This article reviews the anti-penetration principles and strengthening mechanisms of metal materials,ranging from macroscopic failure modes to microscopic structural characteristics,and further summarizes the micro-ma...This article reviews the anti-penetration principles and strengthening mechanisms of metal materials,ranging from macroscopic failure modes to microscopic structural characteristics,and further summarizes the micro-macro correlation in the anti-penetration process.Finally,it outlines the constitutive models and numerical simulation studies utilized in the field of impact and penetration.From the macro perspective,nine frequent penetration failure modes of metal materials are summarized,with a focus on the analysis of the cratering,compression shear,penetration,and plugging stages of the penetration process.The reasons for the formation of adiabatic shear bands(ASBs)in metal materials with different crystal structures are elaborated,and the formation mechanism of the equiaxed grains in the ASB is explored.Both the strength and the toughness of metal materials are related to the materials’crystal structures and microstructures.The toughness is mainly influenced by the deformation mechanism,while the strength is explained by the strengthening mechanism.Therefore,the mechanical properties of metal materials depend on their microstructures,which are subject to the manufacturing process and material composition.Regarding numerical simulation,the advantages and disadvantages of different constitutive models and simulation methods are summarized based on the application characteristics of metal materials in high-speed penetration practice.In summary,this article provides a systematic overview of the macroscopic and microscopic characteristics of metal materials,along with their mechanisms and correlation during the anti-penetration and impact-resistance processes,thereby making an important contribution to the scientific understanding of anti-penetration performance and its optimization in metal materials.展开更多
The FeCrA1 fiber was used to prepare porous metal materials with air-laid technology, and then followed by sintering at 1300 ℃ for a holding period of 2 h in the vacuum. In addition, a novel fractal soft, which was d...The FeCrA1 fiber was used to prepare porous metal materials with air-laid technology, and then followed by sintering at 1300 ℃ for a holding period of 2 h in the vacuum. In addition, a novel fractal soft, which was developed based on the fractal theory and the computer image processing technology, was explored to describe the pore structure of porous metal materials. Furthermore, the fractal dimension of pore structure was calculated by the soft and the effects of magnification and porosity on ffactal dimension were also discussed. The results show that the fractal dimension decreases with increase in the magnification, while it increases continuously with the porosity enhancing. The interrelationship between the fractal dimension and the magnification or porosity can be presented by the equation of D=α_0exp(-x/α_1)+α_2和D=k_2-(k_1-k_2)/[1+exp((θ-k_0)/k_3)], respectively.展开更多
With the rapid developments of marine resource exploitation,mounts of marine engineering equipment are settled on the ocean.When it is not possible to move the damaged equipment into a dry dock,welding operations must...With the rapid developments of marine resource exploitation,mounts of marine engineering equipment are settled on the ocean.When it is not possible to move the damaged equipment into a dry dock,welding operations must be performed in underwater environments.The underwater laser welding/cladding technique is a promising and advanced technique which could be widely applied to the maintenance of the damaged equipment.The present review paper aims to present a critical analysis and engineering overview of the underwater laser welding/cladding technique.First,we elaborated recent advances and key issues of drainage nozzles all over the world.Next,we presented the underwater laser processing and microstructural-mechanical behavior of repaired marine materials.Then,the newly developed powder-feeding based and wire-feeding based underwater laser direct metal deposition techniques were reviewed.The differences between the convection,conduction,and the metallurgical kinetics in the melt pools during underwater laser direct metal deposition and in-air laser direct metal deposition were illustrated.After that,several challenges that need to be overcame to achieve the full potential of the underwater laser welding/cladding technique are proposed.Finally,suggestions for future directions to aid the development of underwater laser welding/cladding technology and underwater metallurgical theory are provided.The present review will not only enrich the knowledge in the underwater repair technology,but also provide important guidance for the potential applications of the technology on the marine engineering.展开更多
Simulation method was designed to divide Laguerre diagram for right circle group with different weight; out-of-core incremental algorithm for Laguerre diagram was constructed; simulation program development and visual...Simulation method was designed to divide Laguerre diagram for right circle group with different weight; out-of-core incremental algorithm for Laguerre diagram was constructed; simulation program development and visualization was done and simulation was realized in user-specified arbitrary area for simulation of metal materials microstructure, which facilitated the practical application and secondary development of Laguerre diagram in the field of material science engineering. Finally, the utilization of a developed software package exemplified the simulation application of microstructure about metal materials and proved its validity.展开更多
Optimization of scrap utilization, through maintaining a reasonable heavy scrap ratio, determination of scrap yield, development of substitutes for scrap, recycling of high-alloy scrap and optimization of scrap utiliz...Optimization of scrap utilization, through maintaining a reasonable heavy scrap ratio, determination of scrap yield, development of substitutes for scrap, recycling of high-alloy scrap and optimization of scrap utilization technology, was investigated in this paper, in terms of the supply of metal materials, production cost, production quality and environment protection. Then, recycling of solid waste resources was discussed, and the utilization conditions and methods of slag-steel, slag-iron, steel-slag, etc. were determined. Finally, the management system for comprehensive resource utilization was introduced.展开更多
