Improved Corrosion Behavior of Biodegradable Mg-4Zn-1Mn Alloy Modified by Sr/F co-doped CaP Micro-arc Oxidation Coatings

The Sr/F co-doped CaP(Sr/F-CaP)coatings were prepared by micro-arc oxidation(MAO)under different voltages to modify the microstructure and corrosion behavior of Mg-4Zn-1Mn alloy.The surface and interface characteristics investigated using scanning electron microscopy(SEM)and energy dispersive X-ray spectrometer(EDS)showed that the MAO coatings displayed uneven crater-like holes and tiny cracks under lower voltage,while they exhibited relatively homogeneous crater-like holes without cracks under higher voltage.The thickness of MAO coatings increased with increasing voltage.The corrosion behavior of Mg-4Zn-1Mn alloy was improved by the MAO coatings.The MAO coatings prepared under 450 V and 500 V voltages possessed the best corrosion resistance with regard to the electrochemical corrosion tests and immersion corrosion tests,respectively.The MAO coatings fabricated under 450-500 V could provide a better corrosion protection effect for the substrate.

Microstructures and tensile properties of as-cast Mg-5Sn-1Si magnesium alloy modified with trace elements of Y,Bi,Sb and Sr

The microstructures and mechanical properties of as-cast Mg-5 Sn-1 Si magnesium alloy modified with trace elements Y,Bi,Sb and Sr were investigated and compared.Results show that the microstructure of the as-cast Mg-5 Sn-1 Si alloy consists ofα-Mg,Mg_(2) Si,Mg_(2) Sn and Mg_(2)(Si_xSn_(1-x))phases.After adding 0.8 wt.%Y,0.3 wt.%Bi,0.9 wt.%Sb and 0.9 wt.%Sr,respectively into the Mg-5 Sn-1 Si magnesium alloy,Mg_(24)Y_(5),Mg_(3) Bi_(2),Mg_(3) Sb_(2) and Mg_(2) Sr phases are precipitated accordingly.Trace elements can refineα-Mg grain and Chinese scriptshaped Mg_(2) Si phase.Refinement efficiency of different trace elements onα-Mg grain and Mg_(2) Si phase is varied.Sr element has the best refinement effect,followed by Sb and Bi,while Y has the least refinement effect.Mg-5 Sn-1 Si-0.9 Sr alloy has higher tensile properties than the other three modified alloys.The refinement mechanism of Y,Bi and Sr elements on Mg-5 Sn-1 Si magnesium alloy can be explained by the growth restriction factors and the solute undercooling.For Mg-5 Sn-1 Si-0.9 Sb alloy,the heterogeneous nuclei of Mg_(3) Sb_(2) phase is the main reason for the refinement of grains and second phases.

Mg-4Sn-1Ce合金的组织及热压缩行为

本文采用光学金相显微镜(OM)、X射线衍射(XRD)、扫描电镜(SEM)以及热压缩实验对Mg-4Sn-1Ce合金的微观组织和热压缩行为进行了研究。结果表明,铸态合金主要由"岛"状的α-Mg、Mg2Sn、Ce4Sn5和MgSnCe相组成。合金在250~450℃和0.001~1s-1应变速率下进行热压缩,热变形激活能Q为162.03 kJ/mol,本构方程为ε=1.3×10^12·[sinh(0.019σ)]^5.6exp[-162030/(RT)]。热压缩温度由250℃升高到450℃,合金显微组织由(扁平状晶粒+挤压流线)组织演变为再结晶等轴晶粒组织。

Improved tensile properties of Mg-8Sn-1Zn alloy induced by minor Ti addition

In this study, the influence of minor titanium(Ti) addition on the microstructure and tensile properties of Mg-8Sn-1Zn based alloys were investigated by means of optical microscopy, X-ray diffraction, scanning electron microscopy, energy dispersive spectrometry, and tensile tests. The results showed that Ti can decrease the secondary dendrite arm spacing(SDAS). The tensile strength of the Mg-8Sn-1Zn-Ti alloys is initially increased by increasing the Ti content up to 0.09 wt.%, but subsequently decreased for further increase of Ti content. The improved tensile properties are attributed to the decreased SDAS and refi ned Mg_2Sn phases, as well as the increased fraction of tin(Sn) segregated regions. The tensile fracture surface of the studied alloys shows mixed characteristics of cleavage and quasi-cleavage fracture. Adding Ti does not significantly change the fracture mode of the studied alloys.

