogenic factors on DBPs and DBP precursors in drinking water sources.In practice,the DBPs(i.e.,their concentration and speciation)originally present in source water and the DBP precursors determined using DBP formation potential tests—in which water samples are dosed with a stoichiometric excess of specific disinfectants in order to maximize DBP formation under certain reaction conditions—can be considered as alternative metrics.When jointly used with other water quality parameters(e.g.,dissolved organic carbon,dissolved organic nitrogen,fluorescence,and molecular weight distribution)and specific contaminants of emerging concern(e.g.,certain pharmaceuticals and personal care products),DBPs and DBP precursors in drinking water sources can provide a more comprehensive picture of water pollution for better managing water resources and ensuring human health. 展开更多
关键词 Disinfection byproducts Disinfection byproduct precursors Drinking water sources Contamination indicator Natural factors Human factors
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Numerical Simulation of the Mechanical Stirring Process in a Tannin-Based Foaming Precursor Resin
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作者 Lan Huang Wenbin Yuan +2 位作者 Hisham Essawy Xiaojian Zhou Xinyi Chen 《Fluid Dynamics & Materials Processing》 EI 2024年第10期2219-2234,共16页
Tannin foam is a new functional material.It can be widely applied to the automobile industry,construction industry,and packaging industry due to its wide range of raw materials,renewable,easily degraded,low cost and a... Tannin foam is a new functional material.It can be widely applied to the automobile industry,construction industry,and packaging industry due to its wide range of raw materials,renewable,easily degraded,low cost and almost no pollution.Preparing tannin foam is a very complex process that includes high temperature,two phases,mechanical agitation,and phase change.To investigate the influence of the stirring velocity and paddle shape,simulation was calculated by making use of the volume of fluid(VOF)method and multiple reference frame(MRF)method in a three-dimensional flow field of tannin-based foaming precursor resin.The gas holdup and velocity magnitude were analysed with various conditions of mechanical velocities and paddle shape in the stirring flow field.The result shows the higher the velocity,the greater the disturbance and paddle shape between the eggbeater and the Rushton turbine,obviously the paddle shape of the eggbeater with a wider range of agitation,which can entrap more air into the tannin-based foaming precursor resin in a short time.Especially when the speed is 1500 rpm,the flow field of the Rushton turbine comes out of a ditch,which decreases the efficiency of mass transfer;there is less air to mix into the tannin-based foaming precursor resin,which causes unevenness.At the same time,the eggbeater shows the marvelous capability of hybrid as it has two vortexes and multiple cycles that make a difference from the Rushton turbine,which has only one vortex and two upper and lower loops;the structure makes the flow field more stable allowed evenness of flow field tannin-based foaming precursor resin.The results reveal that it is beneficial for tannin-based foaming precursor resin to use an eggbeater with a speed of 1500 rpm to reduce the consumption of resources while obtaining a uniform flow field. 展开更多
关键词 Tannin-based foaming precursor resin mechanical agitation numerical simulation volume of fluid(VOF) multiple reference frame(MRF)
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Highly Defective Dark TiO_(2) Modified with Pt: Effects of Precursor Nature and Preparation Method on Photocatalytic Properties
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作者 E.D.Fakhrutdinova O.A.Reutova +6 位作者 T.A.Bugrova I.Yu.Ovsyuk L.S.Kibis O.A.Stonkus D.B.Vasilchenko O.V.Vodyankina V.A.Svetlychnyi 《Transactions of Tianjin University》 EI CAS 2024年第2期198-209,共12页
