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基于HEC-HMS水文模型的潼三段流域2021年秋汛洪水模拟
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作者 娄书建 刘世帆 《人民黄河》 CAS 北大核心 2024年第11期63-67,共5页
水库精细化调度是确保防洪安全与提高水库综合效益的主要措施。以三门峡库区潼关至三门峡大坝间流域(潼三段流域)无测控区为研究区域,基于土壤、土地利用、降水、径流等数据,构建HEC-HMS水文模型,对2021年潼三段流域整个秋汛洪水过程进... 水库精细化调度是确保防洪安全与提高水库综合效益的主要措施。以三门峡库区潼关至三门峡大坝间流域(潼三段流域)无测控区为研究区域,基于土壤、土地利用、降水、径流等数据,构建HEC-HMS水文模型,对2021年潼三段流域整个秋汛洪水过程进行模拟,分析区间各支流洪水叠加过程与径流量变化。采用径流系数法(算术平均法和泰森多边形法)计算潼三段流域径流总量并与实测值对比,验证HEC-HMS水文模型模拟结果的准确性。结果表明:HEC-HMS水文模型在潼三段流域表现出良好的适用性与可靠性,径流总量模拟值与实测值仅相差2.33%,模拟效果显著优于径流系数法。 展开更多
关键词 HEC-hms水文模型 秋汛 洪水模拟 潼三段流域 三门峡库区
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基于HEC-HMS的黄土高塬沟壑区流域城市化对洪水情势的影响 被引量:1
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作者 钟芳倩 霍艾迪 +3 位作者 赵志欣 陈建 杨璐莹 王星 《人民黄河》 CAS 北大核心 2024年第2期67-72,79,共7页
黄土高塬沟壑区城市化过程中下垫面硬化会影响暴雨水文情势,增大洪水模拟预报难度。为实现对流域城市洪水灾害的预警,基于HEC-HMS水文模型,分别率定砚瓦川流域城市化前后不同时期土地利用条件下的产汇流参数,开展极端暴雨洪水情景设计,... 黄土高塬沟壑区城市化过程中下垫面硬化会影响暴雨水文情势,增大洪水模拟预报难度。为实现对流域城市洪水灾害的预警,基于HEC-HMS水文模型,分别率定砚瓦川流域城市化前后不同时期土地利用条件下的产汇流参数,开展极端暴雨洪水情景设计,揭示流域城市化对不同重现期洪水的水文效应。结果表明:建立的HEC-HMS降雨-径流模型适用于黄土高塬沟壑区洪水预报,其模拟综合合格率为81.25%,平均Nash效率系数为0.82;流域城市化对重现期短的洪水要素变化影响较大,且洪量变化幅度大于洪峰变化幅度,100 a一遇洪水的洪峰和洪量的增幅分别为4.54%和6.40%,5 a一遇洪水的洪峰和洪量的增幅分别为7.06%和9.49%;各子流域设计洪水对流域城市化的响应分布具有空间差异性,以西北部地区响应为最强,其次为南部地区,东北部地区最弱。 展开更多
关键词 HEC-hms模型 流域城市化 洪水响应 砚瓦川流域 黄土高塬沟壑区
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基于HEC-HMS模型的三峡区间洪水模拟
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作者 王雨潇 刘波 +3 位作者 王文鹏 吴光东 张天宇 孙营营 《长江科学院院报》 CSCD 北大核心 2024年第6期76-83,共8页
三峡区间面积在长江上游的流域面积占比5.6%,但在三峡入库洪水组成中,区间形成的洪水占比可达10%以上,可见区间暴雨洪水是水库防洪安全必须考量的重要因素。采用2007—2011年三峡入库流量,上游边界寸滩和武隆站实测流量资料,建立了基于H... 三峡区间面积在长江上游的流域面积占比5.6%,但在三峡入库洪水组成中,区间形成的洪水占比可达10%以上,可见区间暴雨洪水是水库防洪安全必须考量的重要因素。采用2007—2011年三峡入库流量,上游边界寸滩和武隆站实测流量资料,建立了基于HEC-HMS的三峡区间洪水模拟模型,用于分析区间暴雨洪水与入库洪水的关系。根据入库洪水来源组成分析和资料特点,提出分类调参、分期检验的区间洪水建模方案:对以上游来水为主型洪水,率定汇流参数;对区间降水贡献较大型洪水,率定产流参数;对2012年以后的模拟洪水过程,以三峡水库运行实录发布的洪水过程线为比对基准。结果表明:模型精度良好,率定期和验证期洪峰流量相对误差在±20%以内,峰现时间误差<3 h;经与长江三峡工程运行实录比对,模型适用于模拟2012年后的三峡入库洪水过程。以20160626场次洪水为典型,分析该场区间洪水对入库洪水的峰值贡献率达27.2%,使得峰现时间提前16 h。研究成果可用于三峡区间洪水的影响研究,也可作为区间流域洪水模拟模型建模方案的技术参考。 展开更多
关键词 三峡区间 洪水过程模拟 HEC-hms模型 参数率定
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Corrosion behavior of pure metals(Ni and Ti)and alloys(316H SS and GH3535)in liquid GaInSn 被引量:1
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作者 Jian-Hui Yu Hong-Xia Xu +3 位作者 Xiang-Xi Ye Bin Leng Han-Xun Qiu Xing-Tai Zhou 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第3期70-83,共14页
In this study,the interactions between a Ga-based liquid metal,GaInSn,and several metal materials,including pure metals(Ni and Ti)and alloys(316H stainless steel(SS)and GH3535),at 650℃were investigated.The aim was to... In this study,the interactions between a Ga-based liquid metal,GaInSn,and several metal materials,including pure metals(Ni and Ti)and alloys(316H stainless steel(SS)and GH3535),at 650℃were investigated.The aim was to evaluate the corrosion performance and select a suitable candidate material for use as a molten salt manometer diaphragm in thermal energy storage systems.The results indicated that the alloys(316H SS and GH3535)exhibited less corrosion than pure metals(Ni and Ti)in liquid GaInSn.Ga-rich binary intermetallic compounds were found to form on the surfaces of all the tested metal materials exposed to liquid GaInSn,as a result of the decomposition of liquid GaInSn and its reaction with the constituent elements of the metal materials.The corrosion mechanism for all the tested materials exposed to liquid GaInSn was also investigated and proposed,which may aid in selecting the optimal candidate material when liquid GaInSn is used as the pressure-sensing medium. 展开更多
关键词 Metal materials Liquid GaInSn CORROSION Intermetallic compounds Thermal energy storage systems
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基于HEC-HMS的资料匮乏山区洪水模拟研究
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作者 葛柯焱 万新宇 +2 位作者 徐洪军 范威 王森 《水力发电》 CAS 2024年第3期19-24,共6页
以白花河小流域为例,探讨缺资料地区HEC-HMS模型的适用效果。通过流域DEM等下垫面数据获取流域信息,采用SCS-CN曲线法、SCS单位线法、指数衰退法、马斯京根演算法进行流域产汇流计算及河道洪水演算,构建了HEC-HMS降雨径流模型,结合广东... 以白花河小流域为例,探讨缺资料地区HEC-HMS模型的适用效果。通过流域DEM等下垫面数据获取流域信息,采用SCS-CN曲线法、SCS单位线法、指数衰退法、马斯京根演算法进行流域产汇流计算及河道洪水演算,构建了HEC-HMS降雨径流模型,结合广东省综合单位线法与推理公式法的结果对模型参数进行率定。结果表明,设计洪水计算结果的误差均小于20%且平均相对误差均小于10%;实测洪水模拟的洪峰流量相对误差小于10%,Nash系数为0.90。HEC-HMS模型进行径流模拟效果较好,可适用于研究区山洪预报。 展开更多
