Metam sodium (MS; sodium N-methyl dithiocarbamate) has emerged as a promising soil fumigant in the US to replace methyl bromide (MeBr). Metam potassium (MK; potassium N-methyl dithiocarbamate) and MS break down ...Metam sodium (MS; sodium N-methyl dithiocarbamate) has emerged as a promising soil fumigant in the US to replace methyl bromide (MeBr). Metam potassium (MK; potassium N-methyl dithiocarbamate) and MS break down into the volatile gas methyl isothiocyanate (MITC) to control soil borne pests. Many studies have focused on MS, but MK has not been studied as thoroughly. The objective of this research was to determine the effect of increasing organic matter (OM) treatments and soil texture to minimize the off-gassing of MS and MK. Bench-scale soil column studies were performed to simulate organic matter treatments that may decrease the volatilization loss of MITC. Incorporation depth of OM simulated surface tillage (0-15 cm) practices. Soil was packed in steel columns and MS or MK was applied at a depth of 15 cm and MITC volatilization was measured using gas chromatography/mass spectroscopy. Volatilization of MITC behaved similarly for MS and MK with MITC movement impacted by soil texture. MITC volatilization was lower from a sandy clay loam than a sandy soil. Surface incorporation of OM did not significantly decrease MITC volatilization. These results suggest that soil texture is the dominant factor reducing MITC off-gassing and prolonging the time needed to control soil borne pests.展开更多
Fumigation is a widely applied approach to mitigate the soil-borne diseases.However,the potential effects of currently applied fumigants on ammonification remain unclear.An 84-day incubation experiment was conducted b...Fumigation is a widely applied approach to mitigate the soil-borne diseases.However,the potential effects of currently applied fumigants on ammonification remain unclear.An 84-day incubation experiment was conducted based on non-fumigated soil(CK)and fumigated soil using three common fumigants,i.e.,chloropicrin(CP),1,3-dichloropropene(1,3-D),and metam sodium(MS).The results showed that,the three fumigants all decreased the microbial C,and the largest reduction(84.7%)occurred with the application of CP.After fumigation,the microbial diversity in the CP treatment rapidly recovered,but that in the 1,3-D treatment decreased and did not recover by the end of the experiment.The application of MS showed no impact on the microbial diversity during the assay,indicating that significantly different microbial diversity can be achieved by choosing different fumigants.Futhermore,the three fumigants showed divergent effects on the enzymes involved in ammonification.The analysis showed that the enzyme variation with CP application was mainly associated with the changed microbial C and N(P<0.05),and not with the microbial community,which was different from the observed effects of 1,3-D or MS application.In addition,the soil quality index showed that CP was still significantly harmful at the end of incubation compared with the good resilience of MS,indicating that CP may not be a suitable fumigant.展开更多
文摘Metam sodium (MS; sodium N-methyl dithiocarbamate) has emerged as a promising soil fumigant in the US to replace methyl bromide (MeBr). Metam potassium (MK; potassium N-methyl dithiocarbamate) and MS break down into the volatile gas methyl isothiocyanate (MITC) to control soil borne pests. Many studies have focused on MS, but MK has not been studied as thoroughly. The objective of this research was to determine the effect of increasing organic matter (OM) treatments and soil texture to minimize the off-gassing of MS and MK. Bench-scale soil column studies were performed to simulate organic matter treatments that may decrease the volatilization loss of MITC. Incorporation depth of OM simulated surface tillage (0-15 cm) practices. Soil was packed in steel columns and MS or MK was applied at a depth of 15 cm and MITC volatilization was measured using gas chromatography/mass spectroscopy. Volatilization of MITC behaved similarly for MS and MK with MITC movement impacted by soil texture. MITC volatilization was lower from a sandy clay loam than a sandy soil. Surface incorporation of OM did not significantly decrease MITC volatilization. These results suggest that soil texture is the dominant factor reducing MITC off-gassing and prolonging the time needed to control soil borne pests.
基金Supported by the National Key Research and Development Program of China(2018YFD0300505)the National Key Technologies Project of China in Urban Agriculture during the 12th Five-Year Plan(2014BAD14B03).
文摘Fumigation is a widely applied approach to mitigate the soil-borne diseases.However,the potential effects of currently applied fumigants on ammonification remain unclear.An 84-day incubation experiment was conducted based on non-fumigated soil(CK)and fumigated soil using three common fumigants,i.e.,chloropicrin(CP),1,3-dichloropropene(1,3-D),and metam sodium(MS).The results showed that,the three fumigants all decreased the microbial C,and the largest reduction(84.7%)occurred with the application of CP.After fumigation,the microbial diversity in the CP treatment rapidly recovered,but that in the 1,3-D treatment decreased and did not recover by the end of the experiment.The application of MS showed no impact on the microbial diversity during the assay,indicating that significantly different microbial diversity can be achieved by choosing different fumigants.Futhermore,the three fumigants showed divergent effects on the enzymes involved in ammonification.The analysis showed that the enzyme variation with CP application was mainly associated with the changed microbial C and N(P<0.05),and not with the microbial community,which was different from the observed effects of 1,3-D or MS application.In addition,the soil quality index showed that CP was still significantly harmful at the end of incubation compared with the good resilience of MS,indicating that CP may not be a suitable fumigant.