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A 3-D Supramolecular Network with 1-D Cation Metal-organic Coordination Polymers and Diverse Motifs from Hydrogen-bonded [M(H_2O)_4]-Carboxylates
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作者 黄坤林 左彦秋 +4 位作者 孙杰 陈新 苗红菊 刘玺 许红 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第11期1393-1397,共5页
One-pot solvothermal reaction of Iransition metal Znn salt with 4,4-bipyddyl (bpy) and 1,4-benzenediacrylic add (H2L) in the presence of Et3N generates a three-dimensional (3-D) supramolecular network with 1-D c... One-pot solvothermal reaction of Iransition metal Znn salt with 4,4-bipyddyl (bpy) and 1,4-benzenediacrylic add (H2L) in the presence of Et3N generates a three-dimensional (3-D) supramolecular network with 1-D cation metal-organic coordination polymer, [Zn(H20)a(bpy)]-L 1, and structurally characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopy, and photoluminescent property. The complex crystallizes in triclinic, space group P1 with a = 7.1291(2), b = 7.3784(3), c = 10.5042(3)A, α = 95.049(2), β = 102.162(2), 7 = 97.027(3)0, V= 532.38(3)A3, C22H24N2O8Zn, Mr = 509.82, De= 1.590 g/cm3, p(MoKa)= 1.207 ram-l, F(000) = 264, Z = 1,the finalR=O.0438and wR=O.lOll for 1589 observed reflections (I 〉 2σ(I)). In the crystal structure, the second building unit composed of [Zn(H2O)4].L constructs two distinct 2-D supramolecular sheets and a neutral 3-D architecture. The title compound 1 shows strong photoluminescence with emission maximum at 2 = 455 nm upon λex.max = 355 nm. 展开更多
关键词 supramolecular structure coordination polymer hydrated ion PHOTOLUMINESCENCE ZINC
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Rare π_5~6…Pb Interactions in a Two-dimensional Metal-organic Coordination Polymer with Two Distinct Kinds of Axially Chiral Units
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作者 陈新 张明星 黄坤林 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2012年第11期1601-1607,共7页
A new metal-organic coordination polymer [Pb(mfpdc)(CH3OH)]n (1, mfpdc = 2,6-dimethyl-4-(2-furanyl) pyridine-3,5-dicarboxylate) was synthesized and characterized by single-crystal X-ray analyses. The crystal i... A new metal-organic coordination polymer [Pb(mfpdc)(CH3OH)]n (1, mfpdc = 2,6-dimethyl-4-(2-furanyl) pyridine-3,5-dicarboxylate) was synthesized and characterized by single-crystal X-ray analyses. The crystal is orthorhombic, space group Pbca, a = 15.6297(18), b = 9.4803(11), c = 18.598(2) A, V= 2755.8(6) A3, Z = 8, Mr= 498.44, Dc= 2.403 Mg/m3, F(000) = 1872, the final R = 0.0275 and wR = 0.0726 (1 〉 2σ(I)). There are interesting polynuclear zigzag (PbOs)n chains in the structure of 1, and there have interesting axially chiral S- and R-unit Pb4L units constructed from prochiral organic ligands through C-H...O bonding. The (R/S)-Pb4L units by sharing Pb centers generate a 2-D coordination network, in which there exist rare n65Pb (3.2610 A) interactions. The solid-state photoluminescent emission of compound 1 appears at 487 nm. 展开更多
关键词 axially chiral unit coordination polymer metal...π interaction PB PHOTOLUMINESCENCE
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Two Metal-organic Coordination Polymers with Rigid Bis(triazole) Ligand: Assembly, Structures, and Fluorescence Properties
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作者 张旭 赵艳琴 +1 位作者 王福生 董桂英 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2016年第5期765-773,共9页
Two new coordination polymers containing rigid bis(triazole), namely, [Ni(btb)_(0.5)(nph)(H_2O)]_n(1) and [Zn(btb)(SO_4)]_n(2)(btb = 4,4a-bis(1,2,4-triazolyl-1-yl)-biphenyl, H_2nph = 3-nitrophthal... Two new coordination polymers containing rigid bis(triazole), namely, [Ni(btb)_(0.5)(nph)(H_2O)]_n(1) and [Zn(btb)(SO_4)]_n(2)(btb = 4,4a-bis(1,2,4-triazolyl-1-yl)-biphenyl, H_2nph = 3-nitrophthalic acid) have been synthesized and characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. Complex 1 shows a 3D trinodal(3,4,4)-connected sqc69 topology. Complex 2 presents a 2D uninodal 4-connected sql network, which is further packed into a 3D supramolecular framework by C-H···O hydrogen bonds. Thermal stabilities and fluorescence properties of two complexes have been discussed in detail. 展开更多