挤压态和热处理态Mg-6Zn-1Mn-4Sn-1.5Nd镁合金的显微组织和力学性能（英文）

利用光学显微镜、X射线衍射仪、扫描电镜、电子背散射衍射、透射电镜、硬度以及力学性能测试等对挤压态和T5处理态的Mg-6Zn-1Mn-4Sn-1.5Nd镁合金的显微组织和力学性能进行研究。研究结果表明:合金铸态的相组成为α(Mg)、Mn、Mg7Zn3、Mg2Sn和MgS nN d相。挤压过程中完成动态再结晶,再结晶晶粒的平均尺寸为7.2μm。T5热处理显著提高挤压态合金的强度。合金的屈服强度和抗拉强度分别增加94 MPa和34 MPa。显微组织分析表明,合金强度的提高主要是由于时效过程中析出高密度的β′1杆状相。

Residual stress and precipitation of Mg-5Zn-3.5Sn-1Mn-0.5Ca-0.5Cu alloy with different quenching rates

The effect of the quenching rate after solution treatment on the residual stress and precipitation behavior of a high strength Mg-5 Zn-3.5 Sn-1 Mn-0.5 Ca-0.5 Cu plate is studied.The simulation results show decreasing temperature gradient in the plate with decreasing quenching rate,which leads to weakened inhomogeneous plastic deformation and decreased residual stress.No dynamic precipitation on the grain boundary happens after either cold water cooling or air cooling,however,air cooling leads to dynamic precipitation of Mg-Zn phase on Mn particles around which a low-density precipitate zone develops after aging treatment.Moreover,the fine and densely distributed Mg-Zn precipitates observed after aging treatment of the cold water cooled alloy are replaced by coarse precipitates with low density for the air cooled alloy.Both the low-density precipitate zone near Mn particles and the coarsening of precipitates are the source of the decrease in hardness and tensile properties of the air cooled alloy.The residual stress drops faster than the hardness with decreasing quenching rate,which makes it possible to lower the residual stress without sacrificing too much age-hardening ability of the alloy.

Characteristics of Faigue Crack Initiation in Ti-5Al-4Sn-2Zr-1Mo-0.7Nd-0.25Si Alloy

The characteristics of fatigue crack initiation in Ti-5AI-4Sn-2Zr1Mo-O.7Nd-O.25Si alloy wereStudied. Two modes Of fatigue crack initiation were found. The Nd-rich phase particles displaybetter resistance to fatigue crack initiation than the matrix at lower stress.

快速凝固Mg-6Zn-1Y-1Ce合金的TEM组织(英文)

利用单辊甩带技术制备快速凝固Mg-6Zn-1Y-1Ce薄带,并利用透射电子显微镜和能谱仪分析薄带组织。结果表明:薄带近辊面区域晶粒内部和晶界处分布着高密度颗粒,颗粒密度在中间区域和自由面区域有所降低;快速凝固合金主要由过饱和的--Mg固溶体、T相和W相组成,同时还存在少量的二十面体准晶相颗粒和Mg4Zn7相颗粒;其中T相为体心正交晶体结构,是由于体心正方结构的Mg12Ce相中部分Mg原子被Zn原子代替而形成的。

Intragranular Rare Earth－rich Phases in As－cast High－temperature Ti－5Al－4Sn－2Zr－1MO－0．25Si－1Nd Alloy

In the as-cast Ti-55 alloy, the intragranular rare earth-rich phase particles are about 1. 0～14 μm in diameter, elliptical, and rich in Nd, Sn, and O. The contents of Nd and Sn on the grain boundaries are higher than those at other sites. The intragranular phases grow preferably at the region on the grain boundaries, which causes the formation of the elliptical morphology of the intragranular phases.

