The Sr/F co-doped CaP(Sr/F-CaP)coatings were prepared by micro-arc oxidation(MAO)under different voltages to modify the microstructure and corrosion behavior of Mg-4Zn-1Mn alloy.The surface and interface characteristi...The Sr/F co-doped CaP(Sr/F-CaP)coatings were prepared by micro-arc oxidation(MAO)under different voltages to modify the microstructure and corrosion behavior of Mg-4Zn-1Mn alloy.The surface and interface characteristics investigated using scanning electron microscopy(SEM)and energy dispersive X-ray spectrometer(EDS)showed that the MAO coatings displayed uneven crater-like holes and tiny cracks under lower voltage,while they exhibited relatively homogeneous crater-like holes without cracks under higher voltage.The thickness of MAO coatings increased with increasing voltage.The corrosion behavior of Mg-4Zn-1Mn alloy was improved by the MAO coatings.The MAO coatings prepared under 450 V and 500 V voltages possessed the best corrosion resistance with regard to the electrochemical corrosion tests and immersion corrosion tests,respectively.The MAO coatings fabricated under 450-500 V could provide a better corrosion protection effect for the substrate.展开更多
The effect of ultrasonic power and treatment time on degassing of Mg-6Zn-1Ca alloy was studied in this paper. The degassing effect was characterized by measuring densities of ingots. The results show that proper ultra...The effect of ultrasonic power and treatment time on degassing of Mg-6Zn-1Ca alloy was studied in this paper. The degassing effect was characterized by measuring densities of ingots. The results show that proper ultrasonic treatment can remove hydrogen from the melt of the Mg-6Zn-1Ca alloy. The ultrasonic degassing effect is closely related to the ultrasonic power density and treatment time. The degassing efficiency increases with an increase in ultrasonic power density when the melt is treated at 690 °C for 120 s, reaching its highest value at 1.2 W·cm-3. When the power density is 1.2 W·cm-3, with an increase in ultrasonic treatment time, the degassing efficiency increases at first, reaches its peak value at 120 s, then decreases as the ultrasonic treatment is further prolonged. In this experiment, the optimum degassing effect with an efficiency of 67.5 % is obtained by ultrasonic treatment with the power density of 1.2 W·cm-3 for 120 s. The maximum density of ingot can be increased from 1.8069 g·cm-3 to 1.8146 g·cm-3(increased by 0.43%).展开更多
The microstructures and mechanical properties of as-cast Mg-5 Sn-1 Si magnesium alloy modified with trace elements Y,Bi,Sb and Sr were investigated and compared.Results show that the microstructure of the as-cast Mg-5...The microstructures and mechanical properties of as-cast Mg-5 Sn-1 Si magnesium alloy modified with trace elements Y,Bi,Sb and Sr were investigated and compared.Results show that the microstructure of the as-cast Mg-5 Sn-1 Si alloy consists ofα-Mg,Mg_(2) Si,Mg_(2) Sn and Mg_(2)(Si_xSn_(1-x))phases.After adding 0.8 wt.%Y,0.3 wt.%Bi,0.9 wt.%Sb and 0.9 wt.%Sr,respectively into the Mg-5 Sn-1 Si magnesium alloy,Mg_(24)Y_(5),Mg_(3) Bi_(2),Mg_(3) Sb_(2) and Mg_(2) Sr phases are precipitated accordingly.Trace elements can refineα-Mg grain and Chinese scriptshaped Mg_(2) Si phase.Refinement efficiency of different trace elements onα-Mg grain and Mg_(2) Si phase is varied.Sr element has the best refinement effect,followed by Sb and Bi,while Y has the least refinement effect.Mg-5 Sn-1 Si-0.9 Sr alloy has higher tensile properties than the other three modified alloys.The refinement mechanism of Y,Bi and Sr elements on Mg-5 Sn-1 Si magnesium alloy can be explained by the growth restriction factors and the solute undercooling.For Mg-5 Sn-1 Si-0.9 Sb alloy,the heterogeneous nuclei of Mg_(3) Sb_(2) phase is the main reason for the refinement of grains and second phases.展开更多
