Flexible, Transparent and Conductive Metal Mesh Films with Ultra‑High FoM for Stretchable Heating and Electromagnetic Interference Shielding

Despite the growing demand for transparent conductive films in smart and wearable electronics for electromagnetic interference(EMI)shielding,achieving a flexible EMI shielding film,while maintaining a high transmittance remains a significant challenge.Herein,a flexible,transparent,and conductive copper(Cu)metal mesh film for EMI shielding is fabricated by self-forming crackle template method and electroplating technique.The Cu mesh film shows an ultra-low sheet resistance(0.18Ω□^(-1)),high transmittance(85.8%@550 nm),and ultra-high figure of merit(>13,000).It also has satisfactory stretchability and mechanical stability,with a resistance increases of only 1.3%after 1,000 bending cycles.As a stretchable heater(ε>30%),the saturation temperature of the film can reach over 110°C within 60 s at 1.00 V applied voltage.Moreover,the metal mesh film exhibits outstanding average EMI shielding effectiveness of 40.4 dB in the X-band at the thickness of 2.5μm.As a demonstration,it is used as a transparent window for shielding the wireless communication electromagnetic waves.Therefore,the flexible and transparent conductive Cu mesh film proposed in this work provides a promising candidate for the next-generation EMI shielding applications.

基于机器视觉的大面积触控屏Metal Mesh缺陷检测

由于在大面积触控屏Metal Mesh的生产过程中,曝光机在长时间运行时会出现运行轨迹偏离,造成金属网断线和毛刺等问题.对此,设计了一种用于检测金属网缺陷的机器视觉检测系统,该机器视觉系统能通过工业摄像机采集图像,然后进行图像增强算法祛除环境干扰,Canny边缘检测算法划定图像边界,能快速检测出缺陷和其坐标位置.

Evaluation of Fracture Resistance for Autopolymerizing Acrylic Resin Materials Reinforced with Glass Fiber Mesh, Metal Mesh and Metal Wire Materials: An in Vitro Study

Statement of problem: Many processes have been applied to improve the fracture resistance of acrylic resin dentures by reinforcing them. The maximum goal of any denture repair is to restore the main strength of the denture and to avoid further fracture. Purpose: This study investigated the ability of self-curing acrylic resin to be strength and deflection of repaired acrylic resin joints reinforced with various reinforcement materials to resist fracture. Material and methods: Transverse strength of polymethyl methacrylate acrylic resin reinforced with glass fiber mesh, metal mesh, and metal wire was evaluated with a 3-point load test on 40 intact specimens (n = 10 for control group) (n = 10 per each reinforcement material group). Fractured joint margins were rounded, a 4-mm gap was placed between them, and then they were repaired with autopolymerizing acrylic resin and retested. Results: Transverse strength for the polymethyl methacrylate acrylic resin samples has showed fracture at the side of sample rather than in the middle area of reinforcement materials and some other samples showed bending statue rather than fracture. Conclusion: Reinforcement with glass fiber mesh, metal mesh, and metal wire produced transverse strength in the side area of resin denture base material rather than in the middle of reinforcement area with bending samples rather than fracture response.

Additive Manufacturing of Large-scale Metal Mesh with Core-shell Composite Structure for Transparent Electromagnetic Shielding/glass Heater

Transparent electromagnetic(EM)shielding glass with a metal mesh has significant potential for application in different fields of EM radiation and anti-EM interference light-transmitting observation windows.In particular,a transparent EM-shielding glass with a large-aspect-ratio metal mesh can effectively alleviate the contradictory problems of shielding effectiveness and light-transmission performance constraints.However,the fabrication of high-aspect-ratio metal meshes on glass substrates has problems such as high cost,complex processes,low efficiency,small area,and easy damage issues,which limit their application in the field of high-performance,transparent EM-shielding glass.Therefore,this paper proposes a composite additive manufacturing process based on electric-field-driven microjet 3D printing and electroplating.By fabricating metal meshes with an Ag-Cu core-shell structure on a glass substrate,EM-shielding glass with high shielding efficiency and light transmission can be manufactured without increasing the aspect ratio of the metal meshes.The prepared Ag-Cu composite metal mesh has excellent optoelectronic properties(period 250𝜇m,line width 10𝜇m,90.1%transmission at 550 nm visible light,square resistance 0.21Ω/sq),efficient electrothermal effect(3 V DC voltage can reach 189°C steady-state temperature),stable EM-shielding effectiveness(average shielding effectiveness 23 dB at X-band),and acceptable mechanical and environmental stability(less than 3%change in square resistance after 150-times adhesion test and less than 6%and 0.6%change in resistance after 72 h in acid and alkali environments,respectively).This method provides a new solution for the mass production of high-performance large-area transparent electric heating/EM-shielding glass.

