Two new coordination polymers based on 4-[（8-hydroxy-5-quinolinyl）azo]-benzenesulfonic acid（H2L）,{[CdL（H2O）2]·H2O}n（1） and {[CdL（en）]·EtOH}n（2）（en=ethylenediamine）,were solvothermally synthesiz...Two new coordination polymers based on 4-[（8-hydroxy-5-quinolinyl）azo]-benzenesulfonic acid（H2L）,{[CdL（H2O）2]·H2O}n（1） and {[CdL（en）]·EtOH}n（2）（en=ethylenediamine）,were solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction.Compounds 1 and 2 exhibit infinite 1D ladder-shaped chain structures,which are isostructural except that the two coordinating water molecules in compound 1 were replaced by one en molecule in compound 2 due to the use of different organic base.Compounds 1 and 2 were constructed into different supramolecular frameworks by hydrogen bonding and π…π stacking interactions.In addition,the fluorescent properties of compounds 1 and 2 were investigated.Furthermore,they were also investigated via IR spectral analysis,elemental analysis,powder X-ray diffraction（PXRD） and thermogravimetric analysis（TGA）.展开更多
One new coordination polymer based on 4-[（8-hydroxy-5-quinolinyl）azo]-benzoic acid（H2L）, { [CdL（H20）]·H2O}n（1） was solvothermally synthesized and structurally characterized by single-crystal X-ray diffrac...One new coordination polymer based on 4-[（8-hydroxy-5-quinolinyl）azo]-benzoic acid（H2L）, { [CdL（H20）]·H2O}n（1） was solvothermally synthesized and structurally characterized by single-crystal X-ray diffrac- tion, infrared spectrometry, elemental analysis, powder X-ray diffraction（PXRD） and thermogravimetric analysis （TGA）. In compound 1, L2- ligands link Cd（II） to form a sinusoidal ruffling layer, in which the carboxylic groups connect Cd（II） into an infinite Cd--O chain. And the layers are further stabilized by hydrogen bonding and π-π in- teractions, forming a three-dimensional（3D） supramolecular network. In addition, the fluorescent property of compound 1 was also investigated.展开更多
基金Supported by the National Basic Research Program of China（No.2012CB821700）, the Major International（Regional） Joint Research Project of National Natural Science Foundation of China（No.21120102034）, the National Natural Science Foundation of China（No.20831002） and the Project of the Education Department of Jilin Province, China（No.2013-328）.
文摘Two new coordination polymers based on 4-[（8-hydroxy-5-quinolinyl）azo]-benzenesulfonic acid（H2L）,{[CdL（H2O）2]·H2O}n（1） and {[CdL（en）]·EtOH}n（2）（en=ethylenediamine）,were solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction.Compounds 1 and 2 exhibit infinite 1D ladder-shaped chain structures,which are isostructural except that the two coordinating water molecules in compound 1 were replaced by one en molecule in compound 2 due to the use of different organic base.Compounds 1 and 2 were constructed into different supramolecular frameworks by hydrogen bonding and π…π stacking interactions.In addition,the fluorescent properties of compounds 1 and 2 were investigated.Furthermore,they were also investigated via IR spectral analysis,elemental analysis,powder X-ray diffraction（PXRD） and thermogravimetric analysis（TGA）.
基金the National Basic Research Program of China，the Major International（Regional） Joint Research Project of National Natural Science Foundation，the National Natural Science Foundation of China，the Project of Education Department of Jilin Province,China
文摘One new coordination polymer based on 4-[（8-hydroxy-5-quinolinyl）azo]-benzoic acid（H2L）, { [CdL（H20）]·H2O}n（1） was solvothermally synthesized and structurally characterized by single-crystal X-ray diffrac- tion, infrared spectrometry, elemental analysis, powder X-ray diffraction（PXRD） and thermogravimetric analysis （TGA）. In compound 1, L2- ligands link Cd（II） to form a sinusoidal ruffling layer, in which the carboxylic groups connect Cd（II） into an infinite Cd--O chain. And the layers are further stabilized by hydrogen bonding and π-π in- teractions, forming a three-dimensional（3D） supramolecular network. In addition, the fluorescent property of compound 1 was also investigated.