关键词 bis(triazole) ligand crystal structure nickel(Ⅱ) coordination polymer fluorescence zinc(Ⅱ) coordination polymer
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Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands
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作者 MEI Zhenzhong WANG Hongyu +2 位作者 KANG Xiuqi SHAO Yongliang GU Jinzhong 《无机化学学报》 SCIE CAS CSCD 北大核心 2024年第9期1795-1802,共8页
Three zincand cobaltcoordination polymers,namely{[Zn_(2)(μ_(6)-adip)(phen)_(2)]·4H_(2)O}_(n)(1),{[Co_(2)(μ_(6)-adip)(bipy)_(2)]·4H_(2)O}_(n)(2),and[Co_(2)(μ4-adip)(μ-bpa)_(2)]_(n)(3)have been constructed... Three zincand cobaltcoordination polymers,namely{[Zn_(2)(μ_(6)-adip)(phen)_(2)]·4H_(2)O}_(n)(1),{[Co_(2)(μ_(6)-adip)(bipy)_(2)]·4H_(2)O}_(n)(2),and[Co_(2)(μ4-adip)(μ-bpa)_(2)]_(n)(3)have been constructed hydrothermally using H4adip(H4adip=5,5′-azanediyldiisophthalic acid),phen(phen=1,10-phenanthroline),bipy(bipy=2,2′-bipyridine),bpa(bpa=bis(4-pyridyl)amine),and zinc and cobalt chlorides at 160℃.The products were isolated as stable crystalline solids and were characterized by IR spectra,elemental analyses,thermogravimetric analyses,and single-crystal X-ray diffrac-tion analyses.Single-crystal X-ray diffraction analyses revealed that three compounds crystallize in the orthorhom-bic system Pnna(1 and 2)or P21212(3)space groups.All compounds exhibit 3D frameworks.The catalytic perfor-mances in the Henry reaction of these compounds were investigated.Compound 3 exhibited an effective catalytic activity in the Henry reaction at 70℃.CCDC:2339391,1;2339392,2;2339393,3. 展开更多
关键词 coordination polymer tetracarboxylic acid catalytic properties Henry reaction
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Syntheses,crystal structures,and catalytic properties of three zinc(Ⅱ),cobalt(Ⅱ)and nickel(Ⅱ)coordination polymers constructed from 5⁃(4⁃carboxyphenoxy)nicotinic acid
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作者 LING Weizhong CHEN Xiangyun +2 位作者 LIU Wenjing HUANG Yingkai LI Yu 《无机化学学报》 SCIE CAS CSCD 北大核心 2024年第9期1803-1810,共8页
Three zinc(Ⅱ),cobalt(Ⅱ),and nickel(Ⅱ)coordination polymers,namely[Zn(μ^(3-)cpna)(μ-dpea)_(0.5)]_(n)(1),[Co(μ^(3-)cpna)(μ-dpey)_(0.5)]_(n)(2),and[Ni(μ^(3-)cpna)(μ-dpey)_(0.5)(H_(2)O)]_(n)(3),have been construc... Three zinc(Ⅱ),cobalt(Ⅱ),and nickel(Ⅱ)coordination polymers,namely[Zn(μ^(3-)cpna)(μ-dpea)_(0.5)]_(n)(1),[Co(μ^(3-)cpna)(μ-dpey)_(0.5)]_(n)(2),and[Ni(μ^(3-)cpna)(μ-dpey)_(0.5)(H_(2)O)]_(n)(3),have been constructed hydrothermally using H_(2)cpna(5-(4-carboxyphenoxy)nicotinic acid),dpea(1,2-di(4-pyridyl)ethane),dpey(1,2-di(4-pyridyl)ethylene),and zinc,cobalt,and nickel chlorides at 160℃.The products were isolated as stable crystalline solids and were characterized by IR spectra,elemental analyses,thermogravimetric analyses,and single-crystal X-ray diffraction analyses.Single-crystal X-ray diffraction analyses revealed that three compounds crystallize in the triclinic system,space group P1.Compounds 1-3 show 2D layer structures.The catalytic activities in the Knoevenagel condensation reaction of these compounds were investigated.Compounds 1 and 2 exhibit effective catalytic activities in the Knoevenagel condensa-tion reaction at room temperature.For this reaction,various parameters were optimized,followed by the investiga-tion of the substrate scope.CCDC:2335676,1;2335677,2;2335678,3. 展开更多
关键词 coordination polymer dicarboxylic acid catalytic property Knoevenagel condensation reaction
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Transition metal coordination polymers with flexible dicarboxylate ligand:Synthesis,characterization,and photoluminescence property
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作者 CUI Peipei LI Xin +5 位作者 CHEN Yilin CHENG Zhilin GAO Feiyan GUO Xu YAN Wenning DENG Yuchen 《无机化学学报》 SCIE CAS CSCD 北大核心 2024年第11期2221-2231,共11页
