NiO-La0.3Ce0.7O2-δ(LDC30) novel anode was investigated for IT-SOFCs(Intermediate Temperature-Solid Oxide Fuel Cells) with LaGaO3-based electrolyte. The results showed that LDC30 has a suitable chemical compatibility ...NiO-La0.3Ce0.7O2-δ(LDC30) novel anode was investigated for IT-SOFCs(Intermediate Temperature-Solid Oxide Fuel Cells) with LaGaO3-based electrolyte. The results showed that LDC30 has a suitable chemical compatibility with NiO and NiO-LDC30 has a good thermal expansion matching with LDC30 interlayer and LSGM(La0.8Sr0.2Ga0.8Mg0.2O3-δ) electrolyte, so NiO-LDC30/LDC30 was considered as a feasible and novel anode system. It was also shown that NiO content plays a key role on polarization performance and morphology of the anode. When the content of NiO was 60%(mass fraction), the polarization loss of anode was the lowest. Next we will optimize the porosity and sintering procedure to modify the microstructure and performance of the anode.展开更多
The Ag/Mg0.2Zn0.8O/ZnMn2O4/p^＋-Si heterostructure devices were fabricated by sol-gel spin coating technique and the resistive switching behavior,conduction mechanism,endurance characteristic,and retention properties ...The Ag/Mg0.2Zn0.8O/ZnMn2O4/p^＋-Si heterostructure devices were fabricated by sol-gel spin coating technique and the resistive switching behavior,conduction mechanism,endurance characteristic,and retention properties were investigated.A distinct bipolar resistive switching behavior of the devices was observed at room temperature.The resistance ratio R_（HRS）/RLRS of high resistance state and low resistance state is as large as four orders of magnitude with a readout voltage of 2.0 V.The dominant conduction mechanism of the device is trap-controlled space charge limited current（SCLC）.The devices exhibit good durability under 1×10^3cycles and the degradation is invisible for more than 10^6 s.展开更多
选择具有双钙钛矿结构的Sr2Fe Nb O6(SFN)及La0.9Sr0.1Ga0.8Mg0.2O3-δ(LSGM)材料混合作为固体氧化物电解池(SOEC)的阴极,在SFN-LSGM中掺杂不同比例的淀粉,经过干压成型并在1400℃下烧结后得到测试样。利用真实密度仪及阿基米德法测定...选择具有双钙钛矿结构的Sr2Fe Nb O6(SFN)及La0.9Sr0.1Ga0.8Mg0.2O3-δ(LSGM)材料混合作为固体氧化物电解池(SOEC)的阴极,在SFN-LSGM中掺杂不同比例的淀粉,经过干压成型并在1400℃下烧结后得到测试样。利用真实密度仪及阿基米德法测定了样品的孔隙率;利用热分析仪测定了不同孔隙率的样品在35~1400℃条件下的热膨胀系数,研究该材料与常用SOEC电解质材料La0.9Sr0.1Ga0.8Mg0.2O3-δ(LSGM)的热匹配性能;之后利用电化学工作站测试了该材料在纯氢气气氛下电导率与孔隙率的关系。结果表明,样品孔隙率与淀粉掺杂量成正比,孔隙率对该材料热膨胀系数影响不大,且该材料与LSGM电解池热匹配性能良好。另外,当样品孔隙率增加时,该材料在850℃纯氢气气氛下的电导率在18%孔隙率时达到最大值。展开更多
In this work, the corrosion behavior of the ascast and extrusion and aging treatment Mg–2Zn–0.2Mn alloy in simulated body fluid(SBF) were studied. The wear behavior of Mg–2Zn–0.2Mn alloy was investigated using pin...In this work, the corrosion behavior of the ascast and extrusion and aging treatment Mg–2Zn–0.2Mn alloy in simulated body fluid(SBF) were studied. The wear behavior of Mg–2Zn–0.2Mn alloy was investigated using pin-on-disk technique and stainless steel as counterbody under a constant sliding velocity at different loads ranging from 2 to 5 N with deionized water and SBF as lubrication.The results showed that the extrusion and aging treatment Mg–2Zn–0.2Mn alloy exhibited better corrosion resistance compared with the as-cast alloy due to finer average grain size, more homogeneous phase distribution, and decrease in porosity. The friction coefficient of fractional pair under SBF and deionized water lubrication were obviously lower than that of dry sliding condition. However, the wear rate of Mg–2Zn–0.2Mn alloy under SBF lubrication was higher than that of dry sliding and deionized water lubrication due to the corrosiveness of SBF accelerated the wear of the magnesium alloy. The magnesium alloy exhibited different wear mechanisms with the variety of loads and lubrication conditions.展开更多