Infrared transparent frequency selective surface based on iterative metallic meshes

In this paper, we present an infrared transparent frequency selective surface（ITFSS） based on iterative metallic meshes, which possesses the properties of high transmittance in infrared band and band-pass effect in millimeter wave band. Cross-slot units are designed on the iterative metallic meshes, which is composed of two same square metallic meshes with a misplaced overlap. In the infrared band of 3–5 μm, the ITFSS has an average transmittance of 80% with a Mg F2 substrate. In the millimeter wave band, a transmittance of-0.74 d B at the resonance frequency of 39.4 GHz is obtained. Moreover, theoretical simulations of the ITFSS diffractive characteristics and transmittance response are also investigated in detail. This ITFSS may be an efficient way to achieve the metamaterial millimeter wave/infrared functional film.

基于FES技术的O_(2)/CO_(2)燃烧气氛下准东煤中不同类型碱金属盐的释放特性

O_(2)/CO_(2)燃烧技术被认为是一种清洁的燃煤发电技术,然而高碱准东煤燃烧过程中释放的大量碱金属通常是引起锅炉受热面积灰、结渣以及腐蚀的重要物质,严重危害了设备的安全稳定运行。因此,探讨O_(2)/CO_(2)燃烧气氛下准东煤中不同类型碱金属盐的释放特性对于煤炭的清洁高效利用具有重要意义。基于火焰发射光谱技术(FES),在金属丝网反应器上研究了煤粉燃烧过程中不同类型碱金属盐在O_(2)/N_(2)和O_(2)/CO_(2)两种气氛下的释放特性。结果表明:在O_(2)/N_(2)气氛下,挥发分燃烧会产生明亮的火焰;与O_(2)/N_(2)气氛相比,O_(2)/CO_(2)气氛下煤粉燃烧强度降低,火焰温度下降,着火时间延迟,挥发分和焦炭的燃烧时间延长,使得煤粉中气相Na的释放过程受到抑制。对于NaAc、Na_(2)CO_(3)和Na_(2)SO_(4)来讲,O_(2)/CO_(2)气氛延迟了其释放过程中质量浓度降低的时间,使煤粉中气相Na从开始释放就进入稳定释放阶段,气相Na质量浓度变化率波动不大;但NaCl会在释放的4 s左右质量浓度变化率变为负值,导致释放的气相Na质量浓度一直降低。同时CO_(2)气氛还会使得NaAc、NaCl等类型盐转化形成更难释放的Na_(2)CO_(3),进一步抑制气相Na的释放过程。而Na_(2)CO_(3)的质量释放率在O_(2)/CO_(2)气氛下也降低的主要原因则是CO_(2)抑制了Na_(2)CO_(3)向Na_(2)O的分解过程。Na_(2)SO_(4)则由于其本身释放就比较困难,因此其质量释放率降低的主要原因是燃料燃烧温度和强度降低导致的。

Understanding of the Relationship between the Properties of Cu(In,Ga)Se_(2) Solar Cells and the Structure of Ag Network Electrodes

