Distribution of 26 Metals in the Waters of the Aquatic Ecosystems of the Cotonou Channel and Lake Nokoué, Benin

Metallic elements have various origins: natural and anthropogenic sources as geochemical, marine and atmospheric sources resulting from the fallout of pollutants emitted or dust raised and which are transported by water and air currents. Thus marine, brackish and fresh continental waters may have high metal concentrations. In addition, some essential metals can become toxic above certain concentration values in aquatic environments. The aquatic ecosystems of Cotonou channel and lake Nokoué receive the pollutants charges from the town cities of Cotonou, Abomey-Calavi and town hall of So Ava. The aim of this study is to analyze waters from Eighteen (18) stations identified in the two ecosystems (nine by ecosystem). The concentrations of magnesium (Mg), calcium (Ca), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), arsenic (As), selenium (Se), cadmium (Cd), beryllium (Be), aluminum (Al), strontium (Sr), molybdenum (Mo), silver (Ag), tin (Sn), barium (Ba), platinum (Pt), mercury (Hg), thallium (Tl), lead (Pb), thorium (Th) and uranium (U) were measured after acid digestion of the water samples using the inductively coupled plasma source mass spectrometer (ICP-MS). The results of the analyses indicate an unequal distribution of metals in the different ecosystems. However, atypical concentrations were observed at some stations of the lake and the channel. Magnesium, calcium and manganese have very high values in Lake Nokoué respectively at Ganvié market station GAN_M (2990 ± 105 mg/L), Ganvié center, station GAN_C (4991 ± 177 mg/L) and Lake middle station MLak4 (10662 ± 17.03 μg/L). On the other hand, iron, aluminum and strontium have very high concentrations in the Cotonou Channel respectively at Agbato station AGB (5236 ± 103 and 8289 ± 519 μg/L) and at the estuary station EST (6118 ± 68 μg/L). The concentrations were compared to wells and cborehole waters in sixth neighborhood of Cotonou. We have used statistical analyzers such as MANOVA which have made it possible to classify the waters and metals in the ecosystems studied compared to groundwater and Well water waters. We use hierarchical clustering on principal components to identify similarities between stations based on metal concentration with R software packages “FactoMineR” and “factoextra”. In general, we can conclude that most of the metals have an anthropogenic source except strontium and major elements (Ca and Mg) which could respectively provide from marine waters and geochemical sources.

Heavy Metal Pollution and Ecological Risk Assessment in Sediments of Xiling Channel Inland Waterway of Guangdong Province

Using the sediment monitoring data of five sections of the Xiling Channel inland waterway of the Pearl River Delta,and using Nemerow composite index,the coefficient of variation,and the index of geoaccumulation( Igeo) and the potential ecological risk index,this paper analyzed and assessed the heavy metal pollution of sediments. The results indicate that Cr reached mild pollution;Cu had a large degree of variation,and the changes of Cr and Zn were significant with fluctuation;the enrichment of heavy metals decreased as follows: Cd > Cu > Cr > Zn> Pb > Ni > Hg > As;Cd had the highest degree of enrichment and belonged to moderate pollution;the ecological hazard of heavy metals was Cd > Hg > Cu > Pb > As > Cr > Ni > Zn,and Cd had the highest ecological hazard and was the main controlling factor of potential ecological risk. In conclusion,the sediments in Xiling Channel inland waterway were polluted by heavy metals to some extent,and cadmium was the main pollutant and had the largest potential ecological risk.

Uniform Flow of Molten Metals in Rectangular Open Channels

The flow of liquids in open channels has been studied since ancient Rome. However, the vast majority of published reports on flow in open channels are focused on the transport of drinking water and sewage disposal. The literature on the transport of molten metals in open channels is quite scarce. In this work, the uniform flow of pig iron and molten aluminum in rectangular open channels is studied. Specific energy curves are constructed and critical heights are analytically determined. The transition from subcritical to supercritical flow is analyzed as a function of the angle of inclination of the channel and the roughness of its walls. Manning’s equation is applied to the pig iron flow using data reported in the literature for molten aluminum. The need to correct the roughness coefficient for pig iron is observed in order to obtain results consistent with those previously reported.