Based on the force-heat equivalence energy density principle,a theoretical model for magnetic metallic materials is developed,which characterizes the temperature-dependent magnetic anisotropy energy by considering the...Based on the force-heat equivalence energy density principle,a theoretical model for magnetic metallic materials is developed,which characterizes the temperature-dependent magnetic anisotropy energy by considering the equivalent relationship between magnetic anisotropy energy and heat energy;then the relationship between the magnetic anisotropy constant and saturation magnetization is considered.Finally,we formulate a temperature-dependent model for saturation magnetization,revealing the inherent relationship between temperature and saturation magnetization.Our model predicts the saturation magnetization for nine different magnetic metallic materials at different temperatures,exhibiting satisfactory agreement with experimental data.Additionally,the experimental data used as reference points are at or near room temperature.Compared to other phenomenological theoretical models,this model is considerably more accessible than the data required at 0 K.The index included in our model is set to a constant value,which is equal to 10/3 for materials other than Fe,Co,and Ni.For transition metals(Fe,Co,and Ni in this paper),the index is 6 in the range of 0 K to 0.65T_(cr)(T_(cr) is the critical temperature),and 3 in the range of 0.65T_(cr) to T_(cr),unlike other models where the adjustable parameters vary according to each material.In addition,our model provides a new way to design and evaluate magnetic metallic materials with superior magnetic properties over a wide range of temperatures.展开更多
Strong impact does serious harm to the military industries so it is necessary to choose reasonable cushioning material and design effective buffers to prevent the impact of equipment.Based on the capillary property en...Strong impact does serious harm to the military industries so it is necessary to choose reasonable cushioning material and design effective buffers to prevent the impact of equipment.Based on the capillary property entangled porous metallic wire materials(EPMWM),this paper designed a composite buffer which uses EPMWM and viscous fluid as cushioning materials under the low-speed impact of the recoil force device of weapon equipment(such as artillery,mortar,etc.).Combined with the capillary model,porosity,hydraulic diameter,maximum pore diameter and pore distribution were used to characterize the pore structure characteristics of EPMWM.The calculation model of the damping force of the composite buffer was established.The low-speed impact test of the composite buffer was conducted.The parameters of the buffer under low-speed impact were identified according to the model,and the nonlinear model of damping force was obtained.The test results show that the composite buffer with EPMWM and viscous fluid can absorb the impact energy from the recoil movement effectively,and provide a new method for the buffer design of weapon equipment(such as artillery,mortar,etc.).展开更多
In this study,the interactions between a Ga-based liquid metal,GaInSn,and several metal materials,including pure metals(Ni and Ti)and alloys(316H stainless steel(SS)and GH3535),at 650℃were investigated.The aim was to...In this study,the interactions between a Ga-based liquid metal,GaInSn,and several metal materials,including pure metals(Ni and Ti)and alloys(316H stainless steel(SS)and GH3535),at 650℃were investigated.The aim was to evaluate the corrosion performance and select a suitable candidate material for use as a molten salt manometer diaphragm in thermal energy storage systems.The results indicated that the alloys(316H SS and GH3535)exhibited less corrosion than pure metals(Ni and Ti)in liquid GaInSn.Ga-rich binary intermetallic compounds were found to form on the surfaces of all the tested metal materials exposed to liquid GaInSn,as a result of the decomposition of liquid GaInSn and its reaction with the constituent elements of the metal materials.The corrosion mechanism for all the tested materials exposed to liquid GaInSn was also investigated and proposed,which may aid in selecting the optimal candidate material when liquid GaInSn is used as the pressure-sensing medium.展开更多
Energy field-assisted machining technology has the potential to overcome the limitations of machining difficult-to-machine metal materials,such as poor machinability,low cutting efficiency,and high energy consumption....Energy field-assisted machining technology has the potential to overcome the limitations of machining difficult-to-machine metal materials,such as poor machinability,low cutting efficiency,and high energy consumption.High-speed dry milling has emerged as a typical green processing technology due to its high processing efficiency and avoidance of cutting fluids.However,the lack of necessary cooling and lubrication in high-speed dry milling makes it difficult to meet the continuous milling requirements for difficult-to-machine metal materials.The introduction of advanced energy-field-assisted green processing technology can improve the machinability of such metallic materials and achieve efficient precision manufacturing,making it a focus of academic and industrial research.In this review,the characteristics and limitations of high-speed dry milling of difficult-to-machine metal materials,including titanium alloys,nickel-based alloys,and high-strength steel,are systematically explored.The laser energy field,ultrasonic energy field,and cryogenic minimum quantity lubrication energy fields are introduced.By analyzing the effects of changing the energy field and cutting parameters on tool wear,chip morphology,cutting force,temperature,and surface quality of the workpiece during milling,the superiority of energy-field-assisted milling of difficult-to-machine metal materials is demonstrated.Finally,the shortcomings and technical challenges of energy-field-assisted milling are summarized in detail,providing feasible ideas for realizing multi-energy field collaborative green machining of difficult-to-machine metal materials in the future.展开更多