Li addition is verified to be an effective method to increase the room temperature ductility and formability of Mg alloys.In the present study,the microstructure,texture,and tensile properties of the extruded Mg-1Zn-x...Li addition is verified to be an effective method to increase the room temperature ductility and formability of Mg alloys.In the present study,the microstructure,texture,and tensile properties of the extruded Mg-1Zn-xLi(wt%,x=0,1,3,5)alloy sheets were studied by X-ray diffraction(XRD),scanning electron microscope(SEM),and electron backscatter diffraction(EBSD).It was found that Li addition resulted in the grain coarsening and the development of new transverse direction(TD)-tilting and{101^(-)0}parallel to extrusion direction textures,which was related to the improved dynamic recrystallization and the increased prismatic slip during extrusion.The Mg-1 Zn-5 Li sheet showed the weakest texture,which contained both basal and TD-tilting oriented grains.No additional phase was formed with Li addition.The yield strength of Mg-1Zn-xLi sheets gradually decreased with increasing Li content,which was mainly related to the grain coarsening and texture weakening.In addition,the ductility of the Mg-1Zn-xLi sheet was remarkably enhanced by Li addition.The elongation of the Mg-1 Zn-5 Li sheet was 30.3%along the TD,which was three times than that of Mg-1 Zn sheet.Microstructural analysis implied that this significant ductility enhancement was associated with the improvement activation of prismatic and basal slips during the tensile tests.This study may provide insights into the development of high-ductility,low-density Mg-Zn-Li based alloys.展开更多
The effect of the quenching rate after solution treatment on the residual stress and precipitation behavior of a high strength Mg-5 Zn-3.5 Sn-1 Mn-0.5 Ca-0.5 Cu plate is studied.The simulation results show decreasing ...The effect of the quenching rate after solution treatment on the residual stress and precipitation behavior of a high strength Mg-5 Zn-3.5 Sn-1 Mn-0.5 Ca-0.5 Cu plate is studied.The simulation results show decreasing temperature gradient in the plate with decreasing quenching rate,which leads to weakened inhomogeneous plastic deformation and decreased residual stress.No dynamic precipitation on the grain boundary happens after either cold water cooling or air cooling,however,air cooling leads to dynamic precipitation of Mg-Zn phase on Mn particles around which a low-density precipitate zone develops after aging treatment.Moreover,the fine and densely distributed Mg-Zn precipitates observed after aging treatment of the cold water cooled alloy are replaced by coarse precipitates with low density for the air cooled alloy.Both the low-density precipitate zone near Mn particles and the coarsening of precipitates are the source of the decrease in hardness and tensile properties of the air cooled alloy.The residual stress drops faster than the hardness with decreasing quenching rate,which makes it possible to lower the residual stress without sacrificing too much age-hardening ability of the alloy.展开更多
In this study, the influence of minor titanium(Ti) addition on the microstructure and tensile properties of Mg-8Sn-1Zn based alloys were investigated by means of optical microscopy, X-ray diffraction, scanning electro...In this study, the influence of minor titanium(Ti) addition on the microstructure and tensile properties of Mg-8Sn-1Zn based alloys were investigated by means of optical microscopy, X-ray diffraction, scanning electron microscopy, energy dispersive spectrometry, and tensile tests. The results showed that Ti can decrease the secondary dendrite arm spacing(SDAS). The tensile strength of the Mg-8Sn-1Zn-Ti alloys is initially increased by increasing the Ti content up to 0.09 wt.%, but subsequently decreased for further increase of Ti content. The improved tensile properties are attributed to the decreased SDAS and refi ned Mg_2Sn phases, as well as the increased fraction of tin(Sn) segregated regions. The tensile fracture surface of the studied alloys shows mixed characteristics of cleavage and quasi-cleavage fracture. Adding Ti does not significantly change the fracture mode of the studied alloys.展开更多
