The effects of Ni addition on the mechanical properties, corrosion behaviors, and corrosion mechanism of Mg Gd_1 Ni_(x) alloys have been investigated by compressive tests, weight loss, hydrogen evolution, and scanning...The effects of Ni addition on the mechanical properties, corrosion behaviors, and corrosion mechanism of Mg Gd_1 Ni_(x) alloys have been investigated by compressive tests, weight loss, hydrogen evolution, and scanning electron microscopy. The results show that the constitution of the second phase is large dependence on Ni/Gd molar ratios, which can transform from LPSO(long-period stacking ordered)+Mg_5 Gd,LPSO to eutectic phase. In addition, with increasing Ni/Gd molar ratios, the content of second phase increases gradually, while the LPSO phase shows a parabola relationship. Furthermore, the formation of Nicontaining LPSO phase not only can improve the strength but also accelerate the degradation of Mg alloys owing to the galvanic corrosion. The optimal properties with ultimate compressive strength, degradation rate are 340 MPa, 2066 mm/y for Mg Gd1 Ni0.75, respectively, which can meet the engineering application standard of fracturing ball and can be used as candidate materials for fracturing ball.展开更多
基金financial support from the National Key Research and Development Program of China (No.2016YFB0301100)the National Natural Science Foundation of China (Grant No. U20A20234, 51874062)+2 种基金the Fundamental Research Funds for the Central Universities (No. 2018CDGFCL0005,2019CDXYCL0031)the Science and Technology Major Project of Shanxi Province (No. 20191102008)Shandong Province major science and technology innovation project (No. 2019JZZY020329)。
文摘The effects of Ni addition on the mechanical properties, corrosion behaviors, and corrosion mechanism of Mg Gd_1 Ni_(x) alloys have been investigated by compressive tests, weight loss, hydrogen evolution, and scanning electron microscopy. The results show that the constitution of the second phase is large dependence on Ni/Gd molar ratios, which can transform from LPSO(long-period stacking ordered)+Mg_5 Gd,LPSO to eutectic phase. In addition, with increasing Ni/Gd molar ratios, the content of second phase increases gradually, while the LPSO phase shows a parabola relationship. Furthermore, the formation of Nicontaining LPSO phase not only can improve the strength but also accelerate the degradation of Mg alloys owing to the galvanic corrosion. The optimal properties with ultimate compressive strength, degradation rate are 340 MPa, 2066 mm/y for Mg Gd1 Ni0.75, respectively, which can meet the engineering application standard of fracturing ball and can be used as candidate materials for fracturing ball.