The relation between the structure of the silver network electrodes and the properties of Cu(In,Ga)Se_(2)(CIGS)solar cells is systemically investigated.The Ag network electrode is deposited onto an Al:ZnO(AZO)thin film,employing a self-forming cracked template.Precise control over the cracked template's structure is achieved through careful adjustment of temperature and humidity.The Ag network electrodes with different coverage areas and network densities are systemically applied to the CIGS solar cells.It is revealed that predominant fill factor(FF)is influenced by the figure of merit of transparent conducting electrodes,rather than sheet resistance,particularly when the coverage area falls within the range of 1.3–5%.Furthermore,a higher network density corresponds to an enhanced FF when the coverage areas of the Ag networks are similar.When utilizing a thinner AZO film,CIGS solar cells with a surface area of 1.0609 cm^(2)exhibit a notable performance improvement,with efficiency increasing from 10.48%to 11.63%.This enhancement is primarily attributed to the increase in FF from 45%to 65%.These findings underscore the considerable potential for reducing the thickness of the transparent conductive oxide(TCO)in CIGS modules with implications for practical applications in photovoltaic technology.

金属网力学性能的数值模拟分析

以下峪口矿辅运大巷锚网支护中的金属网为研究对象,采用Abaqus数值模拟软件,模拟分析了金属网的网目边长、网目形状、网丝直径对金属网力学性能的影响,为金属网的加工和选择提供了依据。

双氢氧化物修饰镍金属网提升电磁屏蔽性能

针对镍金属网在电磁屏蔽中的低吸收效能(SE_(A))和较高反射(SE_(R))问题,通过电沉积方法在镍金属网(NM)表面负载镍铁双氢氧化物(NiFe LDH)纳米片,旨在提升材料的以吸收为主的屏蔽性能。处理后材料的微观结构和电磁特性得到显著改善,尤其是在X波段内实现了优异的56 dB的SE_(A)和2 dB的SE_(R)。同时,NiFe LDH纳米片优化了介电常数、磁导率、衰减常数和阻抗匹配,证明其在电磁屏蔽领域的广泛应用前景,合成简单且成本效益高。

等距螺旋锥齿轮的精确建模与金属粉末注射成型工艺试制

等距螺旋锥齿轮作为一种新型锥齿轮,其螺旋齿面具有法向等距的特点,适用于金属粉末注射成型工艺批量化生产。根据坐标变换理论推导出球面渐开线和等距圆锥螺旋线的参数方程,再基于齿面形成原理建立齿面数学模型;在MATLAB中对齿面数学模型编程计算出齿面离散点坐标,并通过UG逆向工程完成等距螺旋锥齿轮的精确建模;利用ANSYS仿真分析等距螺旋锥齿轮的啮合接触,得出齿轮的传动性能;最后通过金属粉末注射成型工艺完成等距螺旋锥齿轮的试制。研究结果表明,齿面数学模型结合离散点逆向建模可确保模型的精度,金属粉末注射成型工艺可用于等距螺旋锥齿轮的批量化生产。

基于midas Gen的单层球形网壳结构分析及应用研究

基于midas Gen软件模型,在不同应力比下对实体工程金属网壳模型进行分析,获得了工程实体金属网壳模型静力荷载下铸钢铰支座反力、罕遇地震时铸钢铰支座反力、静力荷载销轴反力、罕遇地震销轴反力分布情况。将设计模型得到的实体工程金属网壳荷载–位移曲线与有关设计模型网壳荷载–位移曲线进行对比,通过实体工程金属网壳模型设计实例,分析了不同应力下的杆件位移情况,从而证明了实体工程金属网壳模型设计的准确性及合理性。

金属网格-透明导电氧化物复合型透明电极的瑞利分析和仿真

以氧化铟锡(indium tin oxide,ITO)为代表的透明导电氧化物(transparent conducting oxide,TCO)在当前光电器件中的重要性日益增长.通过在TCO中引入金属网格构成复合电极,可以在保持良好透明性的前提下有效提升电学性能,同时降低对铟的需求量,并为可穿戴设备所需的柔性电极提供可能方案.对此类电极的电学性能分析,如复合电极方阻随金属网格结构参数的变化,可为电极设计与制备提供基本的出发点,但相关理论尚十分缺乏.本文针对典型的方孔方格型金属网格-TCO复合电极,分别展开基于瑞利模型和基于有限元仿真的电学性能分析.结果表明,孔型近似导致的金属通道显著畸变是复合电极的电学计算中瑞利模型在中高开口率下失效的主要原因.据此,我们采用格型修正,通过提升瑞利模型中的原胞外边界对称性来改善金属通道的畸变.与电极仿真的对比表明,修正后瑞利模型的适用范围明显扩大,其结果可与实验数据很好地拟合,为此类复合透明电极的电学数据分析与结构设计提供了简洁高效的理论工具.

