Investigation of Refractory Bricks and Oxide Materials Heated in Hydrogen Reduction Conditions

This study aims to provide the basic knowledge for furnace refractory design by investigating refractory property changes occurred in a hydrogen atmosphere.Since refractory bricks are thermodynamically stable in a hydrogen atmosphere at 1100°C,we tried to find out the minute changes.In this experiment,a refractory brick was prepared by andalusite,mullite chamotte,and clay as raw materials and heated to 1100°C in a 100%hydrogen atmosphere for 72 h.It was found that the strength of the brick was decreased and the color was changed to black by the reduction of impurities.And in addition,this study covered research on the slaking risk of MgO raw materials because the minimum temperature is expected to 400°C in fluidized reduction furnaces unlike shaft furnaces.

Assessment of Cement-Lime as Stabilizer on Mud Bricks

The aim of this study was to evaluate the compressive strength of clay bricks and their stability to water absorption by inserting stabilizers such as lime and cement of 0%, 4%, 6%, 8%, 10%, 12% to 14%. Spectrometric analysis was used to characterize the various stabilizers and the clay used, and tests of resistance and water absorption were also carried out. The clay was found to be an aluminosilicate (15.55% to 17.17% Al2O3 and 42.12% to 44.15% SiO2). The lime contains 90.84% CaO and the cement has 17.80% SiO2, 3.46% Al2O3, 2.43% Fe2O3 and 58.47% CaO in the combined form of tricalcium silicate, dicalcium silicate, tricalcium aluminate and ferro-tetra calcium aluminate. The results showed that the insertion of locally available stabilizers (lime and cement) improved the strength of the material by almost 80% when the lime was increased from 0% to 14% for 14 days. For compressed cement, a 65% increase in strength was observed under the same conditions. Strength increases with drying time, with a 52% increase in strength at 28 days compared to 14 days. Furthermore, compressed cement bricks have a more compact structure, absorbing very little water (32%). In view of all these results, cement appears to be the best stabilizer, and compression improves compressive strength and reduces water absorption.

Tailored deep-eutectic solvent method to enable 3D porous iron fluoride bricks for conversion-type lithium batteries

Conversion-type fluoride cathode can provide considerable energy density for Li batteries,however its scalable and facile synthesis strategies are still lacking.Here,a novel Fe-based deep eutectic solvent composed of nitrite and methylsulfonylmethane is proposed as both the reaction medium and precursor to synthesize O-doped FeF3porous bricks.This method is cheaper,safe,mildly operable,environmentally friendly and recyclable for non-fluorinated metal cations.The homogenization of charge and mass transport in cathode network effectively mitigates the volume extrusion and electrode coarsening even for the micro-sized monolithic particles.The Co-solvation modulated fluoride cathode delivers high reversible capacity in a wide temperature range(486 and 235 mA h g^(-1)at 25℃ and-20℃ respectively),excellent rate performance(312 mA h g^(-1)at 1000 mA g^(-1)),corresponding to an energy density as high as672.1 W h kg^(-1)under a power density of 2154.3 W kg^(-1).The successful operation of fluoride pouchcell with a capacity exceeding 450 mA h g^(-1)(even under thin Li foil and lean electrolyte conditions) indicates its potentiality of commercial application.

Study on Mechanical Properties and Action Mechanism of Leather Industrial Sludge Aggregate Baking-Free Bricks

Taking an industrial sludge and its preparation of sludge wrap shell aggregates(WSAs)instead of sand to prepare baking-free brick as the research object,the development law of mechanical properties and the influence mechanism of macro and micro characteristic parameters of the bricks under different sludge and WSAs replacement rates were studied through the macroscopic mechanical properties test,with the help of nuclear magnetic resonance(NMR),transmission electron microscopy-energy spectrum and other testing technology and pores and cracks analysis system(PCAS)software.The results showed that the compressive strength of each sample decreased with the increase of sludge content.When the sludge content was less than 30%,it was mainly affected by the water-binder ratio.When the sludge content was more than 30%,it was mainly affected by the sludge content.At the age of 7 days,with the increase in replacement rate of WSAs,the compressive strength of the S10 and S30 groups was higher than that of the control group.The compressive strength of the S50 experimental group was 30.38 MPa,and the loss of compressive strength was slight compared with the control group.The water absorption rate of the 28 days S100 experimental group increased by 10.71%compared with the control group.When the content of WSAs was less than 50%,the holes above 0.1μm in the brick can be reduced and transformed into smaller holes,with a decreasing trend of the plane porosity of the brick.The microscopic results of the baking-free brick showed that the three-phase system of WSAs-interface transition area-mortar was poorly bonded and delaminated compared with the gravel aggregate-interface transition area-mortar system,and damage was more likely to occur in the WSAs and interface transition area.The above results show that it is feasible to use sludge and WSAs instead of sand for the preparation of baking-free bricks.This technology not only solves the problem of sludge disposal,but also protects the over-exploitation of mineral resources,and the technology has a broad application prospect and market value.