Under solvothermal conditions,six new coordination polymers(CPs)[Mn(L)(phen)(H_(2)O)]_(n)(1),[Co(L)(phen)(H_(2)O)]_(n)(2),[Cu(L)(phen)(H_(2)O)]_(n)(3),[Zn_(2)(L)_(2)(phen)2(H_(2)O)]_(n)(4),[Zn(L)(phen)]_(n)(5),and[Cd(... Under solvothermal conditions,six new coordination polymers(CPs)[Mn(L)(phen)(H_(2)O)]_(n)(1),[Co(L)(phen)(H_(2)O)]_(n)(2),[Cu(L)(phen)(H_(2)O)]_(n)(3),[Zn_(2)(L)_(2)(phen)2(H_(2)O)]_(n)(4),[Zn(L)(phen)]_(n)(5),and[Cd(L)(phen)2]_(n)(6)were synthesized by reactions of dicarboxylate ligand 2,2'-(1,2-phenylenebis(methylene))bis(sulfanediyl)dinobutyric acid(H_(2)L)and 1,10-phenanthroline(phen)with the corresponding metal salts.Complexes 1-6 have been structurally characterized by single-crystal X-ray diffraction analyses,elemental analysis,IR,thermogravimetric analysis,and powder X-ray diffraction.The structures of 1-6 are 1D chains,which are further connected by hydrogen bonding interac-tions to form 3D supramolecular structures.Among them,1 and 2 are isomorphic with L2-of syn-conformation,while L2-shows anti-conformation in 3-6.In addition,the solid-state photoluminescence property of 4-6 was investigated. 展开更多
关键词 flexible dicarboxylate ligand coordination polymers hydrogen bonding interaction CONFORMATION photoluminescence property
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Syntheses,crystal structures,and quantum chemistry calculation of two Ni(Ⅱ)coordination polymers
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作者 LI Xiumei HUANG Yanju +1 位作者 LIU Bo PAN Yaru 《无机化学学报》 SCIE CAS CSCD 北大核心 2024年第10期2031-2039,共9页
Two new coordination polymers,[Ni(Hpdc)(bib)(H_(2)O)]_(n)(1)and{[Ni(bib)_(3)](ClO_(4))_(2)}_(n)(2),were prepared by mixing Ni^(2+),3,5⁃pyrazoledicarboxylic acid(H3pdc)/p⁃nitrobenzoic acid and 1,4⁃bis(imidazol⁃1⁃ylmeth... Two new coordination polymers,[Ni(Hpdc)(bib)(H_(2)O)]_(n)(1)and{[Ni(bib)_(3)](ClO_(4))_(2)}_(n)(2),were prepared by mixing Ni^(2+),3,5⁃pyrazoledicarboxylic acid(H3pdc)/p⁃nitrobenzoic acid and 1,4⁃bis(imidazol⁃1⁃ylmethyl)butane(bib)by a hydrothermal method,respectively.X⁃ray crystallography reveals a 2D network constructed by six⁃coordinated Ni(Ⅱ)centers,bib,and Hpdc2-ligands in complex 1,while a 2D network is built by Ni(Ⅱ)and bib ligands in 2.Furthermore,the quantum⁃chemical calculations have been performed on‘molecular fragments’extracted from the crystal structure of 1 using the PBE0/LANL2DZ method in Gaussian 16 and the VASP program.CCDC:2343794,1;2343798,2. 展开更多
关键词 coordination polymer nickel(Ⅱ)complex crystal structure quantum⁃chemical calculation
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Syntheses,structures,and properties of three coordination polymers based on 5⁃ethylpyridine⁃2,3⁃dicarboxylic acid and N⁃containing ligands
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作者 TANG Long BIAN Yaxin +3 位作者 CHEN Luyuan HOU Xiangyang WANG Xiao WANG Jijiang 《无机化学学报》 SCIE CAS CSCD 北大核心 2024年第10期1975-1985,共11页
Three coordination polymers[Mn(epda)(2,2'⁃bipy)(H_(2)O)](1),[Mn(epda)(phen)](2),and[Co_(2)(epda)2(bpe)2(H_(2)O)_(4)]·5H_(2)O(3)(H2epda=5⁃ethyl⁃pyridine⁃2,3⁃dicarboxylic acid,2,2'⁃bipy=2,2'⁃bipyridine,... Three coordination polymers[Mn(epda)(2,2'⁃bipy)(H_(2)O)](1),[Mn(epda)(phen)](2),and[Co_(2)(epda)2(bpe)2(H_(2)O)_(4)]·5H_(2)O(3)(H2epda=5⁃ethyl⁃pyridine⁃2,3⁃dicarboxylic acid,2,2'⁃bipy=2,2'⁃bipyridine,phen=phenanthroline,bpe=1,2⁃bis(4⁃pyridyl)ethylene)were synthesized by solvothermal reactions and characterized by single⁃crystal X⁃ray diffraction,thermogravimetric analyses,IR spectroscopy and elemental analysis.1 displays a 1D chain struc⁃ture,and these chains are joined by O-H…O hydrogen bonding andπ⁃πstacking interactions to generate a 2D layer structure.2 displays a 2D layer structure,and adjacent layers are generated 3D architecture throughπ⁃πstacking interactions.3 displays a 1D chain structure,and adjacent chains are generated double layer structure through O-H…O hydrogen bonding.The fluorescent properties of 1 and 3 indicate that they can potentially be used as a luminescent sensor.1 was highly selective and sensitive towards o⁃nitrophenol through different detection mechanisms,however,3 was highly selective and sensitive towards 2,4,6⁃trinitrophenol.In addition,the magnetic behavior of 2 has also been investigated.CCDC:2172533,1,2355773,2,2355774,3. 展开更多