Composite materials exhibit the impressive mechanical properties of high damping and stiffness,which cannot be attained by employing conventional single materials.Along these lines,a novel material architecture is pre...Composite materials exhibit the impressive mechanical properties of high damping and stiffness,which cannot be attained by employing conventional single materials.Along these lines,a novel material architecture is presented in this work in order to fabricate composites with enhanced mechanical characteristics.More specifically,entangled metallic wire materials were used as the active matrix,whereas polyurethane was employed as the reinforcement elements.As a result,an entangled metallic wire material-polyurethane composite with high damping and stiffness was prepared by enforcing the vacuum infiltration method.On top of that,the mechanical properties(loss factor,energy consumption,and average stiffness)of the proposed composite materials were characterized by performing dynamic tests,and its fatigue characteristics were verified by the micro-interface bonding,as well as the macro-damage factor.The impact of the density,preloading spacing,loading amplitude,and exciting frequency on the mechanical properties of the composites were also thoroughly analyzed.The extracted results indicate that the mechanical properties of the composites were significantly enhanced than those of the pure materials due to the introduction of interface friction.Moreover,the average stiffness of the composites was about 10 times the respective value of the entangled metallic wire material.Interestingly,a rise in the loading period leads to some failure between the composite interfaces,which reduces the stiffness property but enhances the damping dissipation properties.Finally,a comprehensive dynamic mechanical model of the composites was established,while it was experimentally verified.The proposed composites possess higher damping features,i.e.,stiffness characteristics,and maintain better fatigue characteristics,which can broaden the application range of the composites.In addition,we provide a theoretical and experimental framework for the research and applications in the field of metal matrix composites.展开更多
Distinct from"rockingchair"lithium-ion batteries(LIBs),the unique anionic intercalation chemistry on the cathode side of dual-ion batteries(DIBs)endows them with intrinsic advantages of low cost,high voltage...Distinct from"rockingchair"lithium-ion batteries(LIBs),the unique anionic intercalation chemistry on the cathode side of dual-ion batteries(DIBs)endows them with intrinsic advantages of low cost,high voltage,and ecofriendly,which is attracting widespread attention,and is expected to achieve the next generation of large-scale energy storage applications.Although the electrochemical reactions on the anode side of DIBs are similar to that of LIBs,in fact,to match the rapid insertion kinetics of anions on the cathode side and consider the compatibility with electrolyte system which also serves as an active material,the anode materials play a very important role,and there is an urgent demand for rational structural design and performance optimization.A review and summarization of previous studies will facilitate the exploration and optimization of DIBs in the future.Here,we summarize the development process and working mechanism of DIBs and exhaustively categorize the latest research of DIBs anode materials and their applications in different battery systems.Moreover,the structural design,reaction mechanism and electrochemical performance of anode materials are briefly discussed.Finally,the fundamental challenges,potential strategies and perspectives are also put forward.It is hoped that this review could shed some light for researchers to explore more superior anode materials and advanced systems to further promote the development of DIBs.展开更多
Extensive in vitro corrosion test systems have been carried out to simulate the in vivo corrosion behavior of biodegradable metallic materials. Various methods have their own unique benefits and limitations. The corro...Extensive in vitro corrosion test systems have been carried out to simulate the in vivo corrosion behavior of biodegradable metallic materials. Various methods have their own unique benefits and limitations. The corrosion mechanism of biodegradable alloys and in vitro corrosion test systems on biodegradable metallic materials are reviewed, to build a reasonable simulated in vitro test system for mimicking the in vivo animal test from the aspects of electrolyte solution selection, surface roughness influence, test methods and evaluation methodology of corrosion rate. Buffered simulated body fluid containing similar components to human blood plasma should be applied as electrolyte solution, such as simulated body fluid (SBF) and culture medium with serum. Surface roughness of samples and ratio of solution volume to sample surface area should be adopted based on the real implant situation, and the dynamic corrosion is preferred. As to the evaluation methodology of corrosion rate, different methods may complement one another.展开更多
Tongling Nonferrous Metals Group Holding Co.,Ltd.has signed a joint venture agreement with a subsidiary of Aero Engine Corporation of China,proposing to establish a JV to engage in the R&D and production of specia...Tongling Nonferrous Metals Group Holding Co.,Ltd.has signed a joint venture agreement with a subsidiary of Aero Engine Corporation of China,proposing to establish a JV to engage in the R&D and production of special aerial metal materials.Presently,the JV project展开更多
Variable strain rate tension tests for 4 metallic materials show that as the strain rate in creases the strain hardening exponent n decreases. The trend follows a two stage linear relation between n and Ig (?). When (...Variable strain rate tension tests for 4 metallic materials show that as the strain rate in creases the strain hardening exponent n decreases. The trend follows a two stage linear relation between n and Ig (?). When (?) < (?)cp, i.e. under quasi-static loading, n can be considered as a constant, but when (?)>(?)cp, n decreases rapidly till an ideal plastic state. n = 0. The characterizations and mechanisms of softening induced by high (?) are discussed.展开更多
Powder metallurgy processes are suitable to produce form-stable solid−liquid phase change materials from miscibility gap alloys.They allow to obtain a composite metallic material with good dispersion of low-melting ac...Powder metallurgy processes are suitable to produce form-stable solid−liquid phase change materials from miscibility gap alloys.They allow to obtain a composite metallic material with good dispersion of low-melting active phase particles in a high-melting passive matrix,preventing leakage of the particles during phase transition and,therefore,increasing the stability of thermal response.Also,the matrix provides structural properties.The aim of this work is to combine conventional powder mixing techniques(simple mixing and ball milling)to improve active phase isolation and mechanical properties of an Al−Sn alloy.As matter of fact,ball milling of Sn powder allows to reduce hardness difference with Al powder;moreover,ball milling of the two powders together results in fine microstructure with improved mechanical properties.In addition,different routes applied showed that thermal response depends on the microstructure and,in particular,on the particle size of the active phase.In more detail,coarse active phase particles provide a fast heat release with small undercooling,while small particles solidify more slowly in a wide range of temperature.On the other hand,melting and,consequently,heat storage are independent of the particle size of the active phase.This potentially allows to“tailor”the thermal response by producing alloys with suitable microstructure.展开更多
