The microstructure evolution and mechanical properties of Mg–6Zn–0.5Ce–xMn(x=0 and 1 wt.%)wrought magnesium alloys were researched,and the morphologies and role of Mn element in the experimental alloys were analyze...The microstructure evolution and mechanical properties of Mg–6Zn–0.5Ce–xMn(x=0 and 1 wt.%)wrought magnesium alloys were researched,and the morphologies and role of Mn element in the experimental alloys were analyzed.The research shows that all of Mn elements form theα-Mn pure phases,which do not participate in the formation of other phases,such as theτ-phases.The mechanical properties of Mn-containing alloys in as-extruded and aged states are superior to Mn-free alloys.During the hot extrusion process,the dispersed fineα-Mn particle phase hinders the migration of grain boundaries and inhibits dynamic recrystallization,which mainly takes effect of grain refining and dispersion hardening.During the aging treatments,the dispersed fineα-Mn particle phase not only hinders the growth of the solution-treated grains,but also becomes the nucleation cores ofβ1 rod-like precipitate phase,which is conducive to increasing the nucleation rate of the precipitate phase.For the aged alloy,the Mn addition mainly takes effect of grain refining and promoting aging strengthening.展开更多
High-temperature compressive deformation behaviors of Mg–6Zn–1.5Y–0.5Ce–0.4Zr alloy were investigated at temperatures and strain rates ranging from 523 to 673 K and from 0.001 to 1 s~(-1),respectively.The studied ...High-temperature compressive deformation behaviors of Mg–6Zn–1.5Y–0.5Ce–0.4Zr alloy were investigated at temperatures and strain rates ranging from 523 to 673 K and from 0.001 to 1 s~(-1),respectively.The studied alloy was mainly composed ofα-Mg,Mg_(3)Zn_(6)Y(I phase),Mg–Zn–Ce and Mg_(3)Zn_(3)Y_(2)(W phase).The constitutive equation of Mg alloy was obtained,and the apparent activation energy(Q)was determined as 200.44 k J/mol,indicating that rare earth phase increases the difficulty of deformation.The work hardening involves three stages:(1)linear hardening stage;(2)strain hardening stage;and(3)softening and steady-state stage.During these three stages,the dislocation aggregation and tangling,dynamic recovery and recrystallization occur sequentially.To characterize the dynamic recrystallization(DRX)volume fraction,the DRX kinetics was investigated using the Avrami-type equation.The deformation mechanism of magnesium alloy under different Zener–Hollomon parameter(Z)value conditions was also studied.At high Z values and intermediate conditions,dislocations rapidly generate and pile up in the alloy.Recrystallization is hardly seen at this time.At low Z condition,the DRX occurs in the alloy.展开更多
通过自制的"T"字形模具研究了不同配比的Zn对Mg-xZn-0.5Y-0.5Zr(x=1.5,2.5,3.5 and 4.5(%,质量分数))系合金热裂敏感性的影响。通过对"T"型试样热节处宏观热裂纹的观察以及石蜡渗透法测定的裂纹的体积来表征其热裂...通过自制的"T"字形模具研究了不同配比的Zn对Mg-xZn-0.5Y-0.5Zr(x=1.5,2.5,3.5 and 4.5(%,质量分数))系合金热裂敏感性的影响。通过对"T"型试样热节处宏观热裂纹的观察以及石蜡渗透法测定的裂纹的体积来表征其热裂倾向性大小。此外采用扫描电镜(SEM)进行合金的组织形貌微观分析和裂纹自由断口表面观察,并利用X射线衍射(XRD)及投射电镜(TEM)等实验手段对其进行物相分析,确定其低熔点相主要组成,进而研究对热裂缺陷的影响。整个熔炼浇注过程利用A/D数模转换器对凝固过程进行了温度-应力采集。结果表明,MgxZn-0.5Y-0.5Zr合金的主要相组成为α-Mg,W相(Mg3Zn3Y2)及I相(Mg3Zn6Y),随着Zn含量从1.5%增加到4.5%,低熔点析出相含量明显增多,提高了枝晶间残余液相的补缩能力,有效的防止了裂纹的萌生和扩展,当Zn含量较低时,液膜理论和凝固收缩补偿理论是诠释热裂纹萌生的主要理论基础。随着Zn含量的增加,残余液相的充分补偿,桥接理论是热裂形成的主要机理。此系合金热裂敏感性由大到小顺序为Mg-1.5Zn-0.5Y-0.5Zr,Mg-2.5Zn-0.5Y-0.5Zr,Mg-3.5Zn-0.5Y-0.5Zr,Mg-4.5Zn-0.5Y-0.5Zr。展开更多
基金funded by National Natural Science Foundation of China(Project No.51701172)Foundation of China Railway Eryuan Engineering Group Co.Ltd.(Project No.KYY2020035(21-21))+1 种基金Natural Science Foundation of Hunan Province(Project No.2018JJ3504)China Postdoctoral Science Foundation(Project No.2018M632977).