The study focused on the modification with platinum of dark defective titania obtained via pulsed laser ablation. Both the method of Pt introduction and the nature of the Pt precursor were varied. All samples exhibite... The study focused on the modification with platinum of dark defective titania obtained via pulsed laser ablation. Both the method of Pt introduction and the nature of the Pt precursor were varied. All samples exhibited similar phase compositions, specific surface areas, and Pt contents. High-resolution transmission electron microscopy coupled with pulsed CO adsorption revealed increased dispersity when photoreduction and the hydroxonitrate complex (Me _(4) N) _(2) [Pt _(2) (OH) _(2) (NO _(3) ) _(8) ] were used. The sample featured a high content of single-atom species and subnano-sized Pt clusters. The X-ray photoelectron spectroscopy results showed that the photoreduction method facilitated the appearance of a larger number of Pt ^(2+) states, which appeared owing to the strong metal-support interaction (SMSI) eff ect of the transfer of electron density from the electron-saturated defects on the TiO _(2) surface to Pt ^(4+) . In the hydrogen evolution reaction, samples with a significant fraction of the Pt ^(2+) ionic component, capable of generating short-lived Pt^(0) single-atom sites under irradiation due to the SMSI eff ect, exhibited the highest photocatalytic activity. The 0.5Pt(C)/TiO_(2) -Ph sample exhibited the highest hydrogen yield with a quantum efficiency of 0.53, retaining its activity even after 8 h of operation. 展开更多
关键词 Dark(black)TiO_(2) Pulsed laser ablation Platinum reduction method precursor type PHOTOCATALYSIS Hydrogen evolution reaction
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Effects of post-mortem aging process on characteristic water-soluble taste-active precursors in yellow-feathered broilers 被引量:4
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作者 Na Xu Xianming Zeng +4 位作者 Lingyun Li Xinyue Zhang Peng Wang Minyi Han Xinglian Xu 《Food Science and Human Wellness》 SCIE CSCD 2023年第1期242-253,共12页
Chilled chicken has become the mainstream of chicken consumption.In order to explore the effect of post-mortem aging on water-soluble flavor precursors of chicken,pH,adenosine triphosphate(ATP)degradation,flavor nucle... Chilled chicken has become the mainstream of chicken consumption.In order to explore the effect of post-mortem aging on water-soluble flavor precursors of chicken,pH,adenosine triphosphate(ATP)degradation,flavor nucleosides,free amino acids and water-soluble low molecular weight peptides were determined using Qingyuan partridge yellow-feathered broilers as material during 0-4℃ post-mortem aging in 48 h.The results showed that the pH value fell to the limit pH 5.64(4 h)in chicken breast and 6.21(3 h)in thigh.Regardless of chicken breast or thigh,ATP dropped rapidly within 3 h.It was found that the K-value in chicken thigh was the lowest at 2 h indicating the freshness was the best.Considering the equivalent umami concentration(EUC),the value at 3 h and 4 h was relatively high,but the corresponding electronic tongue umami value was not high,which further showed that the water-soluble low molecular taste peptide played an important role on the post-mortem aging process.Combined with cluster analysis and partial least squares discriminant analysis(PLS-DA),it was preliminarily inferred that the optimal time for chilled chicken during 0-4℃ post-mortem aging was 2 h,which could provide a theoretical basis for the further processing of fresh chicken. 展开更多
关键词 CHICKEN POST-MORTEM Flavor precursors Low molecular weight peptides(LMWPs)
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Ionospheric precursors of strong earthquakes observed using six GNSS stations data during continuous five years(2011-2015) 被引量:1