The study on mechanism and model of negative bias temperature instability degradation in P-channel metal-oxide-semiconductor field-effect transistors

Negative Bias Temperature Instability （NBTI） has become one of the most serious reliability problems of metaloxide-semiconductor field-effect transistors （MOSFETs）. The degradation mechanism and model of NBTI are studied in this paper. From the experimental results, the exponential value 0.25-0.5 which represents the relation of NBTI degradation and stress time is obtained. Based on the experimental results and existing model, the reaction-diffusion model with H^＋ related species generated is deduced, and the exponent 0.5 is obtained. The results suggest that there should be H^＋ generated in the NBTI degradation. With the real time method, the degradation with an exponent 0.5 appears clearly in drain current shift during the first seconds of stress and then verifies that H^＋ generated during NBTI stress.

Superior material qualities and transport properties of InGaN channel heterostructure grown by pulsed metal organic chemical vapor deposition

Pulsed metal organic chemical vapor deposition is introduced into the growth of InGaN channel heterostructure for improving material qualities and transport properties. High-resolution transmission electron microscopy imaging shows the phase separation free InGaN channel with smooth and abrupt interface. A very high two-dimensional electron gas density of approximately 1.85 x 10^13 cm-2 is obtained due to the superior carrier confinement. In addition, the Hall mobility reaches 967 cruZ/V-s, owing to the suppression of interface roughness scattering. Furthermore, temperature-dependent Hall measurement results show that InGaN channel heterostructure possesses a steady two-dimensional electron gas density over the tested temperature range, and has superior transport properties at elevated temperatures compared with the traditional GaN channel heterostructure. The gratifying results imply that InGaN channel heterostructure grown by pulsed metal organic chemical vapor deposition is a promising candidate for microwave power devices.

Breakdown voltage enhancement in GaN channel and AlGaN channel HEMTs using large gate metal height

A large gate metal height technique is proposed to enhance breakdown voltage in GaN channel and AlGaN channel high-electron-mobility-transistors(HEMTs).For GaN channel HEMTs with gate-drain spacing LGD=2.5μm,the breakdown voltage VBR increases from 518 V to 582 V by increasing gate metal height h from 0.2μm to 0.4μm.For GaN channel HEMTs with LGD=7μm,VBR increases from 953 V to 1310 V by increasing h from 0.8μm to 1.6μm.The breakdown voltage enhancement results from the increase of the gate sidewall capacitance and depletion region extension.For Al0.4Ga0.6N channel HEMT with LGD=7μm,VBR increases from 1535 V to 1763 V by increasing h from 0.8μm to 1.6μm,resulting in a high average breakdown electric field of 2.51 MV/cm.Simulation and analysis indicate that the high gate metal height is an effective method to enhance breakdown voltage in GaN-based HEMTs,and this method can be utilized in all the lateral semiconductor devices.

Unsteady Non-Uniform Flow of Molten Metals in Rectangular Open Channels

In the metallurgical industries, it is very important to characterize the flow of molten metals in open channels given that they are transported through these devices to different plant sections. However, unlike the flow of water which has been studied since ancient times, the flow of molten metals in open channels has received little attention. The unsteady non-uniform flow of blast furnace molten pig iron in a rectangular open channel is analyzed in this work by numerical solution of the Saint-Venant equations. The influence of mesh size on the convergence of molten metal height is studied to determine the proper mesh and time step sizes. A sinusoidal inflow pulse is imposed at the entrance of the channel in order to analyze the propagation of the resulting wave. The influence of the angle of inclination of the channel and the roughness coefficient of the walls on the amplitude and the dynamic behavior of the height of the molten metal are analyzed. Phase portraits of the channel state variables are constructed and interpreted. Numerical simulations show that as the angle of inclination of the channel increases, the amplitude of the formed wave decreases. From 10 degrees onwards, the peak of the wave descends even below the initial height. On the other hand, the roughness coefficient affects the molten pig iron height profiles in an inverse way than the angle of inclination. The amplitude of the formed wave increases as the roughness coefficient increases.