An expression of degree of polarization(DOP) for metallic material is presented based on the three-component polarized bidirectional reflectance distribution function(p BRDF) model with considering specular reflec...An expression of degree of polarization(DOP) for metallic material is presented based on the three-component polarized bidirectional reflectance distribution function(p BRDF) model with considering specular reflection, directional diffuse reflection and ideal diffuse reflection. The three-component p BRDF model with a detailed reflection assumption is validated by comparing simulations with measurements. The DOP expression presented in this paper is related to surface roughness, which makes it more reasonable in physics. Test results for two metallic samples show that the DOP based on the three-component p BRDF model accords well with the measurement and the error of existing DOP expression is significantly reduced by introducing the diffuse reflection. It indicates that our DOP expression describes the polarized reflection properties of metallic surfaces more accurately.展开更多
A Phase-change thermal control unit( PTCU) filled with metallic phase change material( PCM) Bismuth alloy for electric devices thermal protection was developed and investigated experimentally. The PTCU filled with PCM...A Phase-change thermal control unit( PTCU) filled with metallic phase change material( PCM) Bismuth alloy for electric devices thermal protection was developed and investigated experimentally. The PTCU filled with PCM was designed and manufactured. Resistance heating components( RCHs) produced 1 W,3 W, 5 W,7W,and 10 W for simulating heat generation of electronic devices. At various heating power levels,the performance of PTCU were tested during heating period and one duty cycle period. The experimental results show that the PTCU delays RCH reaching the maximum operating temperature. Also,a numerical model was developed to enable interpretation of experimental results and to perform parametric studies. The results confirmed that the PTCU is suitable for electric devices thermal control.展开更多
Based on the three-component assumption that the reflection is divided into specular reflection,directional diffuse reflection,and ideal diffuse reflection,a bidirectional reflectance distribution function(BRDF) mod...Based on the three-component assumption that the reflection is divided into specular reflection,directional diffuse reflection,and ideal diffuse reflection,a bidirectional reflectance distribution function(BRDF) model of metallic materials is presented.Compared with the two-component assumption that the reflection is composed of specular reflection and diffuse reflection,the three-component assumption divides the diffuse reflection into directional diffuse and ideal diffuse reflection.This model effectively resolves the problem that constant diffuse reflection leads to considerable error for metallic materials.Simulation and measurement results validate that this three-component BRDF model can improve the modeling accuracy significantly and describe the reflection properties in the hemisphere space precisely for the metallic materials.展开更多
Biodegradable metals such as magnesium(Mg)and its alloys have attracted extensive attention in biomedical research due to their excellent mechanical properties and biodegradability.However,traditional casting,extrusio...Biodegradable metals such as magnesium(Mg)and its alloys have attracted extensive attention in biomedical research due to their excellent mechanical properties and biodegradability.However,traditional casting,extrusion,and commercial processing have limitations in manufacturing components with a complex shape/structure,and these processes may produce defects such as cavities and gas pores which can degrade the properties and usefulness of the products.Compared to conventional techniques,additive manufacturing(AM)can be used to precisely control the geometry of workpieces made of different Mg-based materials with multiple geometric scales and produce desirable medical products for orthopedics,dentistry,and other fields.However,a detailed and thorough understanding of the raw materials,manufacturing processes,properties,and applications is required to foster the production of commercial Mg-based biomedical components by AM.This review summarizes recent advances and important issues pertaining to AM of Mg-based biomedical products and discusses future development and application trends.展开更多
Although there are methods for testing the stress-strain relation and strength,which are the most fundamental and important properties of metallic materials,their application to small-volume materials and tube compone...Although there are methods for testing the stress-strain relation and strength,which are the most fundamental and important properties of metallic materials,their application to small-volume materials and tube components is lim-ited.In this study,based on energy density equivalence,a new dimensionless elastoplastic load-displacement model for compressed metal rings with isotropy and constitutive power law is proposed to describe the relations among the geometric dimensions,Hollomon law parameters,load,and displacement.Furthermore,a novel test method was developed to determine the elastic modulus,stress-strain relation,yield and tensile strength via ring compression test.The universality and accuracy of the method were verified within a wide range of imaginary materials using finite element analysis(FEA),and the results show that the stress-strain curves obtained by this method are consistent with those inputted in the FEA program.Additionally,a series of ring compression tests were performed for seven metallic materials.It was found that the stress-strain curves and mechanical properties predicted by the method agreed with the uniaxial tensile results.With its low material consumption,the ring compression test has the potential to be as an alternative to traditional tensile test when direct tension method is limited.展开更多
基金funded by Qin Chuang Yuan Talent Project in Shaanxi Province,China(QCYRCXM-2022-274).