Thermo-Mechanical Properties Study of Stabilized Soil Bricks to Sugar Cane Molasses and Cassava Starch Binders

The current study deals Swith thermo-mechanical properties of stabilized soil small bricks with the help of organic binders of sugar cane molasses and cassava starch. Different formulations of soil concrete have been suggested after the geotechnical characterization of samples of soil was taken. From these, it arises that the studied soil is the most plastically clay (of type A3) according to GTR classification. Samples made of small bricks and measured out at 4%, 6% and 8% of binders (molasses, starch or molasses + starch) have been warmed up to different temperatures (100°C, 150°C, 200°C and 250°C) for the rising of the thermic behavior under different conditions and submitted to crushing testings for the estimation of characteristic resistances to the compression. According to the mechanical behavior, we note an improvement of resistances for small bricks measured 4%, 6% and 8%, of molasses respectively of 32.44%, 32.06% and 23.43% against the value of reference for small bricks without molasses. In the same way, the binder (molasses + starch) also reveals an improvement of resistance to the compression of 13.27%, 26.17% and 26.17%. On the contrary, the stabilization with the starch binder did not bring a significative improvement. According to the thermic influence, the heating at 100°C of stabilized small bricks at 4%, 6% and 8% of molasses, reveals a significative improvement of resistances. Moreover, the stabilization with the starch reveals on the contrary a good behavior for heatings at 150°C and 250°C. In short, for the binder (molasses + starch), it is the heating at 200°C that shows some improvements of remarkable resistances. Different analyses of realized statistics also show the effectivity of obtained results. For all realized formulations, the measuring out at 6% of binders (molasses, or molasses + starch) seems as optimal in front of the best thermo-mechanical revealed properties.

Experimental and Numerical Study of Mechanical Behaviour of Fired Clay Bricks after Exposure to High Temperatures

This paper reports the modeling of residual compressive strength of fired clay bricks submitted to elevated temperature. Five formulations were used and the explored temperatures were 95˚C, 200˚C, 550˚C, 700˚C and 950˚C. The stress–strain relationships and the mechanical properties (including Young’s modulus and compressive strength) were assessed using a uniaxial compressive strength machine. A proposed model equation was established and found satisfying. The elastic modulus was evaluated and tested with one existing model together with two proposed models. The proposed model was both satisfying and even more precise than the existing one. The overall results show that the effect of temperature on the mechanical properties of clays can be accurately described through the definition of thermal damage using elastic modulus.

Influence of Firing Temperature on Properties of High Alumina Bricks

To reduce production costs and make full and reasonable use of raw materials,high alumina bricks were prepared using tabular corundum and mullite as aggregates,sillimanite as intermediate particles,and white fused corundum powder,α-alumina micropowder,and Suzhou soil as the matrix,firing at different temperatures(1420,1440,1460,1480,1500 and 1520℃)for 4 h.The apparent porosity(AP),the bulk density(BD),the cold crushing strength(CCS),the thermal shock resistance(TSR),the refractoriness under load(RUL)and the creep rate of the samples were tested.The effects of the firing temperature on the creep rate(1450℃×50 h,under a load of 0.2 MPa)of the samples were studied.The results show that with the sillimanite addition of 22.5 mass%,the sample fired at 1460℃for 4 h performs the best comprehensive properties:the AP of 17.5%,the BD of 2.75 g·cm^(-3),the CCS of 100.5 MPa,the TSR number of 35 cycles,the RUL of 1682℃,and the creep rate of-0.428%,which can prolong the service life of furnaces.