关键词 无资料地区 HEC-hms模型 GIS 山洪 模拟
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HEC-HMS水文模型不同降雨损失方法对比研究
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作者 赵直 冯民权 侯梓良 《水文》 CSCD 北大核心 2024年第2期83-88,共6页
为对比分析HEC-HMS模型三种降雨损失方法在沁河流域的适用性。借助Morris筛选法识别降雨损失方法的关键参数,选用流域内5场雨洪资料进行参数率定和模拟精度分析。结果表明:(1)SCS CN值曲线法、Green-Ampt法、Initial and Uniform法主要... 为对比分析HEC-HMS模型三种降雨损失方法在沁河流域的适用性。借助Morris筛选法识别降雨损失方法的关键参数,选用流域内5场雨洪资料进行参数率定和模拟精度分析。结果表明:(1)SCS CN值曲线法、Green-Ampt法、Initial and Uniform法主要敏感性参数分别为CN值、土壤饱和导水率、恒定损失率。(2)选取洪峰流量、洪水总量、峰现时刻误差以及Nash系数对模型模拟精度进行评价,SCS CN值曲线法和Initial and Uniform法模拟结果达到乙等精度,Green-Ampt法模拟结果达到丙等精度。研究成果可为半湿润地区中小流域降雨损失方法的选择提供参考。 展开更多
关键词 HEC-hms 洪水模拟 降雨损失方法 参数敏感性分析 沁河流域
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考虑Copula-LM-HMS耦联的台风情境下大坝洪水漫顶风险率计算
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作者 李佳 傅志敏 王亚坤 《中国农村水利水电》 北大核心 2024年第1期126-134,共9页
气候变化下台风风暴潮出现频次增加,形成的暴雨洪水对水库大坝安全产生极大威胁。由于部分地区实测流量资料缺少,基于雨量资料的随机模型与水文模型耦合模拟洪水过程线的研究亟待发展。针对现有小流域流量资料缺少问题,研究了基于降雨... 气候变化下台风风暴潮出现频次增加,形成的暴雨洪水对水库大坝安全产生极大威胁。由于部分地区实测流量资料缺少,基于雨量资料的随机模型与水文模型耦合模拟洪水过程线的研究亟待发展。针对现有小流域流量资料缺少问题,研究了基于降雨随机模型与水文模型的Copula-LM-HMS耦联模型,来模拟入库洪水并计算水库大坝洪水漫顶风险率。该模型通过Copula函数与拉丁超立方-蒙特卡罗抽样(Latin Hypercube-Monte Carlo Simulation)生成流域多组7日降雨数据,并通过变倍比放大法缩放处理得到相应降雨序列,利用HEC-HMS水文模型模拟洪水过程线并结合调洪演算得到坝前最高水位,同时考虑风浪作用来模拟台风情景下的库水位变化情况,计算大坝洪水漫顶风险率,并分析不同组合条件对洪水漫顶风险率的影响。余姚市四明湖水库实例分析表明,构建的Copula-LM-HMS耦合模型计算得到的拦河坝在未来台风情境下无漫顶风险,自溃坝最小漫顶风险为0.22%,最大漫顶风险达到2.68%;洪水漫顶风险与降雨分布及起调水位有关,同时风浪作用对洪水漫顶风险影响较大。基于耦合模型进行中小流域洪水漫顶风险率计算,不仅能考虑降雨系列之间的相关性、流域地形特征与实际调洪规则,还可延长无流量资料地区水库大坝应对台风情境下洪水风险的预报期,为保证水库大坝应对未来气候变化影响下的运行安全提供参考。 展开更多
关键词 台风风暴潮 洪水漫顶风险率 随机降雨模拟 HEC-hms水文模型 调洪演算模型
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From Topological Nodal-Line Semimetals to Quantum Spin Hall Insulators in Tetragonal SnX Monolayers(X=F,Cl,Br,I)
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作者 朱晔 赵宝 +3 位作者 薛阳 徐玮 徐文婷 杨中芹 《Chinese Physics Letters》 SCIE EI CAS CSCD 2024年第6期98-111,共14页
Two-dimensional(2D)topological materials have recently garnered significant interest due to their profound physical properties and promising applications for future quantum nanoelectronics.Achieving various topologica... Two-dimensional(2D)topological materials have recently garnered significant interest due to their profound physical properties and promising applications for future quantum nanoelectronics.Achieving various topological states within one type of materials is,however,seldom reported.Based on first-principles calculations and tightbinding models,we investigate topological electronic states in a novel family of 2D halogenated tetragonal stanene(T-SnX,X=F,Cl,Br,I).All the four monolayers are found to be unusual topological nodal-line semimetals(NLSs),protected by a glide mirror symmetry.When spin-orbit coupling(SOC)is turned on,T-SnF and TSnCl are still ascertained as topological NLSs due to the remaining band inversion,primarily composed of Sn pxy orbitals,while T-Sn Br and T-SnI become quantum spin Hall insulators.The phase transition is ascribed to moving up in energy of Sn s orbitals and increasing of SOC strengths.The topology origin in the materials is uniformly rationalized through elementary band representations.The robust and diverse topological states found in the 2D T-SnX monolayers position them as an excellent material platform for development of innovative topological electronics. 展开更多
关键词 TOPOLOGICAL metals quantum
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Analysis and Assessment on the Heavy Metals in a Severely Degraded Subtropical Red Soil Region
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作者 Fang Wang Yun Zhou +5 位作者 Xiangping Fu Yuxiao Zhao Yiyao Wen Xintao Cui Shunbao Lu Yanjie Zhang 《American Journal of Plant Sciences》 CAS 2024年第2期110-121,共12页