关键词 coordination polymers 5⁃ethyl⁃pyridine⁃2 3⁃dicarboxylate ligand crystal structures fluorescent properties magnetic behavior
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Two Novel Cobalt(Ⅱ)/nickel(Ⅱ) Metal-organic Coordination Polymers Based on Flexible Polycarboxylic Acids and Rigid Bis(imidazole) Mix Ligands
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作者 YANG Ming-Xing YAN Zhi-Wei +2 位作者 CHEN Li-Juan LIN Xing-Ye LIN Shen 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2020年第1期147-153,5,共8页
Two novel metal-organic coordination compounds, [Co2(OH)(chdc)1.5(bibp)]n(1) and [Ni(chdc)(bib)]n·2nH2O(2, H2chdc=1,4-cyclohexanedicarboxylic acid, bibp=4,4’-bis(1-imidazolyl)biphenyl, bib=1,4-bis(1-imidazolyl)b... Two novel metal-organic coordination compounds, [Co2(OH)(chdc)1.5(bibp)]n(1) and [Ni(chdc)(bib)]n·2nH2O(2, H2chdc=1,4-cyclohexanedicarboxylic acid, bibp=4,4’-bis(1-imidazolyl)biphenyl, bib=1,4-bis(1-imidazolyl)benzene), were synthesized and characterized. Compound 1 crystallizes in monoclinic system, space group PI with a=10.591(3), b=11.146(3), c=12.264(3) ?, α=89.009(6), β=88.397(4), γ=87.823(3)°, V=1446.0(6) ?3, Dc=1.554 g/cm3, C30H30Co2N4O7, Mr=676.44, F(000)=696, μ(MoKα)=1.202 mm-1, Z=2, R=0.0278 and wR=0.0718. In 1, it contains an interesting tetranuclear Co(Ⅱ) cluster. The neighboring {Co4} clusters are linked by chdc2-ligands to generate a 2D network. The bibp ligands connect adjacent layers to form an open 3 D metal-organic framework. Compound 2 crystallizes in monoclinic system, space group P21/n with a=8.8110(1), b=19.369(1), c=12.7379(4) ?, β=102.952(5)o, V=2118.5(2) ?3, Dc=1.490 g/cm3, C20H24N4NiO6, Mr=475.14, F(000)=992, μ(MoKα)=0.961 mm-1, Z=4, R=0.0306 and wR=0.0738. In 2, each deprotonated chdc 2-ligand links two Ni(Ⅱ) atoms to generate a 1 D chain along the a axis. The adjacent chains are further connected by bib ligands to build up an interesting two-dimensional network. Compound 1 shows antiferromagnetic property. 展开更多
关键词 coordination polymer magnetic properties cobalt(Ⅱ)complex nickel(Ⅱ)complex bis(imidazole)ligand
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Synthesis of energetic coordination polymers based on 4-nitropyrazole by solid-melt crystallization in non-ionization condition
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作者 Ting-wei Wang Shu Bu +4 位作者 Kun Wang Lu Zhang Zhen-xin Yi Shun-guan Zhu Jian-guo Zhang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2023年第10期13-22,共10页
Based on the theory of crystallization,a solvent-free solid-liquid phase crystallization method called solid-melt crystallization was designed to prepare energetic coordination polymers.Two target compounds[Cu(NPyz)_(... Based on the theory of crystallization,a solvent-free solid-liquid phase crystallization method called solid-melt crystallization was designed to prepare energetic coordination polymers.Two target compounds[Cu(NPyz)_(4)NO_(3)]·NO_(3)(ECPs-1)and Cu(NPyz)_(4)(ClO_(4))_(2)(ECCs-2)were prepared through programmed heating and cooling by using 4-nitropyrazole(NPyz),(Cu(NO_(3))_(2)·5H_(2)O and Cu(ClO_(4))_(2)·5H_(2)O) as raw materials.In addition,crystallization pre-experiments and annealing experiments also verified the feasibility of the method.Their structures were confirmed by IR,elemental analysis,single-crystal X-ray diffraction and powder X-ray diffraction.The physicochemical properties and sensitivity test results showed that ECCs-2 has better thermal stability(T_(d)=221℃),while ECPs-1 is less sensitive to mechanical stimuli(IS=12 J,FS=240 N).Calculations based on EXPLO5 and the Kamlet-Jacobs equation showed that ECCs-2 has more considerable detonation performance(P=25.2 GPa,D=7.5 km/s).In comparison,the more intuitive results from the HN test,flame test,thermal resistance test and lead plate explosion test revealed that ECCs-2 has an“acceptable”detonation performance.The laser detonation test also showed that ECCs-2 is a promising excellent laser detonation material(E=408 mJ,P=24 W,τ=17 ms). 展开更多