Effect of Polyethylene Terephthalate Plastic Waste on the Physico-Mechanical and Thermal Characteristics of Stabilized Laterite Bricks

The present work investigated the effect of polyethylene terephthalate (PET) plastic waste on the physico-mechanical and thermal properties of cement-stabilized laterite bricks to see the durability of the modified bricks (CSLB). Samples were formulated by mixing laterite, cement, and different percentages of PET (0%, 3%, 5%, and 7%) by volume. The bricks were produced using the M7MI Hydraform standard interlocking block and kept in the shade for a curing period of 28 days. The addition of 3% to 5% PET to the laterite stabilized with 10% cement results in a decrease in both dry and wet compressive strength, which is determined using the Controlab compression machine. However, the obtained results are in concordance with the standards. The thermal conductivity of CSLB, determined using the box method with the EI700 measurement cell, decreases as the PET content of the mixture increases. A decrease in bulk density from 1.67 to 1.58 g/cm3 was observed.

Thermal and Mechanical Characterization of Compressed Clay Bricks Reinforced by Rice Husks for Optimizing Building in Sahelian Zone

This article deals with the characterization of local materials used in insulation building heat. These materials are bricks of earth compressed and stabilized with rice husks. Thermal conductivity, the specific heat and the thermal diffusivity of materials based on clay incorporating rate of 0, 2%, 4%, 6%, 8% and 10% are determined. The results showed that the clay blocks + rice balls had better thermal insulators than simple clay blocks. However, these composite materials used for the envelope of the building must have sufficient mechanical resistance when used in construction. The measurement of mechanical properties such as compressive strength showed an improvement of 6% and beyond, a drop in resistance when increasing rice husks in clay is observed. These results allow to specify the optimal conditions of use of these materials for the building envelope.

Thermal Properties of Earth Bricks Stabilised with Cement and Sawdust Residue Using the Asymmetrical Hot-Plane Method

This paper presents an experimental study of the characterisation of local materials used in the construction and thermal insulation of buildings. These materials are compressed earth bricks stabilised with cement and sawdust. The thermal conductivity, diffusivity, effusivity, and specific heat of earth-based materials containing cement or sawdust have been determined. The results show that the blocks with earth + sawdust are better thermal insulators than the blocks with simple earth. We observe an improvement in thermal efficiency depending on the presence of sawdust or cement stabilisers. For cement stabilisation, the thermal conductivity increases (λ: 1.04 to 1.36 W·m-1·K-1), the diffusivity increases (from 4.32 × 10-7 to 9.82 × 10-7 m2·s-1), and the effusivity decreases (1404 - 1096 J·m-2·K-1·s-1/2). For sawdust stabilisation, the thermal conductivity decreases (λ: 1.04 to 0.64 W·m-1·K-1), the diffusivity increases (from 4.32 × 10-7 to 5.9 × 10-7 m2·s-1), and the effusivity decreases (1404 - 906 J·m-2·K-1·s-1/2). Improving the structural and thermal efficiency of BTC via stabilisation with derived binders or cement is beneficial for the load-bearing capacity and thermal performance of buildings.

Physico-Chemical Studies of the Bricks in Mud Raw Used in the Construction of Century-Old Huts(Straw Huts):Case of the Urban Commune of Kouroussa

Building construction using cement bricks on the one hand,and mud bricks on the other hand,presents problems of resistance and durability in the face of natural weathering in our country(Republic of Guinea).These difficulties could be linked to non-compliance with standards and the failure to master certain physico-chemical,mechanical and technical parameters when constructing a building.In order to remedy this problem,a series of studies were carried out on samples of mud bricks used in the construction of century-old straw hut buildings in the urban commune of Kouroussa(Republic of Guinea).To this end,the compressive strength of the brick samples was assessed either:0.10 MPa,and sensory techniques of certain characteristics were carried out to evaluate the cohesion of the elements in the brick samples,such as:coward boule technique,hand washing test,withdrawal of a soil(pellet or ring test)and of the jar test.The physico-chemical analyses methods were carried out using XRF(X-Ray Fluorescence Spectrometry),granulometry and Atterberg limits in accordance with NF P 94-051.These results showed a high insoluble residue content(49.9%)and the sample had a clay-like appearance with a low PI(Plasticity Index)=8%.This study could be an alternative guide for the authorities in charge of housing and construction in the Kouroussa prefecture(Republic of Guinea).because,the majority of houses in Upper Guinea are built with mud raw bricks or fired bricks.

