The major elements, trace elements. K-Ar age and Sr-Nd-Pb isotopie systems ofthe Cenozoic volcanic rocks in Daheishan Island and Cishan, Penglai, Shandong Province aremeasured. The volcanic rocks ( olivine-nephelinite...The major elements, trace elements. K-Ar age and Sr-Nd-Pb isotopie systems ofthe Cenozoic volcanic rocks in Daheishan Island and Cishan, Penglai, Shandong Province aremeasured. The volcanic rocks ( olivine-nephelinite and nephcline-basanite ) in Daheishan Islanderupted periodically in an interval of 0.32 Ma, from 8.72 Ma. 8.39 Ma. 8.08 Ma to 7.73 Ma. Thevolcanic rocks arc all rich in light REEs. They are similar to the OIB-type alkali basalt in thetrace elements normalized model by primordial mantle: rich in high field elements such as Nb and Ta,and imcompatible elements such as Cs. Rb, Ba, Th. U. The volcanic rocks show a depletion of K andRb elements. It is suggested by the trace elements that the olivine-nephelinite in Daheishan Islandis originated from deep resources under the continental mantle. ε Nd (0) values of the volcanicrocks in Daheishan Island and Cishan are 5.31~8.51 and 7.33 respectively, suggesting that thevolcanic rocks are from the depleted mantle resources, which have higher Sm/Nd ratios than the CHUR.^(143)Nd /^(144)Nd ratios ot Daheishan Island olivine-nephelinite and Cishan alkali basalts are0.512 910~0.513 074 and 0.513 014 respectively. The ^(87)Sr /^(86)Sr of Daheishan Island volcanicrocks are lower than that of Cishan, 0.703 427 ~0.703 482 and 0.703 895 respectively. The DaheishanIsland olivine-nephelinite has the Pb isotopie values as follows: ^(206)Pb/^(204)Pb= 18.028 9~17.972 8. ^(207)Pb / ^(204)Pb = 15.435 8 ~15.402 2 and ^(208)Pb /^(204)Pb = 38.087 6~37.997 5.lower than those of Cishan basanite. The Cishan basanite has ^(206)Pb/^(204)Pb= 18.240 1. ^(207)Pb/^(204)Pb= 15.564 5 and ^(208)Pb /^(204)Pb = 38.535. The authors suggest that theolivine-nephelinite in Daheishan Island is similar to the E-type MORB or Hawaii OIB, and the alkalibasalts in Cishan similar to the Kerguelen OIB. The dominant mantle components of DM+PREMA andperhaps DM ( Dupal type ) are the dominant mantle components for volcanic rocks in Daheishan Islandand Cishan. The PREMA component plays an important role.展开更多
Plagioclases occur mainly as phenocrysts in volcanic rocks of King George Island, South Shetland Islands, West Antarctica. In basaltic andesites and andesites of Keller Peninsula and Ullman Spur (Admiralty Bay), they ...Plagioclases occur mainly as phenocrysts in volcanic rocks of King George Island, South Shetland Islands, West Antarctica. In basaltic andesites and andesites of Keller Peninsula and Ullman Spur (Admiralty Bay), they are high structure state labradorite andesines; and in high Al basalts and basaltic andesites of Barton and Weaver peninsulas (Maxwell Bay), they are high structure state bytownite anorthites.∑[WT9.BZ]REE, La/Yb ratios and δEu values of plagioclases from Admiralty Bay are higher than those from Maxwell Bay. All plagioclases have rather identical chondrite normalized transitional element distribution patterns, probably reflecting that crystal structure rather than composition of plagioclase controls their diversity. Compositions of plagioclases depend chiefly on those of their host rocks, compositional differences of plagioclases reveal that basaltic magmas in the Admiralty Bay area are more evolved than in the Maxwell Bay area.展开更多
This paper re-describes the characteristics of pre-Ordovician (Pt3) metamorphic volcanic rocks in the Huimin-Manlai region of Yunnan Province from the aspects of petrographic characteristics, rock assemblage, petroche...This paper re-describes the characteristics of pre-Ordovician (Pt3) metamorphic volcanic rocks in the Huimin-Manlai region of Yunnan Province from the aspects of petrographic characteristics, rock assemblage, petrochemistry, REE, trace elements, lead isotopes and geotectonic setting. The metamorphic volcanic rocks maintain blasto-intergranular and blasto-andesitic textures; the volcanic rocks are characterized by a basalt-andesite-dacite assemblage; the volcanic rocks are