由于镁合金凝固温度区间很长,所以容易产生热裂。作为新型的高强度变形镁合金,Mg-Zn-Y(ZW系)合金在半连续铸造过程中极易发生热裂。采用"CRC"(Constrained Rod Casting)铸造热裂试验及冷却曲线热分析方法研究了ZW系中ZW22、Z...由于镁合金凝固温度区间很长,所以容易产生热裂。作为新型的高强度变形镁合金,Mg-Zn-Y(ZW系)合金在半连续铸造过程中极易发生热裂。采用"CRC"(Constrained Rod Casting)铸造热裂试验及冷却曲线热分析方法研究了ZW系中ZW22、ZW42、ZW44、ZW26、ZW62合金的凝固路径,凝固最后阶段剩余液相分数以及锆细化等因素和其热裂倾向的关系。热裂纹位置因子、宽度因子等热裂敏感性因子的表征结果表明,合金的热裂倾向从大到小顺序为:无Zr的ZW62>ZW62>ZW22,ZW42和ZW44>ZW26合金。无Zr的ZW62合金比其他合金具有更大热裂倾向与几方面因素有关:具有最长的凝固温度区间;从枝晶干涉点到凝固终了温度间形成W相,阻碍枝晶间剩余液体的流动性,不利于枝晶间补缩;最后凝固阶段剩余液相最少,且该阶段固相分数随温度降低增长缓慢;粗大组织和发达的枝晶。展开更多
The phase constituent evolution of Mg-Zn-Y-Zr alloys with the mole ratio of Y to Zn both in the as-cast and as-annealed states at the Mg-rich corner was investigated by XRD and SEM/EDS analysis and was further explain...The phase constituent evolution of Mg-Zn-Y-Zr alloys with the mole ratio of Y to Zn both in the as-cast and as-annealed states at the Mg-rich corner was investigated by XRD and SEM/EDS analysis and was further explained from the ternary phase diagram calculation. The results show that the formation of the secondary phases in Mg-Zn-Y-Zr alloys firmly depends on the mole ratio of Y to Zn, and X （Mg 12 YZn）-phase, W （Mg 3 Y 2 Zn 3 ）-phase and I （Mg 3 YZn 6 ）-phase come out in sequence as the ratio of Y to Zn decreases. The mole ratios of Y to Zn with the corresponding phase constituent are suggested quantitatively as follows： the phase constituent is α-Mg ＋ I when the mole ratio of Y to Zn is about 0.164; α-Mg ＋ I ＋W when the mole ratio of Y to Zn is in the range of 0.164 0.33;α-Mg ＋W when the mole ratio of Y to Zn is about 0.33; α-Mg ＋W＋X when the mole ratio of Y to Zn is in the range of 0.33 1.32; and α-Mg ＋X when the mole ratio of Y to Zn is about 1.32. The results also offer a guideline for alloy selection and alloy design in Mg-Zn-Y-Zr system.展开更多
基金supported by Chongqing Talent Plan:Leading Talents in Innovation and Entrepreneurship,China(No.CQYC201903051)University Innovation Research Group of Chongqing,China(No.CXQT20023)+4 种基金Qingnian Project of Science and Technology Research Program of Chongqing Municipal Education Commission,China(No.KJQN202001106)China Postdoctoral Science Foundation(No.2021M700556)Natural Science Foundation of Chongqing,China(No.cstc2021jcyj-bsh X0114)Natural Science Foundation of China(Nos.U20A20234,51874062)Chongqing Foundation and Advanced Research Project,China(No.cstc2019jcyj-zdxm X0010)。
文摘由于镁合金凝固温度区间很长,所以容易产生热裂。作为新型的高强度变形镁合金,Mg-Zn-Y(ZW系)合金在半连续铸造过程中极易发生热裂。采用"CRC"(Constrained Rod Casting)铸造热裂试验及冷却曲线热分析方法研究了ZW系中ZW22、ZW42、ZW44、ZW26、ZW62合金的凝固路径,凝固最后阶段剩余液相分数以及锆细化等因素和其热裂倾向的关系。热裂纹位置因子、宽度因子等热裂敏感性因子的表征结果表明,合金的热裂倾向从大到小顺序为:无Zr的ZW62>ZW62>ZW22,ZW42和ZW44>ZW26合金。无Zr的ZW62合金比其他合金具有更大热裂倾向与几方面因素有关:具有最长的凝固温度区间;从枝晶干涉点到凝固终了温度间形成W相,阻碍枝晶间剩余液体的流动性,不利于枝晶间补缩;最后凝固阶段剩余液相最少,且该阶段固相分数随温度降低增长缓慢;粗大组织和发达的枝晶。
基金Project(50725413)supported by the National Natural Science Foundation of China
文摘The phase constituent evolution of Mg-Zn-Y-Zr alloys with the mole ratio of Y to Zn both in the as-cast and as-annealed states at the Mg-rich corner was investigated by XRD and SEM/EDS analysis and was further explained from the ternary phase diagram calculation. The results show that the formation of the secondary phases in Mg-Zn-Y-Zr alloys firmly depends on the mole ratio of Y to Zn, and X （Mg 12 YZn）-phase, W （Mg 3 Y 2 Zn 3 ）-phase and I （Mg 3 YZn 6 ）-phase come out in sequence as the ratio of Y to Zn decreases. The mole ratios of Y to Zn with the corresponding phase constituent are suggested quantitatively as follows： the phase constituent is α-Mg ＋ I when the mole ratio of Y to Zn is about 0.164; α-Mg ＋ I ＋W when the mole ratio of Y to Zn is in the range of 0.164 0.33;α-Mg ＋W when the mole ratio of Y to Zn is about 0.33; α-Mg ＋W＋X when the mole ratio of Y to Zn is in the range of 0.33 1.32; and α-Mg ＋X when the mole ratio of Y to Zn is about 1.32. The results also offer a guideline for alloy selection and alloy design in Mg-Zn-Y-Zr system.