文摘This article reviews the anti-penetration principles and strengthening mechanisms of metal materials,ranging from macroscopic failure modes to microscopic structural characteristics,and further summarizes the micro-macro correlation in the anti-penetration process.Finally,it outlines the constitutive models and numerical simulation studies utilized in the field of impact and penetration.From the macro perspective,nine frequent penetration failure modes of metal materials are summarized,with a focus on the analysis of the cratering,compression shear,penetration,and plugging stages of the penetration process.The reasons for the formation of adiabatic shear bands(ASBs)in metal materials with different crystal structures are elaborated,and the formation mechanism of the equiaxed grains in the ASB is explored.Both the strength and the toughness of metal materials are related to the materials’crystal structures and microstructures.The toughness is mainly influenced by the deformation mechanism,while the strength is explained by the strengthening mechanism.Therefore,the mechanical properties of metal materials depend on their microstructures,which are subject to the manufacturing process and material composition.Regarding numerical simulation,the advantages and disadvantages of different constitutive models and simulation methods are summarized based on the application characteristics of metal materials in high-speed penetration practice.In summary,this article provides a systematic overview of the macroscopic and microscopic characteristics of metal materials,along with their mechanisms and correlation during the anti-penetration and impact-resistance processes,thereby making an important contribution to the scientific understanding of anti-penetration performance and its optimization in metal materials.
基金Project(2011CB610302) supported by the National Basic Research Program of ChinaProjects(51074130,51134003) supported by the National Natural Science Foundation of ChinaProject(20110491699) supported by the National Science Foundation for Post-doctoral Scientists of China
文摘The FeCrA1 fiber was used to prepare porous metal materials with air-laid technology, and then followed by sintering at 1300 ℃ for a holding period of 2 h in the vacuum. In addition, a novel fractal soft, which was developed based on the fractal theory and the computer image processing technology, was explored to describe the pore structure of porous metal materials. Furthermore, the fractal dimension of pore structure was calculated by the soft and the effects of magnification and porosity on ffactal dimension were also discussed. The results show that the fractal dimension decreases with increase in the magnification, while it increases continuously with the porosity enhancing. The interrelationship between the fractal dimension and the magnification or porosity can be presented by the equation of D=α_0exp(-x/α_1)+α_2和D=k_2-(k_1-k_2)/[1+exp((θ-k_0)/k_3)], respectively.
基金Supported by National Basic Scientific Research Project(Grant No.JCKY2017110B001)Jiangsu Provincial Postgraduate Research&Practice Innovation Program of China(Grant No.KYCX20_0080)。
文摘With the rapid developments of marine resource exploitation,mounts of marine engineering equipment are settled on the ocean.When it is not possible to move the damaged equipment into a dry dock,welding operations must be performed in underwater environments.The underwater laser welding/cladding technique is a promising and advanced technique which could be widely applied to the maintenance of the damaged equipment.The present review paper aims to present a critical analysis and engineering overview of the underwater laser welding/cladding technique.First,we elaborated recent advances and key issues of drainage nozzles all over the world.Next,we presented the underwater laser processing and microstructural-mechanical behavior of repaired marine materials.Then,the newly developed powder-feeding based and wire-feeding based underwater laser direct metal deposition techniques were reviewed.The differences between the convection,conduction,and the metallurgical kinetics in the melt pools during underwater laser direct metal deposition and in-air laser direct metal deposition were illustrated.After that,several challenges that need to be overcame to achieve the full potential of the underwater laser welding/cladding technique are proposed.Finally,suggestions for future directions to aid the development of underwater laser welding/cladding technology and underwater metallurgical theory are provided.The present review will not only enrich the knowledge in the underwater repair technology,but also provide important guidance for the potential applications of the technology on the marine engineering.
基金Funded by National Natural Science Foundation of China(No.50571042)the Natural Science Foundation of Gansu Province of China(Nos.1208RJZA285,1208RJZA121)Lanzhou University of Technology(No.01-0278)
文摘Simulation method was designed to divide Laguerre diagram for right circle group with different weight; out-of-core incremental algorithm for Laguerre diagram was constructed; simulation program development and visualization was done and simulation was realized in user-specified arbitrary area for simulation of metal materials microstructure, which facilitated the practical application and secondary development of Laguerre diagram in the field of material science engineering. Finally, the utilization of a developed software package exemplified the simulation application of microstructure about metal materials and proved its validity.