Study on Phase Change Material in Grooved Bricks for Energy Efficiency of the Buildings

Phase change materials(PCMs)are an interesting technology due to their high density and isothermal behavior during phase change.Phase change material plays a major role in the energy saving of the buildings,which is greatly aided by the incorporation of phase change material into building products such as bricks,cement,gypsum board,etc.In this study,an experiment has been conducted with three identical small chambers made up of normal,grooved and PCM-treated grooved bricks.Before the inclusion of PCM in grooved bricks,PCM material behavior has been studied by different techniques such as DSC,TG/DTA,SEM,and XRD.Thermal properties and thermal stability were investigated by differential scanning calorimeter(DSC)and thermogravimetric analyzer(TGA)respectively.Scanning electron microscopy(SEM)and X-ray diffraction(XRD)were used to determine the microstructure and crystalloid phase of the PCM before and after the accelerated thermal cycling test(0,60,120).These three identical model rooms built were exposed at a temperature just above 40°C with a heater.When the maximum outdoor temperature was 40-41°C,then the temperature of the PCM-treated grooved chamber was 32-33°C.The PCM-treated wall was tested and compared with a conventional and grooved wall.The difference between the PCM-treated grooved chamber and the untreated one was 8-9°C.PCM-treated bricks provided more efficient internal heat retention in summer when the outside temperature increased.

Visual Analysis of Domestic and Foreign Building Brick Skin Research Based on Citespace

With the progress of the times and the leap of science and technology,the application of brick materials and the research on the brick skin in modern architectural design have shown a dual-track development trend of returning to tradition and innovation.Based on the core collection database resources of Web of Science and the CiteSpace visual analysis tool,this paper constructed and analyzed the spatio-temporal map of keyword co-occurrence network,cluster structure,mutation phenomenon,time course and regional distribution map of building brick skin research.The study revealed that in recent years,the research on brick materials has spanned the study of single material properties and extensively involved in the broad world of construction,especially in the integration of green energy-saving technology,the innovation of fine construction technology of brick skin,and the frontier exploration of digital technology in brick masonry,which has shown particularly significant research vitality and development potential.

Bricks and Clicks模式下供应链协调研究

建立了由一个制造商和一个分销商组成的基于电子市场的二级供应链模型,讨论了分销商采用Bricks and Clicks模式分销产品,并在电子渠道进行季节后销售的情况,分析了供应链的契约协调问题及供应链成员的利润情况.研究发现改进的回购契约可以使Bricks and Clicks分销模式下基于电子市场的二级供应链模型达到协调,使分销商的订货量达到供应链最优,并且使供应链成员的利润达到Pareto改进,达到"双赢".最后,通过算例验证了结论.

面向学术出版的数据增强解决方案--基于67Bricks的案例研究

在技术和科研用户需求变化的驱动下,软件开发咨询公司67Bricks着眼于海量数据及数据技术给学术出版业带来的巨大变化和机遇,帮助出版商从传统的内容提供商转型为数据驱动的内容服务商。在技术理念上,以数据技术和人工智能为核心设计模块化平台,使出版商可以更高效、更可靠地创建和管理内容;在业务模式上,通过协作方式,深度参与学术出版商变革的全流程活动;在市场定位上,以与学术出版商建立长期合作伙伴关系为中心,而不是将自身定位为仅提供技术资源的软件供应商。本文对67Bricks助力学术出版商的相关实践进行总结和评价,以供我国学术出版企业在制定数据驱动发展战略时进行比较和借鉴。

Enhanced strength in novel nanocomposites prepared by reinforcing graphene in red soil and fly ash bricks

Low-dimensional nanomaterials such as graphene can be used as a reinforcing agent in building materials to enhance the strength and durability. Common building materials burnt red soil bricks and fly ash bricks were reinforced with various amounts of graphene, and the effect of graphene on the strength of these newly developed nanocomposites was studied. The fly ash brick nanocomposite samples were cured as per their standard curing time, and the burnt red soil brick nanocomposite samples were merely dried in the sun instead of being subjected to the traditional heat treatment for days to achieve sufficient strength. The water absorption ability of the fly ash bricks was also discussed. The compressive strength of all of the graphene-reinforced nanocomposite samples was tested, along with that of some standard (without graphene) composite samples with the same dimensions, to evaluate the effects of the addition of various amounts of graphene on the compressive strength of the bricks.

