Fullerenes (C 60 /C 70 ), clays and rocks near the Permian-Triassic (P/T) boundary in the Meishan section of South China are explored by means of comprehensive analytical techniques, including ultrasonic extraction wi...Fullerenes (C 60 /C 70 ), clays and rocks near the Permian-Triassic (P/T) boundary in the Meishan section of South China are explored by means of comprehensive analytical techniques, including ultrasonic extraction with column purification, high-performance liquid chromatography (HPLC) and matrix assisted laser desorption/ionization time-of- flight mass spectrometry (MALDI TOF MS). The study confirms the existence of fullerenes toward the P/T event boundary and their absence in clays and limestones beyond the boundary. In particular, the white clay, known as the event boundary, contains fullerenes of 0.33 ppb, while the red material, as the first lamina fill of goethite and gypsum on the base of the white clay, contains fullerenes of 1.23 ppb, and the last lamina of 2.50 ppb. Significantly, distinct enrichment of fullerenes is coincident with the disappearance of fossil records of marine species (94%) just at the base of the white clay, implying that geological fullerenes would be one of temporal remnants led by the P/T catastrophic event. This work strongly supports that fullerenes would be one of significant records of the P/T catastrophic event but their origin remains to be studied further.展开更多
The Meishan section of China has been confirmed as the ＂Global Stratotype Section and Point＂ of the P/T boundary. In the section, the authors found several types of iron grains, including pyrite, pure iron grains an...The Meishan section of China has been confirmed as the ＂Global Stratotype Section and Point＂ of the P/T boundary. In the section, the authors found several types of iron grains, including pyrite, pure iron grains and goethite. From the research of macro minerals, it is easy to find that the grains rich in iron appear from the bottom of the event layer of the section. In other words, it is probably residue of the geochemical catastrophe of that time. Therefore, it is important to trace the source of these iron grains and their relationships, which probably provides evidence for volcanic eruption or impact-volcanoes and has directive significance to the crisis during the P/T transitional period. Through the study of the characterization and relationships of these iron grains, the authors make a preliminary discussion on the P/T mass extinction.展开更多
Meishan Section D in Changxing County, Zhejiang Province, China has been selected as the global stratotype of the Permian Triassic boundary and various studies have been done at the boundary, but the gas chromatograp...Meishan Section D in Changxing County, Zhejiang Province, China has been selected as the global stratotype of the Permian Triassic boundary and various studies have been done at the boundary, but the gas chromatographic mass spectrographic analysis of alkane biomarkers has not been investigated. This paper presents the results of a study of the biomarkers analyzed in a series of samples across the Permian Triassic boundary at both Meishan Section A and Section D. The results show that the overall concentration of alkane biomarkers in the Permian Triassic boundary strata is high in Bed 26 while it is low in Bed 27. A variety of biomarker parameters demonstrate that the main sources of organic matter in the sediment are algae and bacteria and that the depositional environment varied from weakly oxidizing to reducing during the studied interval.展开更多
The Global Stratotype Section and Point(GSSP) for the Permian-Triassic boundary was placed in Bed 27 of Meishan section D where the conodont species Hindeodus parvus first occurs.Bed 27 was usually considered comprisi...The Global Stratotype Section and Point(GSSP) for the Permian-Triassic boundary was placed in Bed 27 of Meishan section D where the conodont species Hindeodus parvus first occurs.Bed 27 was usually considered comprising continuouslydeposited,homogeneous silty limestone,with no depositional hiatus near the boundary.Detailed study on the boundary sequence revealed that a typical firmground characterized by Glossifungites ichnofacies developed about 2 cm below the Permian-Triassic boundary in Bed 27.Fossil content and lithology show apparent differences across the firmground crust.The abundance of the Permian bioclasts decreases significantly across the firmground,and is accompanied by a shift of dominating carbonate precipitation from calcite to dolomite.The firmground marked a rapid transgression at the very end of the Late Permian and significant shifts of sedimentary environment and paleoclimate.This transgressive submerging surface is also observed at the Huangzhishan section of the shallow-water carbonate platform facies in Zhejiang Province,the Jiangya section of the lower-slope to basinal-margin facies in Hunan Province,the Pingdingshan section of the basinal facies in Anhui Province of South China,as well as the Selong section in Tibet of the northern peri-Gondwana.The transgressive submerging surface marks the onset of a rapid global transgression at the latest Permian.展开更多