5 different forests of Pinus massoniana, Schima superba, Liquidambar formosana, P. massoniana × S. superba, P. massoniana × L. formosana as the research object were set up to study the Cr, Cu and Zn content ... 5 different forests of Pinus massoniana, Schima superba, Liquidambar formosana, P. massoniana × S. superba, P. massoniana × L. formosana as the research object were set up to study the Cr, Cu and Zn content of degraded red soil region in subtropics. The soil heavy metal pollution degree was evaluated by national environmental quality standard (II class). The results showed that three soil metals of P. massoniana × S. superba were the highest, and the soil metals enrichment ability was strong. The order of single factor pollution index of metal elements was Cu (1.38) > Cr (0.81) > Zn (0.42), and moderately pollution, pollution warning and no pollution, respectively. There was no significant correlation between three soil heavy metals and soil total carbon (TC), total nitrogen (TN) and total phosphorus (TP). These results suggested that the accumulation of heavy metal elements was not derived from the parent material of soil. There was a significant positive correlation between the three metal elements which indicated that the sources of the three elements were similar. The structural equation model showed that the direct and indirect effects among the influencing factors ultimately affected the activity of heavy metals by cascade effects. 展开更多
关键词 Subtropical Forest Type Degraded Red Soil Heavy metals Pollution Evaluation
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Microplastic and Heavy Metals Distributions in Urban Rivers Sediments,China
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作者 SONG Dandan SHANG Yujun +4 位作者 WANG Xiuli ZHUANG Yuwei GUO Hui BI Shuping HU Jianjun 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第4期1015-1025,共11页
This study investigated the distribution of microplastics and heavy metals,along with the interaction between the two in the sediments of urban rivers in China.Results showed that the abundance of microplastics ranged... This study investigated the distribution of microplastics and heavy metals,along with the interaction between the two in the sediments of urban rivers in China.Results showed that the abundance of microplastics ranged from 2412±187.5 to 7638±1312items kg^(-1)dry sediment across different survey stations,with an average abundance at(4388±713)items kg^(-1)dry sediment.Upon further categorization,it was found that transparent fragments were the primary color and type of microplastics present.The potential ecological risk index(RI)of heavy metals in sediments suggested a low level of ecological risk within a majority of the urban rivers studied.Cd was identified as the main potential ecological risk factor in the sediments of the studied areas.There was a relatively good significant linear relationship between the RI of heavy metals and the abundance of microplastics,bolstering the linkage between these two environmental pollutants.However,the concentrations of heavy metals in microplastics were not dependent on their corresponding contents in sediments.In fact,the concentration of Cu,Cd,and As in microplastics were higher than those in the sediments.This finding confirmed that microplastics could serve as carriers of heavy metals and introduce potential risks to aquatic wildlife and human through the food chain. 展开更多
关键词 microplastic heavy metals risk assessment river sediments
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Activating Ru in the pyramidal sites of Ru_(2)P-type structures with earth-abundant transition metals for achieving extremely high HER activity while minimizing noble metal content
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作者 Sayed M.El-Refaei Patrícia A.Russo +4 位作者 Thorsten Schultz Zhe-Ning Chen Patrick Amsalem Norbert Koch Nicola Pinna 《Carbon Energy》 SCIE EI CAS CSCD 2024年第9期80-92,共13页