基于超快激光定域去除的Cu/Ag复合金属网格透明电极性能优化研究

[目的]Ag网格透明电极方块电阻低,但反射率高。[方法]在钠钙玻璃基底表面利用等离子射频磁控溅射沉积Cu/Ag复合金属薄膜,然后采用飞秒脉冲激光定域去除金属层,获得Cu/Ag复合金属网格透明电极。分析了激光能量密度、激光扫描速率和激光扫描线重叠率对电极材料去除的影响机制。[结果]在激光能量密度1.4 J/cm^(2)、激光扫描速率300 mm/s和激光扫描线重叠率70%的工艺参数下获得了综合光电性能最为出色的Cu/Ag复合金属网格透明电极,其平均透光率为87.58%,方块电阻为2.15Ω,品质因子为1.235×10^(-1)Ω^(-1)。[结论]该电极的综合性能与传统商用ITO(掺锡氧化铟)透明电极相比有巨大提升。

玻璃纤维/环氧树脂/不锈钢网复合材料性能研究

为研究金属网厚度、金属网粒度、上层预浸料厚度和铺层角度对复合材料力学性能的影响。制备了1.8 mm厚度的9组玻璃纤维/环氧树脂/不锈钢网复合材料,对其进行正交试验仿真分析,并与试验结果对比。结果表明:仿真与试验的最大偏差为4.36%,证明仿真结果可靠。当金属网厚度为0.4 mm,粒度为590μm,上层预浸料厚度为0.9 mm,铺层角度为0°时力学性能最优。

锚网−围岩接触面注浆充填预应力施加技术

针对松软煤体巷道护表构件主动支护效应差、局部裸露围岩破碎范围持续扩大导致的锚杆、锚索失效问题,开发了网后注浆面型预应力施加技术并进行了实验室试验及现场验证。首先分析了锚网支护围岩变形破坏方式及控制方法,阐述了网后注浆技术原理;其次开展了不同规格型号金属网的网后注浆实验室试验,分别得到了主动面型预应力施加过程中锚杆受力、注浆压力、护表构件变形量及面应力演化规律;最后开展了现场工况下的顶板及两帮网后注浆试验,得到了护表构件在一定变形量前提下的面型预应力施加值,验证了网后注浆技术的适用性。研究结果表明:①金属网与煤壁之间存在间隙是导致支护系统主动支护能力差和锚杆、锚索支护失效的主控因素,围绕金属网与煤壁接触面凹凸不平的结构间隙进行注浆填充、全面封闭围岩是完善锚网支护系统的技术手段;②在金属网与围岩之间进行注浆充填可实现面型主动预应力的施加,面应力变化趋势主要分为:初始面应力恒定阶段、面应力上升阶段、面应力降低至稳定阶段;③网后注浆过程中,面应力变化趋势与注浆压力、金属网变形量紧密相关,面应力上升过程中,注浆压力、金属网变形量也随之升高;④网后注浆可缓解锚杆托盘应力集中程度,面应力上升过程中可使得应力集中的锚杆预紧力呈现出小幅度降低趋势,受力较为均匀的锚杆预紧力呈现出同步上升趋势。所得研究成果有望成为锚杆支护配套技术,为复杂困难巷道治理提供技术储备与理论参考。

金属网基油水分离材料的制备与应用

特异性润湿材料为处理含油污水的新型材料。在各种润湿性材料中,聚合物材料存在表面活性剂污染及降解等缺陷,而金属网基材料具有较好的自清洁性能,并且,具有较高的力学强度及分离效率,两者均被广泛应用于含油废水的油水分离处理。文章叙述了含油污水的主要来源及传统油水分离技术存在的问题,介绍了表面润湿性的基本原理,包括空气中接触角(弹性模型、Wenzel模型及Cassie-Baxter模型)、滚动角等,然后,分别对超疏水/亲油、超亲水/水下超疏油材料的制备方法及特点进行介绍,并且,重点分析了材料表面微观结构及表面能对油水分离效果的影响,最后,结合工业生产中存在的问题及实际需求对未来金属网基油水分离材料的发展进行了展望。