Both gradual and sharp decrease in organic and carbonate carbon isotope values were detected across the Permian-Triassic boundary in the Meishan section, Changxing, Zhejiang Province, China. The gradual decrease in or...Both gradual and sharp decrease in organic and carbonate carbon isotope values were detected across the Permian-Triassic boundary in the Meishan section, Changxing, Zhejiang Province, China. The gradual decrease in organic carbon isotope values started at the bottom of Bed 23, coinciding with the strong oscillations of total organic carbon (TOC) contents, indicates increasing fluxes from carbonate to organic carbon reservoir during this interval. A 2.3‰ sharp drop of inorganic carbon isotope values occurred at the uppermost part of Bed 24e. A 3.7‰ sharp drop of organic carbon isotope values occurred in Bed 26. The dramatic drop of inorganic carbon isotope value of 8‰ reported previously is not confirmed from the unweathered carbonate samples in Bed 27. The large-scale fluctuation of organic carbon isotope values in the Yinkeng Formation reflects different extent of mixing of marine and terrestrial organic matters. The gradual depletion and subsequent sharp drop of carbon isotopes near the展开更多
The event Permian-Triassic boundary (EPTB) is well marked by the famous 'white clay' of bed 25 in Mei-shan Section located in Changxing county, Zhejiang province of China. In this note, the white clay as well ...The event Permian-Triassic boundary (EPTB) is well marked by the famous 'white clay' of bed 25 in Mei-shan Section located in Changxing county, Zhejiang province of China. In this note, the white clay as well as its overlying and underlying sequences is investigated particularly for mineralogical records. The investigation yields three findings that contribute to better understanding the scenario of the EPTB mass extinction. (i) A red goethite-rich microlayer (0.3 mm) is first recognized to be horizontally widespread on the base of the white clay in the section. The microlayer should be considered as a macro geochemical indicator naturally tracing a catastrophic initiation at the EPTB. (ii) An interruption of marine carbonate deposition is discovered due to blank of carbonate minerals in the white clay. The discovery provides significant evidence of a marine acidification event that would occur in the paleo-ocean with marine acidity estimated at pH【4.0 at least and be triggered by the ultimate展开更多
This study is based on both a generic and species level investigation of the individual size of the latest Permian conodont Neogondolella Pa elements collected from Meishan Section A, Changxing, Zhejiang Province. In ...This study is based on both a generic and species level investigation of the individual size of the latest Permian conodont Neogondolella Pa elements collected from Meishan Section A, Changxing, Zhejiang Province. In this study, an obvious size reduction of Neogondolella Pa elements within bed 24e of the upper Changxing Limestone is recognized. The size variation of the Neogon- dolella occurs simultaneously with some important events including the negative shift of δ 13C, change in the ratio of the abundance of cyanobacterial biomarkers versus that of other general bacterial biomarkers and the shallowing of the sea water. Through the investigation of the paleoenvironmental changes and the analysis of the paleoecology of the conodont genus Neogondolella, the authors propose that the major factors for the size reduction of species of the conodont genus Neogondolella are food shortages caused by the mass extinction, the shallowing of the sea water as well as the in- crease in opacity of the sea water during the end Permian. The same phenomenon of Neogondolella size reduction is also observed in preliminary research from the same horizon at Shangsi Section, Sichuan Province. All the evidence suggests that there was a mass extinction that occurred at the horizon of bed 24e, and the evidence supports the viewpoint of a multi-phase mass extinction during the Permian and Triassic transition in South China.展开更多
Samples were collected continuously and systematically from Beds 2 to 30 of the Meishan D section, and nearly 4,000 foraminiferal specimens were recognized. In total, 72 species （partially including undetermined spec...Samples were collected continuously and systematically from Beds 2 to 30 of the Meishan D section, and nearly 4,000 foraminiferal specimens were recognized. In total, 72 species （partially including undetermined species and conformis species） in 34 genera of foraminifers were identified. Twelve foraminiferal community zones were established from Beds 2 to 27 based on the abundance, dominance, diversity, and equitability of the foraminiferal fauna and a functional morphological analysis of the dominant and characteristic species. The habitat type indicated by each community zone and the sedimentary features were used to determine the paleo-water depths and the relative changes in sea level. We generated curves of both the habitat type and the hydrodynamic conditions, which together indicate the relative changes in the paleo-water depth and the substrate features in the studied area during the Changhsingian. This study discusses the possible relationship between the foraminiferal community zones and the sea-level changes based on a statistical analysis of the foraminiferal community zones.展开更多
