The Mg-Al-Zn-Y-Ce system is one of the key systems for designing high-strength Mg alloys. The purpose of the present article is to develop a thermodynamic database for the Mg-Al-Zn-Y-Ce multicomponent system to design...The Mg-Al-Zn-Y-Ce system is one of the key systems for designing high-strength Mg alloys. The purpose of the present article is to develop a thermodynamic database for the Mg-Al-Zn-Y-Ce multicomponent system to design Mg alloys using the calculation of phase diagrams （CALPHAD） method, where the Gibbs energies of solution phases such as liquid, fcc, bcc, and hcp phases were described by the subregular solution model, whereas those of all the compounds were described by the sublattice model. The thermodynamic parameters describing Gibbs energies of the different phases in this database were evaluated by fitting the experimental data for phase equilibria and thermodynamic properties. On the basis of this database, a lot of information concerning stable and metastable phase equilibria of isothermal and vertical sections, molar fractions of constituent phases, the liquidus projection, etc., can be predicted. This database is expected to play an important role in the design of Mg alloys.展开更多
对含Y的Mg-Al-Zn系镁合金宽幅型材进行了不同温度的挤压,并进行了显微组织、XRD、力学性能和耐腐蚀性能的测试与对比分析。结果表明,当挤压温度从300℃升高至450℃,该宽幅型材的晶粒尺寸减小,晶面织构强度先基本不变后明显下降,抗拉强...对含Y的Mg-Al-Zn系镁合金宽幅型材进行了不同温度的挤压,并进行了显微组织、XRD、力学性能和耐腐蚀性能的测试与对比分析。结果表明,当挤压温度从300℃升高至450℃,该宽幅型材的晶粒尺寸减小,晶面织构强度先基本不变后明显下降,抗拉强度和冲击韧度下降,伸长率和耐腐蚀性能先提高后下降。与300℃的挤压型材相比,350℃挤压的型材能使平均晶粒尺寸增大6μm,晶面织构强度基本不变,抗拉强度减小3 MPa,冲击韧度下降3.43%,伸长率增加2.2%,腐蚀电位正移104 m V。展开更多
The hot deformation behavior of a Mg-Al-Y-Zn magnesium alloy was investigated by hot compressive testing on a Gleeble-1500 thermal simulator at the temperature ranging from 523 to 673 K with the strain rate varying fr...The hot deformation behavior of a Mg-Al-Y-Zn magnesium alloy was investigated by hot compressive testing on a Gleeble-1500 thermal simulator at the temperature ranging from 523 to 673 K with the strain rate varying from 0.001 to 1 s^-1. The relationships among flow stress, strain rate, and deformation temperature were analyzed, and the deformation activation energy and stress exponent were calculated. Microstructure evolution of the alloy under different conditions was examined. The results indicated that the maximum value of the flow stress increased with the decrease of deformation temperature or the increase of strain rate. Under the present deformation conditions, dynamic recrystallization （DRX） occurred in the alloy, which was the main softening mechanism during deformation at elevated temperature. The deformation temperature and strain had significant effects on the microstructure of the alloy.展开更多
To improve lower current efficiency of Mg-based sacrificial anode,a Mg-based sacrificial anode material with yttrium addition was investigated.Its electrochemical properties were evaluated by the galvanostatic method,...To improve lower current efficiency of Mg-based sacrificial anode,a Mg-based sacrificial anode material with yttrium addition was investigated.Its electrochemical properties were evaluated by the galvanostatic method,and its microstructure and constitution were characterized by metallurgical microscope and X-ray diffraction.The results showed that,the addition of yttrium refined dentrite grains,maximized current efficiency,and minimized potential of magnesium sacrificial anode.When 0.1% yttrium was doped,the anode showed the highest current efficiency,62.5%,which improved its current efficiency by 14%.展开更多
基金This study was financially supported by the National Natural Science Foundation of China and Chongqing Science and Technology Commission.
文摘The Mg-Al-Zn-Y-Ce system is one of the key systems for designing high-strength Mg alloys. The purpose of the present article is to develop a thermodynamic database for the Mg-Al-Zn-Y-Ce multicomponent system to design Mg alloys using the calculation of phase diagrams （CALPHAD） method, where the Gibbs energies of solution phases such as liquid, fcc, bcc, and hcp phases were described by the subregular solution model, whereas those of all the compounds were described by the sublattice model. The thermodynamic parameters describing Gibbs energies of the different phases in this database were evaluated by fitting the experimental data for phase equilibria and thermodynamic properties. On the basis of this database, a lot of information concerning stable and metastable phase equilibria of isothermal and vertical sections, molar fractions of constituent phases, the liquidus projection, etc., can be predicted. This database is expected to play an important role in the design of Mg alloys.
文摘对含Y的Mg-Al-Zn系镁合金宽幅型材进行了不同温度的挤压,并进行了显微组织、XRD、力学性能和耐腐蚀性能的测试与对比分析。结果表明,当挤压温度从300℃升高至450℃,该宽幅型材的晶粒尺寸减小,晶面织构强度先基本不变后明显下降,抗拉强度和冲击韧度下降,伸长率和耐腐蚀性能先提高后下降。与300℃的挤压型材相比,350℃挤压的型材能使平均晶粒尺寸增大6μm,晶面织构强度基本不变,抗拉强度减小3 MPa,冲击韧度下降3.43%,伸长率增加2.2%,腐蚀电位正移104 m V。
基金This project was financially supported by the Key Laboratory for Nonferrous Metal of the Ministry of Education of China.
文摘The hot deformation behavior of a Mg-Al-Y-Zn magnesium alloy was investigated by hot compressive testing on a Gleeble-1500 thermal simulator at the temperature ranging from 523 to 673 K with the strain rate varying from 0.001 to 1 s^-1. The relationships among flow stress, strain rate, and deformation temperature were analyzed, and the deformation activation energy and stress exponent were calculated. Microstructure evolution of the alloy under different conditions was examined. The results indicated that the maximum value of the flow stress increased with the decrease of deformation temperature or the increase of strain rate. Under the present deformation conditions, dynamic recrystallization （DRX） occurred in the alloy, which was the main softening mechanism during deformation at elevated temperature. The deformation temperature and strain had significant effects on the microstructure of the alloy.
基金Project supported by the Key Disciplinary Construction Special Fund of Shaanxi Province (101-00X902)
文摘To improve lower current efficiency of Mg-based sacrificial anode,a Mg-based sacrificial anode material with yttrium addition was investigated.Its electrochemical properties were evaluated by the galvanostatic method,and its microstructure and constitution were characterized by metallurgical microscope and X-ray diffraction.The results showed that,the addition of yttrium refined dentrite grains,maximized current efficiency,and minimized potential of magnesium sacrificial anode.When 0.1% yttrium was doped,the anode showed the highest current efficiency,62.5%,which improved its current efficiency by 14%.
