Series of activated carbon(AC)modified MgFe-layered double hydroxides(LDH/ACs)were synthesized using ultrasonic-assisted co-precipitation method.Herein the mass ratio of Mg/Fe-LDH and AC was varied at 1.55,2.34,and 2....Series of activated carbon(AC)modified MgFe-layered double hydroxides(LDH/ACs)were synthesized using ultrasonic-assisted co-precipitation method.Herein the mass ratio of Mg/Fe-LDH and AC was varied at 1.55,2.34,and 2.86,respectively.The calcinations of corresponding LDH/ACs were obtained at 723 K for 5 h and named as LDO-AC-1.55,LDO-AC-2.34 and LDO-AC-2.86,respectively.These products were characterized by Fourier transform infrared spectroscopy(FT-IR),X-ray diffraction(XRD),Brunauer-Emmett-Teller(BET)measurements and scanning electron microscopy(SEM).LDO-ACs were applied for the removal of methyl orange(MO).The result showed that aggregation degree of MgFe-LDH decreased in the existence of AC.The pore sizes of LDO-AC-1.55,LDO-AC-2.34 and LDO-AC-2.86 markedly increased with the sharp decreasing of surface area.The values of the statured adsorption capacity of LDO-AC-1.55,LDO-AC-2.34 and LDO-AC-2.86 were obviously higher than those of MgFe-layered double hydroxides fabricated by traditional method(LDO0).The mechanism for the enhanced adsorption may be that the loose macrospore structure of LDO-AC-1.55,LDO-AC-2.34 and LDO-AC-2.86 abbreviates the diffusion resistance and bore repulsive force of MO molecular coupled with its space confinement effect in contrast with LDO0,which is favor for the free self-assembly of MO to form intercalation compound.MO-loaded LDO-AC-2.34 was regenerated by calcination and reused several times,still retaining its original adsorption capacity.展开更多
基金Supported by the National Natural Science Foundation of China(31201305)the Natural Science Foundation of Shaanxi Province(2016JM2018)
文摘Series of activated carbon(AC)modified MgFe-layered double hydroxides(LDH/ACs)were synthesized using ultrasonic-assisted co-precipitation method.Herein the mass ratio of Mg/Fe-LDH and AC was varied at 1.55,2.34,and 2.86,respectively.The calcinations of corresponding LDH/ACs were obtained at 723 K for 5 h and named as LDO-AC-1.55,LDO-AC-2.34 and LDO-AC-2.86,respectively.These products were characterized by Fourier transform infrared spectroscopy(FT-IR),X-ray diffraction(XRD),Brunauer-Emmett-Teller(BET)measurements and scanning electron microscopy(SEM).LDO-ACs were applied for the removal of methyl orange(MO).The result showed that aggregation degree of MgFe-LDH decreased in the existence of AC.The pore sizes of LDO-AC-1.55,LDO-AC-2.34 and LDO-AC-2.86 markedly increased with the sharp decreasing of surface area.The values of the statured adsorption capacity of LDO-AC-1.55,LDO-AC-2.34 and LDO-AC-2.86 were obviously higher than those of MgFe-layered double hydroxides fabricated by traditional method(LDO0).The mechanism for the enhanced adsorption may be that the loose macrospore structure of LDO-AC-1.55,LDO-AC-2.34 and LDO-AC-2.86 abbreviates the diffusion resistance and bore repulsive force of MO molecular coupled with its space confinement effect in contrast with LDO0,which is favor for the free self-assembly of MO to form intercalation compound.MO-loaded LDO-AC-2.34 was regenerated by calcination and reused several times,still retaining its original adsorption capacity.