Rational design of efficient pH-universal hydrogen evolution reaction catalysts to enable large-scale hydrogen production via electrochemical water splitting is of great significance,yet a challenging task.Herein,Ru a... Rational design of efficient pH-universal hydrogen evolution reaction catalysts to enable large-scale hydrogen production via electrochemical water splitting is of great significance,yet a challenging task.Herein,Ru atoms in the Ru_(2)P structure were replaced with M=Co,Ni,or Mo to produce M_(2-x)Ru_(x)P nanocrystals.The metals show strong site preference,with Co and Ni occupying the tetrahedral sites and Ru the square pyramidal sites of the CoRuP and NiRuP Ru_(2)P-type structures.The presence of Co or Ni in the tetrahedral sites leads to charge redistribution for Ru and,according to density functional theory calculations,a significant increase in the Ru d-band centers.As a result,the intrinsic activity of CoRuP and NiRuP increases considerably compared to Ru_(2)P in both acidic and alkaline media.The effect is not observed for MoRuP,in which Mo prefers to occupy the pyramidal sites.In particular,CoRuP shows state-of-the-art activity,outperforming Ru_(2)P with Pt-like activity in 0.5 M H_(2)SO_(4)(η10=12.3 mV;η100=52 mV;turnover frequency(TOF)=4.7 s^(-1)).It remains extraordinarily active in alkaline conditions(η10=12.9 mV;η100=43.5 mV)with a TOF of 4.5 s^(-1),which is 4x higher than that of Ru_(2)P and 10x that of Pt/C.Further increase in the Co content does not lead to drastic loss of activity,especially in alkaline medium,where,for example,the TOF of Co_(1.9)Ru_(0.1)P remains comparable to that of Ru_(2)P and higher than that of Pt/C,highlighting the viability of the adopted approach to prepare cost-efficient catalysts. 展开更多
关键词 electrocatalysis ruthenium phosphide transition metal phosphonates
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Accumulation of Heavy Metals in Maga-Pouss Rice Fields (Far-North Region, Cameroon) and Transfer to Rice Grains
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作者 Diane Madomguia Gilbert Bello Basokdou +3 位作者 Kalieu W. Appoline Isabelle Patrice Kuitekam Dongo Edouard Nya Serge Hubert Zebaze Togouet 《Agricultural Sciences》 2024年第3期311-326,共16页
Monitoring of heavy metals contamination of agricultural products and their transfer and bioaccumulation in crops like rice has become a hot topic worldwide over the last two decades. The present study was carried out... Monitoring of heavy metals contamination of agricultural products and their transfer and bioaccumulation in crops like rice has become a hot topic worldwide over the last two decades. The present study was carried out to determine the accumulation of heavy metals in rice fields and their transfer to rice grains. Soil, irrigation water and rice grains samples were gathered in Maga-Pouss, Far-North, Cameroon. Concentrations of six heavy metals (lead, cadmium, zinc, copper, iron and mercury) were evaluated by Atomic Absorption Spectrophotometer (AAS). Mercury was not detected in this study. Average concentrations of metals were in this order (in mg/kg): Fe (188.60 ± 97.06) > Pb (63.63 ± 7.11) > Cd (2.59 ± 0.29) > Zn (1.10 ± 1.05) > Cu (0.80 ± 0.73) in water and Pb (105.50 ± 31.11) > Fe (105.50 ± 31.11) > Cu (45.93 ± 14.39) > Zn (22.52 ± 6.40) > Cd (3.15 ± 0.49) in soil. Water in Maga-Pouss rice fields appears to be more harmful than the soil, notably for lead, cadmium and copper. In rice grains, heavy metals were found in this order (mg/kg): Fe (188.01 ± 82.62) > Cu (27.20 ± 0.00) > Zn (23.61 ± 12.42) > Pb (19.50 ± 19.91) > Cd (2.02 ± 1.05). The mean bioconcentration factor (BCF) of metals from soil to rice grains was in the following order: Fe (2.60) > Zn (1.05) > Cd (0.64) > Cu (0.59) > Pb (0.18). From water to rice grains, the order is: Cu (37.26) > Zn (22.49) > Cd (6.97) > Pb (2.74) > Fe (1.94). Rice field pH and electrical conductivity favored the uptake of lead, copper and cadmium by rice grains. The findings of this study will be good documentation for risk assessment, and decision-making by environmental managers in this region. 展开更多
关键词 Heavy metals Rice Field Bioconcenration Factor Maga-Pouss ACCUMULATION
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Single crystal growth and characterization of 166-type magnetic kagome metals
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作者 Huangyu Wu Jinjin Liu +5 位作者 Yongkai Li Peng Zhu Liu Yang Fuhong Chen Deng Hu Zhiwei Wang 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第9期145-150,共6页
