The occurrence of γ phase, a high\|pressure polymorph of olivine (α phase), in the shock veins of Si\| xiangkou chondrite was due to a greater cooling rate (>10 000℃·s -1 ) in the veins. Because γ phas...The occurrence of γ phase, a high\|pressure polymorph of olivine (α phase), in the shock veins of Si\| xiangkou chondrite was due to a greater cooling rate (>10 000℃·s -1 ) in the veins. Because γ phase partially reverted to β phase and no back\|transformation from β phase to α phase took place, the shock veins of Peace River chondrite with a cooling rate of 1 000\2 000℃·s -1 contain a great amount of β phase. In the shock veins of Mbale chondrite with a cooling rate of <500℃·s -1 , the majority of γ phase reverted to α phase. The heat dissipation in shock veins took place after a stage of shock compression of chondrite parent body, and the parent body was broken into fragmental pieces. Cooling rate in the shock veins constrained the back\|transformations of (Mg,Fe)\-2SiO\-4 high\|pressure polymorphs.展开更多
Superparamagnetic monodisperse Mg0.8Mn0.2Fe2O4 nanoparticles have been successfully synthesized in liquid polyol at elevated temperature of 200 °C. Diethylene glycol(DEG) used here plays dual role in synthesis ...Superparamagnetic monodisperse Mg0.8Mn0.2Fe2O4 nanoparticles have been successfully synthesized in liquid polyol at elevated temperature of 200 °C. Diethylene glycol(DEG) used here plays dual role in synthesis as it acts as reducing agent and alternatively coats the surface of nanoparticles while synthesis and thereby maintaining uniform size and dispersibility. Powder X-ray diffraction(XRD) and magnetic measurements showed that the sample is cubic spinel and superparamagnetic at room temperature. Raman spectra confirmed the formation of the Mg0.8Mn0.2Fe2O4 nanoparticles.The nanoparticles exhibit very good stability in water due to in situ coating with DEG molecules.展开更多
文摘The occurrence of γ phase, a high\|pressure polymorph of olivine (α phase), in the shock veins of Si\| xiangkou chondrite was due to a greater cooling rate (>10 000℃·s -1 ) in the veins. Because γ phase partially reverted to β phase and no back\|transformation from β phase to α phase took place, the shock veins of Peace River chondrite with a cooling rate of 1 000\2 000℃·s -1 contain a great amount of β phase. In the shock veins of Mbale chondrite with a cooling rate of <500℃·s -1 , the majority of γ phase reverted to α phase. The heat dissipation in shock veins took place after a stage of shock compression of chondrite parent body, and the parent body was broken into fragmental pieces. Cooling rate in the shock veins constrained the back\|transformations of (Mg,Fe)\-2SiO\-4 high\|pressure polymorphs.
基金the Council of Scientific and Industrial Research, India for the award of senior research fellowship (File. 09/1077/(0001)/ 2012/EMR-1)
文摘Superparamagnetic monodisperse Mg0.8Mn0.2Fe2O4 nanoparticles have been successfully synthesized in liquid polyol at elevated temperature of 200 °C. Diethylene glycol(DEG) used here plays dual role in synthesis as it acts as reducing agent and alternatively coats the surface of nanoparticles while synthesis and thereby maintaining uniform size and dispersibility. Powder X-ray diffraction(XRD) and magnetic measurements showed that the sample is cubic spinel and superparamagnetic at room temperature. Raman spectra confirmed the formation of the Mg0.8Mn0.2Fe2O4 nanoparticles.The nanoparticles exhibit very good stability in water due to in situ coating with DEG molecules.