basic-intermediate-intermediate-acid in chemical composition, belonging to semi-alkaline rocks, with calc-alkaline series and tholeiite series coexisting, and they are characterized by low TiO2 contents; their REE distribution patterns are of the LREE-enrichment right-inclined type; the volcanic rocks are enriched in large cation elements and commonly enriched in Th and partly depleted in Ti, Cr and P, belonging to the Gondwana type as viewed from their Pb isotopic composition; petrochemically the data points fall mostly within the field of island-arc volcanic rocks. All these characteristics provided new evidence for the existence of original Tethysan island-arc volcanic rocks in the region studied.展开更多
Precise in situ zircon U-Pb dating and Lu-Hf isotopic measurement using an LA-ICP-MS system, whole-rock major and trace element geochemistry and Sr-Nd isotope geochemistry were conducted on the volcanic host rocks of ...Precise in situ zircon U-Pb dating and Lu-Hf isotopic measurement using an LA-ICP-MS system, whole-rock major and trace element geochemistry and Sr-Nd isotope geochemistry were conducted on the volcanic host rocks of the Tongyu copper deposit on the basis of further understanding of its geological characteristics. Three zircon samples from the volcanic host rocks yielded 206Pb/238 U weighted average ages ranging from 436±4 Ma to 440±5 Ma, which are statistically indistinguishable and coeval with the ca. 440 Ma northward subduction event of the Paleo-Qinling oceanic slab. The volcanic host rocks were products of magmatic differentiation that evolved from basalt to andesite to dacite to rhyolite, forming an integrated tholeiitic island arc volcanic rock suite. The primitive mantle-normalized trace element patterns for most samples show characteristics of island arc volcanic rocks, such as relative enrichment of LILE(e.g. Th, U, Pb and La) and depletion of HFSE(e.g. Nb, Ta, Ti, Zr and Hf). Discrimination diagrams of Ta/Yb vs Th/Yb, Ta vs Th, Yb vs Th/Ta, Ta/Hf vs Th/Hf, Hf/3 vs Th vs Nb/16, La vs La/Nb and Nb vs Nb/Th all suggest that both the volcanic host rocks from the Tongyu copper deposit and the volcanic rocks from the regional Xieyuguan Group were formed in an island arc environment related to subduction of an oceanic slab. Values of ISr(0.703457 to 0.708218) and εNd(t)(-2 to 5.8) indicate that the source materials of volcanic rocks from the Tongyu copper deposit and the Xieyuguan Group originated from the metasomatised mantle wedge with possible crustal material assimilation. Most of the volcanic rock samples show good agreement with the values of typical island arc volcanic rocks in the ISr-εNd(t) diagram. The involvement of crustal-derived material in the magma of the volcanic rocks from the Tongyu copper deposit was also reflected in the zircon εHf(t) values, which range from-3.08 to 10.7, and the existence of inherited ancient xenocrystic zircon cores(2616±39 Ma and 1297±22 Ma). The mineralization of the Tongyu copper deposit shows syn-volcanic characteristics such as layered orebodies interbedded with the volcanic rock strata, thus, the zircon U-Pb age of the volcanic host rocks can approximately represent the mineralization age of the Tongyu copper deposit. Both the Meigou pluton and the volcanic host rocks were formed during the ca. 440 Ma northward subduction of the Paleo-Qinling Ocean when high oxygen fugacity aqueous hydrothermal fluid released by dehydration of the slab and the overlying sediments fluxed into the mantle wedge, triggered partial melting of the mantle wedge, and activated and extracted Cu and other ore-forming elements. The magma and ore-bearing fluid upwelled and erupted, and consequently formed the island arc volcanic rock suite and the Tongyu VHMS-type copper deposit.展开更多