Kagome magnets were predicted to be a good platform to investigate correlated topology band structure,Chern quantum phase,and geometrical frustration due to their unique lattice geometry.Here we reported single crysta... Kagome magnets were predicted to be a good platform to investigate correlated topology band structure,Chern quantum phase,and geometrical frustration due to their unique lattice geometry.Here we reported single crystal growth of 166-type kagome magnetic materials,including HfMn_(6)Sn_(6),ZrMn_(6)Sn_(6),GdMn_(6)Sn_(6)and GdV_(6)Sn_(6),by using the flux method with Sn as the flux.Among them,HfMn_(6)Sn_(6)and ZrMn_(6)Sn_(6)single crystals were grown for the first time.X-ray diffraction measurements reveal that all four samples crystallize in HfFe6Ge6-type hexagonal structure with space group P6/mmm.All samples show metallic behavior from temperature dependence of resistivity measurements,and the dominant carrier is hole,except for GdV6Sn6 which is electron dominated.All samples have magnetic order with different transition temperatures,HfMn_(6)Sn_(6),ZrMn_(6)Sn_(6)and GdV_(6)Sn_(6)are antiferromagnetic with TN of 541 K,466 K and 4 K respectively,while GdMn_(6)Sn_(6)is ferrimagnetic with the critical temperature of about 470 K.This study will enrich the research platform of magnetic kagome materials and help explore the novel quantum phenomena in these interesting materials.The dataset of specific crystal structure parameters for HfMn_(6)Sn_(6)are available in Science Data Bank,with the link. 展开更多
关键词 kagome metal single crystal growth crystal structure physical property
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Characterization of Nutrients,Heavy Metals,Petroleum and Their Impact on Phytoplankton in Laizhou Bay:Implications for Environmental Management and Monitoring
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作者 WANG Kai ZHAO Linlin +3 位作者 ZHU Yugui YANG Liqiang WANG Yunfeng HONG Xuguang 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第3期822-834,共13页
The Laizhou Bay(LB)represents a substantial ecological area that is vulnerable to human activities and confronts diverse environmental challenges.This study provides a comprehensive characterization of nutrients,petro... The Laizhou Bay(LB)represents a substantial ecological area that is vulnerable to human activities and confronts diverse environmental challenges.This study provides a comprehensive characterization of nutrients,petroleum,heavy metals,and phytoplankton community structure across seven distinct areas in LB.The results indicate relatively high concentrations of NO_(2)-N,SiO_(4)-Si,and NO_(3)-N in the Southwest Laizhou Bay(SWLB)and Huanghe River Estuary(HRE).In contrast,the East Laizhou bay(ELB)and the North of Huanghe River Estuary(NHRE)exhibit the highest concentrations of heavy metals(As,Cr and Hg).The areas with high phytoplankton density and community diversity are mainly located in the SWLB.After adjusting for basic environmental factors,phytoplankton density and Margalef richness index D are significantly associated with nutrients(NO_(3)-N,NO_(2)-N,NH_(4)-N,SiO_(4)-Si),and heavy metal(Cr)concentrations.We highlight that,in addition to Xiaoqinghe River,nutrients brought by the Mihe River in the SWLB and heavy metal(Cr)pollution in the ELB resulting from industrial and mining activities along the coast significantly influence phytoplankton growth and community structure.Therefore,it is recommended that more monitoring and management efforts be focused on these regions in the future. 展开更多
关键词 Huanghe River Estuary Laizhou Bay NUTRIENTS heavy metals PHYTOPLANKTON BIODIVERSITY
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Valuable metals recovery from spent ternary lithium-ion battery:A review
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作者 Hao Liao Shengen Zhang +3 位作者 Bo Liu Xuefeng He Jixin Deng Yunji Ding 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第12期2556-2581,共26页