关键词 4-Amino-1 2 5-oxadiazole-3-carbohydrazide Crystallization coordination polymers Laser Primary explosives
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Encapsulation of lipases on coordination polymers and their catalytic performance in glycerolysis and esterification
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作者 Can Zeng Nanjing Zhong 《Grain & Oil Science and Technology》 CAS 2023年第3期113-119,共7页
In this study,lipases of CALB(Candida antarctica lipase B),TLL(Thermomyces lanuginosa lipase),RML(Rhizomucor miehei lipase),CALA(Candida antarctica lipase A)and LU(Lecitase?Ultra)were encapsulated into the nucleotideh... In this study,lipases of CALB(Candida antarctica lipase B),TLL(Thermomyces lanuginosa lipase),RML(Rhizomucor miehei lipase),CALA(Candida antarctica lipase A)and LU(Lecitase?Ultra)were encapsulated into the nucleotidehybrid metal coordination polymers(CPs)for diacylglyerols(DAG)preparation.Guanosine 5'-monophosphate(GMP)and adenosine 5'-monophosphate(AMP)were used as coordinating molecules,and metal ions of Fe^(3+),Ba^(2+),Mn^(2+),Ni^(2+)and Cr^(3+)were applied to prepare matrix.Results indicated that,besides Ba^(2+)with AMP,all other metal ions can coordinate with AMP and GMP to generate CPs.In addition,the AMP/Ni was amorphous when standing temperature was 4℃,while it was crystalline when standing temperature was from 30 to 180℃.DAG content from 47.55%to 64.99%was obtained from glycerolysis by CALB@GMP/Ba,RML@GMP/Ba,TLL@GMP/Ba,RML@GMP/Mn and TLL@GMP/Mn.Additionally,CALB@GMP/Fe showed selectivity towards DAG formation in the esterification and DAG content up to 61.88%was obtained. 展开更多
关键词 LIPASE coordination polymers ENCAPSULATION GLYCEROLYSIS ESTERIFICATION
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Two Isostructural 2-D Metal(Ⅱ)-organic Coordination Polymers from 4,4'-Bipyridyl and (E)-2,6-Dimethyl-4-styrylpyridine-3,5-dicarboxylic Acid 被引量:3
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作者 黄坤林 高杰 傅世平 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2010年第5期752-756,共5页
(E)-2,6-Dimethyl-4-styrylpyridine-3,5-dicarboxylic acid (H2mspda) is firstly employed in coordination chemistry.Two isostructural two-dimensional (2-D) 4-connected metal-organic coordination polymers with a gene... (E)-2,6-Dimethyl-4-styrylpyridine-3,5-dicarboxylic acid (H2mspda) is firstly employed in coordination chemistry.Two isostructural two-dimensional (2-D) 4-connected metal-organic coordination polymers with a general formula of {M2[(mspda)2(bpy)(H2O)2]}n (M=Zn(1) and Co(2)) are assembled from H2mspda,4,4'-bipyridyl (bpy),zinc and cobalt ions under hydrothermal conditions,and characterized by single-crystal X-ray diffraction analyses.Complex 1 crystallizes in monoclinic,space group P21/n with a=14.551(4),b=10.941(3),c=14.945(4),β=98.817(4)o,V=2351.3(1)3,Dc=1.511 g/cm3,μ(MoKα)=1.090 mm-1,F(000)=1104,Z=4,the final R=0.0335 and wR=0.0485 for 3296 observed reflections (I 〉 2σ(I)).In compound 1,mspda2-spacers are only arrayed in a head-to-tail fashion which corresponds to a 2-D coordination polymer.Solid-state H2mspda and complex 1 have expected photoluminescence (λem=475~496 nm) at room temperature. 展开更多
关键词 metal-organic coordination polymer pyridinedicarboxyfic acid photoluminescence COBALT ZINC
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Synthesis and Characterization of a Novel 3D Coordination Polymer Based on Cu(II) Cations and Mellitic Acid 被引量:1
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作者 杨娥 覃业燕 +3 位作者 曹新医 林启普 尹培秀 姚元根 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第8期985-989,共5页
A new mellitate complex [Cu3(μ2-mellitate)(μ2-H2O)(H2O)2·H2O]n 1 has been synthesized by the reaction of mellitic acid and Cu(CH3COO)2·H2O in the presence of base. Crystallographic data for 1: C12... A new mellitate complex [Cu3(μ2-mellitate)(μ2-H2O)(H2O)2·H2O]n 1 has been synthesized by the reaction of mellitic acid and Cu(CH3COO)2·H2O in the presence of base. Crystallographic data for 1: C12H8O16Cu3, Mr = 598.80, orthorhombic, Pbcn, a = 8.4378(6), b = 10.0396(7), c = 17.6799(12)A, V = 1497.70(18)A^3, Z = 4, De = 2.656 g/cm^3, μ = 4.327 mm^-1, F(000) = 1180, R = 0.0431 and wR = 0.0964 for 1075 observed reflections (I 〉 2σ(I)). X-ray crystal structural analysis revealed that the mellitate anions behave as the bridging ligands and link eight copper atoms repeatedly to form a novel three-dimensional metal-organic coordination polymer with two different rhombic tunnels in the solid-state structure. 展开更多