文摘Optimization of scrap utilization, through maintaining a reasonable heavy scrap ratio, determination of scrap yield, development of substitutes for scrap, recycling of high-alloy scrap and optimization of scrap utilization technology, was investigated in this paper, in terms of the supply of metal materials, production cost, production quality and environment protection. Then, recycling of solid waste resources was discussed, and the utilization conditions and methods of slag-steel, slag-iron, steel-slag, etc. were determined. Finally, the management system for comprehensive resource utilization was introduced.
基金Project supported by the Natural Science Foundation of Chongqing(Grant No.CSTB2022NSCQ-MSX0391)。
文摘Based on the force-heat equivalence energy density principle,a theoretical model for magnetic metallic materials is developed,which characterizes the temperature-dependent magnetic anisotropy energy by considering the equivalent relationship between magnetic anisotropy energy and heat energy;then the relationship between the magnetic anisotropy constant and saturation magnetization is considered.Finally,we formulate a temperature-dependent model for saturation magnetization,revealing the inherent relationship between temperature and saturation magnetization.Our model predicts the saturation magnetization for nine different magnetic metallic materials at different temperatures,exhibiting satisfactory agreement with experimental data.Additionally,the experimental data used as reference points are at or near room temperature.Compared to other phenomenological theoretical models,this model is considerably more accessible than the data required at 0 K.The index included in our model is set to a constant value,which is equal to 10/3 for materials other than Fe,Co,and Ni.For transition metals(Fe,Co,and Ni in this paper),the index is 6 in the range of 0 K to 0.65T_(cr)(T_(cr) is the critical temperature),and 3 in the range of 0.65T_(cr) to T_(cr),unlike other models where the adjustable parameters vary according to each material.In addition,our model provides a new way to design and evaluate magnetic metallic materials with superior magnetic properties over a wide range of temperatures.
基金supported by the National Natural Science Foundation of China (Grant No.51805086)。
文摘Strong impact does serious harm to the military industries so it is necessary to choose reasonable cushioning material and design effective buffers to prevent the impact of equipment.Based on the capillary property entangled porous metallic wire materials(EPMWM),this paper designed a composite buffer which uses EPMWM and viscous fluid as cushioning materials under the low-speed impact of the recoil force device of weapon equipment(such as artillery,mortar,etc.).Combined with the capillary model,porosity,hydraulic diameter,maximum pore diameter and pore distribution were used to characterize the pore structure characteristics of EPMWM.The calculation model of the damping force of the composite buffer was established.The low-speed impact test of the composite buffer was conducted.The parameters of the buffer under low-speed impact were identified according to the model,and the nonlinear model of damping force was obtained.The test results show that the composite buffer with EPMWM and viscous fluid can absorb the impact energy from the recoil movement effectively,and provide a new method for the buffer design of weapon equipment(such as artillery,mortar,etc.).
基金supported by the National Natural Science Foundation of China(Nos.12005289 and 52071331)the National Key R&D Program of China(No.2019YFA0210000)the State Key Laboratory of Nuclear Detection and Electronics,University of Science and Technology of China(No.SKLPDE-KF-202316)。
文摘In this study,the interactions between a Ga-based liquid metal,GaInSn,and several metal materials,including pure metals(Ni and Ti)and alloys(316H stainless steel(SS)and GH3535),at 650℃were investigated.The aim was to evaluate the corrosion performance and select a suitable candidate material for use as a molten salt manometer diaphragm in thermal energy storage systems.The results indicated that the alloys(316H SS and GH3535)exhibited less corrosion than pure metals(Ni and Ti)in liquid GaInSn.Ga-rich binary intermetallic compounds were found to form on the surfaces of all the tested metal materials exposed to liquid GaInSn,as a result of the decomposition of liquid GaInSn and its reaction with the constituent elements of the metal materials.The corrosion mechanism for all the tested materials exposed to liquid GaInSn was also investigated and proposed,which may aid in selecting the optimal candidate material when liquid GaInSn is used as the pressure-sensing medium.
基金supported by the National Key R&D Program of China(Grant No.2020YFB2010500).
文摘Energy field-assisted machining technology has the potential to overcome the limitations of machining difficult-to-machine metal materials,such as poor machinability,low cutting efficiency,and high energy consumption.High-speed dry milling has emerged as a typical green processing technology due to its high processing efficiency and avoidance of cutting fluids.However,the lack of necessary cooling and lubrication in high-speed dry milling makes it difficult to meet the continuous milling requirements for difficult-to-machine metal materials.The introduction of advanced energy-field-assisted green processing technology can improve the machinability of such metallic materials and achieve efficient precision manufacturing,making it a focus of academic and industrial research.In this review,the characteristics and limitations of high-speed dry milling of difficult-to-machine metal materials,including titanium alloys,nickel-based alloys,and high-strength steel,are systematically explored.The laser energy field,ultrasonic energy field,and cryogenic minimum quantity lubrication energy fields are introduced.By analyzing the effects of changing the energy field and cutting parameters on tool wear,chip morphology,cutting force,temperature,and surface quality of the workpiece during milling,the superiority of energy-field-assisted milling of difficult-to-machine metal materials is demonstrated.Finally,the shortcomings and technical challenges of energy-field-assisted milling are summarized in detail,providing feasible ideas for realizing multi-energy field collaborative green machining of difficult-to-machine metal materials in the future.