The as-cast and as-extruded Mg–9Li–1Al–xCa alloys(x=0,0.2;wt%)were prepared by a simple alloying process followed by hot extrusion with an extrusion ratio of 28.2.The microstructures of the as-cast and as-extruded...The as-cast and as-extruded Mg–9Li–1Al–xCa alloys(x=0,0.2;wt%)were prepared by a simple alloying process followed by hot extrusion with an extrusion ratio of 28.2.The microstructures of the as-cast and as-extruded Mg–9Li–1Al–xCa alloys were observed to investigate the effect of calcium(Ca)element on the Mg–9Li–1Al(LA91)alloy,and the crystallographic calculations between Al_(2)Ca and the matrix(α-Mg andβ-Li phases)were examined on the basis of the edge-to-edge matching model.The experimental results indicate that the addition of 0.2 wt%Ca into LA91 alloy reduce the size of theα-Mg phases in the as-cast alloy and that ofβ-Li phases in the as-extruded alloy due to the Al_(2)Ca particles distributed inside the matrix.Crystallographic calculation results suggested that there is a good crystallographic matching between the matrix and Al_(2)Ca,which confirmed that Al_(2)Ca particles can act as a heterogeneous nucleation site for bothα-Mg andβ-Li phases and were effective grain refiners for LA91 alloy.展开更多
The microstructure of Mg-8Zn-1Y alloy solidified under super-high pressure was analyzed through X-ray diffraction(XRD), scanning electron microscopy(SEM) and energy dispersive spectroscopy(EDS). And, compression...The microstructure of Mg-8Zn-1Y alloy solidified under super-high pressure was analyzed through X-ray diffraction(XRD), scanning electron microscopy(SEM) and energy dispersive spectroscopy(EDS). And, compression deformation behavior at room-temperature was studied. The results showed that the microstructure of Mg-8Zn-1Y alloy solidified under ambient pressure and super-high pressure was both mainly composed of ■-Mg and quasicrystal I-Mg3Zn6 Y. Solidification under super-high pressure contributed to refining solidified microstructure and changing morphology of the intergranular second phase. The morphology of intergranular second phase(quasicrystal I-Mg3Zn6Y) was transformed from continuous network(ambient pressure) to long island(high pressure) and finally to granular(super-high pressure) with the increase in pressure. The compressive strength, yield strength and rupture strain of the samples solidified under ambient pressure were significantly improved from 262.6 MPa, 244.4 MPa and 13.3% to 437.3 MPa, 368.9 MPa and 24.7% under the pressure of 6 GPa, respectively. Under ambient pressure, cleavage plane on compressive fracture was large and smooth. When it was solidified under the pressure ranging from 4 to 6 GPa, cleavage plane on compressive fracture was small and coarse. In addition, dimple, tear ridge and lobate patterns existed.展开更多
In this study,uniaxial hot compression tests were carried out between 200 and 400℃ over strain rates of0.001-1 s-1 to investigate the hot deformation behavior of Mg-2 Zn-1 Al-0.2 RE alloy with coarse grains.The avera...In this study,uniaxial hot compression tests were carried out between 200 and 400℃ over strain rates of0.001-1 s-1 to investigate the hot deformation behavior of Mg-2 Zn-1 Al-0.2 RE alloy with coarse grains.The average activation energy was measured to be 174.51 kJ/mol.In addition,a constitutive relation based on the Arrhenius equation was established.Dynamic recrystallization(DRX) kinetics were studied by Avrami equation to characterize the evolution of DRX volume fraction.DRX was favored at high temperatures of 300-400℃ and low strain rates of 0.001-0.01 s-1.According to dynamic material model and Prasad’s instability criterion,a maximum power dissipation of 38% and 32% occurs at 400℃/0.001 s-1 and 400℃/0.01 s-1,respectively.According to the proce ssing map,330-400℃/0.001-0.01 s-1was determined as the optimum deformation parameter range.展开更多
In order to investigate the effect of extrusion on Mg-4Zn-1Y alloy, microstructure and mechanical properties were analyzed by optical microscopy(OM), scanning electron microscopy(SEM), transmission electron micros...In order to investigate the effect of extrusion on Mg-4Zn-1Y alloy, microstructure and mechanical properties were analyzed by optical microscopy(OM), scanning electron microscopy(SEM), transmission electron microscopy(TEM), X-ray diffraction(XRD), energy dispersive spectrum(EDS) and tensile testing.The results indicated that the microstructure was obviously refined by extrusion and dynamic recrystallization.The second phases were dynamic precipitated and distributed more dispersively through extrusion.W-Phases(Mg3Zn3Y2) were twisted and broken, while I-Phases(Mg3Zn6Y) were spheroidized by deformation.Twin bands were formed to achieve the large deformation and hinder the slip of dislocations effectively to improve tensile properties.The tensile strength and elongation of extruded Mg-4Zn-1Y alloy were 254.94 MPa and 17.9% respectively which were improved greatly compared with those of as-cast alloy.The strengthening mechanisms of the extruded alloy were mainly fine-grain strengthening and distortion strengthening.展开更多