Meishan Section in Changxing County of Zhejiang Province is one of the four candidates of the global stratotype section and point (GSSP) of the Permian and Triassic boundary (PTB), and currently the conodonts have bee...Meishan Section in Changxing County of Zhejiang Province is one of the four candidates of the global stratotype section and point (GSSP) of the Permian and Triassic boundary (PTB), and currently the conodonts have been widely accepted as the index fossils to define the Permian and Triassic boundary. The previous studies on the Lower Triassic conodonts at Meishan Section are summarized and the recent discovery of the Lower Triassic conodonts there is reported. The recognized data from the section indicate that Meishan is the best selection of the GSSP of PTB.展开更多
This paper provides a synthetic review of researches on Meishan Section D, the Global Stratotype Section and Point of the Permian-Triassic Boundary （PTB）. The history of research, geographic and geological setting o...This paper provides a synthetic review of researches on Meishan Section D, the Global Stratotype Section and Point of the Permian-Triassic Boundary （PTB）. The history of research, geographic and geological setting of the section are briefly introduced. Changhsingian to ＂Griesbachian＂ conodont and ammonoid zonations, the most perfect Permo-Triassic zonations over the world, are presented, with a short discussion on the age of Otoceras, The Changhsingian to ＂Griesbachian＂ strata are subdivided into three 3rd order sequences, and the sedimentary structure of each sequence is indicated. The paper presents a correlation of the Changhsingian to ＂Griesbachian＂ magneetostratigraphy of the Meishan section with the general scale, and informed the negation of a short magnetic reversal at the PTB suggested by Zhu and Liu （1999）. Recent developments of chemostratigraphy of δ^13C and δ^34S are introduced, especially the discovery of more than one negative δ^13C excursions across the PTB. Two important molecular researches reveal the profound changes at the base of eco-system, the microbial catastrophy, and the euxinic conditions in the photic zone during the Permian-Triassic superanoxic event. The paper reports the changes in dating the age of PTB since 2001. According to recent achievements, the age of volcanogenic claybed 25, 14 cm below the PTB, is now set at 252.4±0.3 Ma. A discussion on the eventostratigraphy concludes that, although there is a major event episode at beds 25-26, the events across the PTB at Meishan are multi-episodic and commenced prior to the Event Beds 25-26, thus the possibility that the mass extinction was mainly induced by an exterrestrial impact is largely excluded.展开更多
基金the National Natural Science Foundation of China(No.40072055,40232025) the Research Fund for the Doctoral Program of Higher Education(No.20040290005).
文摘Fullerenes (C 60 /C 70 ), clays and rocks near the Permian-Triassic (P/T) boundary in the Meishan section of South China are explored by means of comprehensive analytical techniques, including ultrasonic extraction with column purification, high-performance liquid chromatography (HPLC) and matrix assisted laser desorption/ionization time-of- flight mass spectrometry (MALDI TOF MS). The study confirms the existence of fullerenes toward the P/T event boundary and their absence in clays and limestones beyond the boundary. In particular, the white clay, known as the event boundary, contains fullerenes of 0.33 ppb, while the red material, as the first lamina fill of goethite and gypsum on the base of the white clay, contains fullerenes of 1.23 ppb, and the last lamina of 2.50 ppb. Significantly, distinct enrichment of fullerenes is coincident with the disappearance of fossil records of marine species (94%) just at the base of the white clay, implying that geological fullerenes would be one of temporal remnants led by the P/T catastrophic event. This work strongly supports that fullerenes would be one of significant records of the P/T catastrophic event but their origin remains to be studied further.
基金This research was supported by the National Natural Science Foundation of China （Nos. 40232025 40072055+1 种基金 40572020） the Research Fund for the Doctoral Program of Higher Education （No. 20040290005）.
文摘The Meishan section of China has been confirmed as the ＂Global Stratotype Section and Point＂ of the P/T boundary. In the section, the authors found several types of iron grains, including pyrite, pure iron grains and goethite. From the research of macro minerals, it is easy to find that the grains rich in iron appear from the bottom of the event layer of the section. In other words, it is probably residue of the geochemical catastrophe of that time. Therefore, it is important to trace the source of these iron grains and their relationships, which probably provides evidence for volcanic eruption or impact-volcanoes and has directive significance to the crisis during the P/T transitional period. Through the study of the characterization and relationships of these iron grains, the authors make a preliminary discussion on the P/T mass extinction.