基金National Natural Science Foundation of China(Grant No.52175162,51805086 and 51975123)Natural Science Foundation of Fujian Province(Grant No.2019J01210)Health education joint project of Fujian Province(Grant No.2019-WJ-01)。
文摘Composite materials exhibit the impressive mechanical properties of high damping and stiffness,which cannot be attained by employing conventional single materials.Along these lines,a novel material architecture is presented in this work in order to fabricate composites with enhanced mechanical characteristics.More specifically,entangled metallic wire materials were used as the active matrix,whereas polyurethane was employed as the reinforcement elements.As a result,an entangled metallic wire material-polyurethane composite with high damping and stiffness was prepared by enforcing the vacuum infiltration method.On top of that,the mechanical properties(loss factor,energy consumption,and average stiffness)of the proposed composite materials were characterized by performing dynamic tests,and its fatigue characteristics were verified by the micro-interface bonding,as well as the macro-damage factor.The impact of the density,preloading spacing,loading amplitude,and exciting frequency on the mechanical properties of the composites were also thoroughly analyzed.The extracted results indicate that the mechanical properties of the composites were significantly enhanced than those of the pure materials due to the introduction of interface friction.Moreover,the average stiffness of the composites was about 10 times the respective value of the entangled metallic wire material.Interestingly,a rise in the loading period leads to some failure between the composite interfaces,which reduces the stiffness property but enhances the damping dissipation properties.Finally,a comprehensive dynamic mechanical model of the composites was established,while it was experimentally verified.The proposed composites possess higher damping features,i.e.,stiffness characteristics,and maintain better fatigue characteristics,which can broaden the application range of the composites.In addition,we provide a theoretical and experimental framework for the research and applications in the field of metal matrix composites.
基金financial support provided by the National Natural Science Foundation of China(22075089)the Project of Science and Technology of Jieyang City(2019026)the Fundamental and Applied Fundamental Research Project of Zhuhai City(22017003200023).
文摘Distinct from"rockingchair"lithium-ion batteries(LIBs),the unique anionic intercalation chemistry on the cathode side of dual-ion batteries(DIBs)endows them with intrinsic advantages of low cost,high voltage,and ecofriendly,which is attracting widespread attention,and is expected to achieve the next generation of large-scale energy storage applications.Although the electrochemical reactions on the anode side of DIBs are similar to that of LIBs,in fact,to match the rapid insertion kinetics of anions on the cathode side and consider the compatibility with electrolyte system which also serves as an active material,the anode materials play a very important role,and there is an urgent demand for rational structural design and performance optimization.A review and summarization of previous studies will facilitate the exploration and optimization of DIBs in the future.Here,we summarize the development process and working mechanism of DIBs and exhaustively categorize the latest research of DIBs anode materials and their applications in different battery systems.Moreover,the structural design,reaction mechanism and electrochemical performance of anode materials are briefly discussed.Finally,the fundamental challenges,potential strategies and perspectives are also put forward.It is hoped that this review could shed some light for researchers to explore more superior anode materials and advanced systems to further promote the development of DIBs.
基金Project(2012CB619102) supported by National Basic Research Program of ChinaProject(31070847) supported by National Natural Science Foundation of China
文摘Extensive in vitro corrosion test systems have been carried out to simulate the in vivo corrosion behavior of biodegradable metallic materials. Various methods have their own unique benefits and limitations. The corrosion mechanism of biodegradable alloys and in vitro corrosion test systems on biodegradable metallic materials are reviewed, to build a reasonable simulated in vitro test system for mimicking the in vivo animal test from the aspects of electrolyte solution selection, surface roughness influence, test methods and evaluation methodology of corrosion rate. Buffered simulated body fluid containing similar components to human blood plasma should be applied as electrolyte solution, such as simulated body fluid (SBF) and culture medium with serum. Surface roughness of samples and ratio of solution volume to sample surface area should be adopted based on the real implant situation, and the dynamic corrosion is preferred. As to the evaluation methodology of corrosion rate, different methods may complement one another.
文摘Tongling Nonferrous Metals Group Holding Co.,Ltd.has signed a joint venture agreement with a subsidiary of Aero Engine Corporation of China,proposing to establish a JV to engage in the R&D and production of special aerial metal materials.Presently,the JV project
文摘Variable strain rate tension tests for 4 metallic materials show that as the strain rate in creases the strain hardening exponent n decreases. The trend follows a two stage linear relation between n and Ig (?). When (?) < (?)cp, i.e. under quasi-static loading, n can be considered as a constant, but when (?)>(?)cp, n decreases rapidly till an ideal plastic state. n = 0. The characterizations and mechanisms of softening induced by high (?) are discussed.