A group of εNd-La/Nb, Ba/Nb, Nb/Th diagrams are used to study mantleheterogeneity. Island-arc basalts (IAB) are distributed in a triangle of these diagrams.Three end-member components (the MORB-type depleted mantle, ...A group of εNd-La/Nb, Ba/Nb, Nb/Th diagrams are used to study mantleheterogeneity. Island-arc basalts (IAB) are distributed in a triangle of these diagrams.Three end-member components (the MORB-type depleted mantle, the fiuid released fromsubducted oceanic crust and the sediments from the continental crust) of the source ofIAB may be displayed in these diagrams. Two types of IAB are identified. They areof the two-component type (with little continental sediments), such as the basalts fromAleutians and New Britain, and the three-component type, such as those from Sunda,Lesser Antilles and Andes. In addition, the EMII type mantle-derived rocks may alsobe divided into two groups. One is exemplifled by continental flood basalts and someperidotite xenoliths, similar to IAB, with high La/Nb and Ba/Nb and low Nb/Th ratios.The other includes the Samoa-type oceanic island basalts, with low La/Nb and Ba/Nband high Nb/Th ratios. The corresponding two sub-components of EMII are EMIIM,which is related to the metasomatism of lithosphere mantle by fluids released from thesubducted oceanic crust, and EMIISR, related to the intervention of recycling continentalsediments into the convective mantle.展开更多
Detailed studies indicate that a typical island-arc magmatic zone exists in the Lianghe-Raofeng-Wuliba area of south Qinling. This is characterized by continental marginal andesite and bimodal volcanic rock associatio...Detailed studies indicate that a typical island-arc magmatic zone exists in the Lianghe-Raofeng-Wuliba area of south Qinling. This is characterized by continental marginal andesite and bimodal volcanic rock association which was formed in a rift environment within an oceanic island-arc. The island-arc magmatic zone is the product of Devonian-Carboniferous oceanic crust sub-duction and rifting of Mianlue ancient oceanic basin. The presence of the island-arc magmatic zone suggests that the Mianxian-Lueyang suture zone had extended to the Bashan arcuate area. The Sunjiahe volcanic rock association of the Xixiang Group formed in a volcanic-arc setting which should have a close relationship with Mianlue suture zone.展开更多
基金supported by the National Major Fundamental Research and Development Project(No.G2000046703).
文摘The major elements, trace elements. K-Ar age and Sr-Nd-Pb isotopie systems ofthe Cenozoic volcanic rocks in Daheishan Island and Cishan, Penglai, Shandong Province aremeasured. The volcanic rocks ( olivine-nephelinite and nephcline-basanite ) in Daheishan Islanderupted periodically in an interval of 0.32 Ma, from 8.72 Ma. 8.39 Ma. 8.08 Ma to 7.73 Ma. Thevolcanic rocks arc all rich in light REEs. They are similar to the OIB-type alkali basalt in thetrace elements normalized model by primordial mantle: rich in high field elements such as Nb and Ta,and imcompatible elements such as Cs. Rb, Ba, Th. U. The volcanic rocks show a depletion of K andRb elements. It is suggested by the trace elements that the olivine-nephelinite in Daheishan Islandis originated from deep resources under the continental mantle. ε Nd (0) values of the volcanicrocks in Daheishan Island and Cishan are 5.31~8.51 and 7.33 respectively, suggesting that thevolcanic rocks are from the depleted mantle resources, which have higher Sm/Nd ratios than the CHUR.^(143)Nd /^(144)Nd ratios ot Daheishan Island olivine-nephelinite and Cishan alkali basalts are0.512 910~0.513 074 and 0.513 014 respectively. The ^(87)Sr /^(86)Sr of Daheishan Island volcanicrocks are lower than that of Cishan, 0.703 427 ~0.703 482 and 0.703 895 respectively. The DaheishanIsland olivine-nephelinite has the Pb isotopie values as follows: ^(206)Pb/^(204)Pb= 18.028 9~17.972 8. ^(207)Pb / ^(204)Pb = 15.435 8 ~15.402 2 and ^(208)Pb /^(204)Pb = 38.087 6~37.997 5.lower than those of Cishan basanite. The Cishan basanite has ^(206)Pb/^(204)Pb= 18.240 1. ^(207)Pb/^(204)Pb= 15.564 5 and ^(208)Pb /^(204)Pb = 38.535. The authors suggest that theolivine-nephelinite in Daheishan Island is similar to the E-type MORB or Hawaii OIB, and the alkalibasalts in Cishan similar to the Kerguelen OIB. The dominant mantle components of DM+PREMA andperhaps DM ( Dupal type ) are the dominant mantle components for volcanic rocks in Daheishan Islandand Cishan. The PREMA component plays an important role.