基金ThisresearchissupportedbytheNationalNaturalScienceFoundationofChina (No .40 0 72 0 11) theMinistryofScienceandTechnology (No .2 0 0 1DEA2 0 0 2 0 )andLaboratoryofEarthSurfaceSystem HubeiProvince .
文摘Meishan Section D in Changxing County, Zhejiang Province, China has been selected as the global stratotype of the Permian Triassic boundary and various studies have been done at the boundary, but the gas chromatographic mass spectrographic analysis of alkane biomarkers has not been investigated. This paper presents the results of a study of the biomarkers analyzed in a series of samples across the Permian Triassic boundary at both Meishan Section A and Section D. The results show that the overall concentration of alkane biomarkers in the Permian Triassic boundary strata is high in Bed 26 while it is low in Bed 27. A variety of biomarker parameters demonstrate that the main sources of organic matter in the sediment are algae and bacteria and that the depositional environment varied from weakly oxidizing to reducing during the studied interval.
基金supported by National Basic Research Program of China(Grant No. 2011CB808905)National Natural Science Foundation of China(Grant Nos.41102056,41273081,40973050 & J0930006)State Key Laboratory of Palaeobiology and Stratigraphy(Grant No.20121102)
文摘The Global Stratotype Section and Point(GSSP) for the Permian-Triassic boundary was placed in Bed 27 of Meishan section D where the conodont species Hindeodus parvus first occurs.Bed 27 was usually considered comprising continuouslydeposited,homogeneous silty limestone,with no depositional hiatus near the boundary.Detailed study on the boundary sequence revealed that a typical firmground characterized by Glossifungites ichnofacies developed about 2 cm below the Permian-Triassic boundary in Bed 27.Fossil content and lithology show apparent differences across the firmground crust.The abundance of the Permian bioclasts decreases significantly across the firmground,and is accompanied by a shift of dominating carbonate precipitation from calcite to dolomite.The firmground marked a rapid transgression at the very end of the Late Permian and significant shifts of sedimentary environment and paleoclimate.This transgressive submerging surface is also observed at the Huangzhishan section of the shallow-water carbonate platform facies in Zhejiang Province,the Jiangya section of the lower-slope to basinal-margin facies in Hunan Province,the Pingdingshan section of the basinal facies in Anhui Province of South China,as well as the Selong section in Tibet of the northern peri-Gondwana.The transgressive submerging surface marks the onset of a rapid global transgression at the latest Permian.
基金This work was supported by the Major Basic Research Projects of the Ministry of Science Technology of China (Grant No. G2000077700) Opening Laboratory of Palaeobiology and Stratigraphy of Nanjing Institute of Geology and Palaeontology, the Chinese
文摘Both gradual and sharp decrease in organic and carbonate carbon isotope values were detected across the Permian-Triassic boundary in the Meishan section, Changxing, Zhejiang Province, China. The gradual decrease in organic carbon isotope values started at the bottom of Bed 23, coinciding with the strong oscillations of total organic carbon (TOC) contents, indicates increasing fluxes from carbonate to organic carbon reservoir during this interval. A 2.3‰ sharp drop of inorganic carbon isotope values occurred at the uppermost part of Bed 24e. A 3.7‰ sharp drop of organic carbon isotope values occurred in Bed 26. The dramatic drop of inorganic carbon isotope value of 8‰ reported previously is not confirmed from the unweathered carbonate samples in Bed 27. The large-scale fluctuation of organic carbon isotope values in the Yinkeng Formation reflects different extent of mixing of marine and terrestrial organic matters. The gradual depletion and subsequent sharp drop of carbon isotopes near the
基金This work was partly supported by the National Natural Science Foundation of China (Grant Nos. 40072055 and 40043010).
文摘The event Permian-Triassic boundary (EPTB) is well marked by the famous 'white clay' of bed 25 in Mei-shan Section located in Changxing county, Zhejiang province of China. In this note, the white clay as well as its overlying and underlying sequences is investigated particularly for mineralogical records. The investigation yields three findings that contribute to better understanding the scenario of the EPTB mass extinction. (i) A red goethite-rich microlayer (0.3 mm) is first recognized to be horizontally widespread on the base of the white clay in the section. The microlayer should be considered as a macro geochemical indicator naturally tracing a catastrophic initiation at the EPTB. (ii) An interruption of marine carbonate deposition is discovered due to blank of carbonate minerals in the white clay. The discovery provides significant evidence of a marine acidification event that would occur in the paleo-ocean with marine acidity estimated at pH【4.0 at least and be triggered by the ultimate
基金supported by the National Natural Science Foundation of China(Grant No.40232025)the GeoTurn Group of China University of Geosciences.