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作者 H.E.Eshkuvatov B.J.Ahmedov +3 位作者 Y.A.Tillayev M.Arslan Tariq M.Ali Shah Libo Liu 《Geodesy and Geodynamics》 CSCD 2023年第1期65-79,共15页
This study reports the morphological characteristics of anomalous variations in Global Navigation Satellite System Total Electron Content(GNSS-TEC) prior to the strong local earthquakes(EQ) that occurred during the pe... This study reports the morphological characteristics of anomalous variations in Global Navigation Satellite System Total Electron Content(GNSS-TEC) prior to the strong local earthquakes(EQ) that occurred during the period of 2011-2015.We have analyzed 20 earthquakes of magnitude M> 5.6.A statistical technique is implemented on the data of six GNSS stations located in Tashkent,Kitab,and Maidanak in Uzbekistan,and Islamabad,Multan,Quetta in Pakistan.The results show continuous anomalous variations in TEC during 24 h befo re the occupancy of local earthquakes.It is shown that the precursors before the occurrence of strong earthquakes,in particular of magnitude 5.7,7.7,7.5,7.8 and 7.3 are detected near Eastern Uzbekistan(26 May 2013),Southwestern Pakistan(24 September 2013),Hindukush region of Afghanistan(26 October 2015),and Central Nepal(25 April 2015) and(12 May 2015),respectively.The ionospheric anomalies appearing before the strong earthquakes at six GNSS stations are registered in 14cases(70%) out of 20 selected EQs.It is depicted that anomalies referred to as ionospheric precursors appeared about 1-7 days prior to the occurrence of strong earthquakes. 展开更多
关键词 GNSS TEC EARTHQUAKES Ionospheric precursors
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Uniform deposition of ultra-thin TiO_(2) film on mica substrate by atmospheric pressure chemical vapor deposition: Effect of precursor concentration 被引量:2
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作者 Ming Liu Ying Li +4 位作者 Rui Wang Guoqiang Shao Pengpeng Lv Jun Li Qingshan Zhu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第8期99-107,共9页
The performance of pearlescent pigment significantly affected by the grain size and the roughness of deposited film. The effect of TiCl_(4) concentration on the initial deposition of TiO_(2) on mica by atmospheric pre... The performance of pearlescent pigment significantly affected by the grain size and the roughness of deposited film. The effect of TiCl_(4) concentration on the initial deposition of TiO_(2) on mica by atmospheric pressure chemical vapor deposition(APCVD) was investigated. The precursor concentration significantly affected the deposition and morphology of TiO_(2) grains assembling the film. The deposition time for fully covering the surface of mica decreased from 120 to 10 s as the TiCl_(4) concentration increased from 0.38%to 2.44%. The grain size increased with the TiCl_(4) concentration. The AFM and TEM analysis demonstrated that the aggregation of TiO_(2) clusters at the initial stage finally result to the agglomeration of fine TiO_(2) grains at high TiCl_(4) concentrations. Following the results, it was suggested that the nucleation density and size was easy to be adjusted when the TiCl_(4) concentration is below 0.90%. 展开更多
关键词 Chemical vapor deposition TiO_(2)thin film Nucleation reaction precursor concentration Pearlescent pigment
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In situ formed ultrafine metallic Ni from nickel(Ⅱ) acetylacetonate precursor to realize an exceptional hydrogen storage performance of MgH_(2)-Ni-EG nanocomposite 被引量:1
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作者 Shaoyang Shen Liuzhang Ouyang +3 位作者 Jiangwen Liu Hui Wang Xu-Sheng Yang Min Zhu 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第9期3174-3185,共12页