The corrosion behaviors of T5 (225 ℃, 6.5 h) and T6 (460 ℃, 2 h + 225 ℃, 12 h) peak-aged Mg-7Gd- 5Y-1Nd-0.5Zr alloys with oxide films were investigated by optical microscope (OM), scanning electron microsco...The corrosion behaviors of T5 (225 ℃, 6.5 h) and T6 (460 ℃, 2 h + 225 ℃, 12 h) peak-aged Mg-7Gd- 5Y-1Nd-0.5Zr alloys with oxide films were investigated by optical microscope (OM), scanning electron microscopy (SEM), and energy-dispersive spectroscopy (EDS). The weight loss rates and electrochemical tests were also analyzed. The thicknesses of T5 and T6 oxide films are roughly 0.6 and 1.0 μm, respectively. The components of oxide films mainly consist of O, Mg, Y, Nd, and Gd, and the T6 oxide film results in surfaces with larger peaks than T5 oxide film. In addition, Y, Nd, and Gd peaks are all higher than those of Mg-7Gd-5Y- 1Nd-0.5Zr alloys, but Mg peak is consistently far below than that of the alloys. The specimens could be arranged in de- creasing order of corrosion rates and corrosion current densi- ties: T6 oxide film 〈 T5 oxide film 〈 T6 without oxide film 〈 T5 without oxide film. The oxide films are compact to increase the corrosion resistance for Mg-7Gd-5Y-1Nd-0.5Zr alloys, which will provide a guiding insight into the corrosion and protection of Mg-RE alloys in atmospheric environments.展开更多
The mechanical behavior of solution heat-treated and pre-aged Mg–6Zn–1Gd–1Er alloys during hot compression(from 180 to 330℃)has been investigated.The results showed that the flow stress curves of the pre-aged samp...The mechanical behavior of solution heat-treated and pre-aged Mg–6Zn–1Gd–1Er alloys during hot compression(from 180 to 330℃)has been investigated.The results showed that the flow stress curves of the pre-aged sample(PAS)intersected with that of the solution heat-treated sample(SHTS)during hot compression.At 180℃,when the true strain is 0.27 and 0.47,the PAS showed larger and smaller stress(210.80 MPa vs.207.58 MPa and 205.67 MPa vs.207.93 MPa)than the SHTS,respectively.These phenomena were due to the stronger interaction of W phase and dislocations/twins under the strain of 0.27,while dynamic recrystallization softening occurred under the strain of 0.47.When the temperature increased to 330℃,the flow stress of PAS and SHTS showed an opposite trend to that of 180℃.Continuous dynamic recrystallization and particle stimulated nucleation based on slip operations are the main deformation mechanisms under 330℃.At the true strain is 0.33 and 0.53,the PAS has smaller and larger stress(61.32 MPa vs.63.69 MPa and 58.75 MPa vs.57.09 MPa)than the SHTS,respectively.The increasing deformation resistance of dynamic precipitation improved the flow stress under smaller strain and dynamic recrystallization decreased the flow stress under high strain,which resulted the opposite phenomena of SHTS.展开更多
文摘The Sr/F co-doped CaP(Sr/F-CaP)coatings were prepared by micro-arc oxidation(MAO)under different voltages to modify the microstructure and corrosion behavior of Mg-4Zn-1Mn alloy.The surface and interface characteristics investigated using scanning electron microscopy(SEM)and energy dispersive X-ray spectrometer(EDS)showed that the MAO coatings displayed uneven crater-like holes and tiny cracks under lower voltage,while they exhibited relatively homogeneous crater-like holes without cracks under higher voltage.The thickness of MAO coatings increased with increasing voltage.The corrosion behavior of Mg-4Zn-1Mn alloy was improved by the MAO coatings.The MAO coatings prepared under 450 V and 500 V voltages possessed the best corrosion resistance with regard to the electrochemical corrosion tests and immersion corrosion tests,respectively.The MAO coatings fabricated under 450-500 V could provide a better corrosion protection effect for the substrate.
