采用溶胶-凝胶法制备出Y_(2-2 x)MgTiO_(6)∶2 x Eu^(3+)(YMT∶2 x Eu^(3+),0≤x≤0.11)新型红色荧光粉。通过X射线衍射仪(XRD)检测样品的纯度,结果显示YMT∶Eu^(3+)样品属于单斜晶系,空间群为P21/n,无其他杂相。扫描电子显微镜(SEM)照...采用溶胶-凝胶法制备出Y_(2-2 x)MgTiO_(6)∶2 x Eu^(3+)(YMT∶2 x Eu^(3+),0≤x≤0.11)新型红色荧光粉。通过X射线衍射仪(XRD)检测样品的纯度,结果显示YMT∶Eu^(3+)样品属于单斜晶系,空间群为P21/n,无其他杂相。扫描电子显微镜(SEM)照片显示荧光粉为2μm的不规则颗粒。当激发波长为264 nm时,发射光谱出现四个尖锐的发射峰,分别位于591(^(5)D_(0)→^(7)F_(1))、619(^(5)D_(0)→^(7)F_(2))、657(^(5)D_(0)→^(7)F_(3))和693 nm(^(5)D_(0)→^(7)F_(4))。Eu^(3+)离子之间能量传递为电偶极子-电偶极子(d-d)相互作用。YMT∶0.14Eu^(3+)荧光粉的CIE色度坐标为(0.645,0.332),与红光标准色坐标(0.67,0.33)非常接近。变温PL光谱及热激活能计算结果显示荧光粉具有一定的热稳定性,因此YMT∶Eu^(3+)是一种具有潜在应用价值的LED红色荧光粉。展开更多
采用高温固相法合成了La_(2)MgTiO_(6)∶Mn^(4+)、La_(2)MgTiO_(6)∶Pr^(3+)、La_(2)MgTiO_(6)∶Pr^(3+),Mn^(4+)单掺杂和双掺杂荧光粉,并通过X射线衍射、扫描电镜、荧光光谱等测试方法对荧光粉的物相结构、形貌和发光特性进行了表征及...采用高温固相法合成了La_(2)MgTiO_(6)∶Mn^(4+)、La_(2)MgTiO_(6)∶Pr^(3+)、La_(2)MgTiO_(6)∶Pr^(3+),Mn^(4+)单掺杂和双掺杂荧光粉,并通过X射线衍射、扫描电镜、荧光光谱等测试方法对荧光粉的物相结构、形貌和发光特性进行了表征及分析。结果表明:成功合成了La_(2)MgTiO_(6)∶Mn^(4+)、La_(2)MgTiO_(6)∶Pr^(3+)、La_(2)MgTiO_(6)∶Pr^(3+),Mn^(4+)荧光粉且均为纯相;样品的粒径为1~2μm;La_(2)MgTiO_(6)∶Mn^(4+)在650~750 nm的红光发射是来自Mn^(4+)的2 E 1→4 A 2跃迁,La_(2)MgTiO_(6)∶Pr^(3+)在红光区域600~660 nm具有强烈的发射,归属为Pr^(3+)的3 P 0→3 H 6和3 P 0→3 F 2跃迁。当Mn^(4+)与Pr^(3+)共同掺杂于La_(2)MgTiO_(6)时,来自Mn^(4+)、Pr^(3+)不同波段的红光发射使荧光粉的发射光谱与植物光敏色素P r与P fr吸收光谱的重叠程度大幅增加,表明Mn^(4+)、Pr^(3+)共掺有效拓宽了La_(2)MgTiO_(6)荧光粉的红光发射区域,更符合植物照明的需求,在LED植物照明领域具有更明显的潜在应用价值。展开更多
This article explores the effects of doping ferroelectric materials MgTiO_(3) with different proportions on the properties of polyaniline(PANI).PANI/MgTiO_(3) composites were prepared by in-situ composite method.Fouri...This article explores the effects of doping ferroelectric materials MgTiO_(3) with different proportions on the properties of polyaniline(PANI).PANI/MgTiO_(3) composites were prepared by in-situ composite method.Fourier transform infrared spectroscopy(FTIR)and X-ray diffraction(XRD)were used to characterize the structure of the composites.Scanning electron microscope(SEM)was used to characterize the morphology of the composites.The thermal stability of the composites was investigated by thermogravimetry(TG)and derivative thermogravimetry(DTG).Electrochemical methods(cyclic voltammetry(CV),electrochemical impedance spectroscopy(EIS),and constant current charge-discharge test)were used to compare and analyze the electrochemical performance of the composites.TG-DTG analysis and electrochemical experiments all show that the thermal stability and electrochemical properties of the PANI/MgTiO_(3) composite with a mass ratio of 82/18(w/w)are the best.The results indicate that there is a synergistic effect between PANI and MgTiO_(3),which improves the performances of the PANI when the appropriate amount of MgTiO_(3) is added.展开更多
Hydroxyapatite-magnesium titanate composite nanopowders have been developed using a mechanothermal process.Thermal treatment of the milled powders at 700℃resulted in the formation of HAp/MgTiO_(3)-MgO nanocomposite.X...Hydroxyapatite-magnesium titanate composite nanopowders have been developed using a mechanothermal process.Thermal treatment of the milled powders at 700℃resulted in the formation of HAp/MgTiO_(3)-MgO nanocomposite.X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),and energy dispersive X-ray spectroscopy(EDX)techniques were utilized to characterize the synthesized powders.The results revealed that the dominant phases after mechanical activation were hydroxyapatite,anatase(TiO_(2))and periclase(MgO);while after thermal annealing process at 700℃,hydroxyapatite along with geikielite(MgTiO_(3))and periclase(MgO)were the major phases.Based on the XRD analysis,the evaluation of structural features of the samples indicated that the average crystallite sizes of hydroxyapatite after 10 h of milling and subsequent thermal treatment at 700℃were about 21 nm and 34 nm,respectively.Microscopic observations illustrated that the synthesized powders contained large agglomerates which consisted of significantly finer particles with spheroidal morphology.It is concluded that the mechanothermal method can be used to produce hydroxyapatite-based nanocomposite with appropriate structural and morphological features.展开更多