It has been well known that doping nano-scale catalysts can significantly improve both the kinetics and reversible hydrogen storage capacity of MgH_(2) . However, so far it is still a challenge to directly synthesize ... It has been well known that doping nano-scale catalysts can significantly improve both the kinetics and reversible hydrogen storage capacity of MgH_(2) . However, so far it is still a challenge to directly synthesize ultrafine catalysts(e.g., < 5 nm), mainly because of the complicated chemical reaction processes. Here, a facile one-step high-energy ball milling process is developed to in situ form ultrafine Ni nanoparticles from the nickel acetylacetonate precursor in the MgH_(2) matrix. With the combined action of ultrafine metallic Ni and expanded graphite(EG), the formed MgH_(2)-Ni-EG nanocomposite with the optimized doping amounts of Ni and EG can still release 7.03 wt.% H_(2) within 8.5 min at 300 ℃ after 10 cycles. At a temperature close to room temperature(50 ℃), it can also absorb 2.42 wt.% H_(2) within 1 h. It can be confirmed from the microstructural characterization analysis that the in situ formed ultrafine metallic Ni is transformed into Mg_(2)Ni/Mg_(2)NiH_4 in the subsequent hydrogen absorption and desorption cycles. It is calculated that the dehydrogenation activation energy of the MgH_(2)-Ni-EG nanocomposite is also reduced obviously in comparison with the pure MgH_(2) . Our work provides a methodology to significantly improve the hydrogen storage performance of MgH_(2) by combining the in situ formed and uniformly dispersed ultrafine metallic catalyst from the precursor and EG. 展开更多
关键词 Hydrogen storage Magnesium hydride Nickel precursor Size effect Expanded graphite
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Nano-single-crystal-constructed submicron MnCO_(3) hollow spindles enabled by solid precursor transition combined Ostwald ripening in situ on graphene toward exceptional interfacial and capacitive lithium storage 被引量:2
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作者 Jiamin Fei Shiqiang Zhao +6 位作者 Xiaoxu Bo Furong Xie Guanghui Li Ebrahim-Alkhalil MAAhmed Qingcheng Zhang Huile Jin Zhiqun Lin 《Carbon Energy》 SCIE CSCD 2023年第8期98-113,共16页
Hollow structuring has been identified as an effective strategy to enhance the cycling stability of electrodes for rechargeable batteries due to the outstanding volume expansion buffering efficiency,which motivates ar... Hollow structuring has been identified as an effective strategy to enhance the cycling stability of electrodes for rechargeable batteries due to the outstanding volume expansion buffering efficiency,which motivates ardent pursuing on the synthetic approaches of hollow materials.Herein,an intriguing route,combining solid precursor transition and Ostwald ripening(SPTOR),is developed to craft nano single-crystal(SC)-constructed MnCO_(3) submicron hollow spindles homogeneously encapsulated in a reduced graphene oxide matrix(MnCO_(3) SMHSs/rGO).It is noteworthy that the H-bonding interaction between Mn_(3)O_(4) nanoparticles(NPs)and oxygen-containing groups on GO promotes uniform anchoring of Mn_(3)O_(4) NPs on GO,mild reductant ascorbic acid triggers the progressive solid-to-solid transition from Mn_(3)O_(4) NPs to MnCO_(3) submicron solid spindles(SMSSs)in situ on GO,and the Ostwald ripening process induces the gradual dissolution of interior polycrystals of MnCO_(3) SMSSs and subsequent recrystallization on surface SCs of MnCO_(3) SMHSs.Remarkably,MnCO_(3) SMHSs/rGO delivers a 500th lithium storage capacity of 2023 mAh g^(-1) at 1000 mAg^(-1),which is 10 times higher than that of MnCO_(3) microspheres/rGO fabricated from a conventional Mn^(2+)salt precursor(202 mAh g^(-1)).The ultrahigh capacity and ultralong lifespan of MnCO_(3) SMHSs/rGO can be primarily attributed to the superior reaction kinetics and reversibility combined with exceptional interfacial and capacitive lithium storage capability,enabled by the fast ion/electron transfer,large specific surface area,and robust electrode pulverization inhibition efficacy.Moreover,fascinating in-depth lithium storage reactions of MnCO_(3) are observed such as the oxidation of Mn^(2+)in MnCO_(3) to Mn^(3+)in charge process after long-term cycles and the further lithiation of Li_(2)CO_(3) in discharge process.As such,the Carbon Energy.SPTOR approach may represent a viable strategy for crafting various hollow functional materials with metastable nanomaterials as precursors. 展开更多