Fast ion diffusion alloy layer facilitating 3D mesh substrate for dendrite-free zinc-ion hybrid capacitors

Although aqueous zinc ion hybrid capacitors have advantageous integration of batteries and supercapacitors,they still suffer from the inherent problems of dendrite growth and interfacial side reactions on Zn anodes.Herein,a universal fast zinc-ion diffusion layer on a three-dimensional(3 D)mesh structure model is demonstrated to effectively improve Zn plating/stripping reversibility.The fast ion diffusion alloy layer accelerates the Zn^(2+)migration in an orderly manner to homogenize Zn^(2+)flux and overcomes the defects of the commercial mesh substrate,effectively avoiding dendrite growth and side reactions.Consequently,the proof-of-concept silver-zinc alloy modified stainless steel mesh delivers superb reversibility with the high coulombic efficiency over 99.4%at 4 mA cm^(-2)after 1600 cycles and excellent reliability of over 830 h at 1 mA cm^(-2),Its feasibility is also evidenced in commercial zinc ion hybrid capacitors with activated carbon as the cathode.This work enriches the fundamental comprehension of fast zinc-ion diffusion layer combined with a 3 D substrate on the Zn deposition and opens a universal approach to design advanced host for Zn electrodes in zinc ion hybrid capacitors.

肿瘤治疗电场的双层金属丝网传感器电场测试方法研究

目的提出并验证了一种双层金属丝网传感器(MWMS)测量肿瘤治疗电场(TTFields)的新方法。方法通过COMSOL建立圆柱模型并进行仿真,验证了双层MWMS的有效性。明胶和NaCl按照一定比例配置来模拟头颅内部组织和用猪肌肉替代肿瘤组织,并设计单层MWMS测量系统验证单层MWMS测量效果。结果仿真结果表明,双层MWMS在测量精度上明显优于单层MWMS。实际测试结果表明,单层MWMS可以测出模拟头颅内部组织区域的电场强度和猪肌肉所在位置。结论双层MWMS为TTFields的电场测量提供了更加精确的工具。

14煤层开采铺设金属网人工假顶可行性分析

胜利煤矿一采区规划开采的煤层为14煤层和近距离下伏的15煤层,为确保在采15煤层的开采安全,提出在开采14煤层时工作面顶板铺设金属网形成人工假顶,对14煤开采后的人工假顶进行可靠性分析,采用简支梁稳定分析法,确定人工假顶极限状态的厚度为5.74 m。根据水化学实验可得,采空区积水对铺设金属网有腐蚀性,分析采空区铺设的金属网有效赋存时间不超过3 a。结合再生顶板形成时间分析确定,当15煤层与14煤层存在1 m以上的层间距时,15煤至少需要在14煤层开采完毕3.5 a后进行采掘活动;当15煤层与14煤层合层时,15煤至少需要在14煤层开采完毕5 a后进行采掘活动。

建筑用碳纤维-金属网复合材料的力学性能研究

用热固性环氧斜纹编织预浸料、不锈钢丝网、铝合金丝网分别制备纯碳纤维板试样、碳纤维—不锈钢丝网复合材料、碳纤维—铝合金丝网复合材料。测试3种复合材料的抗折强度、抗压强度、抗冲击性能及经腐蚀后的力学性能。结果表明:纯碳纤维板的抗折强度、抗压强度均处于最低水平;经质量分数为5%的NaCl溶液腐蚀后力学性能均不同程度下降;经过金属网增强后的复合材料力学性能明显增强,其中,加入不锈钢丝网的复合材料具有较高的抗折强度、抗压强度、抗冲击性能。综上可知,碳纤维-不锈钢丝网复合材料的力学性能更佳。