Superparamagnetic monodisperse Mg0.8Mn0.2Fe2O4 nanoparticles have been successfully synthesized in liquid polyol at elevated temperature of 200 °C. Diethylene glycol（DEG） used here plays dual role in synthesis ...Superparamagnetic monodisperse Mg0.8Mn0.2Fe2O4 nanoparticles have been successfully synthesized in liquid polyol at elevated temperature of 200 °C. Diethylene glycol（DEG） used here plays dual role in synthesis as it acts as reducing agent and alternatively coats the surface of nanoparticles while synthesis and thereby maintaining uniform size and dispersibility. Powder X-ray diffraction（XRD） and magnetic measurements showed that the sample is cubic spinel and superparamagnetic at room temperature. Raman spectra confirmed the formation of the Mg0.8Mn0.2Fe2O4 nanoparticles.The nanoparticles exhibit very good stability in water due to in situ coating with DEG molecules.展开更多
Thermoelectric materials Mg2Si0.8Sn0.2 were sintered under three different conditions including no electricity sintering（NCS）, low electricity sintering（LCS）,and high electricity sintering（HCS）. Thermoelectric p...Thermoelectric materials Mg2Si0.8Sn0.2 were sintered under three different conditions including no electricity sintering（NCS）, low electricity sintering（LCS）,and high electricity sintering（HCS）. Thermoelectric performance and microstructure of three group samples were measured and compared. The results indicate that the application of electric current during the sintering process changes the microstructure and significantly increases the density of samples, and increases the electric conductivity and the power factor. The electric current activated/assisted sintering is an effective way to obtain thermoelectric materials with excellent performance.展开更多
文摘NiO-La0.3Ce0.7O2-δ(LDC30) novel anode was investigated for IT-SOFCs(Intermediate Temperature-Solid Oxide Fuel Cells) with LaGaO3-based electrolyte. The results showed that LDC30 has a suitable chemical compatibility with NiO and NiO-LDC30 has a good thermal expansion matching with LDC30 interlayer and LSGM(La0.8Sr0.2Ga0.8Mg0.2O3-δ) electrolyte, so NiO-LDC30/LDC30 was considered as a feasible and novel anode system. It was also shown that NiO content plays a key role on polarization performance and morphology of the anode. When the content of NiO was 60%(mass fraction), the polarization loss of anode was the lowest. Next we will optimize the porosity and sintering procedure to modify the microstructure and performance of the anode.
基金Funded by the National Natural Science Foundation of China(No.51262003)the Guangxi Key Laboratory of Information Materials(Guilin University of Electronic Technology),China(No.1110908-10-Z)
文摘The Ag/Mg0.2Zn0.8O/ZnMn2O4/p^＋-Si heterostructure devices were fabricated by sol-gel spin coating technique and the resistive switching behavior,conduction mechanism,endurance characteristic,and retention properties were investigated.A distinct bipolar resistive switching behavior of the devices was observed at room temperature.The resistance ratio R_（HRS）/RLRS of high resistance state and low resistance state is as large as four orders of magnitude with a readout voltage of 2.0 V.The dominant conduction mechanism of the device is trap-controlled space charge limited current（SCLC）.The devices exhibit good durability under 1×10^3cycles and the degradation is invisible for more than 10^6 s.