关键词 hollow structure interfacial and capacitive lithium storage lithium-ion battery MnCO_(3) Ostwald ripening solid precursor transition
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Lineament analysis as a seismic precursor:The El Mayor Cucapah earthquake of April 4,2010(MW7.2),Baja California,Mexico
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作者 Rosendo Romero-Andrade Manuel E.Trejo-Soto +2 位作者 Karan Nayak Daniel Hernández-Andrade Naccieli Bojorquez-Pacheco 《Geodesy and Geodynamics》 CSCD 2023年第2期121-129,共9页
An earthquake called the MW7.2“El Mayor Cucapah”earthquake on April 4,2010 has been analyzed for seismic precursor.The changes in the lineament system concerning its pattern and time intervals were analyzed during t... An earthquake called the MW7.2“El Mayor Cucapah”earthquake on April 4,2010 has been analyzed for seismic precursor.The changes in the lineament system concerning its pattern and time intervals were analyzed during the earthquake preparation period and occurrence using the automated lineament detection method.The Landsat 5 TM images were processed using LESSA and ADALGEO software obtaining similar results.The statistical analysis revealed the stress accumulation due to plate interaction during earthquake formation.The study shows that the number of extracted lineaments changes rapidly about 23 months before the earthquake,and the systems return to the initial stage after 23 months.Most lineaments coincide with the extension of the San Andreas Fault as NW direction is the dominant trend.Thus,it can be concluded that the featural changes within the Rose diagram corresponding to the different strokes direction along with oriented elongation lines as disclosed in the present study using satellite images could be identified as a mid-term and/or short-term precursors of the earthquake.However,even though the dynamism of the El Mayor Cucapah earthquake is found in the extracted lineaments,it is possible to isolate more significant earthquakes even if new ones appear near the zone.Moreover,using two algorithms for lineament detection allows for the tectonics to corroborate the obtained lineaments and dynamism. 展开更多
关键词 Lineament analysis EARTHQUAKE Landsat images Seismic precursor
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Not Follicular but Dermal Melanocyte Precursors Are Histopathologically Retained in Vitiligo
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作者 Atsushi Tanemura Ryoko Kawabe +5 位作者 Yuka Sudo Kazunori Yokoi Takanobu Kabasawa Mitsuru Futakuchi Tamio Suzuki Manabu Fujimoto 《Journal of Cosmetics, Dermatological Sciences and Applications》 CAS 2023年第1期38-44,共7页
Although perifollicular repigmentation in the vitiligo lesions is owing to activation of follicular melanocyte stem cells and/or precursor cells followed by supplying matured melanocytes, the underlying mechanism of d... Although perifollicular repigmentation in the vitiligo lesions is owing to activation of follicular melanocyte stem cells and/or precursor cells followed by supplying matured melanocytes, the underlying mechanism of diffuse repigmentation on the whole vitiligo surface remains still unknown. In addition to the presence of remaining melanocytes, it is conceivable that dermal melanocyte precursor cells contribute to induce diffuse repigmentation after treatment. Therefore, we investigated here whether dermal and follicular melanocyte precursor cells were reduced or not in vitiligo lesions. We performed an immunostaining for Nestin and p75NGFR as dermal melanocyte precursor cells and MITF/Fzd4 as follicular melanocyte precursor cells and compared the positive cells number between lesions and non-lesions (n = 11). Although MITF<sup>+</sup>/Fzd4<sup>+</sup> cells in the hair follicle were significantly decreased in number in the lesions, Nestin<sup>+</sup> and p75NGFR<sup>+</sup> cells were not. This result indicates that dermal precursor cells could be retained in the vitiligo lesions but be disturbed to differentiate into matured melanocytes. 展开更多
