For the purpose of developing an alkali leaching solvent extraction directly from alkali solution process, the extraction of niobium from alkali solution by long chain alkyl quaternary ammonium salt (methyltrioctylamm...For the purpose of developing an alkali leaching solvent extraction directly from alkali solution process, the extraction of niobium from alkali solution by long chain alkyl quaternary ammonium salt (methyltrioctylammonium chloride R 4NCl) in toluene was investigated. The experiments were carried out under conditions of 25 ℃, Nb(Ⅴ) concentration 0.01 mol/L, pH 10.7 13.8, R 4NCl concentration 0.02 0.14 mol/L. It has been found that the distribution ratio of niobium increases with increasing R 4NCl concentration and with decreasing KCl concentration, but it shows maximum value at pH value of about 12 and decreases below or above this pH value. Distribution ratio of niobium goes up to over 1 000 in appropriate conditions, and so it has been proved that R 4NCl is an effective extractant for extraction of niobium from alkali solution.展开更多
The authors developed a nitrate ion-selective electrode（ISE） based on poly（vinyl chloride）（PVC） membrane with methyltrioctylammonium nitrate as a carrier and 1-decanol as a plasticizer.The performance of the nit...The authors developed a nitrate ion-selective electrode（ISE） based on poly（vinyl chloride）（PVC） membrane with methyltrioctylammonium nitrate as a carrier and 1-decanol as a plasticizer.The performance of the nitrate-sensitive membranes was optimized by tuning the composition of components.The electrode exhibits a linear response with a Nernstian slope of（52±1.0） mV per decade for the nitrate ion concentration ranging from 5.8×10-5 mol/L to 1.0 mol/L.The electrode can be used to detect a low concentration of nitrate ions down to 3×10-5 mol/L in a pH range of 2.1―11.5 without any compensation.The advantage of the electrode includes simple preparation,short response time and good repeatability.The detection performance of the novel electrode on nitrate ions has been tested for water samples.展开更多
文摘For the purpose of developing an alkali leaching solvent extraction directly from alkali solution process, the extraction of niobium from alkali solution by long chain alkyl quaternary ammonium salt (methyltrioctylammonium chloride R 4NCl) in toluene was investigated. The experiments were carried out under conditions of 25 ℃, Nb(Ⅴ) concentration 0.01 mol/L, pH 10.7 13.8, R 4NCl concentration 0.02 0.14 mol/L. It has been found that the distribution ratio of niobium increases with increasing R 4NCl concentration and with decreasing KCl concentration, but it shows maximum value at pH value of about 12 and decreases below or above this pH value. Distribution ratio of niobium goes up to over 1 000 in appropriate conditions, and so it has been proved that R 4NCl is an effective extractant for extraction of niobium from alkali solution.
基金Supported by the Project of Wuxi Pollution Prevention Funding Agency,China(No.2008-1)
文摘The authors developed a nitrate ion-selective electrode（ISE） based on poly（vinyl chloride）（PVC） membrane with methyltrioctylammonium nitrate as a carrier and 1-decanol as a plasticizer.The performance of the nitrate-sensitive membranes was optimized by tuning the composition of components.The electrode exhibits a linear response with a Nernstian slope of（52±1.0） mV per decade for the nitrate ion concentration ranging from 5.8×10-5 mol/L to 1.0 mol/L.The electrode can be used to detect a low concentration of nitrate ions down to 3×10-5 mol/L in a pH range of 2.1―11.5 without any compensation.The advantage of the electrode includes simple preparation,short response time and good repeatability.The detection performance of the novel electrode on nitrate ions has been tested for water samples.
