Mg-xwt.%CuY(x=15,20,25)composites were successfully prepared by reactive mechanical alloying(RMA).X-ray diffraction(XRD)measurement shows that main phases of the as milled composites are MgH_(2) and Mg_(2)Cu,and they ...Mg-xwt.%CuY(x=15,20,25)composites were successfully prepared by reactive mechanical alloying(RMA).X-ray diffraction(XRD)measurement shows that main phases of the as milled composites are MgH_(2) and Mg_(2)Cu,and they converted into Mg and MgCu_(2) after dehydrogenation,respectively.Pressure-Composition-Isotherm(PCI)test shows that the composites exhibit double pressure plateau at each isothermal desorption process.The hydrogen absorption and desorption kinetics of the composites become worse with increasing x content,indicating that Mg-Cu phase has a negative effect on the hydrogen sorption properties of the composites.It is supposed that the good hydrogen sorption properties of the composites attribute to the catalyst effect of yttrium hydride distributed in Mg substrate and the particles size reduction and crystal defects formed by RMA.展开更多
文摘Mg-xwt.%CuY(x=15,20,25)composites were successfully prepared by reactive mechanical alloying(RMA).X-ray diffraction(XRD)measurement shows that main phases of the as milled composites are MgH_(2) and Mg_(2)Cu,and they converted into Mg and MgCu_(2) after dehydrogenation,respectively.Pressure-Composition-Isotherm(PCI)test shows that the composites exhibit double pressure plateau at each isothermal desorption process.The hydrogen absorption and desorption kinetics of the composites become worse with increasing x content,indicating that Mg-Cu phase has a negative effect on the hydrogen sorption properties of the composites.It is supposed that the good hydrogen sorption properties of the composites attribute to the catalyst effect of yttrium hydride distributed in Mg substrate and the particles size reduction and crystal defects formed by RMA.