文摘选择具有双钙钛矿结构的Sr2Fe Nb O6(SFN)及La0.9Sr0.1Ga0.8Mg0.2O3-δ(LSGM)材料混合作为固体氧化物电解池(SOEC)的阴极,在SFN-LSGM中掺杂不同比例的淀粉,经过干压成型并在1400℃下烧结后得到测试样。利用真实密度仪及阿基米德法测定了样品的孔隙率;利用热分析仪测定了不同孔隙率的样品在35~1400℃条件下的热膨胀系数,研究该材料与常用SOEC电解质材料La0.9Sr0.1Ga0.8Mg0.2O3-δ(LSGM)的热匹配性能;之后利用电化学工作站测试了该材料在纯氢气气氛下电导率与孔隙率的关系。结果表明,样品孔隙率与淀粉掺杂量成正比,孔隙率对该材料热膨胀系数影响不大,且该材料与LSGM电解池热匹配性能良好。另外,当样品孔隙率增加时,该材料在850℃纯氢气气氛下的电导率在18%孔隙率时达到最大值。
基金financially supported by the National Natural Science Foundation of China (Nos. 51271131 and 51071108)
文摘In this work, the corrosion behavior of the ascast and extrusion and aging treatment Mg–2Zn–0.2Mn alloy in simulated body fluid(SBF) were studied. The wear behavior of Mg–2Zn–0.2Mn alloy was investigated using pin-on-disk technique and stainless steel as counterbody under a constant sliding velocity at different loads ranging from 2 to 5 N with deionized water and SBF as lubrication.The results showed that the extrusion and aging treatment Mg–2Zn–0.2Mn alloy exhibited better corrosion resistance compared with the as-cast alloy due to finer average grain size, more homogeneous phase distribution, and decrease in porosity. The friction coefficient of fractional pair under SBF and deionized water lubrication were obviously lower than that of dry sliding condition. However, the wear rate of Mg–2Zn–0.2Mn alloy under SBF lubrication was higher than that of dry sliding and deionized water lubrication due to the corrosiveness of SBF accelerated the wear of the magnesium alloy. The magnesium alloy exhibited different wear mechanisms with the variety of loads and lubrication conditions.
基金the Council of Scientific and Industrial Research, India for the award of senior research fellowship (File. 09/1077/(0001)/ 2012/EMR-1)
文摘Superparamagnetic monodisperse Mg0.8Mn0.2Fe2O4 nanoparticles have been successfully synthesized in liquid polyol at elevated temperature of 200 °C. Diethylene glycol（DEG） used here plays dual role in synthesis as it acts as reducing agent and alternatively coats the surface of nanoparticles while synthesis and thereby maintaining uniform size and dispersibility. Powder X-ray diffraction（XRD） and magnetic measurements showed that the sample is cubic spinel and superparamagnetic at room temperature. Raman spectra confirmed the formation of the Mg0.8Mn0.2Fe2O4 nanoparticles.The nanoparticles exhibit very good stability in water due to in situ coating with DEG molecules.
基金financially supported by the National Natural Science Foundation of China (Nos. 50975190 and 51101111)Shanxi Province Science Foundation for Youths (No. 2011021022-3)+1 种基金Shanxi Scholarship Council of China (No. 2012-033)the Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi
文摘Thermoelectric materials Mg2Si0.8Sn0.2 were sintered under three different conditions including no electricity sintering（NCS）, low electricity sintering（LCS）,and high electricity sintering（HCS）. Thermoelectric performance and microstructure of three group samples were measured and compared. The results indicate that the application of electric current during the sintering process changes the microstructure and significantly increases the density of samples, and increases the electric conductivity and the power factor. The electric current activated/assisted sintering is an effective way to obtain thermoelectric materials with excellent performance.