关键词 Melanocyte precursor Cells p75NGFR NESTIN Frizzled4 VITILIGO
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Active precursor promoting nucleation/growth of MwW zeolite and controlling its morphology
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作者 Shi-Wei Cao Peng Xiao +7 位作者 Jjie Wang Yu Sun Yun-Shan Shang Ya-Fen Ge Qi Liu Yan-Jun Gong Guang Moo Zhi-Hong Li 《Petroleum Science》 SCIE EI CAS CSCD 2023年第3期1922-1933,共12页
MWW zeolites is an important catalyst in petrochemical industry.However,the efficient preparation of Mww zeolites still faces challenges,and the origin of influential factors for regulating its structure properties al... MWW zeolites is an important catalyst in petrochemical industry.However,the efficient preparation of Mww zeolites still faces challenges,and the origin of influential factors for regulating its structure properties also remains obscure.Herein,we designed a nanoscale amorphous silica-alumina species denoted as active precursor(APS),and adopt the APS in the HMI mixture to synthesize MCM-22 zeolite(APS-MWW)successfully.To reveal the distinctive role of APS in promoting the crystallization of MWW zeolites,two crystal materials(ITQ-1 and MCM-22)and one mother liquor(ML)as seeds to synthesize three types of MWW zeolites.Typically,when adding APS in the synthetic mixture,the HMI amount was reduced to less than a quarter and crystallization time was reduced to 36 h.APS-MWW sample provides a smaller particle size(2-4μm)and thinner stacked layer thickness(5-20 nm).Synchrotron radiation Small Angle X-ray Scattering(SAXS)shows each seed has a different impact on the species'fractal structure and size distribution in the mixture,which is highly related to the nucleation and growth of MWW zeolites.APS shows a large number of 6 membered ring(MR)structure units which play a sig-nificant role in boosting the rapid nucleation and growth of APS-MwW zeolite.Among the synthesized MWW zeolites,the APS-MWW performs the highest ethylbenzene yield in the alkylation reaction of benzene-ethylene,which is attributed to its moderate flake thickness,appropriate texture properties and more external surface acidity.The results will provide a new perspective for producing MwW-types zeolites by using the available and effective active precursor. 展开更多
关键词 MWW zeolites Active precursor Small-angle X-ray scattering Benzene-ethylene alkylation reaction
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Medium-term surgical outcomes and health-related quality of life after laparoscopic vs open colorectal cancer resection: SF-36 health survey questionnaire
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作者 Chao-Ming Hung Kuo-Chuan Hung +11 位作者 Hon-Yi Shi Shih-Bin Su Hui-Ming Lee Meng-Che Hsieh Cheng-Hao Tseng Shung-Eing Lin Chih-Cheng Chen Chao-Ming Tseng Ying-Nan Tsai Chi-Zen Chen Jung-Fa Tsai Chong-Chi Chiu 《World Journal of Gastrointestinal Endoscopy》 2023年第3期163-176,共14页
BACKGROUND Previous studies that compared the postoperative health-related quality of life(HRQoL)outcomes after receiving laparoscopic resection(LR)or open resection(OR)in patients with colorectal cancer(CRC)have diff... BACKGROUND Previous studies that compared the postoperative health-related quality of life(HRQoL)outcomes after receiving laparoscopic resection(LR)or open resection(OR)in patients with colorectal cancer(CRC)have different conclusions.AIM To explore the medium-term effect of postoperative HRQoL in such patients.METHODS This study randomized 567 patients undergoing non-metastatic CRC surgery managed by one surgeon to the LR or OR groups.HRQoL was assessed during