关键词 mellitate COPPER metal-organic coordination polymer rhombic tunnel
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Synthesis,crystal structure and adsorption properties of a novel Fe(Ⅲ) porous coordination polymer containing 1,4-naphthalenedicarboxylate ligand 被引量:1
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作者 陈金喜 孟伟伟 张若冰 《Journal of Southeast University(English Edition)》 EI CAS 2011年第1期107-110,共4页
A novel porous coordination polymer,iron naphthalenedicarboxylate Fe(OH)(1,4-NDC)·2H2O is hydrothermally synthesized by the reaction of FeSO4·7H2O and 1,4-naphthalenedicarboxylic acid(1,4-H2NDC) at 150... A novel porous coordination polymer,iron naphthalenedicarboxylate Fe(OH)(1,4-NDC)·2H2O is hydrothermally synthesized by the reaction of FeSO4·7H2O and 1,4-naphthalenedicarboxylic acid(1,4-H2NDC) at 150℃.The compound crystallizes in a tetragonal space group P42/nmc:a=2.1447(4) nm,c=0.68849(14) nm,V=3.1669(11) nm3,Z=8,R=0.0845,wR=0.1829.The crystal structure exhibits a three-dimensional framework which is composed of infinite chains of corner-sharing octahedral Fe(OH)2O4 with 1,4-NDC ligands forming two types of channels with square-shaped cross-sections.The large channels present a cross-section of 0.76 nm×0.76 nm,while the small channels are about 0.30 nm×0.30 nm.No structural transformation occurs after removing the guest water molecules,while a robust structure generates with permanent porosity.The adsorption measurements show that the anhydrous sample of the compound can adsorb CO2 into its pores.The adsorption isotherms for methanol,acetone,tetrahydrofuran and benzene are also measured. 展开更多
关键词 porous coordination polymer selective adsorption 1 4-naphthalenedicarboxylic acid
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Combination of Nitrogen-Rich Skeleton and Coordination Group:Synthesis of a High-Energy Primary Explosive Based on 1H-Tetrazole-5-Carbohydrazide
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作者 Tingwei Wang Zujia Lu +6 位作者 Shu Bu Baolong Kuang Lu Zhang Zhenxin Yi Kun Wang Shunguan Zhu Jianguo Zhang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第1期271-277,共7页
The high energy coordination compounds Cu(TZCA)_(2)(ClO_(4))_(2)(ECCs-1) was prepared by 1H-tetrazole-5-carbohydrazide(TZCA) with a high energy skeleton and a strong coordination ability group.At the same time,the rea... The high energy coordination compounds Cu(TZCA)_(2)(ClO_(4))_(2)(ECCs-1) was prepared by 1H-tetrazole-5-carbohydrazide(TZCA) with a high energy skeleton and a strong coordination ability group.At the same time,the reaction activity of the ligand was explored,and the single crystal structure of it and intermediate were obtained.The structures of all substances were characterized by IR and EA.And the structure and composition of ECCs-1 are confirmed by ESP,AC,SEM and ICP-OES.Physical and chemical properties tests show that ECCs-1 has an acceptable thermal stability(T_(d)=177℃) and extremely sensitive mechanical stimulation(IS=1 J,FS=5 N).The comprehensive performance test results show that ECCs-1 has excellent initiation ability.In addition,the decomposition mechanism of ECCs-1 is explored from two aspects of experiment and theoretical calculation. 展开更多
关键词 1H-tetrazole-5-carbohydrazide Primary explosive Decomposition mechanism coordination polymers Laser
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Amino-modified UiO-66-NH_(2) reinforced polyurethane based polymer electrolytes for high-voltage solid-state lithium metal batteries
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作者 Danru Huang Lin Wu +5 位作者 Qi Kang Zhiyong Shen Qiaosheng Huang Wenjie Lin Fei Pei Yunhui Huang 《Nano Research》 SCIE EI CSCD 2024年第11期9662-9670,共9页