Ternary lithium-ion batteries(LIBs),widely used in new energy vehicles and electronic products,are known for their high en-ergy density,wide operating temperature range,and excellent cycling performance.With the rapid... Ternary lithium-ion batteries(LIBs),widely used in new energy vehicles and electronic products,are known for their high en-ergy density,wide operating temperature range,and excellent cycling performance.With the rapid development of the battery industry,the recycling of spent ternary LIBs has become a hot topic because of their economic value and environmental concerns.To date,a con-siderable amount of literature has reported on the recycling of spent ternary LIBs designed to provide an efficient,economical,and envir-onmentally friendly method for battery recycling.This article examines the latest developments in various technologies for recycling spent ternary LIBs in both research and practical production,including pretreatment,pyrometallurgy,hydrometallurgy,pyro-hydrometallurgy,and direct regeneration.Suggestions for addressing challenges based on the benefits and disadvantages of each method are made.Finally,through a comparison of the feasibility and economic benefits of various technologies,the challenges faced during battery recycling are summarized,and future development directions are proposed. 展开更多
关键词 spent ternary LIBs recycling technologies valuable metals economic analysis
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Assessment of Heavy Metals Contamination of Topsoil and Street Dust around Cement Factory in Southern Jordan
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作者 Omar Ali Al-Khashman Alia Omar Al-Khashman +2 位作者 Navasingh Rajesh Jesudoss Hynes Hani M. Alnawafleh Pitchumani Shenbaga Velu 《Journal of Environmental Protection》 2024年第6期672-696,共25页
Evaluation of assessment of the metal processes governing the metals distribution in soil and dust samples is very significant and protects the health of human and ecological system. Recently, special attention has gi... Evaluation of assessment of the metal processes governing the metals distribution in soil and dust samples is very significant and protects the health of human and ecological system. Recently, special attention has given to the assessment of metals pollution impact on soil and dust within industrial areas. This study aims to assess the metal contamination levels in the topsoil and street dust around the cement factory in Qadissiya area, southern Jordan. The levels of seven metals (namely Fe, Zn, Cu, Pb, Cr, Cd, and Mn) were analyzed using Flame Atomic Absorption Spec-trophotometer (FAAS) to monitor, evaluate, and to compare topsoil and road dust pollution values of metals of the different types of urban area. The physicochemical parameters which believed to affect the mobility of metals in the soil of the study area were determined such as pH, EC, TOM, CaCO3 and CEC. The levels of metal in soil samples are greater on the surface but decrease in the lower part as a result of the basic nature of soil. The mean values of the metals in soil can be arranged in the following order: Zn > Pb > Mn > Fe > Cu > Cr > Cd. The relatively high concentration of metals in the soil sample was attributed to anthropogenic activities such as traffic emissions, cement factory and agricultural activities. Correlation coefficient analysis and the spatial distribution of indices and the results of statistical analysis indicate three groups of metals: Fe and Mn result by natural origin, Zn, Pb, Cu and Zn result by anthropogenic origin (mainly motor vehicle traffic and abrasion of tires) while Cd is mixed origin. The higher content level values of metals of anthropogenic source in soil samples indicate that it is a source of contamination of air in the studied area. . 展开更多
关键词 Cement Dust Heavy metals Contamination Risk Assessment Statistical Analysis JORDAN
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Environmental characteristics of trace metals in seawater from the Ninety East Ridge in the Indian Ocean
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作者 Jingxi LI Di ZHANG +3 位作者 Fenghua JIANG Hong CHEN Wei CAO Chengjun SUN 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2024年第4期1119-1129,共11页