the preoperative period and 3,6,and 12 mo postoperative using a modified version of the 36-Item Short Form(SF-36)Health Survey questionnaire,emphasizing eight specific items.RESULTS This cohort randomly assigned 541 patients to receive LR(n=296)or OR(n=245)surgical procedures.More episodes of postoperative urinary tract infection(P<0.001),wound infection(P<0.001),and pneumonia(P=0.048)were encountered in the OR group.The results demonstrated that the LR group subjectively gained mildly better general health(P=0.045),moderately better physical activity(P=0.006),and significantly better social function recovery(P=0.0001)3 mo postoperatively.Only the aspect of social function recovery was claimed at 6 mo,with a significant advantage in the LR group(P=0.001).No clinical difference was found in HRQoL during the 12 mo.CONCLUSION Our results demonstrated that LR resulted in better outcomes,including intra-operative blood loss,surgery-related complications,course of recovery,and especially some health domains of HRQoL at least within 6 mo postoperatively.Patients should undergo LR if there is no contraindication. 展开更多
关键词 Health-related quality of life medium-term result LAPAROSCOPIC Open surgery Non-metastatic colorectal cancer
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An Attempt to Analyze a Human Nervous System Algorithm for Sensing Earthquake Precursors
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作者 Da Cao 《Open Journal of Earthquake Research》 2023年第1期1-25,共25页
We statistically validate the 2011-2022 earthquake prediction records of Ada, the sixth finalist of the 2nd China AETA in 2021, who made 147 earthquake predictions (including 60% of magnitude 5.5 earthquakes) with a p... We statistically validate the 2011-2022 earthquake prediction records of Ada, the sixth finalist of the 2nd China AETA in 2021, who made 147 earthquake predictions (including 60% of magnitude 5.5 earthquakes) with a prediction accuracy higher than 70% and a confidence level of 95% over a 12-year period. Since the reliable earthquake precursor signals described by Ada and the characteristics of Alfvén waves match quite well, this paper proposes a hypothesis on how earthquakes are triggered based on the Alfvén (Q G) torsional wave model of Gillette et al. When the plume of the upper mantle column intrudes into the magma and lithosphere of the soft flow layer during the exchange of hot and cold molten material masses deep inside the Earth’s interior during ascent and descent, it is possible to form body and surface plasma sheets under certain conditions to form Alfven nonlinear isolated waves, and Alfven waves often perturb the geomagnetic field, releasing huge heat and kinetic energy thus triggering earthquakes. To explain the complex phenomenon of how Ada senses Alvfen waves and how to locate epicenters, we venture to speculate that special magnetosensory cells in a few human bodies can sense earthquake precursors and attempt to hypothesize an algorithm that analyzes how the human biological nervous system encodes and decodes earthquake precursors and explains how human magnetosensory cells can solve complex problems such as predicting earthquake magnitude and locating epicenters. 展开更多
关键词 Earthquake Prediction Earthquake precursors Mantle Column Plume ASTHENOSPHERE Alfven Isolated Waves Human Magnetic Induction Cells Neuronal Spikes Bayesian Algorithm
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广州市2022年臭氧污染特征与成因分析 被引量:1
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作者 黄继章 高健 +9 位作者 余美芳 高锐 裴成磊 杨素霞 张金谱 宋伟 李磊 李银松 郭昊 叶子铭 《中国环境科学》 EI CAS CSCD 北大核心 2024年第6期3100-3110,共11页