Solid-state polymer electrolytes(SPEs)are candidate schemes for meeting the safety and energy density needs of advanced lithium-based battery because of their improved mechanical and electrochemical stability compared... Solid-state polymer electrolytes(SPEs)are candidate schemes for meeting the safety and energy density needs of advanced lithium-based battery because of their improved mechanical and electrochemical stability compared to traditional liquid electrolytes.However,low ionic conductivity and side reactions occurring in traditional high-voltage lithium metal batteries(LMBs)hinder their practical applications.Here,amino-modified metal-organic frameworks(UiO-66-NH_(2))with abundant defects as multifunctional fillers in the polyurethane based SPEs achieve the collaborative promotion of the mechanical strength and room temperature ionic conductivity.The surface modified amino groups serve as anchoring points for oxygen atoms of polymer chains,forming a firmly hydrogen-bond interface with polycarbonate-based polyurethane frameworks.The rich interfaces between UiO-66-NH_(2) and polymers dramatically decrease the crystallization of polymer chains and reduce ion transport impedance,which markedly boosted the ionic conductivity to 2.1×10^(−4) S·cm^(−1) with a high Li+transference numbers of 0.71.As a result,LiFePO4∣SPEs∣Li cells exhibit prominent cyclability for 700 cycles under 0.5 C with 96.5%capacity retention.The LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)(NCM622)∣SPEs∣Li cells deliver excellent long-term lifespan for 260 cycles with a high capacity retention of 91.9%and high average Coulombic efficiency(98.5%)under ambient conditions.This simple and effective hybrid SPE design strategy sheds a milestone significance light for high-voltage Li-metal batteries. 展开更多
关键词 solid-state polymer electrolyte metal-organic frameworks POLYURETHANE lithium metal batteries high voltage interface
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Activating coordinative conjugated polymer via interfacial electron transfer for efficient CO_(2) electroreduction
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作者 Jing Zhang Jia-Jun Dai +13 位作者 De-Quan Cao Heng Xu Xing-Yu Ding Chun-Hua Zhen Beate Paulus Jin-Yu Ye Qian Liang Jun-Ke Liu Shi-Jun Xie Sai-Sai Deng Zhen Wang Jun-Tao Li Yao Zhou Shi-Gang Sun 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第8期313-323,I0009,共12页
With tunable local electronic environment,high mass density of MN4sites,and ease of preparation,metal-organic conjugated coordinative polymer(CCP) with inherent electronic conductivity provides a promising alternative... With tunable local electronic environment,high mass density of MN4sites,and ease of preparation,metal-organic conjugated coordinative polymer(CCP) with inherent electronic conductivity provides a promising alternative to the well-known M-N-C electrocatalysts.Herein,the coordination reaction between Cu^(2+)and 1,2,4,5-tetraaminobenzene(TAB) was conducted on the surface of metallic Cu nanowires,forming a thin layer of CuN4-based CCP(Cu-TAB) on the Cu nanowire.More importantly,interfacial transfer of electrons from Cu core to the CuN4-based CCP nanoshell was observed within the resulting CuTAB@Cu,which was found to enrich the local electronic density of the CuN4sites.As such,the CuTAB@Cu demonstrates much improved affinity to the*COOH intermediate formed from the rate determining step;the energy barrier for C-C coupling,which is critical to convert CO_(2)into C2products,is also decreased.Accordingly,it delivers a current density of-9.1 mA cm^(-2)at a potential as high as 0.558 V(vs.RHE) in H-type cell and a Faraday efficiency of 46.4% for ethanol.This work emphasizes the profound role of interfacial interaction in tuning the local electronic structure and activating the CuN4-based CCPs for efficient electroreduction of CO_(2). 展开更多
关键词 metal-organic solid compounds Conjugated coordinative polymer Solid-solid interfacial electron transfer MN_(4)sites Electrocatalysis