The Ninety East Ridge in the Indian Ocean has complex and unique characteristics.The concentrations and distribution characteristics of 10 trace metals(V,Cr,Mn,Fe,Co,Ni,Cu,Cd,Pb,and U)in seawater from the Ninety East ... The Ninety East Ridge in the Indian Ocean has complex and unique characteristics.The concentrations and distribution characteristics of 10 trace metals(V,Cr,Mn,Fe,Co,Ni,Cu,Cd,Pb,and U)in seawater from the Ninety East Ridge in the Indian Ocean were investigated.Results show that the average concentrations of different trace metals in all the collected seawater samples were 1.134μg/L for V,0.158μg/L for Cr,0.489μg/L for Mn,0.427μg/L for Fe,0.011μg/L for Co,0.395μg/L for Ni,0.403μg/L for Cu,0.097μg/L for Cd,0.139μg/L for Pb,and 3.470μg/L for U.Differences in the horizontal and vertical distributions of all measured trace metals were revealed,and the occurrence of high concentrations was nonuniform.In addition,the significant differences in the concentration distribution of different trace metals in seawater on both sides of the Ninety East Ridge present regional segmentation in the area for various trace metals in deep sea water.This study provided basic data for future investigations on the environmental and ecological impact of trace metals in the Indian Ocean and the potential water mass transport mechanism. 展开更多
关键词 trace metal environmental characteristic Ninety East Ridge seawater Indian Ocean
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Evaluation of Agricultural Contamination Level by Heavy Metals and Pesticides in Sediments of Rivers and Water Bodies for Shrimp Fishing in the Lower Ouémé: Case of the Aguigadji, Ahlan and Sele Stations in Benin
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作者 Souradjou Orou Goura Fadéby Modeste Gouissi +3 位作者 Armelle Sabine Yélignan Hounkpatin Wakili Bolatito Yessoufou Tayéwo Sylvain Biaou Nonvignon Martial Fassinou 《Advances in Materials Physics and Chemistry》 CAS 2024年第2期25-46,共22页
This study assessed sediment contamination by heavy metals and pesticide active ingredients linked to chemical inputs used in agricultural activities in the lower Ouémé. Pesticide residues from the organochl... This study assessed sediment contamination by heavy metals and pesticide active ingredients linked to chemical inputs used in agricultural activities in the lower Ouémé. Pesticide residues from the organochlorine, pyrethroid and organophosphorus families were investigated by gas chromatography, and heavy metals (Cd, Pb, As, Ni, Zn, Fe, Mg, Cr and Hg) by atomic absorption spectrophotometry. The metallic pollution indices, the contamination factor (CF) and the ecological risk index were calculated. The results revealed 8 active ingredients in the rainy season and 9 in the dry season. Glyphosate was the active ingredient with the highest concentration at all stations, 9.65 ± 0.84 mg/kg recorded in the dry season at the Aguigadji station. All glyphosate values were above the EQS. DDT, Atrazine and Endosulfan also showed high concentrations in the dry and rainy seasons. Emamectin, Abamectin and Lambda Cyhalothrin also showed high concentrations in the dry season at Aguigadji, Ahlan and Sele. Only glyphosate was recorded at the control station (Toho), but in very low concentrations. Lead showed the highest concentrations at all the stations, 265.96 ± 21.02 mg/Kg in the rainy season and 255.38 ± 79.09 mg/Kg in the dry season, all detected at the Aguigadji station and above the EQS. Zn, Ni, Fe, Cu and Cr were all representative in both the dry and rainy seasons at the contaminated stations. Manganese showed high concentrations in the rainy season. Pb showed very high contamination (FC ≥ 6) at the Aguigadji and Ahlan stations and significant contamination (3 ≤ FC 6) at the Sele station in both the rainy and dry seasons. Ni, Hg and Cd, showed either moderate or significant contamination at the contaminated stations. The risk values showed a considerable ecological Ri (190 ≤ Ri < 380) in the rainy season and a moderate ecological Ri (95 ≤ Ri < 190) in the dry season at these contaminated stations. 展开更多
关键词 PESTICIDES Heavy metals SEDIMENTS Shrimp Fishing Area Lower Ouémé
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Extraction of Valuable Metals from Titanium-bearing Blast Furnace Slag by Acid Leaching
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作者 刘燕 CHEN Xuegui +2 位作者 MAO Shuaidong XIAO Yadong LI Jiacong 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第2期376-385,共10页