基金supported by the Major State Basic Research Development Program of China(2013CB632203)the National Key Technology R&D Program of China(2012BAF09B01)+2 种基金the Liaoning Provincial Natural Science Foundation(Grant No.201202072)the Program for Liaoning Excellent Talents in University(Grant No.LJQ2012023)the Fundamental Research Foundation of Central Universities(N120509002 and N120309003)
文摘The effect of ultrasonic power and treatment time on degassing of Mg-6Zn-1Ca alloy was studied in this paper. The degassing effect was characterized by measuring densities of ingots. The results show that proper ultrasonic treatment can remove hydrogen from the melt of the Mg-6Zn-1Ca alloy. The ultrasonic degassing effect is closely related to the ultrasonic power density and treatment time. The degassing efficiency increases with an increase in ultrasonic power density when the melt is treated at 690 °C for 120 s, reaching its highest value at 1.2 W·cm-3. When the power density is 1.2 W·cm-3, with an increase in ultrasonic treatment time, the degassing efficiency increases at first, reaches its peak value at 120 s, then decreases as the ultrasonic treatment is further prolonged. In this experiment, the optimum degassing effect with an efficiency of 67.5 % is obtained by ultrasonic treatment with the power density of 1.2 W·cm-3 for 120 s. The maximum density of ingot can be increased from 1.8069 g·cm-3 to 1.8146 g·cm-3(increased by 0.43%).
基金the financial support by the Natioal Natural Science Foundation of China(Nos.:51571086 and 51271073)the financial support from the Natural Science Foundation of Henan Polytechnic University(No.:B2010-20)。
文摘The microstructures and mechanical properties of as-cast Mg-5 Sn-1 Si magnesium alloy modified with trace elements Y,Bi,Sb and Sr were investigated and compared.Results show that the microstructure of the as-cast Mg-5 Sn-1 Si alloy consists ofα-Mg,Mg_(2) Si,Mg_(2) Sn and Mg_(2)(Si_xSn_(1-x))phases.After adding 0.8 wt.%Y,0.3 wt.%Bi,0.9 wt.%Sb and 0.9 wt.%Sr,respectively into the Mg-5 Sn-1 Si magnesium alloy,Mg_(24)Y_(5),Mg_(3) Bi_(2),Mg_(3) Sb_(2) and Mg_(2) Sr phases are precipitated accordingly.Trace elements can refineα-Mg grain and Chinese scriptshaped Mg_(2) Si phase.Refinement efficiency of different trace elements onα-Mg grain and Mg_(2) Si phase is varied.Sr element has the best refinement effect,followed by Sb and Bi,while Y has the least refinement effect.Mg-5 Sn-1 Si-0.9 Sr alloy has higher tensile properties than the other three modified alloys.The refinement mechanism of Y,Bi and Sr elements on Mg-5 Sn-1 Si magnesium alloy can be explained by the growth restriction factors and the solute undercooling.For Mg-5 Sn-1 Si-0.9 Sb alloy,the heterogeneous nuclei of Mg_(3) Sb_(2) phase is the main reason for the refinement of grains and second phases.