Properties of New Mullite-SiC Bricks for CDQ Shafts

Currently the service life of CDQ shafts in China is mainly restricted by the properties of the inclined flue bricks.In this work,based on the systematic analysis of the damage mechanism of inclined flue refractories,high performance mullite-SiC bricks were developed.The bricks were produced by corundum,andalusite,SiC and other high purity raw materials.Metal silicon and alumina ultra micropowder were added to form dispersion multi-phase structure,fortifying the matrix and improving the microstructure.The products have excellent properties such as low porosity,high density,good wear resistance,high refractoriness under load,and good thermal shock resistance.The products can replace the ordinary mullite-SiC bricks and obtain a good service life.

不同锆基原料对MgO-Al-C材料性能的影响

为提高MgO-Al-C滑板材料的抗热震性,以98烧结镁砂和98电熔镁砂、金属Al粉、N220炭黑(25~20 nm)、造粒氧化锆微粉、氧化锆空心微珠为原料,酚醛树脂为结合剂,制备了MgO-Al-C材料。研究了造粒氧化锆微粉加入量(质量分数分别为0、1%、2%、3%、4%)或氧化锆空心微珠加入量(质量分数分别为0、2%、4%、6%)对MgO-Al-C材料常温性能、高温性能、物相组成及显微结构的影响。结果表明:1)造粒氧化锆微粉是团聚体,具有多孔结构和可压缩性,可吸收热应力;加入量为2%(w)时,有利于提高材料的抗热震性,比未添加的试样Z0强度保持率提高了3.9%,其他性能与试样Z0的几乎持平。2)氧化锆空心微珠为中空结构,具有弹性,同样可吸收热应力;加入量为4%(w)时,可明显改善材料的抗热震性,比未添加的试样Z0强度保持率提高了8%;显气孔率为12.4%,体积密度为2.87 g·cm^(-3),与试样Z0的相比致密度有所提高;对改善材料的抗氧化性有一定效果,氧化层厚度较试样Z0的降低了0.15 mm,其他性能与试样Z0的相比没有明显变化。

Mechanical and Frost-resistance Properties of Rural Area Building Waste Hollow Bricks

Serving as recycled coarse aggregate,the pretreated rural building waste was added into the concrete hollow bricks in the varying replacement of 0,20%,40%,60%,80% and 100%.By testing its compressive strength,flexural strength,mass and strength loss after freeze-thaw cycles,the impact of the different replacement on mechanical and frost-resistance properties of concrete hollow bricks was presented through SEM analysis.The experimental results show that,with the increase in recycled coarse aggregate replacement rate,the mechanical and frost-resistance properties show a downward trend;when the replacement rate is 40%,28 d compressive strength and flexural strength of concrete hollow brick demonstrate the good peak value which meet the requirement of the national standard for ordinary small concrete hollow bricks;the interfacial structures of the pretreated recycled concrete is more complicated than those of concrete made of natural aggregate,but the former enjoys better interface bonding and tight structure.

Corrosion Mechanism of Ladle Furnace Refining Slag to Fired MgO-CaO Bricks

Corrosion effect of ladle furnace （LF） refining slag on fired MgO-CaO bricks with about 34% CaO was studied by static crucible method,and corrosion mechanism was analyzed by techniques of scan electron micrograph,energy dispersive spectrometer,and X-ray diffraction. The results show that：MgO-CaO bricks exhibit excellent corrosion resistance but poor penetration resistance to LF refining slag; oxidation of （Mg·Fe）O in reaction zone results in volume expansion forming cracks; penetration of 2CaO·Fe2O3 （C2F） from slag to MgO-CaO bricks increases liquid phases which accelerates corrosion of the bricks; a protective layer of 2CaO·SiO2 formed on reaction interface prevents penetration of C2F to the bricks.