文摘This study is based on both a generic and species level investigation of the individual size of the latest Permian conodont Neogondolella Pa elements collected from Meishan Section A, Changxing, Zhejiang Province. In this study, an obvious size reduction of Neogondolella Pa elements within bed 24e of the upper Changxing Limestone is recognized. The size variation of the Neogon- dolella occurs simultaneously with some important events including the negative shift of δ 13C, change in the ratio of the abundance of cyanobacterial biomarkers versus that of other general bacterial biomarkers and the shallowing of the sea water. Through the investigation of the paleoenvironmental changes and the analysis of the paleoecology of the conodont genus Neogondolella, the authors propose that the major factors for the size reduction of species of the conodont genus Neogondolella are food shortages caused by the mass extinction, the shallowing of the sea water as well as the in- crease in opacity of the sea water during the end Permian. The same phenomenon of Neogondolella size reduction is also observed in preliminary research from the same horizon at Shangsi Section, Sichuan Province. All the evidence suggests that there was a mass extinction that occurred at the horizon of bed 24e, and the evidence supports the viewpoint of a multi-phase mass extinction during the Permian and Triassic transition in South China.
基金supported by the Foundation of the Geological Survey of China [grant no. 121201004000150021]
文摘Samples were collected continuously and systematically from Beds 2 to 30 of the Meishan D section, and nearly 4,000 foraminiferal specimens were recognized. In total, 72 species （partially including undetermined species and conformis species） in 34 genera of foraminifers were identified. Twelve foraminiferal community zones were established from Beds 2 to 27 based on the abundance, dominance, diversity, and equitability of the foraminiferal fauna and a functional morphological analysis of the dominant and characteristic species. The habitat type indicated by each community zone and the sedimentary features were used to determine the paleo-water depths and the relative changes in sea level. We generated curves of both the habitat type and the hydrodynamic conditions, which together indicate the relative changes in the paleo-water depth and the substrate features in the studied area during the Changhsingian. This study discusses the possible relationship between the foraminiferal community zones and the sea-level changes based on a statistical analysis of the foraminiferal community zones.
文摘Meishan Section in Changxing County of Zhejiang Province is one of the four candidates of the global stratotype section and point (GSSP) of the Permian and Triassic boundary (PTB), and currently the conodonts have been widely accepted as the index fossils to define the Permian and Triassic boundary. The previous studies on the Lower Triassic conodonts at Meishan Section are summarized and the recent discovery of the Lower Triassic conodonts there is reported. The recognized data from the section indicate that Meishan is the best selection of the GSSP of PTB.
基金The work was supported by the National Natural Science Foundation of China(project no.40232025).
文摘This paper provides a synthetic review of researches on Meishan Section D, the Global Stratotype Section and Point of the Permian-Triassic Boundary （PTB）. The history of research, geographic and geological setting of the section are briefly introduced. Changhsingian to ＂Griesbachian＂ conodont and ammonoid zonations, the most perfect Permo-Triassic zonations over the world, are presented, with a short discussion on the age of Otoceras, The Changhsingian to ＂Griesbachian＂ strata are subdivided into three 3rd order sequences, and the sedimentary structure of each sequence is indicated. The paper presents a correlation of the Changhsingian to ＂Griesbachian＂ magneetostratigraphy of the Meishan section with the general scale, and informed the negation of a short magnetic reversal at the PTB suggested by Zhu and Liu （1999）. Recent developments of chemostratigraphy of δ^13C and δ^34S are introduced, especially the discovery of more than one negative δ^13C excursions across the PTB. Two important molecular researches reveal the profound changes at the base of eco-system, the microbial catastrophy, and the euxinic conditions in the photic zone during the Permian-Triassic superanoxic event. The paper reports the changes in dating the age of PTB since 2001. According to recent achievements, the age of volcanogenic claybed 25, 14 cm below the PTB, is now set at 252.4±0.3 Ma. A discussion on the eventostratigraphy concludes that, although there is a major event episode at beds 25-26, the events across the PTB at Meishan are multi-episodic and commenced prior to the Event Beds 25-26, thus the possibility that the mass extinction was mainly induced by an exterrestrial impact is largely excluded.