基金financially supported by the National Natural Science Foundation of China (Nos. U1764253, U2037601, U1910213, 51971044, and 52001037)the Qinghai Science and Technology Program, China (No. 2018GX-A1)
文摘Li addition is verified to be an effective method to increase the room temperature ductility and formability of Mg alloys.In the present study,the microstructure,texture,and tensile properties of the extruded Mg-1Zn-xLi(wt%,x=0,1,3,5)alloy sheets were studied by X-ray diffraction(XRD),scanning electron microscope(SEM),and electron backscatter diffraction(EBSD).It was found that Li addition resulted in the grain coarsening and the development of new transverse direction(TD)-tilting and{101^(-)0}parallel to extrusion direction textures,which was related to the improved dynamic recrystallization and the increased prismatic slip during extrusion.The Mg-1 Zn-5 Li sheet showed the weakest texture,which contained both basal and TD-tilting oriented grains.No additional phase was formed with Li addition.The yield strength of Mg-1Zn-xLi sheets gradually decreased with increasing Li content,which was mainly related to the grain coarsening and texture weakening.In addition,the ductility of the Mg-1Zn-xLi sheet was remarkably enhanced by Li addition.The elongation of the Mg-1 Zn-5 Li sheet was 30.3%along the TD,which was three times than that of Mg-1 Zn sheet.Microstructural analysis implied that this significant ductility enhancement was associated with the improvement activation of prismatic and basal slips during the tensile tests.This study may provide insights into the development of high-ductility,low-density Mg-Zn-Li based alloys.
基金supported by the National Key Research and Development Program of China[2016YFB0301105]the National Key Research and Development Plan[2017YFB0103904]
文摘The effect of the quenching rate after solution treatment on the residual stress and precipitation behavior of a high strength Mg-5 Zn-3.5 Sn-1 Mn-0.5 Ca-0.5 Cu plate is studied.The simulation results show decreasing temperature gradient in the plate with decreasing quenching rate,which leads to weakened inhomogeneous plastic deformation and decreased residual stress.No dynamic precipitation on the grain boundary happens after either cold water cooling or air cooling,however,air cooling leads to dynamic precipitation of Mg-Zn phase on Mn particles around which a low-density precipitate zone develops after aging treatment.Moreover,the fine and densely distributed Mg-Zn precipitates observed after aging treatment of the cold water cooled alloy are replaced by coarse precipitates with low density for the air cooled alloy.Both the low-density precipitate zone near Mn particles and the coarsening of precipitates are the source of the decrease in hardness and tensile properties of the air cooled alloy.The residual stress drops faster than the hardness with decreasing quenching rate,which makes it possible to lower the residual stress without sacrificing too much age-hardening ability of the alloy.
基金supported by the National Natural Science Foundation of China(Grant no.51404166)Shanxi Province Science Foundation for Youths(2013021013-4)+2 种基金Research Project Supported by Shanxi Scholarship Council of China(2014-023)Technological Innovation Programs of Higher Education Institutions Shanxi(Grant no.2014120)the Advanced Programs of Department of Human Resources and Social Security of Shanxi Province for Returned Scholars(2013101)
文摘In this study, the influence of minor titanium(Ti) addition on the microstructure and tensile properties of Mg-8Sn-1Zn based alloys were investigated by means of optical microscopy, X-ray diffraction, scanning electron microscopy, energy dispersive spectrometry, and tensile tests. The results showed that Ti can decrease the secondary dendrite arm spacing(SDAS). The tensile strength of the Mg-8Sn-1Zn-Ti alloys is initially increased by increasing the Ti content up to 0.09 wt.%, but subsequently decreased for further increase of Ti content. The improved tensile properties are attributed to the decreased SDAS and refi ned Mg_2Sn phases, as well as the increased fraction of tin(Sn) segregated regions. The tensile fracture surface of the studied alloys shows mixed characteristics of cleavage and quasi-cleavage fracture. Adding Ti does not significantly change the fracture mode of the studied alloys.