文摘Plagioclases occur mainly as phenocrysts in volcanic rocks of King George Island, South Shetland Islands, West Antarctica. In basaltic andesites and andesites of Keller Peninsula and Ullman Spur (Admiralty Bay), they are high structure state labradorite andesines; and in high Al basalts and basaltic andesites of Barton and Weaver peninsulas (Maxwell Bay), they are high structure state bytownite anorthites.∑[WT9.BZ]REE, La/Yb ratios and δEu values of plagioclases from Admiralty Bay are higher than those from Maxwell Bay. All plagioclases have rather identical chondrite normalized transitional element distribution patterns, probably reflecting that crystal structure rather than composition of plagioclase controls their diversity. Compositions of plagioclases depend chiefly on those of their host rocks, compositional differences of plagioclases reveal that basaltic magmas in the Admiralty Bay area are more evolved than in the Maxwell Bay area.
基金This research was granted by the National Natural Science Foundation of China (Grant No. 40372105).
文摘This paper re-describes the characteristics of pre-Ordovician (Pt3) metamorphic volcanic rocks in the Huimin-Manlai region of Yunnan Province from the aspects of petrographic characteristics, rock assemblage, petrochemistry, REE, trace elements, lead isotopes and geotectonic setting. The metamorphic volcanic rocks maintain blasto-intergranular and blasto-andesitic textures; the volcanic rocks are characterized by a basalt-andesite-dacite assemblage; the volcanic rocks are basic-intermediate-intermediate-acid in chemical composition, belonging to semi-alkaline rocks, with calc-alkaline series and tholeiite series coexisting, and they are characterized by low TiO2 contents; their REE distribution patterns are of the LREE-enrichment right-inclined type; the volcanic rocks are enriched in large cation elements and commonly enriched in Th and partly depleted in Ti, Cr and P, belonging to the Gondwana type as viewed from their Pb isotopic composition; petrochemically the data points fall mostly within the field of island-arc volcanic rocks. All these characteristics provided new evidence for the existence of original Tethysan island-arc volcanic rocks in the region studied.