兆瓦级双馈机组齿轮箱高速轴轴系故障分析及预防方法

兆瓦级双馈机组齿轮箱高速轴轴系随运行年限增加出现断齿、窜动、轴承高温、轴承跑圈等故障。针对这些问题,根据实际运行数据,从轴系润滑、轴承装配、对中维护三方面分析故障原因,提出齿轮箱“四步”清洗、轴承孔金属修复、安装窜动预警装置等维护、保养和预防措施。机组实际运行结果证明该方法有效,可供技术人员在解决类似问题时参考。

液态金属冷却快堆子通道分析软件SACOS-LMR研发与工程应用

子通道分析方法是反应堆堆芯设计和热工水力分析的重要手段之一,对于我国提出的压水堆-快堆-聚变堆三步走核能发展战略,开发适用于液态金属冷却快堆热工安全分析的子通道分析程序具有重要意义。本文基于西安交通大学热工水力研究室自主开发的压水堆子通道程序SACOS,通过添加液态金属快堆特有的模型,如绕丝模型、盒间流模型、液态金属对流换热模型等,扩展至适用于液态金属快堆的子通道分析程序SACOS-LMR,该程序具备对液态金属快堆组件开展稳态和瞬态热工水力分析的功能。结合卡尔斯鲁厄开展的37棒钠冷瞬态实验,完成了SACOS-LMR程序的瞬态功能验证。基于验证后的SACOS-LMR程序,对欧洲铅冷快堆(ALFRED)堆芯开展了稳态工况和瞬态事故工况下的热工安全特性分析,计算结果合理,且与同类程序保持一致,表明SACOS-LMR程序可用于液态金属快堆的堆芯设计和热工水力分析研究。

质子交换膜燃料电池金属双极板流道结构及制造工艺

金属双极板因具有强度高、导电性和传热能力好、能量损失小、密封性好等优势,且加工方便、加工成本低、可制造超薄厚度及高体积比功率等特性,逐渐成为双极板材料的首选,而流道结构设计和制造工艺是影响金属双极板成形质量和工作性能的关键。对比了金属双极板常用传统流道结构与新型流道结构,分析了结构变化对燃料电池性能的影响;梳理了金属双极板的冲压成形、液压成形、软膜成形、辊轧成形、电磁成形、特种成形等塑性成形工艺技术及成形装备;最后对金属双极板的流道结构设计与制造工艺进行了展望。

Surface topography evolvement of galvanized steels in sheet metal forming

U-channel forming tests were performed to investigate the surface topography evolvement of hot-dip galvanized(GI) and galvannealed(GA) steels and the effects of die hardness on sheet metal forming(SMF). Experimental results indicate that the surface roughness values of the two galvanized steels increase with the number of forming,i.e.,the surface topographies of galvanized steels are roughened in SMF. Moreover,GI steel has a better ability of damage-resistance than GA steel. The mechanisms of topography evolvement are different in the forming of GI and GA steels. Scratch is the main form of surface damage in the forming of GI steels. The severity of scratch can be decreased by increasing die hardness. GA steel results in exfoliating of the coating firstly and then severe scratching. The surface topography of galvannealed steels can be improved by increasing die hardness. However,the hardness should not be too high.

An analytical threshold voltage model for dual-strained channel PMOSFET

Based on the analysis of vertical electric potential distribution across the dual-channel strained p-type Si/strained Si1-xGex/relaxd Si1-yGey（s-Si/s-SiGe/Si1-yGey） metal-oxide-semiconductor field-effect transistor （PMOSFET）, analytical expressions of the threshold voltages for buried channel and surface channel are presented. And the maximum allowed thickness of s-Si is given, which can ensure that the strong inversion appears earlier in the buried channel （compressive strained SiGe） than in the surface channel （tensile strained Si）, because the hole mobility in the buried channel is higher than that in the surface channel. Thus they offer a good accuracy as compared with the results of device simulator ISE. With this model, the variations of threshold voltage and maximum allowed thickness of s-Si with design parameters can be predicted, such as Ge fraction, layer thickness, and doping concentration. This model can serve as a useful tool for p-channel s-Si/s-SiGe/Si1-yGey metal-oxide-semiconductor field-effect transistor （MOSFET） designs.