基金The authors are grateful for the financial supports from National Natural Science Foundation of China(51171212)Chongqing Science and Technology Commission(CSTC2012JJJQ50001,CSTC2013jcyjC60001,cstc2012ggB 50003)+1 种基金The National Science and Technology Program of China(2013DFA71070)the Fundamental Research Funds for the Central Universities(CDJZR13138801).
文摘The as-cast and as-extruded Mg–9Li–1Al–xCa alloys(x=0,0.2;wt%)were prepared by a simple alloying process followed by hot extrusion with an extrusion ratio of 28.2.The microstructures of the as-cast and as-extruded Mg–9Li–1Al–xCa alloys were observed to investigate the effect of calcium(Ca)element on the Mg–9Li–1Al(LA91)alloy,and the crystallographic calculations between Al_(2)Ca and the matrix(α-Mg andβ-Li phases)were examined on the basis of the edge-to-edge matching model.The experimental results indicate that the addition of 0.2 wt%Ca into LA91 alloy reduce the size of theα-Mg phases in the as-cast alloy and that ofβ-Li phases in the as-extruded alloy due to the Al_(2)Ca particles distributed inside the matrix.Crystallographic calculation results suggested that there is a good crystallographic matching between the matrix and Al_(2)Ca,which confirmed that Al_(2)Ca particles can act as a heterogeneous nucleation site for bothα-Mg andβ-Li phases and were effective grain refiners for LA91 alloy.
基金Project supported by National Natural Science Foundation of China(51475486)Natural Science Foundation of Hebei Province(E2013501096)
文摘The microstructure of Mg-8Zn-1Y alloy solidified under super-high pressure was analyzed through X-ray diffraction(XRD), scanning electron microscopy(SEM) and energy dispersive spectroscopy(EDS). And, compression deformation behavior at room-temperature was studied. The results showed that the microstructure of Mg-8Zn-1Y alloy solidified under ambient pressure and super-high pressure was both mainly composed of ■-Mg and quasicrystal I-Mg3Zn6 Y. Solidification under super-high pressure contributed to refining solidified microstructure and changing morphology of the intergranular second phase. The morphology of intergranular second phase(quasicrystal I-Mg3Zn6Y) was transformed from continuous network(ambient pressure) to long island(high pressure) and finally to granular(super-high pressure) with the increase in pressure. The compressive strength, yield strength and rupture strain of the samples solidified under ambient pressure were significantly improved from 262.6 MPa, 244.4 MPa and 13.3% to 437.3 MPa, 368.9 MPa and 24.7% under the pressure of 6 GPa, respectively. Under ambient pressure, cleavage plane on compressive fracture was large and smooth. When it was solidified under the pressure ranging from 4 to 6 GPa, cleavage plane on compressive fracture was small and coarse. In addition, dimple, tear ridge and lobate patterns existed.
基金the National Key Research and Development Program of China(2016YFB0301104)National Natural Science Foundation of China(51771043)。
文摘In this study,uniaxial hot compression tests were carried out between 200 and 400℃ over strain rates of0.001-1 s-1 to investigate the hot deformation behavior of Mg-2 Zn-1 Al-0.2 RE alloy with coarse grains.The average activation energy was measured to be 174.51 kJ/mol.In addition,a constitutive relation based on the Arrhenius equation was established.Dynamic recrystallization(DRX) kinetics were studied by Avrami equation to characterize the evolution of DRX volume fraction.DRX was favored at high temperatures of 300-400℃ and low strain rates of 0.001-0.01 s-1.According to dynamic material model and Prasad’s instability criterion,a maximum power dissipation of 38% and 32% occurs at 400℃/0.001 s-1 and 400℃/0.01 s-1,respectively.According to the proce ssing map,330-400℃/0.001-0.01 s-1was determined as the optimum deformation parameter range.