基金jointly supported by the National Natural Science Foundation of China(Grant Nos.41272092,41421002 and 41072068)Program for Changjiang Scholars and Innovative Research Team in University(Grant IRT1281)+1 种基金Natural Science Basic Research Program of Shaanxi Province,China(Grant No.2013JZ013)Graduate Innovation Funds of Northwest University,China(Grant No.YZZ12006)
文摘Precise in situ zircon U-Pb dating and Lu-Hf isotopic measurement using an LA-ICP-MS system, whole-rock major and trace element geochemistry and Sr-Nd isotope geochemistry were conducted on the volcanic host rocks of the Tongyu copper deposit on the basis of further understanding of its geological characteristics. Three zircon samples from the volcanic host rocks yielded 206Pb/238 U weighted average ages ranging from 436±4 Ma to 440±5 Ma, which are statistically indistinguishable and coeval with the ca. 440 Ma northward subduction event of the Paleo-Qinling oceanic slab. The volcanic host rocks were products of magmatic differentiation that evolved from basalt to andesite to dacite to rhyolite, forming an integrated tholeiitic island arc volcanic rock suite. The primitive mantle-normalized trace element patterns for most samples show characteristics of island arc volcanic rocks, such as relative enrichment of LILE(e.g. Th, U, Pb and La) and depletion of HFSE(e.g. Nb, Ta, Ti, Zr and Hf). Discrimination diagrams of Ta/Yb vs Th/Yb, Ta vs Th, Yb vs Th/Ta, Ta/Hf vs Th/Hf, Hf/3 vs Th vs Nb/16, La vs La/Nb and Nb vs Nb/Th all suggest that both the volcanic host rocks from the Tongyu copper deposit and the volcanic rocks from the regional Xieyuguan Group were formed in an island arc environment related to subduction of an oceanic slab. Values of ISr(0.703457 to 0.708218) and εNd(t)(-2 to 5.8) indicate that the source materials of volcanic rocks from the Tongyu copper deposit and the Xieyuguan Group originated from the metasomatised mantle wedge with possible crustal material assimilation. Most of the volcanic rock samples show good agreement with the values of typical island arc volcanic rocks in the ISr-εNd(t) diagram. The involvement of crustal-derived material in the magma of the volcanic rocks from the Tongyu copper deposit was also reflected in the zircon εHf(t) values, which range from-3.08 to 10.7, and the existence of inherited ancient xenocrystic zircon cores(2616±39 Ma and 1297±22 Ma). The mineralization of the Tongyu copper deposit shows syn-volcanic characteristics such as layered orebodies interbedded with the volcanic rock strata, thus, the zircon U-Pb age of the volcanic host rocks can approximately represent the mineralization age of the Tongyu copper deposit. Both the Meigou pluton and the volcanic host rocks were formed during the ca. 440 Ma northward subduction of the Paleo-Qinling Ocean when high oxygen fugacity aqueous hydrothermal fluid released by dehydration of the slab and the overlying sediments fluxed into the mantle wedge, triggered partial melting of the mantle wedge, and activated and extracted Cu and other ore-forming elements. The magma and ore-bearing fluid upwelled and erupted, and consequently formed the island arc volcanic rock suite and the Tongyu VHMS-type copper deposit.
文摘A group of εNd-La/Nb, Ba/Nb, Nb/Th diagrams are used to study mantleheterogeneity. Island-arc basalts (IAB) are distributed in a triangle of these diagrams.Three end-member components (the MORB-type depleted mantle, the fiuid released fromsubducted oceanic crust and the sediments from the continental crust) of the source ofIAB may be displayed in these diagrams. Two types of IAB are identified. They areof the two-component type (with little continental sediments), such as the basalts fromAleutians and New Britain, and the three-component type, such as those from Sunda,Lesser Antilles and Andes. In addition, the EMII type mantle-derived rocks may alsobe divided into two groups. One is exemplifled by continental flood basalts and someperidotite xenoliths, similar to IAB, with high La/Nb and Ba/Nb and low Nb/Th ratios.The other includes the Samoa-type oceanic island basalts, with low La/Nb and Ba/Nband high Nb/Th ratios. The corresponding two sub-components of EMII are EMIIM,which is related to the metasomatism of lithosphere mantle by fluids released from thesubducted oceanic crust, and EMIISR, related to the intervention of recycling continentalsediments into the convective mantle.
文摘Detailed studies indicate that a typical island-arc magmatic zone exists in the Lianghe-Raofeng-Wuliba area of south Qinling. This is characterized by continental marginal andesite and bimodal volcanic rock association which was formed in a rift environment within an oceanic island-arc. The island-arc magmatic zone is the product of Devonian-Carboniferous oceanic crust sub-duction and rifting of Mianlue ancient oceanic basin. The presence of the island-arc magmatic zone suggests that the Mianxian-Lueyang suture zone had extended to the Bashan arcuate area. The Sunjiahe volcanic rock association of the Xixiang Group formed in a volcanic-arc setting which should have a close relationship with Mianlue suture zone.