文摘采用溶胶-凝胶法制备出Y_(2-2 x)MgTiO_(6)∶2 x Eu^(3+)(YMT∶2 x Eu^(3+),0≤x≤0.11)新型红色荧光粉。通过X射线衍射仪(XRD)检测样品的纯度,结果显示YMT∶Eu^(3+)样品属于单斜晶系,空间群为P21/n,无其他杂相。扫描电子显微镜(SEM)照片显示荧光粉为2μm的不规则颗粒。当激发波长为264 nm时,发射光谱出现四个尖锐的发射峰,分别位于591(^(5)D_(0)→^(7)F_(1))、619(^(5)D_(0)→^(7)F_(2))、657(^(5)D_(0)→^(7)F_(3))和693 nm(^(5)D_(0)→^(7)F_(4))。Eu^(3+)离子之间能量传递为电偶极子-电偶极子(d-d)相互作用。YMT∶0.14Eu^(3+)荧光粉的CIE色度坐标为(0.645,0.332),与红光标准色坐标(0.67,0.33)非常接近。变温PL光谱及热激活能计算结果显示荧光粉具有一定的热稳定性,因此YMT∶Eu^(3+)是一种具有潜在应用价值的LED红色荧光粉。
文摘采用高温固相法合成了La_(2)MgTiO_(6)∶Mn^(4+)、La_(2)MgTiO_(6)∶Pr^(3+)、La_(2)MgTiO_(6)∶Pr^(3+),Mn^(4+)单掺杂和双掺杂荧光粉,并通过X射线衍射、扫描电镜、荧光光谱等测试方法对荧光粉的物相结构、形貌和发光特性进行了表征及分析。结果表明:成功合成了La_(2)MgTiO_(6)∶Mn^(4+)、La_(2)MgTiO_(6)∶Pr^(3+)、La_(2)MgTiO_(6)∶Pr^(3+),Mn^(4+)荧光粉且均为纯相;样品的粒径为1~2μm;La_(2)MgTiO_(6)∶Mn^(4+)在650~750 nm的红光发射是来自Mn^(4+)的2 E 1→4 A 2跃迁,La_(2)MgTiO_(6)∶Pr^(3+)在红光区域600~660 nm具有强烈的发射,归属为Pr^(3+)的3 P 0→3 H 6和3 P 0→3 F 2跃迁。当Mn^(4+)与Pr^(3+)共同掺杂于La_(2)MgTiO_(6)时,来自Mn^(4+)、Pr^(3+)不同波段的红光发射使荧光粉的发射光谱与植物光敏色素P r与P fr吸收光谱的重叠程度大幅增加,表明Mn^(4+)、Pr^(3+)共掺有效拓宽了La_(2)MgTiO_(6)荧光粉的红光发射区域,更符合植物照明的需求,在LED植物照明领域具有更明显的潜在应用价值。
基金Funded by the Natural Science Foundation of Liaoning Province(No.20180550736)Research Foundation of Educational Committee of Liaoning Province(No.JDL2019004)Guangxi Key Laboratory of Information Materials(Guilin University of Electronic Technology)(No.191008-K)。
文摘This article explores the effects of doping ferroelectric materials MgTiO_(3) with different proportions on the properties of polyaniline(PANI).PANI/MgTiO_(3) composites were prepared by in-situ composite method.Fourier transform infrared spectroscopy(FTIR)and X-ray diffraction(XRD)were used to characterize the structure of the composites.Scanning electron microscope(SEM)was used to characterize the morphology of the composites.The thermal stability of the composites was investigated by thermogravimetry(TG)and derivative thermogravimetry(DTG).Electrochemical methods(cyclic voltammetry(CV),electrochemical impedance spectroscopy(EIS),and constant current charge-discharge test)were used to compare and analyze the electrochemical performance of the composites.TG-DTG analysis and electrochemical experiments all show that the thermal stability and electrochemical properties of the PANI/MgTiO_(3) composite with a mass ratio of 82/18(w/w)are the best.The results indicate that there is a synergistic effect between PANI and MgTiO_(3),which improves the performances of the PANI when the appropriate amount of MgTiO_(3) is added.
基金research affairs of Islamic Azad University,Najafabad Branch,for supporting this research.
文摘Hydroxyapatite-magnesium titanate composite nanopowders have been developed using a mechanothermal process.Thermal treatment of the milled powders at 700℃resulted in the formation of HAp/MgTiO_(3)-MgO nanocomposite.X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),and energy dispersive X-ray spectroscopy(EDX)techniques were utilized to characterize the synthesized powders.The results revealed that the dominant phases after mechanical activation were hydroxyapatite,anatase(TiO_(2))and periclase(MgO);while after thermal annealing process at 700℃,hydroxyapatite along with geikielite(MgTiO_(3))and periclase(MgO)were the major phases.Based on the XRD analysis,the evaluation of structural features of the samples indicated that the average crystallite sizes of hydroxyapatite after 10 h of milling and subsequent thermal treatment at 700℃were about 21 nm and 34 nm,respectively.Microscopic observations illustrated that the synthesized powders contained large agglomerates which consisted of significantly finer particles with spheroidal morphology.It is concluded that the mechanothermal method can be used to produce hydroxyapatite-based nanocomposite with appropriate structural and morphological features.