基金Project supported by General Program of Liaoning Province Committee of Education(L2012035)Liaoning Province Science and Technology Plan(2013201018)Liaoning Province University Innovation Team Support Plan
文摘In order to investigate the effect of extrusion on Mg-4Zn-1Y alloy, microstructure and mechanical properties were analyzed by optical microscopy(OM), scanning electron microscopy(SEM), transmission electron microscopy(TEM), X-ray diffraction(XRD), energy dispersive spectrum(EDS) and tensile testing.The results indicated that the microstructure was obviously refined by extrusion and dynamic recrystallization.The second phases were dynamic precipitated and distributed more dispersively through extrusion.W-Phases(Mg3Zn3Y2) were twisted and broken, while I-Phases(Mg3Zn6Y) were spheroidized by deformation.Twin bands were formed to achieve the large deformation and hinder the slip of dislocations effectively to improve tensile properties.The tensile strength and elongation of extruded Mg-4Zn-1Y alloy were 254.94 MPa and 17.9% respectively which were improved greatly compared with those of as-cast alloy.The strengthening mechanisms of the extruded alloy were mainly fine-grain strengthening and distortion strengthening.
基金financially supported by the National Natural Science Foundation of China(No.51204020)the National Basic Research Program of China(Nos.2013CB632202 and 2013CB632205)
文摘The corrosion behaviors of T5 (225 ℃, 6.5 h) and T6 (460 ℃, 2 h + 225 ℃, 12 h) peak-aged Mg-7Gd- 5Y-1Nd-0.5Zr alloys with oxide films were investigated by optical microscope (OM), scanning electron microscopy (SEM), and energy-dispersive spectroscopy (EDS). The weight loss rates and electrochemical tests were also analyzed. The thicknesses of T5 and T6 oxide films are roughly 0.6 and 1.0 μm, respectively. The components of oxide films mainly consist of O, Mg, Y, Nd, and Gd, and the T6 oxide film results in surfaces with larger peaks than T5 oxide film. In addition, Y, Nd, and Gd peaks are all higher than those of Mg-7Gd-5Y- 1Nd-0.5Zr alloys, but Mg peak is consistently far below than that of the alloys. The specimens could be arranged in de- creasing order of corrosion rates and corrosion current densi- ties: T6 oxide film 〈 T5 oxide film 〈 T6 without oxide film 〈 T5 without oxide film. The oxide films are compact to increase the corrosion resistance for Mg-7Gd-5Y-1Nd-0.5Zr alloys, which will provide a guiding insight into the corrosion and protection of Mg-RE alloys in atmospheric environments.
基金supported by the National Natural Science Foundation of China(Grant Nos.52174362,51975207,and 11772127)the Hunan Provincial Natural Science Foundation for Excellent Young Scholars of China(Grant No.2019JJ30010)+2 种基金the Hunan Provincial Natural Science Foundation of China(Grant No.2018JJ3101)the Scientific Research Fund of Hunan Provincial Education Department(Grant No.17B059)the Leading Plan for Scientific and Technological Innovation of High-Tech Industries—Heavy Haul Equipment R&D and Intelligent Handling(No.2021GK4008).
文摘The mechanical behavior of solution heat-treated and pre-aged Mg–6Zn–1Gd–1Er alloys during hot compression(from 180 to 330℃)has been investigated.The results showed that the flow stress curves of the pre-aged sample(PAS)intersected with that of the solution heat-treated sample(SHTS)during hot compression.At 180℃,when the true strain is 0.27 and 0.47,the PAS showed larger and smaller stress(210.80 MPa vs.207.58 MPa and 205.67 MPa vs.207.93 MPa)than the SHTS,respectively.These phenomena were due to the stronger interaction of W phase and dislocations/twins under the strain of 0.27,while dynamic recrystallization softening occurred under the strain of 0.47.When the temperature increased to 330℃,the flow stress of PAS and SHTS showed an opposite trend to that of 180℃.Continuous dynamic recrystallization and particle stimulated nucleation based on slip operations are the main deformation mechanisms under 330℃.At the true strain is 0.33 and 0.53,the PAS has smaller and larger stress(61.32 MPa vs.63.69 MPa and 58.75 MPa vs.57.09 MPa)than the SHTS,respectively.The increasing deformation resistance of dynamic precipitation improved the flow stress under smaller strain and dynamic recrystallization decreased the flow stress under high strain,which resulted the opposite phenomena of SHTS.