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Synthesis and Crystal Structure of a Two-dimensional Coordination Polymer Constructed by Thiophene-2,5-dicarboxylic Acid and 1,4-Bis(imidazol-1-yl)-butane 被引量:14
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作者 刘博 国佳 +3 位作者 周实 王庆伟 李秀梅 李传碧 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2013年第2期199-204,共6页
A metal-organic coordination polymer [Cd(tdc)(bimb)(μ2-H2O)]n (H2tdc = thiophe-ne-2,5-dicarboxylic acid, bimb = 1,4-bis(imidazol-l-yl)-butane) 1 has been hydrothermally synthe- sized and characterized by el... A metal-organic coordination polymer [Cd(tdc)(bimb)(μ2-H2O)]n (H2tdc = thiophe-ne-2,5-dicarboxylic acid, bimb = 1,4-bis(imidazol-l-yl)-butane) 1 has been hydrothermally synthe- sized and characterized by elemental analysis, IR, TG, luminescence spectrum and single-crystal X-ray diffraction. Colorless crystals crystallize in the triclinic system, space group P^-1 with a = 5.8945(3), b = 10.3129(5), c = 11.2226(5) A, a = 95.1430(10),β = 97.9020(10), γ = 90.5910(10)°, V = 672.84(6) A^3, C11H11CdN2O5S, Mr= 395.68, De = 1.953 g/cm^3, μ(MoKa) = 1.797 mm^-1, F(000) = 390, Z = 2, the final R = 0.0209 and wR = 0.0508 for 2514 observed reflections (I 〉 2σ(I)). The structure of 1 exhibits a two-dimensional layer-like structure. 展开更多
关键词 hydrothermal synthesis crystal structure coordination polymer
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Recent Advances of Lanthanide-transition Heterometallic Coordination Polymers 被引量:7
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作者 王金 赵小庆 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2014年第1期7-18,共12页
With the improvement of high-tech and emergence of crossing and new fields, lanthanide-transition (Ln-M) heterometallic coordination polymers have attracted much attention of many researchers, which exhibit novel st... With the improvement of high-tech and emergence of crossing and new fields, lanthanide-transition (Ln-M) heterometallic coordination polymers have attracted much attention of many researchers, which exhibit novel structures and unique properties with potential applications in the nonlinear optical materials, fluorescent materials, superconducting materials, magnetic materials, catalysis, bio-simulation, adsorption and separation, and so on. It is thus necessary to summarize Ln-M heterometallic coordination polymers. According to the transition metal ions, those coordination polymers are divided into six parts to explore the current applications and future developments. 展开更多
关键词 lanthanide-transition coordination polymer STRUCTURE PROPERTY
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Synthesis and Crystal Structure of a New Two-dimensional Manganese Coordination Polymer:[Mn(L)(1,4-bdc)] 被引量:9
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作者 孔治国 马晓媛 +1 位作者 徐占林 王秀艳 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2011年第7期927-930,共4页
A new coordination polymer, [Mn(L)(1,4-bdc)] (L = 11-fluoro-dipyrido[3,2- a:2",3 "- c]phenazine, 1,4-bdc - benzene-1,4-dicarboxylate), has been synthesized through the hydrothermal method and characterized by... A new coordination polymer, [Mn(L)(1,4-bdc)] (L = 11-fluoro-dipyrido[3,2- a:2",3 "- c]phenazine, 1,4-bdc - benzene-1,4-dicarboxylate), has been synthesized through the hydrothermal method and characterized by elemental analysis, IR and single-crystal X-ray diffraction. It crystallizes in triclinic, space group P1 with a = 9.7544(9), b = 10.8254(10), c = 11.5288(10) A, a = 114.1300(10), β = 96.6110(10), y = 105.0390(10)°, V= 1038.62(16)/k3, Z= 2, C26H13FMnN404, Mr = 519.34, Dc = 1.661 g/cm3, F(000) = 526, ,u(MoKa) = 0.691 mm^-, R = 0.0405 and wR = 0.0977. The 1,4-bdc dianions link the neighboring Mn(II) atoms to yield a two-dimensional layer structure. The L ligands are attached on both sides of the layer. The π-π interactions between the L ligands of neighboring layers result in a three-dimensional supramolecular architecture. 展开更多
关键词 manganese complex crystal structure coordination polymer
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