Mg-4Sn-1Zn生物镁合金均匀化处理制度研究

研究了均匀化处理温度和时间对铸态Mg-4Sn-1Zn合金显微组织及力学性能的影响。结果表明,铸态Mg-4Sn-1Zn合金中存在严重的枝晶偏析,合金中分布着大量粗大相,主要为Mg2Sn和MgSnZn共晶相。在均匀化处理过程中,温度对合金成分均匀化效果的影响更大,而时间的影响相对较小。合金经过410℃×12h均匀化处理后,铸态组织中的粗大相全部溶入基体中,达到了最佳的均匀化效果,此时合金的显微硬度(HV)为60。因而确定Mg-4Sn-1Zn合金的最优均匀化制度为410℃×12h。

挤压温度对Mg-6Zn-1Mn-4Sn-0.5Y镁合金组织和性能的影响（英文）

通过光学显微镜(OM),X射线衍射(XRD),扫描电子显微镜(SEM),电子背散射衍射(EBSD)以及拉伸试验对360和420℃挤压的Mg-6Zn-1Mn-4Sn-0.5Y变形镁合金的组织和性能进行了研究。结果表明,合金铸态和时效态的相组成为α-Mg,Mn,Mg_7Zn_3,Mg_2Sn,和MgSnY相。挤压温度从360℃增加到420℃,动态再结晶完成,晶粒长大,合金的屈服强度、抗拉强度以及延伸率分别由259 MPa,350 MPa和18.3%降低至239 MPa,332 MPa和12.5%。理论计算和拉伸试验结果表明,细晶强化和固溶强化对合金屈服强度的增加产生决定性影响。

Evolution of microstructure and tensile properties of extruded Mg-4Zn-1Y alloy

In order to investigate the effect of extrusion on Mg-4Zn-1Y alloy, microstructure and mechanical properties were analyzed by optical microscopy（OM）, scanning electron microscopy（SEM）, transmission electron microscopy（TEM）, X-ray diffraction（XRD）, energy dispersive spectrum（EDS） and tensile testing.The results indicated that the microstructure was obviously refined by extrusion and dynamic recrystallization.The second phases were dynamic precipitated and distributed more dispersively through extrusion.W-Phases（Mg3Zn3Y2） were twisted and broken, while I-Phases（Mg3Zn6Y） were spheroidized by deformation.Twin bands were formed to achieve the large deformation and hinder the slip of dislocations effectively to improve tensile properties.The tensile strength and elongation of extruded Mg-4Zn-1Y alloy were 254.94 MPa and 17.9% respectively which were improved greatly compared with those of as-cast alloy.The strengthening mechanisms of the extruded alloy were mainly fine-grain strengthening and distortion strengthening.

Zn对均匀态Mg-4Sn合金组织及耐蚀性能的影响

研究了添加1%的Zn对均匀态Mg-4Sn合金微观组织及耐蚀性能的影响。利用OM、SEM、XRD、析氢失重试验以及极化曲线来分析两种合金的耐蚀性能。结果表明,Zn细化了Mg-4Sn合金的晶粒尺寸,由179.09μm减小到91.53μm,有颗粒状和长条状的Mg_(2)Sn相弥散分布于α-Mg基体中,Zn以固溶的方式存在于基体中。析氢失重测试结果表明,Zn提高了Mg-4Sn合金的耐蚀性能,这主要归因于Mg-4Sn-1Zn合金晶粒细小,并且Zn的添加使Mg_(2)Sn相分布更加均匀。极化曲线测得Mg-4Sn、Mg-4Sn-1Zn的自腐蚀电流密度分别为2.332×10^(-5)、3.848×10^(-6)μA/cm^(2)。因此,Mg-4Sn-1Zn合金的耐蚀性高于Mg-4Sn合金。

基于温度模糊PID控制的镁合金挤压性能研究

对Mg-4Al-1Mn-0.5Ce镁合金试样进行了常规PID控制和模糊PID控制的挤压成形,并进行了力学性能和显微组织的测试、对比和分析。结果表明:与常规PID控制相比,经模糊PID控制后试样的抗拉强度、屈服强度各增大了19、22 MPa,力学性能得到提升。模糊PID控制的效果优于常规PID控制。