Transport of yttrium metal ions through fibers supported liquid membrane solvent extraction

A novel idea of transport of yttrium(Ⅲ) metal ions through fibers supported liquid membrane in two stage processes namely source to membrane and membrane to receiving phase has been proposed.The fibers supported liquid membrane was impregnated with different concentrations carrier.The experimental variables explored were concentration of yttrium(Ⅲ) ions,pH of source phase,PC-88A concentration in membrane phase,acid concentration in receiving phase and stirring speed.The pre-concentration of yttrium(Ⅲ) ions ...

Direct simulation of MHD flows in dual-coolant liquid metal fusion blanket using a consistent and conservative scheme

Direct simulation of 3-D MHD(magnetohydrodynamics) flows in liquid metal fusion blanket with flow channel insert(FCI) has been conducted.Two kinds of pressure equilibrium slot (PES) in FCI,which are used to balance the pressure difference between the inside and outside of FCI,are considered with a slot in Hartmann wall or a slot in side wall,respectively.The velocity and pressure distribution of FCI made of SiC/SiC_f are numerically studied to illustrate the 3-D MHD flow effects,which clearly show that the flows in fusion blanket with FCI are typical three-dimensional issues and the assumption of 2-D fully developed flows is not the real physical problem of the MHD flows in dual-coolant liquid metal fusion blanket.The optimum opening location of PES has been analyzed based on the 3-D pressure and velocity distributions.

Experimental Base of an Innovation S-Channel to Reduce MHD Pressure Drop

Consequent on MHD geometry sensibility phenomena was measured in an accident case;the more detail experiments have been conducted at the liquid metal experimental loop upgrade facility (LMEL-U). The experimental results indicate that MHD pressure drop can be greatly reduced in the special designed ducts. Base on the experimental data, an innovation channel concept (tentatively called as the secondary flow channel, short in “S-channel”) is addressed as a reducing MHD pressure drop channel for the application of a liquid metal blanket system in fusion reactor. It may be a dawn for solving MHD pressure drop key issue of liquid metal blanket system.

10 nm金属氧化物半导体场效应晶体管中的热噪声特性分析

随着金属氧化物半导体场效应晶体管(MOSFET)器件等比例缩小至纳米级的较小尺寸,一方面导致的短沟道效应已严重影响热噪声;另一方面使栅、源、漏区及衬底区的热噪声占有比越来越高,而传统热噪声模型主要考虑较大尺寸器件的沟道热噪声,且其模型未考虑到沟道饱和区.本文针对小尺寸纳米级MOSFET器件,并根据器件结构特征和热噪声的基本特性,建立了10 nm器件的热噪声模型,该模型体现沟道区、衬底区及栅、源、漏区,同时考虑到沟道饱和区的热噪声.在模型的基础上,分析沟道热噪声、总热噪声随偏置参量及器件参数之间的关系,验证了沟道饱和区热噪声的存在,并与已有实验结果一致,所得结论有助于提高纳米级小尺寸MOSFET器件的工作效率、寿命及响应速度等.

一次触发闪电金属汽化通道的亮度与电流特征

2022年夏季在广州从化人工引雷试验场的一次触发闪电过程中,获取了近距离的高分辨率图像、通道底部电流波形和高速摄像数据。此次触发闪电的高分辨率图像清晰展现了多回击过程金属汽化通道段的空间位移,汽化通道在连续电流过程中呈现类似火焰的发光特征。结合高速摄像与通道底部电流数据,研究回击与连续电流过程中金属汽化通道段亮度与电流强度的相关性,结果表明:相比于回击峰值电流,其平方与回击峰值亮度的相关性更强,相关系数分别为0.940和0.955(均达到0.001显著性水平)。对于伴随长连续电流的回击过程,回击下降部分与之后连续电流过程光电线性相关性拟合的斜率有明显差异。叠加在长连续电流过程上的多个M分量脉冲亮度峰值相对于电流峰值时间滞后,较小的脉冲峰值电流对应较大的亮度峰值滞后时间。