To realize the resource utilization of the valuable metals in the titanium-containing blast furnace slag,the process route of “hydrochloric acid leaching-electrolysis-carbonization and carbon dioxide capture-preparat... To realize the resource utilization of the valuable metals in the titanium-containing blast furnace slag,the process route of “hydrochloric acid leaching-electrolysis-carbonization and carbon dioxide capture-preparation of calcium carbonate” was proposed.In this study,the influences of process conditions on the leaching rates of calcium,magnesium,aluminum,and iron and the phases of the leaching residue were investigated for the leaching process.The experimental results show that the HCl solution could selectively leach the elements from the titanium-containing blast furnace slag.The better leaching conditions are the HCl solution concentration of 4 mol/L,the leaching time of 30 min,the ratio of liquid volume to solid gas of 10 mL/g,and the stirring paddle speed of 300 r/min.Under the conditions,the leaching rates of calcium,magnesium,aluminum,and iron can reach 85.87%,73.41%,81.35%,and 59.08%,and the leaching rate of titanium is 10.71%.The iron and the aluminum are removed from the leachate to obtain iron-aluminum water purification agents,and the magnesium is removed from the leachate to obtain magnesium hydroxide.The leaching residue phase is dominated by perovskite,followed by magnesium silicate and tricalcium aluminate,and the titaniumrich material could be obtained from the leaching residue by desiliconization. 展开更多
关键词 titanium-containing blast furnace slag acid leaching valuable metals comprehensive utilization
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Release characteristics and stabilization of heavy metals in antimony tailings in Yunnan Province,China
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作者 LUO Guangfei ZHANG Jin +2 位作者 HAN Zhiwei OUYANG Jidi WU Pan 《Journal of Mountain Science》 SCIE CSCD 2024年第10期3337-3352,共16页
The pollution caused by the mining and smelting of heavy metals is becoming an increasingly severe environmental problem.In this study,the environmental risks of mine tailings were explored using typical antimony tail... The pollution caused by the mining and smelting of heavy metals is becoming an increasingly severe environmental problem.In this study,the environmental risks of mine tailings were explored using typical antimony tailings(the depth of the sample taken from the ground to the deepest position of 120 cm)from the Zuoxiguo mine in Yunnan Province,Southwest China.The tailings were examined to explore the geological background,distribution characteristics,and release characteristics of heavy metals.Additionally,stabilizer treatments for heavy metals were investigated in consideration of waste treatment.The results showed that the contents of Sb and As(8.93×103 and 425 mg/kg,respectively)in the tailings were considerably higher than the local soil background values,suggesting that these metals pose a considerable threat to the surrounding environment.The geological background values of Cr,Cd,Pb,Cu,and Zn were relatively low.The results of static release showed that Sb,As,Cd,and Cr leached from the tailings more easily than Cu,Zn,and Pb under acidic conditions(pH=2.98).Geo-accumulation indices and potential ecological risk indices showed that Sb,As,Cd,and Pb were highly enriched in the tailings,whereas Cu,Cr,and Zn contents were relatively low.The single factor ecological risk index of the mining area showed that Sb and As are high ecological risk factors,whereas Cr,Cu,Zn,Cd,and Pb are not.The results of the orthogonal test results showed that by adding 15.0%(m/m)fly ash and 15.0%(m/m)zeolite powder to the quicklime and curing for 28 d,a significant stabilization effect was observed for Sb,As,and Pb.This study helps determine the priority control components for characteristic heavy metals in antimony tailings,and provides valuable insights regarding the formulation of appropriate mitigation strategies. 展开更多
关键词 Heavy metals Antimony mine Tailing dumps Environmental pollution Release characteristics Stabilization efficiency
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