A novel lightweight,radiation-shielding Mg-Ta-Al layered metal-matrix composite(LMC)was successful designed by doping the extremely refractory metal(Ta)into Mg sheets.These Mg-based LMCs sheets shows excellent radiati...A novel lightweight,radiation-shielding Mg-Ta-Al layered metal-matrix composite(LMC)was successful designed by doping the extremely refractory metal(Ta)into Mg sheets.These Mg-based LMCs sheets shows excellent radiation-dose shield effect,about 145 krad·a^(−1),which is about 17 times of traditional Mg alloy,while its surface density is only about 0.9 g·cm^(−2),reducing by 60%than that of pure Ta.The quantitate relationship between radiation-dose and the materials’thickness was also confirmed to the logistic function when the surface density is in the range of 0.6-1.5 g·cm^(−2).Meantime,the rolling parameters,interface microstructure and mechanical properties in both as-rolled and annealing treated samples were evaluated.The sheets possess a special dissimilar atoms diffusion transitional zone containing an obvious inter-diffusion Mg-Al interface and the unique micro-corrugated Ta-Al interface,as well as a thin Al film with a thickness of about 10μm.The special zone could reduce the stress concentration and enhance the strength of Mg-Ta-Al LMCs.The interface bonding strength reaches up to 54-76 MPa.The ultimate tensile strength(UTS)and yield strength(TYS)of the Mg-Ta-Al sheet were high to 413 MPa and 263 MPa,respectively,along with an elongation of 5.8%.The molecular dynamics(MD)analysis results show that the two interfaces exhibit different formation mechanism,the Mg-Al interface primarily depended on Mg/Al atoms diffusion basing point defects movement,while the Ta-Al interface with a micro-interlock pining shape formed by close-packed planes slipping during high temperature strain-induced deformation process.展开更多
New Mg2Si based alloy were prepared by mechanical alloying. Sintering temperature was from 825 to 865K, which indicated that few Mg2Si were produced at lower temperature while MgO were produced at higher temperature. ...New Mg2Si based alloy were prepared by mechanical alloying. Sintering temperature was from 825 to 865K, which indicated that few Mg2Si were produced at lower temperature while MgO were produced at higher temperature. Microstructure image showed that at sintering temperature of 855K, Mg2Si were mostly synthesized with the reaction of purity magnesia powder and silicon powder. Hardness and wear tests proved that the new synthetic silicon magnesium alloy had higher hardness and good wear resistance. Under the same testing conditions, it is found that the hardness of the new material is 420.50, and pure magnesium is only 41.65.In the same experiments it is also found that under the same pressure, pure magnesium alloys than silicon wearing capacity of pure magnesium is 2 times as high that of Mg2Si based alloy. It shows that Mg2Si based alloy is the ideal material for the wear parts of car engine cylinder liner because of its small density, stable dimension, high hardness and wear-resisting.展开更多
A review of crystallochemical thermodynamic and phase diagram data of Mg RE and Al RE based systems is presented. On the basis also of their possible applications, special attention is given to the Mg rich and Al ...A review of crystallochemical thermodynamic and phase diagram data of Mg RE and Al RE based systems is presented. On the basis also of their possible applications, special attention is given to the Mg rich and Al rich alloys and to the effects of rare earth additions on their properties. A summary of the experimental work carried out by our research group on several binary and ternary alloys is reported: that is Mg RE, Al RE, and Mg RE RE′ and Al RE RE′ with two different rare earth metals. A number of regularities observed in the formation and in the crystallochemistry of binary and ternary Mg rich or Al rich phases are summarised and discussed. Their application to a fine planning of alloys having a well defined structure is suggested.展开更多
基金supported by the National Natural Science Foundation of China(grant no.52192603,52275308).
文摘A novel lightweight,radiation-shielding Mg-Ta-Al layered metal-matrix composite(LMC)was successful designed by doping the extremely refractory metal(Ta)into Mg sheets.These Mg-based LMCs sheets shows excellent radiation-dose shield effect,about 145 krad·a^(−1),which is about 17 times of traditional Mg alloy,while its surface density is only about 0.9 g·cm^(−2),reducing by 60%than that of pure Ta.The quantitate relationship between radiation-dose and the materials’thickness was also confirmed to the logistic function when the surface density is in the range of 0.6-1.5 g·cm^(−2).Meantime,the rolling parameters,interface microstructure and mechanical properties in both as-rolled and annealing treated samples were evaluated.The sheets possess a special dissimilar atoms diffusion transitional zone containing an obvious inter-diffusion Mg-Al interface and the unique micro-corrugated Ta-Al interface,as well as a thin Al film with a thickness of about 10μm.The special zone could reduce the stress concentration and enhance the strength of Mg-Ta-Al LMCs.The interface bonding strength reaches up to 54-76 MPa.The ultimate tensile strength(UTS)and yield strength(TYS)of the Mg-Ta-Al sheet were high to 413 MPa and 263 MPa,respectively,along with an elongation of 5.8%.The molecular dynamics(MD)analysis results show that the two interfaces exhibit different formation mechanism,the Mg-Al interface primarily depended on Mg/Al atoms diffusion basing point defects movement,while the Ta-Al interface with a micro-interlock pining shape formed by close-packed planes slipping during high temperature strain-induced deformation process.
基金Funded by the " 973 " Program of China (No. 2007CB613502)
文摘New Mg2Si based alloy were prepared by mechanical alloying. Sintering temperature was from 825 to 865K, which indicated that few Mg2Si were produced at lower temperature while MgO were produced at higher temperature. Microstructure image showed that at sintering temperature of 855K, Mg2Si were mostly synthesized with the reaction of purity magnesia powder and silicon powder. Hardness and wear tests proved that the new synthetic silicon magnesium alloy had higher hardness and good wear resistance. Under the same testing conditions, it is found that the hardness of the new material is 420.50, and pure magnesium is only 41.65.In the same experiments it is also found that under the same pressure, pure magnesium alloys than silicon wearing capacity of pure magnesium is 2 times as high that of Mg2Si based alloy. It shows that Mg2Si based alloy is the ideal material for the wear parts of car engine cylinder liner because of its small density, stable dimension, high hardness and wear-resisting.
文摘A review of crystallochemical thermodynamic and phase diagram data of Mg RE and Al RE based systems is presented. On the basis also of their possible applications, special attention is given to the Mg rich and Al rich alloys and to the effects of rare earth additions on their properties. A summary of the experimental work carried out by our research group on several binary and ternary alloys is reported: that is Mg RE, Al RE, and Mg RE RE′ and Al RE RE′ with two different rare earth metals. A number of regularities observed in the formation and in the crystallochemistry of binary and ternary Mg rich or Al rich phases are summarised and discussed. Their application to a fine planning of alloys having a well defined structure is suggested.