文摘Powder metallurgy processes are suitable to produce form-stable solid−liquid phase change materials from miscibility gap alloys.They allow to obtain a composite metallic material with good dispersion of low-melting active phase particles in a high-melting passive matrix,preventing leakage of the particles during phase transition and,therefore,increasing the stability of thermal response.Also,the matrix provides structural properties.The aim of this work is to combine conventional powder mixing techniques(simple mixing and ball milling)to improve active phase isolation and mechanical properties of an Al−Sn alloy.As matter of fact,ball milling of Sn powder allows to reduce hardness difference with Al powder;moreover,ball milling of the two powders together results in fine microstructure with improved mechanical properties.In addition,different routes applied showed that thermal response depends on the microstructure and,in particular,on the particle size of the active phase.In more detail,coarse active phase particles provide a fast heat release with small undercooling,while small particles solidify more slowly in a wide range of temperature.On the other hand,melting and,consequently,heat storage are independent of the particle size of the active phase.This potentially allows to“tailor”the thermal response by producing alloys with suitable microstructure.
文摘An expression of degree of polarization(DOP) for metallic material is presented based on the three-component polarized bidirectional reflectance distribution function(p BRDF) model with considering specular reflection, directional diffuse reflection and ideal diffuse reflection. The three-component p BRDF model with a detailed reflection assumption is validated by comparing simulations with measurements. The DOP expression presented in this paper is related to surface roughness, which makes it more reasonable in physics. Test results for two metallic samples show that the DOP based on the three-component p BRDF model accords well with the measurement and the error of existing DOP expression is significantly reduced by introducing the diffuse reflection. It indicates that our DOP expression describes the polarized reflection properties of metallic surfaces more accurately.
文摘A Phase-change thermal control unit( PTCU) filled with metallic phase change material( PCM) Bismuth alloy for electric devices thermal protection was developed and investigated experimentally. The PTCU filled with PCM was designed and manufactured. Resistance heating components( RCHs) produced 1 W,3 W, 5 W,7W,and 10 W for simulating heat generation of electronic devices. At various heating power levels,the performance of PTCU were tested during heating period and one duty cycle period. The experimental results show that the PTCU delays RCH reaching the maximum operating temperature. Also,a numerical model was developed to enable interpretation of experimental results and to perform parametric studies. The results confirmed that the PTCU is suitable for electric devices thermal control.
文摘Based on the three-component assumption that the reflection is divided into specular reflection,directional diffuse reflection,and ideal diffuse reflection,a bidirectional reflectance distribution function(BRDF) model of metallic materials is presented.Compared with the two-component assumption that the reflection is composed of specular reflection and diffuse reflection,the three-component assumption divides the diffuse reflection into directional diffuse and ideal diffuse reflection.This model effectively resolves the problem that constant diffuse reflection leads to considerable error for metallic materials.Simulation and measurement results validate that this three-component BRDF model can improve the modeling accuracy significantly and describe the reflection properties in the hemisphere space precisely for the metallic materials.
基金This work was financially supported by the Guangdong Basic and Applied Basic Research Foundation(No.2020B1515120078,2021A1515111140,and 2021B1515120059)National Key Research and Development Project of China(No.2020YFC1107202)+3 种基金Science Research Cultivation Program(PY2022002)Science and Technology Planning Project of Guangzhou(No.202206010030)City University of Hong Kong Donation Research Grants[DONRMG No.9229021 and 9220061]as well as City University of Hong Kong Strategic Research Grant[SRG 7005505].
文摘Biodegradable metals such as magnesium(Mg)and its alloys have attracted extensive attention in biomedical research due to their excellent mechanical properties and biodegradability.However,traditional casting,extrusion,and commercial processing have limitations in manufacturing components with a complex shape/structure,and these processes may produce defects such as cavities and gas pores which can degrade the properties and usefulness of the products.Compared to conventional techniques,additive manufacturing(AM)can be used to precisely control the geometry of workpieces made of different Mg-based materials with multiple geometric scales and produce desirable medical products for orthopedics,dentistry,and other fields.However,a detailed and thorough understanding of the raw materials,manufacturing processes,properties,and applications is required to foster the production of commercial Mg-based biomedical components by AM.This review summarizes recent advances and important issues pertaining to AM of Mg-based biomedical products and discusses future development and application trends.
基金Supported by National Natural Science Foundation of China(Grant Nos.11872320 and 12072294)
文摘Although there are methods for testing the stress-strain relation and strength,which are the most fundamental and important properties of metallic materials,their application to small-volume materials and tube components is lim-ited.In this study,based on energy density equivalence,a new dimensionless elastoplastic load-displacement model for compressed metal rings with isotropy and constitutive power law is proposed to describe the relations among the geometric dimensions,Hollomon law parameters,load,and displacement.Furthermore,a novel test method was developed to determine the elastic modulus,stress-strain relation,yield and tensile strength via ring compression test.The universality and accuracy of the method were verified within a wide range of imaginary materials using finite element analysis(FEA),and the results show that the stress-strain curves obtained by this method are consistent with those inputted in the FEA program.Additionally,a series of ring compression tests were performed for seven metallic materials.It was found that the stress-strain curves and mechanical properties predicted by the method agreed with the uniaxial tensile results.With its low material consumption,the ring compression test has the potential to be as an alternative to traditional tensile test when direct tension method is limited.