文摘The microstructure evolution and mechanical properties of Mg–6Zn–0.5Ce–xMn(x=0 and 1 wt.%)wrought magnesium alloys were researched,and the morphologies and role of Mn element in the experimental alloys were analyzed.The research shows that all of Mn elements form theα-Mn pure phases,which do not participate in the formation of other phases,such as theτ-phases.The mechanical properties of Mn-containing alloys in as-extruded and aged states are superior to Mn-free alloys.During the hot extrusion process,the dispersed fineα-Mn particle phase hinders the migration of grain boundaries and inhibits dynamic recrystallization,which mainly takes effect of grain refining and dispersion hardening.During the aging treatments,the dispersed fineα-Mn particle phase not only hinders the growth of the solution-treated grains,but also becomes the nucleation cores ofβ1 rod-like precipitate phase,which is conducive to increasing the nucleation rate of the precipitate phase.For the aged alloy,the Mn addition mainly takes effect of grain refining and promoting aging strengthening.
基金Project(2016YFB0301101)supported by the National Key Research and Development Program of ChinaProjects(51571040,U1764253,51531002)supported by the National Natural Science Foundation of China。
基金Project (50271054) supported by the National Natural Science Foundation of ChinaProject (20070700003) supported by the Doctorate Programs Foundation of Ministry of Education of China+1 种基金Project (102102210031) supported by the Science and Technologies Foundation of Henan Province,ChinaProject (2010A430008) supported by the Natural Science Foundation of Henan Educational Committee of China
基金financially supported by the National Key R&D Program of China(2016YFB0301100)the Natural Science Foundation of Chongqing,China(cstc2019jcyj-msxmX0505)the support of the“111 Project”(B16007)by the Ministry of Education and Fundamental Research Fund of Central Universities in China(Grant No.2018CDJDCL0019)。
文摘High-temperature compressive deformation behaviors of Mg–6Zn–1.5Y–0.5Ce–0.4Zr alloy were investigated at temperatures and strain rates ranging from 523 to 673 K and from 0.001 to 1 s~(-1),respectively.The studied alloy was mainly composed ofα-Mg,Mg_(3)Zn_(6)Y(I phase),Mg–Zn–Ce and Mg_(3)Zn_(3)Y_(2)(W phase).The constitutive equation of Mg alloy was obtained,and the apparent activation energy(Q)was determined as 200.44 k J/mol,indicating that rare earth phase increases the difficulty of deformation.The work hardening involves three stages:(1)linear hardening stage;(2)strain hardening stage;and(3)softening and steady-state stage.During these three stages,the dislocation aggregation and tangling,dynamic recovery and recrystallization occur sequentially.To characterize the dynamic recrystallization(DRX)volume fraction,the DRX kinetics was investigated using the Avrami-type equation.The deformation mechanism of magnesium alloy under different Zener–Hollomon parameter(Z)value conditions was also studied.At high Z values and intermediate conditions,dislocations rapidly generate and pile up in the alloy.Recrystallization is hardly seen at this time.At low Z condition,the DRX occurs in the alloy.
文摘通过自制的"T"字形模具研究了不同配比的Zn对Mg-xZn-0.5Y-0.5Zr(x=1.5,2.5,3.5 and 4.5(%,质量分数))系合金热裂敏感性的影响。通过对"T"型试样热节处宏观热裂纹的观察以及石蜡渗透法测定的裂纹的体积来表征其热裂倾向性大小。此外采用扫描电镜(SEM)进行合金的组织形貌微观分析和裂纹自由断口表面观察,并利用X射线衍射(XRD)及投射电镜(TEM)等实验手段对其进行物相分析,确定其低熔点相主要组成,进而研究对热裂缺陷的影响。整个熔炼浇注过程利用A/D数模转换器对凝固过程进行了温度-应力采集。结果表明,MgxZn-0.5Y-0.5Zr合金的主要相组成为α-Mg,W相(Mg3Zn3Y2)及I相(Mg3Zn6Y),随着Zn含量从1.5%增加到4.5%,低熔点析出相含量明显增多,提高了枝晶间残余液相的补缩能力,有效的防止了裂纹的萌生和扩展,当Zn含量较低时,液膜理论和凝固收缩补偿理论是诠释热裂纹萌生的主要理论基础。随着Zn含量的增加,残余液相的充分补偿,桥接理论是热裂形成的主要机理。此系合金热裂敏感性由大到小顺序为Mg-1.5Zn-0.5Y-0.5Zr,Mg-2.5Zn-0.5Y-0.5Zr,Mg-3.5Zn-0.5Y-0.5Zr,Mg-4.5Zn-0.5Y-0.5Zr。