选取2022年O_(3)及其前体物观测数据、气象观测数据和ERA5再分析数据,结合基于观测的模型(OBM)和后向轨迹模型,分析了2022年广州市O_(3)污染特征,识别了O_(3)生成控制区及关键敏感型物种,并从O_(3)前体物排放、气象条件和区域传输3个方... 选取2022年O_(3)及其前体物观测数据、气象观测数据和ERA5再分析数据,结合基于观测的模型(OBM)和后向轨迹模型,分析了2022年广州市O_(3)污染特征,识别了O_(3)生成控制区及关键敏感型物种,并从O_(3)前体物排放、气象条件和区域传输3个方面开展了O_(3)污染成因分析.结果表明:广州市O_(3)生成以VOCs控制和NO_(x)-VOCs协同控制为主,现阶段VOCs和NO_(x)减排比例应不低于1:1;O_(3)生成对含氧VOCs最为敏感,其次是植物源VOCs(BVOCs)、烯烃、芳香烃和烷烃;2022年广州市O_(3)前体物NO_(x)和VOCs浓度同比下降14.7%和30.4%,但副高强盛、台风外围环流影响频繁叠加强辐射、高温、低湿等不利气象条件和区域传输抵消了广州市本地前体物减排的成效,造成O_(3)浓度上升,其中典型O_(3)污染过程(2022年9月16~22日)气流轨迹由西北、西南方向气团转变为东和东南方向气团,易受到来自周边城市区域传输影响.建议下一步持续推动NO_(x)减排,促进O_(3)对NO_(x)敏感性向正敏感性的转变,同时积极构建区域联防联控机制,降低区域传输贡献. 展开更多
关键词 广州市 臭氧污染 基于观测的模型(OBM) 前体物 气象条件 区域传输
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Medium-term forecast of daily passenger volume of high speed railway based on DLP-WNNMedium-term forecast of dailypassenger volume of high speedrailway based on DLP-WNN
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作者 Tangjian Wei Xingqi Yang +1 位作者 Guangming Xu Feng Shi 《Railway Sciences》 2023年第1期121-139,共19页
Purpose – This paper aims to propose a medium-term forecast model for the daily passenger volume of HighSpeed Railway (HSR) systems to predict the daily the Origin-Destination (OD) daily volume formultiple consecutiv... Purpose – This paper aims to propose a medium-term forecast model for the daily passenger volume of HighSpeed Railway (HSR) systems to predict the daily the Origin-Destination (OD) daily volume formultiple consecutivedays (e.g. 120 days).Design/methodology/approach – By analyzing the characteristics of the historical data on daily passengervolume of HSR systems, the date and holiday labels were designed with determined value ranges.In accordance to the autoregressive characteristics of the daily passenger volume of HSR, the Double LayerParallel Wavelet Neural Network (DLP-WNN) model suitable for the medium-term (about 120 d) forecast of thedaily passenger volume of HSR was established. The DLP-WNN model obtains the daily forecast result byweighed summation of the daily output values of the two subnets. Subnet 1 reflects the overall trend of dailypassenger volumes in the recent period, and subnet 2 the daily fluctuation of the daily passenger volume toensure the accuracy of medium-term forecast.Findings – According to the example application, in which the DLP-WNN modelwas used for the medium-termforecast of the daily passenger volumes for 120 days for typical O-D pairs at 4 different distances, the averageabsolute percentage error is 7%-12%, obviously lower than the results measured by the Back Propagation (BP)neural network, the ELM (extreme learning machine), the ELMAN neural network, the GRNN (generalizedregression neural network) and the VMD-GA-BP. The DLP-WNN model was verified to be suitable for themedium-term forecast of the daily passenger volume of HSR.Originality/value – This study proposed a Double Layer Parallel structure forecast model for medium-termdaily passenger volume (about 120 days) of HSR systems by using the date and holiday labels and WaveletNeural Network. The predict results are important input data for supporting the line planning, scheduling andother decisions in operation and management in HSR systems. 展开更多
关键词 High speed railway Passenger flow forecast Daily passenger volume medium-term forecast Wavelet neural network
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中国大陆强震发生前地震活动增强统计特征分析
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作者 呼楠 石富强 +5 位作者 季灵运 刘洁 祁玉萍 王光明 张丽峰 郭蕾 《地震学报》 CSCD 北大核心 2024年第2期226-241,共16页
依据《中国震例》(1966—2017年)对1966年以来中国大陆东部M_(S)>6.0、西部M_(S)>7.0强震前地震活动增强的异常现象特征进行了系统的梳理,并试图总结不同活动构造地块周缘强震前地震活动增强的异常时空演化特征。结果显示:①我国... 依据《中国震例》(1966—2017年)对1966年以来中国大陆东部M_(S)>6.0、西部M_(S)>7.0强震前地震活动增强的异常现象特征进行了系统的梳理,并试图总结不同活动构造地块周缘强震前地震活动增强的异常时空演化特征。结果显示:①我国大陆大震前普遍存在地震活动增强现象,33个震例中有21个震例存在震前地震活动增强异常,占比达64%;②西部地区大多数震例的地震活动增强空间范围表现为中间尺度或构造尺度,且主震震级越大,越有可能出现大范围的地震活动增强;③西部地区出现中强地震活动增强的概率高于东部地区,前兆地震活动增强的平均震级较大,发生大震(M>7.0)的概率增大;④西部地区地震活动增强的时间尺度与震级成正比,而东部地区随着震级增大,更可能出现中期到中短期的地震活动增强异常;⑤多数西部地区震例在震前出现不同时间尺度的地震活动增强叠加的现象;⑥川滇菱形地块的强震前均出现了中长期尺度的地震条带交会现象、不同空间尺度的地震空区以及中短期尺度的中小震活动增强现象,并且对大震地点有较好的指示意义。巴颜喀拉东边界与北、西及南边界大震前存在显著的不同地震活动增强特征,震前未出现中强地震围空的现象。 展开更多
关键词 前兆地震活动增强 统计特征 活动地块 地震前兆模型
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